Stajčić, Aleksandar

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248a7350-c600-41a3-b827-6334f304b050
  • Stajčić, Aleksandar (11)
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Author's Bibliography

Influence of Novel SrTiO3/MnO2 Hybrid Nanoparticles on Poly(methyl methacrylate) Thermal and Mechanical Behavior

Elhmali, Houda Taher; Stajčić, Ivana; Stajčić, Aleksandar; Pešić, Ivan; Jovanović, Marija; Petrović, Miloš; Radojević, Vesna

(2024)

TY  - JOUR
AU  - Elhmali, Houda Taher
AU  - Stajčić, Ivana
AU  - Stajčić, Aleksandar
AU  - Pešić, Ivan
AU  - Jovanović, Marija
AU  - Petrović, Miloš
AU  - Radojević, Vesna
PY  - 2024
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/12718
AB  - While dental poly methyl methacrylate(PMMA) possesses distinctive qualities such as ease of fabrication, cost-effectiveness, and favorable physical and mechanical properties, these attributes alone are inadequate to impart the necessary impact strength and hardness. Consequently, pure PMMA is less suitable for dental applications. This research focused on the incorporation of Strontium titanate (SrTiO3-STO) and hybrid filler STO/Manganese oxide (MnO2) to improve impact resistance and hardness. The potential of STO in reinforcing PMMA is poorly investigated, while hybrid filler STO/MnO2 has not been presented yet. Differential scanning calorimetry is conducted in order to investigate the agglomeration influence on the PMMA glass transition temperature (Tg), as well as the leaching of residual monomer and volatile additives that could pose a threat to human health. It has been determined that agglomeration with 1 wt% loading had no influence on Tg, while the first scan revealed differences in evaporation of small molecules, in favor of composite PMMA-STO/MnO2, which showed the trapping potential of volatiles. Investigations of mechanical properties have revealed the significant influence of hybrid STO/MnO2 filler on microhardness and total absorbed impact energy, which were increased by 89.9% and 145.4%, respectively. Results presented in this study revealed the reinforcing potential of hybrid nanoparticles that could find application in other polymers as well.
T2  - Polymers
T1  - Influence of Novel SrTiO3/MnO2 Hybrid Nanoparticles on Poly(methyl methacrylate) Thermal and Mechanical Behavior
VL  - 16
IS  - 2
SP  - 278
DO  - 10.3390/polym16020278
ER  - 
@article{
author = "Elhmali, Houda Taher and Stajčić, Ivana and Stajčić, Aleksandar and Pešić, Ivan and Jovanović, Marija and Petrović, Miloš and Radojević, Vesna",
year = "2024",
abstract = "While dental poly methyl methacrylate(PMMA) possesses distinctive qualities such as ease of fabrication, cost-effectiveness, and favorable physical and mechanical properties, these attributes alone are inadequate to impart the necessary impact strength and hardness. Consequently, pure PMMA is less suitable for dental applications. This research focused on the incorporation of Strontium titanate (SrTiO3-STO) and hybrid filler STO/Manganese oxide (MnO2) to improve impact resistance and hardness. The potential of STO in reinforcing PMMA is poorly investigated, while hybrid filler STO/MnO2 has not been presented yet. Differential scanning calorimetry is conducted in order to investigate the agglomeration influence on the PMMA glass transition temperature (Tg), as well as the leaching of residual monomer and volatile additives that could pose a threat to human health. It has been determined that agglomeration with 1 wt% loading had no influence on Tg, while the first scan revealed differences in evaporation of small molecules, in favor of composite PMMA-STO/MnO2, which showed the trapping potential of volatiles. Investigations of mechanical properties have revealed the significant influence of hybrid STO/MnO2 filler on microhardness and total absorbed impact energy, which were increased by 89.9% and 145.4%, respectively. Results presented in this study revealed the reinforcing potential of hybrid nanoparticles that could find application in other polymers as well.",
journal = "Polymers",
title = "Influence of Novel SrTiO3/MnO2 Hybrid Nanoparticles on Poly(methyl methacrylate) Thermal and Mechanical Behavior",
volume = "16",
number = "2",
pages = "278",
doi = "10.3390/polym16020278"
}
Elhmali, H. T., Stajčić, I., Stajčić, A., Pešić, I., Jovanović, M., Petrović, M.,& Radojević, V.. (2024). Influence of Novel SrTiO3/MnO2 Hybrid Nanoparticles on Poly(methyl methacrylate) Thermal and Mechanical Behavior. in Polymers, 16(2), 278.
https://doi.org/10.3390/polym16020278
Elhmali HT, Stajčić I, Stajčić A, Pešić I, Jovanović M, Petrović M, Radojević V. Influence of Novel SrTiO3/MnO2 Hybrid Nanoparticles on Poly(methyl methacrylate) Thermal and Mechanical Behavior. in Polymers. 2024;16(2):278.
doi:10.3390/polym16020278 .
Elhmali, Houda Taher, Stajčić, Ivana, Stajčić, Aleksandar, Pešić, Ivan, Jovanović, Marija, Petrović, Miloš, Radojević, Vesna, "Influence of Novel SrTiO3/MnO2 Hybrid Nanoparticles on Poly(methyl methacrylate) Thermal and Mechanical Behavior" in Polymers, 16, no. 2 (2024):278,
https://doi.org/10.3390/polym16020278 . .

Structural and Morphological Characterization of Strontium Ferrite-Ethylcellulose Nanocomposite for Application in Membrane Technology

Stajčić, Aleksandar; Radović, Ivana M.

(2023)

TY  - CHAP
AU  - Stajčić, Aleksandar
AU  - Radović, Ivana M.
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10591
AB  - Among many possible fields of application, membrane technology is very valuable for biological and medical purposes. As a young field with high potential for further expansion, it is of great interest for researches. This chapter presents preparation and characterization of magnetic nanocomposite membranes. Ethylcellulose-strontium ferrite (EC-SrFe12O19) nanocomposites were prepared via solvent casting method with applied low magnetic field. In order to identify morphological and topological changes induced by membrane processing, scanning electron microscopy (FESEM) and atomic force microscopy (AFM) were performed. Orientation of nanoparticles and formation of two-phase structure caused by the influence of magnetic field were observed. Infrared spectroscopy with Fourier transformation (FTIR) was used to prove the stability of starting components during processing of nanocomposite membrane. Nanoparticles’ high reinforcing potential was proved by micro Vickers method and tensile test. Modulus of elasticity in EC-SrFe12O19 samples has increased up to 135%, compared to pure EC. The permeability of magnetic nanocomposite membranes was tested by monitoring the output pressure change of the nitrogen/oxygen mixtures, as well as pure nitrogen, using custom-made laboratory device. This technique also enabled investigation of membranes’ mechanical performance by following changes in permeability with the pressure for each sample. Orientation of magnetic SrFe12O19 nanoparticles led to a formation of highly reinforced membranes that have potential application in membrane technology.
T2  - Bioceramics, Biomimetic and Other Compatible Materials Features for Medical Applications
T1  - Structural and Morphological Characterization of Strontium Ferrite-Ethylcellulose Nanocomposite for Application in Membrane Technology
SP  - 231
EP  - 251
DO  - 10.1007/978-3-031-17269-4_12
ER  - 
@inbook{
author = "Stajčić, Aleksandar and Radović, Ivana M.",
year = "2023",
abstract = "Among many possible fields of application, membrane technology is very valuable for biological and medical purposes. As a young field with high potential for further expansion, it is of great interest for researches. This chapter presents preparation and characterization of magnetic nanocomposite membranes. Ethylcellulose-strontium ferrite (EC-SrFe12O19) nanocomposites were prepared via solvent casting method with applied low magnetic field. In order to identify morphological and topological changes induced by membrane processing, scanning electron microscopy (FESEM) and atomic force microscopy (AFM) were performed. Orientation of nanoparticles and formation of two-phase structure caused by the influence of magnetic field were observed. Infrared spectroscopy with Fourier transformation (FTIR) was used to prove the stability of starting components during processing of nanocomposite membrane. Nanoparticles’ high reinforcing potential was proved by micro Vickers method and tensile test. Modulus of elasticity in EC-SrFe12O19 samples has increased up to 135%, compared to pure EC. The permeability of magnetic nanocomposite membranes was tested by monitoring the output pressure change of the nitrogen/oxygen mixtures, as well as pure nitrogen, using custom-made laboratory device. This technique also enabled investigation of membranes’ mechanical performance by following changes in permeability with the pressure for each sample. Orientation of magnetic SrFe12O19 nanoparticles led to a formation of highly reinforced membranes that have potential application in membrane technology.",
journal = "Bioceramics, Biomimetic and Other Compatible Materials Features for Medical Applications",
booktitle = "Structural and Morphological Characterization of Strontium Ferrite-Ethylcellulose Nanocomposite for Application in Membrane Technology",
pages = "231-251",
doi = "10.1007/978-3-031-17269-4_12"
}
Stajčić, A.,& Radović, I. M.. (2023). Structural and Morphological Characterization of Strontium Ferrite-Ethylcellulose Nanocomposite for Application in Membrane Technology. in Bioceramics, Biomimetic and Other Compatible Materials Features for Medical Applications, 231-251.
https://doi.org/10.1007/978-3-031-17269-4_12
Stajčić A, Radović IM. Structural and Morphological Characterization of Strontium Ferrite-Ethylcellulose Nanocomposite for Application in Membrane Technology. in Bioceramics, Biomimetic and Other Compatible Materials Features for Medical Applications. 2023;:231-251.
doi:10.1007/978-3-031-17269-4_12 .
Stajčić, Aleksandar, Radović, Ivana M., "Structural and Morphological Characterization of Strontium Ferrite-Ethylcellulose Nanocomposite for Application in Membrane Technology" in Bioceramics, Biomimetic and Other Compatible Materials Features for Medical Applications (2023):231-251,
https://doi.org/10.1007/978-3-031-17269-4_12 . .

Impact- and Thermal-Resistant Epoxy Resin Toughened with Acacia Honey

Stajčić, Ivana; Veljković, Filip; Petrović, Miloš; Veličković, Suzana; Radojević, Vesna; Vlahović, Branislav; Stajčić, Aleksandar

(2023)

TY  - JOUR
AU  - Stajčić, Ivana
AU  - Veljković, Filip
AU  - Petrović, Miloš
AU  - Veličković, Suzana
AU  - Radojević, Vesna
AU  - Vlahović, Branislav
AU  - Stajčić, Aleksandar
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/11093
AB  - High performance polymers with bio-based modifiers are promising materials in terms of applications and environmental impact. In this work, raw acacia honey was used as a bio-modifier for epoxy resin, as a rich source of functional groups. The addition of honey resulted in the formation of highly stable structures that were observed in scanning electron microscopy images as separate phases at the fracture surface, which were involved in the toughening of the resin. Structural changes were investigated, revealing the formation of a new aldehyde carbonyl group. Thermal analysis confirmed the formation of products that were stable up to 600 °C, with a glass transition temperature of 228 °C. An energy-controlled impact test was performed to compare the absorbed impact energy of bio-modified epoxy containing different amounts of honey with unmodified epoxy resin. The results showed that bio-modified epoxy resin with 3 wt% of acacia honey could withstand several impacts with full recovery, while unmodified epoxy resin broke at first impact. The absorbed energy at first impact was 2.5 times higher for bio-modified epoxy resin than it was for unmodified epoxy resin. In this manner, by using simple preparation and a raw material that is abundant in nature, a novel epoxy with high thermal and impact resistance was obtained, opening a path for further research in this field.
T2  - Polymers
T1  - Impact- and Thermal-Resistant Epoxy Resin Toughened with Acacia Honey
VL  - 15
IS  - 10
SP  - 2261
DO  - 10.3390/polym15102261
ER  - 
@article{
author = "Stajčić, Ivana and Veljković, Filip and Petrović, Miloš and Veličković, Suzana and Radojević, Vesna and Vlahović, Branislav and Stajčić, Aleksandar",
year = "2023",
abstract = "High performance polymers with bio-based modifiers are promising materials in terms of applications and environmental impact. In this work, raw acacia honey was used as a bio-modifier for epoxy resin, as a rich source of functional groups. The addition of honey resulted in the formation of highly stable structures that were observed in scanning electron microscopy images as separate phases at the fracture surface, which were involved in the toughening of the resin. Structural changes were investigated, revealing the formation of a new aldehyde carbonyl group. Thermal analysis confirmed the formation of products that were stable up to 600 °C, with a glass transition temperature of 228 °C. An energy-controlled impact test was performed to compare the absorbed impact energy of bio-modified epoxy containing different amounts of honey with unmodified epoxy resin. The results showed that bio-modified epoxy resin with 3 wt% of acacia honey could withstand several impacts with full recovery, while unmodified epoxy resin broke at first impact. The absorbed energy at first impact was 2.5 times higher for bio-modified epoxy resin than it was for unmodified epoxy resin. In this manner, by using simple preparation and a raw material that is abundant in nature, a novel epoxy with high thermal and impact resistance was obtained, opening a path for further research in this field.",
journal = "Polymers",
title = "Impact- and Thermal-Resistant Epoxy Resin Toughened with Acacia Honey",
volume = "15",
number = "10",
pages = "2261",
doi = "10.3390/polym15102261"
}
Stajčić, I., Veljković, F., Petrović, M., Veličković, S., Radojević, V., Vlahović, B.,& Stajčić, A.. (2023). Impact- and Thermal-Resistant Epoxy Resin Toughened with Acacia Honey. in Polymers, 15(10), 2261.
https://doi.org/10.3390/polym15102261
Stajčić I, Veljković F, Petrović M, Veličković S, Radojević V, Vlahović B, Stajčić A. Impact- and Thermal-Resistant Epoxy Resin Toughened with Acacia Honey. in Polymers. 2023;15(10):2261.
doi:10.3390/polym15102261 .
Stajčić, Ivana, Veljković, Filip, Petrović, Miloš, Veličković, Suzana, Radojević, Vesna, Vlahović, Branislav, Stajčić, Aleksandar, "Impact- and Thermal-Resistant Epoxy Resin Toughened with Acacia Honey" in Polymers, 15, no. 10 (2023):2261,
https://doi.org/10.3390/polym15102261 . .
2
1

Fractal reconstruction of fiber-reinforced polymer composites

Radović, Ivana M.; Mitić, Vojislav V.; Stajčić, Aleksandar; Serpa, Cristina; Ribar, Srđan; Ranđelović, Branislav; Vlahović, Branislav

(Belgrade : Serbian Ceramic Society, 2021)

TY  - CONF
AU  - Radović, Ivana M.
AU  - Mitić, Vojislav V.
AU  - Stajčić, Aleksandar
AU  - Serpa, Cristina
AU  - Ribar, Srđan
AU  - Ranđelović, Branislav
AU  - Vlahović, Branislav
PY  - 2021
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10787
AB  - Polymers offer the possibility of different reinforcement incorporation due to a broad range of chemical structures.Along with this feature, their light weight and processing ease made them a class of materials that have been applied in construction parts, drug delivery agents or electronic devices. Epoxy-based composites have used as insulators in microelectronic devices due to its chemical resistance, good adhesion properties and endurance. As epoxies have low fracture resistance, they are often reinforced with different kinds of fibers.With thorough knowledge of the structure, physical properties can be predicted and included in the processing of future composites, especially that electronic materials minituarization brought micro- and nanoscale level properties at spotlight. Fractal nature analysis is a mathematical method that has proved to be efficient in grain interface properties applied on perovskite ceramic materials.In our study, fiber shape reconstruction and determination of Hausdorff dimension have been achieved with the application of fractal regression model employed in software Fractal Real Finder opening a new path for the prediction of reinforcement shape and size, all with the aim of processing composite materials with desired properties.
PB  - Belgrade : Serbian Ceramic Society
C3  - Advanced Ceramics and Application : 9th Serbian Ceramic Society Conference : program and the book of abstracts; September 20-21, 2021; Belgrade
T1  - Fractal reconstruction of fiber-reinforced polymer composites
SP  - 49
UR  - https://hdl.handle.net/21.15107/rcub_vinar_10787
ER  - 
@conference{
author = "Radović, Ivana M. and Mitić, Vojislav V. and Stajčić, Aleksandar and Serpa, Cristina and Ribar, Srđan and Ranđelović, Branislav and Vlahović, Branislav",
year = "2021",
abstract = "Polymers offer the possibility of different reinforcement incorporation due to a broad range of chemical structures.Along with this feature, their light weight and processing ease made them a class of materials that have been applied in construction parts, drug delivery agents or electronic devices. Epoxy-based composites have used as insulators in microelectronic devices due to its chemical resistance, good adhesion properties and endurance. As epoxies have low fracture resistance, they are often reinforced with different kinds of fibers.With thorough knowledge of the structure, physical properties can be predicted and included in the processing of future composites, especially that electronic materials minituarization brought micro- and nanoscale level properties at spotlight. Fractal nature analysis is a mathematical method that has proved to be efficient in grain interface properties applied on perovskite ceramic materials.In our study, fiber shape reconstruction and determination of Hausdorff dimension have been achieved with the application of fractal regression model employed in software Fractal Real Finder opening a new path for the prediction of reinforcement shape and size, all with the aim of processing composite materials with desired properties.",
publisher = "Belgrade : Serbian Ceramic Society",
journal = "Advanced Ceramics and Application : 9th Serbian Ceramic Society Conference : program and the book of abstracts; September 20-21, 2021; Belgrade",
title = "Fractal reconstruction of fiber-reinforced polymer composites",
pages = "49",
url = "https://hdl.handle.net/21.15107/rcub_vinar_10787"
}
Radović, I. M., Mitić, V. V., Stajčić, A., Serpa, C., Ribar, S., Ranđelović, B.,& Vlahović, B.. (2021). Fractal reconstruction of fiber-reinforced polymer composites. in Advanced Ceramics and Application : 9th Serbian Ceramic Society Conference : program and the book of abstracts; September 20-21, 2021; Belgrade
Belgrade : Serbian Ceramic Society., 49.
https://hdl.handle.net/21.15107/rcub_vinar_10787
Radović IM, Mitić VV, Stajčić A, Serpa C, Ribar S, Ranđelović B, Vlahović B. Fractal reconstruction of fiber-reinforced polymer composites. in Advanced Ceramics and Application : 9th Serbian Ceramic Society Conference : program and the book of abstracts; September 20-21, 2021; Belgrade. 2021;:49.
https://hdl.handle.net/21.15107/rcub_vinar_10787 .
Radović, Ivana M., Mitić, Vojislav V., Stajčić, Aleksandar, Serpa, Cristina, Ribar, Srđan, Ranđelović, Branislav, Vlahović, Branislav, "Fractal reconstruction of fiber-reinforced polymer composites" in Advanced Ceramics and Application : 9th Serbian Ceramic Society Conference : program and the book of abstracts; September 20-21, 2021; Belgrade (2021):49,
https://hdl.handle.net/21.15107/rcub_vinar_10787 .

The Nano-Scale Modified BaTiO3 Morphology Influence on Electronic Properties and Ceramics Fractal Nature Frontiers

Mitić, Vojislav V.; Lazović, Goran; Lu, Chun-An; Paunović, Vesna; Radović, Ivana M.; Stajčić, Aleksandar; Vlahović, Branislav

(2020)

TY  - JOUR
AU  - Mitić, Vojislav V.
AU  - Lazović, Goran
AU  - Lu, Chun-An
AU  - Paunović, Vesna
AU  - Radović, Ivana M.
AU  - Stajčić, Aleksandar
AU  - Vlahović, Branislav
PY  - 2020
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/9010
AB  - The BaTiO3 ceramics applications based on electronic properties have very high gradient scientific and industrial-technological interests. Our scientific research has been based on nano BaTiO3 modified with Yttrium based organometallic salt (MOD-Y). The samples have been consolidated at a sintering temperature of 1350 °C. Within the study, the new frontiers for different electronic properties between the layers of BaTiO3 grains have been introduced. The research target was grain boundary investigations and the influence on dielectric properties. After scanning electron microscopy and dielectric measurements, it has been established that modified BaTiO3 samples with larger grains showed a better compact state that led to a higher dielectric constant value. DC bias stability was also investigated and showed a connection between the grain size and capacitance stability. Analyses of functions that could approximate experimental curves were successfully employed. Practical application of fractal corrections was performed, based on surface (αs) and pore size (αp) corrections, which resulted in obtainment of the relation between the capacitance and Curie temperature. Successful introduction of fractal corrections for capacitance-Curie temperature dependence for a set of experimental data is an important step towards further miniaturization of intergranular capacitors. © 2020 by the authors.
T2  - Applied Sciences
T1  - The Nano-Scale Modified BaTiO3 Morphology Influence on Electronic Properties and Ceramics Fractal Nature Frontiers
VL  - 10
IS  - 10
SP  - 3485
DO  - 10.3390/app10103485
ER  - 
@article{
author = "Mitić, Vojislav V. and Lazović, Goran and Lu, Chun-An and Paunović, Vesna and Radović, Ivana M. and Stajčić, Aleksandar and Vlahović, Branislav",
year = "2020",
abstract = "The BaTiO3 ceramics applications based on electronic properties have very high gradient scientific and industrial-technological interests. Our scientific research has been based on nano BaTiO3 modified with Yttrium based organometallic salt (MOD-Y). The samples have been consolidated at a sintering temperature of 1350 °C. Within the study, the new frontiers for different electronic properties between the layers of BaTiO3 grains have been introduced. The research target was grain boundary investigations and the influence on dielectric properties. After scanning electron microscopy and dielectric measurements, it has been established that modified BaTiO3 samples with larger grains showed a better compact state that led to a higher dielectric constant value. DC bias stability was also investigated and showed a connection between the grain size and capacitance stability. Analyses of functions that could approximate experimental curves were successfully employed. Practical application of fractal corrections was performed, based on surface (αs) and pore size (αp) corrections, which resulted in obtainment of the relation between the capacitance and Curie temperature. Successful introduction of fractal corrections for capacitance-Curie temperature dependence for a set of experimental data is an important step towards further miniaturization of intergranular capacitors. © 2020 by the authors.",
journal = "Applied Sciences",
title = "The Nano-Scale Modified BaTiO3 Morphology Influence on Electronic Properties and Ceramics Fractal Nature Frontiers",
volume = "10",
number = "10",
pages = "3485",
doi = "10.3390/app10103485"
}
Mitić, V. V., Lazović, G., Lu, C., Paunović, V., Radović, I. M., Stajčić, A.,& Vlahović, B.. (2020). The Nano-Scale Modified BaTiO3 Morphology Influence on Electronic Properties and Ceramics Fractal Nature Frontiers. in Applied Sciences, 10(10), 3485.
https://doi.org/10.3390/app10103485
Mitić VV, Lazović G, Lu C, Paunović V, Radović IM, Stajčić A, Vlahović B. The Nano-Scale Modified BaTiO3 Morphology Influence on Electronic Properties and Ceramics Fractal Nature Frontiers. in Applied Sciences. 2020;10(10):3485.
doi:10.3390/app10103485 .
Mitić, Vojislav V., Lazović, Goran, Lu, Chun-An, Paunović, Vesna, Radović, Ivana M., Stajčić, Aleksandar, Vlahović, Branislav, "The Nano-Scale Modified BaTiO3 Morphology Influence on Electronic Properties and Ceramics Fractal Nature Frontiers" in Applied Sciences, 10, no. 10 (2020):3485,
https://doi.org/10.3390/app10103485 . .
4
1
4

Solvent effects on structural changes in self-healing epoxy composites

Radović, Ivana M.; Stajčić, Aleksandar; Radisavljević, Anđela; Veljković, Filip M.; Čebela, Maria; Mitić, Vojislav V.; Radojević, Vesna

(2020)

TY  - JOUR
AU  - Radović, Ivana M.
AU  - Stajčić, Aleksandar
AU  - Radisavljević, Anđela
AU  - Veljković, Filip M.
AU  - Čebela, Maria
AU  - Mitić, Vojislav V.
AU  - Radojević, Vesna
PY  - 2020
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/9609
AB  - Nowadays, there is a very high importance of composite research and variety of their applications in the modern world. In that sense, we researched hollow glass capillaries filled with dissolved Grubbs catalyst (GC) and dicyclopentadiene (DCPD) were incorporated into a fiber-reinforced epoxy with the aim of improving the flow of healing agents to the crack site. The morphological investigation of the crack site was performed using field emission scanning electron microscopy (FESEM), showing the difference between the samples depending on the used solvent. The software analysis of sample photographs has been performed by calculating the fractured/healed surface area of the samples, revealing that approximately 20% of the volume was affected by the impact. Fourier transform infrared spectroscopy (FTIR) revealed that poly (dicyclopentadiene) (PDCPD) formed at the healed interface. However, the FTIR investigation of catalyst stability in different solvents showed structural changes in GC and partial deactivation. The mechanical tests of the samples showed that a recovery of 60% after 24 h at room temperature could be achieved through the use of a solvent and very low concentration of GC. The performed research results are a good base to develop the model for predicting the processes and morphology, with the goal to design the final mechanical and in the future, thermal, properties in advance. This opens a new direction for future research in the field of composite healing. © 2020 Elsevier B.V.
T2  - Materials Chemistry and Physics
T1  - Solvent effects on structural changes in self-healing epoxy composites
VL  - 256
DO  - 10.1016/j.matchemphys.2020.123761
ER  - 
@article{
author = "Radović, Ivana M. and Stajčić, Aleksandar and Radisavljević, Anđela and Veljković, Filip M. and Čebela, Maria and Mitić, Vojislav V. and Radojević, Vesna",
year = "2020",
abstract = "Nowadays, there is a very high importance of composite research and variety of their applications in the modern world. In that sense, we researched hollow glass capillaries filled with dissolved Grubbs catalyst (GC) and dicyclopentadiene (DCPD) were incorporated into a fiber-reinforced epoxy with the aim of improving the flow of healing agents to the crack site. The morphological investigation of the crack site was performed using field emission scanning electron microscopy (FESEM), showing the difference between the samples depending on the used solvent. The software analysis of sample photographs has been performed by calculating the fractured/healed surface area of the samples, revealing that approximately 20% of the volume was affected by the impact. Fourier transform infrared spectroscopy (FTIR) revealed that poly (dicyclopentadiene) (PDCPD) formed at the healed interface. However, the FTIR investigation of catalyst stability in different solvents showed structural changes in GC and partial deactivation. The mechanical tests of the samples showed that a recovery of 60% after 24 h at room temperature could be achieved through the use of a solvent and very low concentration of GC. The performed research results are a good base to develop the model for predicting the processes and morphology, with the goal to design the final mechanical and in the future, thermal, properties in advance. This opens a new direction for future research in the field of composite healing. © 2020 Elsevier B.V.",
journal = "Materials Chemistry and Physics",
title = "Solvent effects on structural changes in self-healing epoxy composites",
volume = "256",
doi = "10.1016/j.matchemphys.2020.123761"
}
Radović, I. M., Stajčić, A., Radisavljević, A., Veljković, F. M., Čebela, M., Mitić, V. V.,& Radojević, V.. (2020). Solvent effects on structural changes in self-healing epoxy composites. in Materials Chemistry and Physics, 256.
https://doi.org/10.1016/j.matchemphys.2020.123761
Radović IM, Stajčić A, Radisavljević A, Veljković FM, Čebela M, Mitić VV, Radojević V. Solvent effects on structural changes in self-healing epoxy composites. in Materials Chemistry and Physics. 2020;256.
doi:10.1016/j.matchemphys.2020.123761 .
Radović, Ivana M., Stajčić, Aleksandar, Radisavljević, Anđela, Veljković, Filip M., Čebela, Maria, Mitić, Vojislav V., Radojević, Vesna, "Solvent effects on structural changes in self-healing epoxy composites" in Materials Chemistry and Physics, 256 (2020),
https://doi.org/10.1016/j.matchemphys.2020.123761 . .
15
2
14

The Artificial Neural Networks Applied for Microelectronics Intergranular Relations Determination

Mitić, Vojislav V.; Lazović, Goran; Ribar, Srđan; Lu, Chun-An; Radović, Ivana M.; Stajčić, Aleksandar; Fecht, Hans; Vlahović, Branislav

(2020)

TY  - JOUR
AU  - Mitić, Vojislav V.
AU  - Lazović, Goran
AU  - Ribar, Srđan
AU  - Lu, Chun-An
AU  - Radović, Ivana M.
AU  - Stajčić, Aleksandar
AU  - Fecht, Hans
AU  - Vlahović, Branislav
PY  - 2020
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/9728
AB  - This paper is based on fundamental research to develop the interface structure around the grains and to control the layers between two grains, as a prospective media for high-level electronic parameters integrations. We performed the experiments based on nano-BaTiO3 powders with Y additives. All results on dielectric parameters on submicron level are the part of global values the same measured characteristics at the bulk samples. The original idea is to develop the new computing ways to network electronic parameters in thin layers between the grains on the way to get and to compare the values on the samples. Artificial neural networks are computing tools that map input-output data and could be applied on ceramic electronic parameters. These are developed in the manner signals are processed in biological neural networks. The signals are processed by using elements which represent artificial neurons, which have a simple function to process input signal, as well as adjustable parameter which has an influence to change output signal. The total network output presents the sum of a large number neurons outputs. This important research idea is to connect analysis results and neural networks. There is a great interest to connect all of these microcapacitances by neural network with the goal to compare the results in the standard bulk samples measurements frame and microelectronics parameters. The final result of the study was functional relation definition between consolidation parameters, voltage (U) and relative capacitance change, from the level of the bulk sample down to the grains boundaries.
T2  - Integrated Ferroelectrics
T1  - The Artificial Neural Networks Applied for Microelectronics Intergranular Relations Determination
VL  - 212
IS  - 1
SP  - 135
EP  - 146
DO  - 10.1080/10584587.2020.1819042
ER  - 
@article{
author = "Mitić, Vojislav V. and Lazović, Goran and Ribar, Srđan and Lu, Chun-An and Radović, Ivana M. and Stajčić, Aleksandar and Fecht, Hans and Vlahović, Branislav",
year = "2020",
abstract = "This paper is based on fundamental research to develop the interface structure around the grains and to control the layers between two grains, as a prospective media for high-level electronic parameters integrations. We performed the experiments based on nano-BaTiO3 powders with Y additives. All results on dielectric parameters on submicron level are the part of global values the same measured characteristics at the bulk samples. The original idea is to develop the new computing ways to network electronic parameters in thin layers between the grains on the way to get and to compare the values on the samples. Artificial neural networks are computing tools that map input-output data and could be applied on ceramic electronic parameters. These are developed in the manner signals are processed in biological neural networks. The signals are processed by using elements which represent artificial neurons, which have a simple function to process input signal, as well as adjustable parameter which has an influence to change output signal. The total network output presents the sum of a large number neurons outputs. This important research idea is to connect analysis results and neural networks. There is a great interest to connect all of these microcapacitances by neural network with the goal to compare the results in the standard bulk samples measurements frame and microelectronics parameters. The final result of the study was functional relation definition between consolidation parameters, voltage (U) and relative capacitance change, from the level of the bulk sample down to the grains boundaries.",
journal = "Integrated Ferroelectrics",
title = "The Artificial Neural Networks Applied for Microelectronics Intergranular Relations Determination",
volume = "212",
number = "1",
pages = "135-146",
doi = "10.1080/10584587.2020.1819042"
}
Mitić, V. V., Lazović, G., Ribar, S., Lu, C., Radović, I. M., Stajčić, A., Fecht, H.,& Vlahović, B.. (2020). The Artificial Neural Networks Applied for Microelectronics Intergranular Relations Determination. in Integrated Ferroelectrics, 212(1), 135-146.
https://doi.org/10.1080/10584587.2020.1819042
Mitić VV, Lazović G, Ribar S, Lu C, Radović IM, Stajčić A, Fecht H, Vlahović B. The Artificial Neural Networks Applied for Microelectronics Intergranular Relations Determination. in Integrated Ferroelectrics. 2020;212(1):135-146.
doi:10.1080/10584587.2020.1819042 .
Mitić, Vojislav V., Lazović, Goran, Ribar, Srđan, Lu, Chun-An, Radović, Ivana M., Stajčić, Aleksandar, Fecht, Hans, Vlahović, Branislav, "The Artificial Neural Networks Applied for Microelectronics Intergranular Relations Determination" in Integrated Ferroelectrics, 212, no. 1 (2020):135-146,
https://doi.org/10.1080/10584587.2020.1819042 . .
11
4
10

Ceramics, materials, microelectronics and graph theory new frontiers

Ranđelović, Branislav M.; Mitić, Vojislav V.; Ribar, Srđan; Lu, Chun-An; Radović, Ivana M.; Stajčić, Aleksandar; Novaković, Igor; Vlahović, Branislav

(2020)

TY  - JOUR
AU  - Ranđelović, Branislav M.
AU  - Mitić, Vojislav V.
AU  - Ribar, Srđan
AU  - Lu, Chun-An
AU  - Radović, Ivana M.
AU  - Stajčić, Aleksandar
AU  - Novaković, Igor
AU  - Vlahović, Branislav
PY  - 2020
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/9763
AB  - This research is focused on further developing of application and use of graph theory in order to describe relations between grains and to establish control over layers. We used functionalized BaTiO3 nanoparticles coated with Yttrium-based salt. The capacitance change results on super-microstructure levels are the part of the measured values on the bulk samples. The new idea is graph theory application for determination of electronic parameters distribution at the grain boundary and to compare them with the bulk measured values. We present them with vertices in graph, corresponding with grains, connected with edges. Capacitance change with applied voltage was measured on samples sintered in air and nitrogen, up to 100 V. Using graph theory, it has been shown that capacitance change can be successfully calculated on the layers between grains. Within the idea how to get parameters values at microlevel between the grains and pores, mathematical tool can be developed. Besides previously described 1D case, some original calculations for 2D cases were performed in this study, proving successful graph theory use for the calculation of values at nanolevel, leading to a further minituarization in micropackaging.
T2  - Modern Physics Letters B
T1  - Ceramics, materials, microelectronics and graph theory new frontiers
VL  - 34
SP  - 2150159
DO  - 10.1142/S0217984921501591
ER  - 
@article{
author = "Ranđelović, Branislav M. and Mitić, Vojislav V. and Ribar, Srđan and Lu, Chun-An and Radović, Ivana M. and Stajčić, Aleksandar and Novaković, Igor and Vlahović, Branislav",
year = "2020",
abstract = "This research is focused on further developing of application and use of graph theory in order to describe relations between grains and to establish control over layers. We used functionalized BaTiO3 nanoparticles coated with Yttrium-based salt. The capacitance change results on super-microstructure levels are the part of the measured values on the bulk samples. The new idea is graph theory application for determination of electronic parameters distribution at the grain boundary and to compare them with the bulk measured values. We present them with vertices in graph, corresponding with grains, connected with edges. Capacitance change with applied voltage was measured on samples sintered in air and nitrogen, up to 100 V. Using graph theory, it has been shown that capacitance change can be successfully calculated on the layers between grains. Within the idea how to get parameters values at microlevel between the grains and pores, mathematical tool can be developed. Besides previously described 1D case, some original calculations for 2D cases were performed in this study, proving successful graph theory use for the calculation of values at nanolevel, leading to a further minituarization in micropackaging.",
journal = "Modern Physics Letters B",
title = "Ceramics, materials, microelectronics and graph theory new frontiers",
volume = "34",
pages = "2150159",
doi = "10.1142/S0217984921501591"
}
Ranđelović, B. M., Mitić, V. V., Ribar, S., Lu, C., Radović, I. M., Stajčić, A., Novaković, I.,& Vlahović, B.. (2020). Ceramics, materials, microelectronics and graph theory new frontiers. in Modern Physics Letters B, 34, 2150159.
https://doi.org/10.1142/S0217984921501591
Ranđelović BM, Mitić VV, Ribar S, Lu C, Radović IM, Stajčić A, Novaković I, Vlahović B. Ceramics, materials, microelectronics and graph theory new frontiers. in Modern Physics Letters B. 2020;34:2150159.
doi:10.1142/S0217984921501591 .
Ranđelović, Branislav M., Mitić, Vojislav V., Ribar, Srđan, Lu, Chun-An, Radović, Ivana M., Stajčić, Aleksandar, Novaković, Igor, Vlahović, Branislav, "Ceramics, materials, microelectronics and graph theory new frontiers" in Modern Physics Letters B, 34 (2020):2150159,
https://doi.org/10.1142/S0217984921501591 . .
10
5
11

The influence of barium ferrite nanoparticles on morphological and mechanical properties of ethyl cellulose based nanocomposites

Stajčić, Aleksandar; Radović, Ivana M.; Ćosović, Vladan; Grujić, Aleksandar S.; Stajić-Trošić, Jasna T.; Jančić-Heinemann, Radmila

(2019)

TY  - JOUR
AU  - Stajčić, Aleksandar
AU  - Radović, Ivana M.
AU  - Ćosović, Vladan
AU  - Grujić, Aleksandar S.
AU  - Stajić-Trošić, Jasna T.
AU  - Jančić-Heinemann, Radmila
PY  - 2019
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/8597
AB  - This study presents preparation and characterization of ethyl cellulose based nanocomposites. Successful use of simple solvent casting technique provided nanocomposites with high loads of barium ferrite magnetic nanopowder in the polymer matrix, promising significant improvement of mechanical properties. Investigation of morphology revealed formation of agglomerates that are still on nanoscopic level. Nanocomposite thin films with a higher content of the magnetic powder showed substantial enhancement of break strength, elongation and microhardness compared to the pure ethyl cellulose, which was the primary aim of this research.
T2  - Science of Sintering
T1  - The influence of barium ferrite nanoparticles on morphological and mechanical properties of ethyl cellulose based nanocomposites
VL  - 51
IS  - 3
SP  - 277
EP  - 283
DO  - 10.2298/SOS1903277S
ER  - 
@article{
author = "Stajčić, Aleksandar and Radović, Ivana M. and Ćosović, Vladan and Grujić, Aleksandar S. and Stajić-Trošić, Jasna T. and Jančić-Heinemann, Radmila",
year = "2019",
abstract = "This study presents preparation and characterization of ethyl cellulose based nanocomposites. Successful use of simple solvent casting technique provided nanocomposites with high loads of barium ferrite magnetic nanopowder in the polymer matrix, promising significant improvement of mechanical properties. Investigation of morphology revealed formation of agglomerates that are still on nanoscopic level. Nanocomposite thin films with a higher content of the magnetic powder showed substantial enhancement of break strength, elongation and microhardness compared to the pure ethyl cellulose, which was the primary aim of this research.",
journal = "Science of Sintering",
title = "The influence of barium ferrite nanoparticles on morphological and mechanical properties of ethyl cellulose based nanocomposites",
volume = "51",
number = "3",
pages = "277-283",
doi = "10.2298/SOS1903277S"
}
Stajčić, A., Radović, I. M., Ćosović, V., Grujić, A. S., Stajić-Trošić, J. T.,& Jančić-Heinemann, R.. (2019). The influence of barium ferrite nanoparticles on morphological and mechanical properties of ethyl cellulose based nanocomposites. in Science of Sintering, 51(3), 277-283.
https://doi.org/10.2298/SOS1903277S
Stajčić A, Radović IM, Ćosović V, Grujić AS, Stajić-Trošić JT, Jančić-Heinemann R. The influence of barium ferrite nanoparticles on morphological and mechanical properties of ethyl cellulose based nanocomposites. in Science of Sintering. 2019;51(3):277-283.
doi:10.2298/SOS1903277S .
Stajčić, Aleksandar, Radović, Ivana M., Ćosović, Vladan, Grujić, Aleksandar S., Stajić-Trošić, Jasna T., Jančić-Heinemann, Radmila, "The influence of barium ferrite nanoparticles on morphological and mechanical properties of ethyl cellulose based nanocomposites" in Science of Sintering, 51, no. 3 (2019):277-283,
https://doi.org/10.2298/SOS1903277S . .
2
3
4

Novel membrane-supported hydrogel for removal of heavy metals

Stajčić, Aleksandar; Nastasović, Aleksandra B.; Stajić-Trošić, Jasna T.; Marković, Jelena P.; Onjia, Antonije E.; Radovanović, Filip

(Elsevier, 2015)

TY  - JOUR
AU  - Stajčić, Aleksandar
AU  - Nastasović, Aleksandra B.
AU  - Stajić-Trošić, Jasna T.
AU  - Marković, Jelena P.
AU  - Onjia, Antonije E.
AU  - Radovanović, Filip
PY  - 2015
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/7530
AB  - Polyethersulfone membranes with integrated negatively-charged hydrogel of crosslinked poly(acrylamido-2-methylpropane sulfonic acid) were prepared by a combination of a liquid phase inversion process with photopolymerization and crosslinking of functional monomers included in the casting solution. A designed experiment was conducted to select the optimal composition for preparing membranes with a sufficient degree of swelling and ion exchange capacity. Scanning electron microscopy images revealed an ultrafine hybrid structure with an interconnected network of submicron particles embedded within the microporous polyethersulfone support. An intramembrane diffusion model was used to describe kinetics of heavy metal sorption by these hydrogels and the calculated apparent diffusion coefficients were 2–3 times larger than in commercial ion-exchange resins. Equilibrium sorption of heavy metals was described using a semi-empirical Langmuir model.
PB  - Elsevier
T2  - Journal of Environmental Chemical Engineering
T1  - Novel membrane-supported hydrogel for removal of heavy metals
VL  - 3
IS  - 1
SP  - 453
EP  - 461
DO  - 10.1016/j.jece.2015.01.005
ER  - 
@article{
author = "Stajčić, Aleksandar and Nastasović, Aleksandra B. and Stajić-Trošić, Jasna T. and Marković, Jelena P. and Onjia, Antonije E. and Radovanović, Filip",
year = "2015",
abstract = "Polyethersulfone membranes with integrated negatively-charged hydrogel of crosslinked poly(acrylamido-2-methylpropane sulfonic acid) were prepared by a combination of a liquid phase inversion process with photopolymerization and crosslinking of functional monomers included in the casting solution. A designed experiment was conducted to select the optimal composition for preparing membranes with a sufficient degree of swelling and ion exchange capacity. Scanning electron microscopy images revealed an ultrafine hybrid structure with an interconnected network of submicron particles embedded within the microporous polyethersulfone support. An intramembrane diffusion model was used to describe kinetics of heavy metal sorption by these hydrogels and the calculated apparent diffusion coefficients were 2–3 times larger than in commercial ion-exchange resins. Equilibrium sorption of heavy metals was described using a semi-empirical Langmuir model.",
publisher = "Elsevier",
journal = "Journal of Environmental Chemical Engineering",
title = "Novel membrane-supported hydrogel for removal of heavy metals",
volume = "3",
number = "1",
pages = "453-461",
doi = "10.1016/j.jece.2015.01.005"
}
Stajčić, A., Nastasović, A. B., Stajić-Trošić, J. T., Marković, J. P., Onjia, A. E.,& Radovanović, F.. (2015). Novel membrane-supported hydrogel for removal of heavy metals. in Journal of Environmental Chemical Engineering
Elsevier., 3(1), 453-461.
https://doi.org/10.1016/j.jece.2015.01.005
Stajčić A, Nastasović AB, Stajić-Trošić JT, Marković JP, Onjia AE, Radovanović F. Novel membrane-supported hydrogel for removal of heavy metals. in Journal of Environmental Chemical Engineering. 2015;3(1):453-461.
doi:10.1016/j.jece.2015.01.005 .
Stajčić, Aleksandar, Nastasović, Aleksandra B., Stajić-Trošić, Jasna T., Marković, Jelena P., Onjia, Antonije E., Radovanović, Filip, "Novel membrane-supported hydrogel for removal of heavy metals" in Journal of Environmental Chemical Engineering, 3, no. 1 (2015):453-461,
https://doi.org/10.1016/j.jece.2015.01.005 . .
13
14
17

Asymmetric hydrogel membranes for heavy metal adsorption

Stajčić, Aleksandar; Radovanović, Filip; Nastasović, Aleksandra B.; Stajić-Trošić, Jasna T.; Marković, Jelena P.; Onjia, Antonije E.

(Belgrade : Institute of Technical Sciences of SASA, 2013)

TY  - CONF
AU  - Stajčić, Aleksandar
AU  - Radovanović, Filip
AU  - Nastasović, Aleksandra B.
AU  - Stajić-Trošić, Jasna T.
AU  - Marković, Jelena P.
AU  - Onjia, Antonije E.
PY  - 2013
UR  - http://dais.sanu.ac.rs/123456789/800
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/7536
AB  - Hydrogels containing strong acid groups have been used in the past for the removal of heavy metals. Unfortunately such hydrogels exhibit poor mechanical properties and are generally difficult to handle. In this work we prepared asymmetric membranes incorporatingcross-linked 2-acrylamido-2-methyl-1-propane sulfonic acid (AMPS) hydrogel by combining photopolymerization and liquid phase inversion. An experimental design measuring water content and ion-exchange capacity of these membranes was used to select the optimal membrane composition for the removal of Pb2+, Ni2+, and Cd2+ ions from aqueous solutions. The results demonstrated fast sorption kinetics and high capacity for the investigated metals.
PB  - Belgrade : Institute of Technical Sciences of SASA
C3  - Program and the Book of Abstracts / Twelfth Young Researchers' Conference Materials Sciences and Engineering December 11-13, 2013, Belgrade, Serbia
T1  - Asymmetric hydrogel membranes for heavy metal adsorption
SP  - 40
EP  - 40
UR  - https://hdl.handle.net/21.15107/rcub_vinar_7536
ER  - 
@conference{
author = "Stajčić, Aleksandar and Radovanović, Filip and Nastasović, Aleksandra B. and Stajić-Trošić, Jasna T. and Marković, Jelena P. and Onjia, Antonije E.",
year = "2013",
abstract = "Hydrogels containing strong acid groups have been used in the past for the removal of heavy metals. Unfortunately such hydrogels exhibit poor mechanical properties and are generally difficult to handle. In this work we prepared asymmetric membranes incorporatingcross-linked 2-acrylamido-2-methyl-1-propane sulfonic acid (AMPS) hydrogel by combining photopolymerization and liquid phase inversion. An experimental design measuring water content and ion-exchange capacity of these membranes was used to select the optimal membrane composition for the removal of Pb2+, Ni2+, and Cd2+ ions from aqueous solutions. The results demonstrated fast sorption kinetics and high capacity for the investigated metals.",
publisher = "Belgrade : Institute of Technical Sciences of SASA",
journal = "Program and the Book of Abstracts / Twelfth Young Researchers' Conference Materials Sciences and Engineering December 11-13, 2013, Belgrade, Serbia",
title = "Asymmetric hydrogel membranes for heavy metal adsorption",
pages = "40-40",
url = "https://hdl.handle.net/21.15107/rcub_vinar_7536"
}
Stajčić, A., Radovanović, F., Nastasović, A. B., Stajić-Trošić, J. T., Marković, J. P.,& Onjia, A. E.. (2013). Asymmetric hydrogel membranes for heavy metal adsorption. in Program and the Book of Abstracts / Twelfth Young Researchers' Conference Materials Sciences and Engineering December 11-13, 2013, Belgrade, Serbia
Belgrade : Institute of Technical Sciences of SASA., 40-40.
https://hdl.handle.net/21.15107/rcub_vinar_7536
Stajčić A, Radovanović F, Nastasović AB, Stajić-Trošić JT, Marković JP, Onjia AE. Asymmetric hydrogel membranes for heavy metal adsorption. in Program and the Book of Abstracts / Twelfth Young Researchers' Conference Materials Sciences and Engineering December 11-13, 2013, Belgrade, Serbia. 2013;:40-40.
https://hdl.handle.net/21.15107/rcub_vinar_7536 .
Stajčić, Aleksandar, Radovanović, Filip, Nastasović, Aleksandra B., Stajić-Trošić, Jasna T., Marković, Jelena P., Onjia, Antonije E., "Asymmetric hydrogel membranes for heavy metal adsorption" in Program and the Book of Abstracts / Twelfth Young Researchers' Conference Materials Sciences and Engineering December 11-13, 2013, Belgrade, Serbia (2013):40-40,
https://hdl.handle.net/21.15107/rcub_vinar_7536 .