TY  - JOUR
AU  - Nikolić, Violeta N.
AU  - Vasić, Milica M.
AU  - Kisić, Danilo
PY  - 2019
UR  - https://linkinghub.elsevier.com/retrieve/pii/S002245961930177X
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/8160
AB  - Two samples containing 2-line ferrihydrite and copper oxide were synthesized by coprecipitation method, via variation of Fe3+ and Cu2+ precursors milimolar ratio (3:1 and 3:3.1), while the other synthesis parameters were kept constant. Annealing treatment at 1100 °C resulted in the formation of c-CuFe2O4-CuO-α-Fe2O3 and c-CuFe2O4-CuO nanocomposites, respectively. A comparison of properties of the prepared samples was performed by XRD, FTIR and EPR measurements. Formation mechanism of the nanocomposites is discussed with a reference to the influence of Jahn-Teller effect in CuO phase on the final CuFe2O4 structure. For the first time, it is shown that the amount of Fe3+ precursor is of key importance for the size of CuFe2O4 nanoparticles, and enables preparation of c-CuFe2O4 nanoparticles of the same crystallite size (46 nm) in different nanocomposite materials. © 2019 Elsevier Inc.
T2  - Journal of Solid State Chemistry
T1  - Observation of c-CuFe2O4 nanoparticles of the same crystallite size in different nanocomposite materials: The influence of Fe3+ cations
VL  - 275
SP  - 187
EP  - 196
DO  - 10.1016/j.jssc.2019.04.007
ER  - 

@article{
author = "Nikolić, Violeta N. and Vasić, Milica M. and Kisić, Danilo",
year = "2019",
abstract = "Two samples containing 2-line ferrihydrite and copper oxide were synthesized by coprecipitation method, via variation of Fe3+ and Cu2+ precursors milimolar ratio (3:1 and 3:3.1), while the other synthesis parameters were kept constant. Annealing treatment at 1100 °C resulted in the formation of c-CuFe2O4-CuO-α-Fe2O3 and c-CuFe2O4-CuO nanocomposites, respectively. A comparison of properties of the prepared samples was performed by XRD, FTIR and EPR measurements. Formation mechanism of the nanocomposites is discussed with a reference to the influence of Jahn-Teller effect in CuO phase on the final CuFe2O4 structure. For the first time, it is shown that the amount of Fe3+ precursor is of key importance for the size of CuFe2O4 nanoparticles, and enables preparation of c-CuFe2O4 nanoparticles of the same crystallite size (46 nm) in different nanocomposite materials. © 2019 Elsevier Inc.",
journal = "Journal of Solid State Chemistry",
title = "Observation of c-CuFe2O4 nanoparticles of the same crystallite size in different nanocomposite materials: The influence of Fe3+ cations",
volume = "275",
pages = "187-196",
doi = "10.1016/j.jssc.2019.04.007"
}

Nikolić, V. N., Vasić, M. M.,& Kisić, D.. (2019). Observation of c-CuFe2O4 nanoparticles of the same crystallite size in different nanocomposite materials: The influence of Fe3+ cations. in Journal of Solid State Chemistry, 275, 187-196.
https://doi.org/10.1016/j.jssc.2019.04.007

Nikolić VN, Vasić MM, Kisić D. Observation of c-CuFe2O4 nanoparticles of the same crystallite size in different nanocomposite materials: The influence of Fe3+ cations. in Journal of Solid State Chemistry. 2019;275:187-196.
doi:10.1016/j.jssc.2019.04.007 .

Nikolić, Violeta N., Vasić, Milica M., Kisić, Danilo, "Observation of c-CuFe2O4 nanoparticles of the same crystallite size in different nanocomposite materials: The influence of Fe3+ cations" in Journal of Solid State Chemistry, 275 (2019):187-196,
https://doi.org/10.1016/j.jssc.2019.04.007 . .

TY  - JOUR
AU  - Nikolić, Violeta N.
AU  - Vasić, Milica M.
AU  - Milić, Mirjana M.
PY  - 2018
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/7876
AB  - Samples containing CuFe2O4 and CuO nanoparticles were synthesized by coprecipitation method and subjected to thermal treatment at 300 °C, 500 °C, 700 °C, 900 °C and 1100 °C. Depending on the synthesis conditions, high-temperature treatment of the prepared samples brought to the formation of CuFe2O4 with a tetragonal or cubic structure, which was confirmed by X-ray diffraction analysis. The influence of formation mechanism onto the crystallite sizes of nanoparticles and structural transformation of CuFe2O4 is discussed. For the first time it was shown that variations of the initial amount of Fe3+ and Cu2+ ions precursors resulted in the formation of low- and high-temperature CuFe2O4 phase at the same annealing temperature, 1100 °C. © 2018
T2  - Ceramics International
T1  - Observation of low- and high-temperature CuFe2O4 phase at 1100 °C: The influence of Fe3+ ions on CuFe2O4 structural transformation
VL  - 44
IS  - 17
SP  - 21145
EP  - 21152
DO  - 10.1016/j.ceramint.2018.08.157
ER  - 

@article{
author = "Nikolić, Violeta N. and Vasić, Milica M. and Milić, Mirjana M.",
year = "2018",
abstract = "Samples containing CuFe2O4 and CuO nanoparticles were synthesized by coprecipitation method and subjected to thermal treatment at 300 °C, 500 °C, 700 °C, 900 °C and 1100 °C. Depending on the synthesis conditions, high-temperature treatment of the prepared samples brought to the formation of CuFe2O4 with a tetragonal or cubic structure, which was confirmed by X-ray diffraction analysis. The influence of formation mechanism onto the crystallite sizes of nanoparticles and structural transformation of CuFe2O4 is discussed. For the first time it was shown that variations of the initial amount of Fe3+ and Cu2+ ions precursors resulted in the formation of low- and high-temperature CuFe2O4 phase at the same annealing temperature, 1100 °C. © 2018",
journal = "Ceramics International",
title = "Observation of low- and high-temperature CuFe2O4 phase at 1100 °C: The influence of Fe3+ ions on CuFe2O4 structural transformation",
volume = "44",
number = "17",
pages = "21145-21152",
doi = "10.1016/j.ceramint.2018.08.157"
}

Nikolić, V. N., Vasić, M. M.,& Milić, M. M.. (2018). Observation of low- and high-temperature CuFe2O4 phase at 1100 °C: The influence of Fe3+ ions on CuFe2O4 structural transformation. in Ceramics International, 44(17), 21145-21152.
https://doi.org/10.1016/j.ceramint.2018.08.157

Nikolić VN, Vasić MM, Milić MM. Observation of low- and high-temperature CuFe2O4 phase at 1100 °C: The influence of Fe3+ ions on CuFe2O4 structural transformation. in Ceramics International. 2018;44(17):21145-21152.
doi:10.1016/j.ceramint.2018.08.157 .

Nikolić, Violeta N., Vasić, Milica M., Milić, Mirjana M., "Observation of low- and high-temperature CuFe2O4 phase at 1100 °C: The influence of Fe3+ ions on CuFe2O4 structural transformation" in Ceramics International, 44, no. 17 (2018):21145-21152,
https://doi.org/10.1016/j.ceramint.2018.08.157 . .

TY  - JOUR
AU  - Vasić, Milica M.
AU  - Čebela, Maria
AU  - Pašti, Igor A.
AU  - Amaral, Luis
AU  - Hercigonja, Radmila V.
AU  - Santos, Diogo M. F.
AU  - Šljukić, Biljana
PY  - 2018
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/1943
AB  - Palladium ion-exchanged zeolite X (PdX) was prepared by zeolite impregnation with palladium acetylacetonate, followed by thermal degradation of the salt. PdX was characterised using SEM-EDS, ICP-OES and XRD. Analysis revealed presence of 7.78 wt.% of Pd in the form of PdO. Subsequently, PdX was tested for hydrogen evolution reaction (HER) in alkaline medium using linear scan voltammetry, chronoamperometry and electrochemical impedance spectroscopy measurements. The influence of addition of carbon black on the materials catalytic performance was also investigated. The HER kinetic parameters, including Tafel slope, exchange current density and activation energy, were determined. In order to provide atomic-level insights, experimental results were complemented by density functional theory calculations. It is suggested that favourable hydrogen adsorption energetics on PdO is responsible for efficient HER catalysis by this novel electrocatalyst. (c) 2017 Elsevier Ltd. All rights reserved.
T2  - Electrochimica Acta
T1  - Efficient hydrogen evolution electrocatalysis in alkaline medium using Pd-modified zeolite X
VL  - 259
SP  - 882
EP  - 892
DO  - 10.1016/j.electacta.2017.11.020
ER  - 

@article{
author = "Vasić, Milica M. and Čebela, Maria and Pašti, Igor A. and Amaral, Luis and Hercigonja, Radmila V. and Santos, Diogo M. F. and Šljukić, Biljana",
year = "2018",
abstract = "Palladium ion-exchanged zeolite X (PdX) was prepared by zeolite impregnation with palladium acetylacetonate, followed by thermal degradation of the salt. PdX was characterised using SEM-EDS, ICP-OES and XRD. Analysis revealed presence of 7.78 wt.% of Pd in the form of PdO. Subsequently, PdX was tested for hydrogen evolution reaction (HER) in alkaline medium using linear scan voltammetry, chronoamperometry and electrochemical impedance spectroscopy measurements. The influence of addition of carbon black on the materials catalytic performance was also investigated. The HER kinetic parameters, including Tafel slope, exchange current density and activation energy, were determined. In order to provide atomic-level insights, experimental results were complemented by density functional theory calculations. It is suggested that favourable hydrogen adsorption energetics on PdO is responsible for efficient HER catalysis by this novel electrocatalyst. (c) 2017 Elsevier Ltd. All rights reserved.",
journal = "Electrochimica Acta",
title = "Efficient hydrogen evolution electrocatalysis in alkaline medium using Pd-modified zeolite X",
volume = "259",
pages = "882-892",
doi = "10.1016/j.electacta.2017.11.020"
}

Vasić, M. M., Čebela, M., Pašti, I. A., Amaral, L., Hercigonja, R. V., Santos, D. M. F.,& Šljukić, B.. (2018). Efficient hydrogen evolution electrocatalysis in alkaline medium using Pd-modified zeolite X. in Electrochimica Acta, 259, 882-892.
https://doi.org/10.1016/j.electacta.2017.11.020

Vasić MM, Čebela M, Pašti IA, Amaral L, Hercigonja RV, Santos DMF, Šljukić B. Efficient hydrogen evolution electrocatalysis in alkaline medium using Pd-modified zeolite X. in Electrochimica Acta. 2018;259:882-892.
doi:10.1016/j.electacta.2017.11.020 .

Vasić, Milica M., Čebela, Maria, Pašti, Igor A., Amaral, Luis, Hercigonja, Radmila V., Santos, Diogo M. F., Šljukić, Biljana, "Efficient hydrogen evolution electrocatalysis in alkaline medium using Pd-modified zeolite X" in Electrochimica Acta, 259 (2018):882-892,
https://doi.org/10.1016/j.electacta.2017.11.020 . .