Kuzman, Sanja

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Authority KeyName Variants
orcid::0000-0001-9657-9122
  • Kuzman, Sanja (21)
  • Ćulubrk, Sanja (11)
Projects
Materials of Reduced Dimensions for Efficient Light Harvesting and Energy conversion NanoTBTech - Nanoparticles-based 2D thermal bioimaging technologies
Size-, shape- and structure- dependent properties of nanoparticles and nanocomposites Canada Excellence Research Chairs (CERC) program
Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200017 (University of Belgrade, Institute of Nuclear Sciences 'Vinča', Belgrade-Vinča) Ministry of Education, Science and Technological Development of the Republic of Serbia
European Regional Development Fund [TK141] Ministry of Education, Science, and Technological Development of the Republic of Serbia
National Recruitment Program of High-end Foreign Experts [GDT20185200479] NATO Science for Peace and Security Programme [G5751]
VEGA [2/0051/20] APV Provincial Secretetariat for Science and Technlogocal Development of the Republic of Serbia [114-451-1850/2014-03]
China-Poland Intergovernmental Science and Technology Cooperation Program [Grant No. 2020[15]/10] Chinese National Foreign Experts Program for “Belt and Road Initiative” Innovative Talent Exchange [Grant No. DL2021035001L]
Chongqing Recruitment Program for 100 Overseas Innovative Talents [2015013] Chongqing University of Posts and Telecommunications (CQUPT) - National High-end Foreign Experts Recruitment Program [Grant GDT20185200479]
Chongqing University of Posts and Telecommunications, Estonian Research Council [Grant No. PUT PRG111] COST Action [CA16217 “ENIUS”]
COST Action [CA16217, ENIUS] COST [CA16217] “ENIUS”
Estonian Research Council [PUT PRG111] Physics of amorphous and nanostructural materials
Graphitic and Inorganic Low-dimensional Nanostructures Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200019 (University of Belgrade, Institute for the Application of Nuclear Energy - INEP)
Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200161 (University of Belgrade, Faculty of Pharmacy) Implementation and evaluation of a new molecular method for a quick detection of a mecA gene directly in swabs originated from humans, animals and their environment
Kind Saud University, Riyadh, Saudi Arabia : Researchers Supporting Project [RSP2024R304] Ministry of Education, Science and Technological development of the Republic of Serbia
Ministry of Education, Science and Technological Development of the Republic of Serbia [451-03-2/2020- 14/20-0302002] Ministry of Education, Science and Technological Development of the Republic of Serbia [451-03-2/2020-14/20-0302002]

Author's Bibliography

Concentration and temperature dependence of Pr3+ f-f emissions in La(PO3)3

Antić, Željka; Racu, Andrei V.; Medić, Mina; Alodhayb, Abdullah N.; Kuzman, Sanja; Brik, Mikhail G.; Dramićanin, Miroslav

(2024)

TY  - JOUR
AU  - Antić, Željka
AU  - Racu, Andrei V.
AU  - Medić, Mina
AU  - Alodhayb, Abdullah N.
AU  - Kuzman, Sanja
AU  - Brik, Mikhail G.
AU  - Dramićanin, Miroslav
PY  - 2024
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/13020
AB  - La(PO3)3 activated with different concentrations of Pr3+ was synthesized by a solid-state process. The obtained powder was composed of chunks of several microns in size, typical for this type of synthesis. X-ray diffraction confirmed an orthorhombic crystal structure with the C2221 space group. The electronic band structures and density of states of La(PO3)3 and La(PO3)3:Pr3+ are calculated and presented. The visible and near-infrared emissions from Pr3+ [Xe]4f2 [Xe]4f2 electronic transitions were detected under 442 nm excitation. The red emission from the 1D2 state dominates visible spectra while emissions from the 3P0,1,2 states have smaller intensities. The 1D2 emission centered around 1020 nm is detected in the near-infrared spectral range. Intensities of 3P0 emissions increased with an increase in Pr concentration, while 1D2 emissions decreased in intensity. We found that the main process responsible for the 1D2 state decay is the Pr(1D2) + Pr(3H4) Pr(1G4) + Pr(3F3,4) cross-relaxation between two Pr ions of electric dipole-dipole character. This finding is supported by 1D2 emission decay measurements, which revealed a reduction of average decay constants from 242 μs for a 0.5 mol% doped sample to 11 μs for a 10 mol% doped sample and an increasingly stronger non-exponential behavior of emission decay patterns with an increase in Pr3+ concentration.
T2  - Optical Materials
T1  - Concentration and temperature dependence of Pr3+ f-f emissions in La(PO3)3
VL  - 150
SP  - 115226
DO  - 10.1016/j.optmat.2024.115226
ER  - 
@article{
author = "Antić, Željka and Racu, Andrei V. and Medić, Mina and Alodhayb, Abdullah N. and Kuzman, Sanja and Brik, Mikhail G. and Dramićanin, Miroslav",
year = "2024",
abstract = "La(PO3)3 activated with different concentrations of Pr3+ was synthesized by a solid-state process. The obtained powder was composed of chunks of several microns in size, typical for this type of synthesis. X-ray diffraction confirmed an orthorhombic crystal structure with the C2221 space group. The electronic band structures and density of states of La(PO3)3 and La(PO3)3:Pr3+ are calculated and presented. The visible and near-infrared emissions from Pr3+ [Xe]4f2 [Xe]4f2 electronic transitions were detected under 442 nm excitation. The red emission from the 1D2 state dominates visible spectra while emissions from the 3P0,1,2 states have smaller intensities. The 1D2 emission centered around 1020 nm is detected in the near-infrared spectral range. Intensities of 3P0 emissions increased with an increase in Pr concentration, while 1D2 emissions decreased in intensity. We found that the main process responsible for the 1D2 state decay is the Pr(1D2) + Pr(3H4) Pr(1G4) + Pr(3F3,4) cross-relaxation between two Pr ions of electric dipole-dipole character. This finding is supported by 1D2 emission decay measurements, which revealed a reduction of average decay constants from 242 μs for a 0.5 mol% doped sample to 11 μs for a 10 mol% doped sample and an increasingly stronger non-exponential behavior of emission decay patterns with an increase in Pr3+ concentration.",
journal = "Optical Materials",
title = "Concentration and temperature dependence of Pr3+ f-f emissions in La(PO3)3",
volume = "150",
pages = "115226",
doi = "10.1016/j.optmat.2024.115226"
}
Antić, Ž., Racu, A. V., Medić, M., Alodhayb, A. N., Kuzman, S., Brik, M. G.,& Dramićanin, M.. (2024). Concentration and temperature dependence of Pr3+ f-f emissions in La(PO3)3. in Optical Materials, 150, 115226.
https://doi.org/10.1016/j.optmat.2024.115226
Antić Ž, Racu AV, Medić M, Alodhayb AN, Kuzman S, Brik MG, Dramićanin M. Concentration and temperature dependence of Pr3+ f-f emissions in La(PO3)3. in Optical Materials. 2024;150:115226.
doi:10.1016/j.optmat.2024.115226 .
Antić, Željka, Racu, Andrei V., Medić, Mina, Alodhayb, Abdullah N., Kuzman, Sanja, Brik, Mikhail G., Dramićanin, Miroslav, "Concentration and temperature dependence of Pr3+ f-f emissions in La(PO3)3" in Optical Materials, 150 (2024):115226,
https://doi.org/10.1016/j.optmat.2024.115226 . .

Comparative analysis of Ag NPs functionalized with olive leaf extract and oleuropein and toxicity in human trophoblast cells and peripheral blood lymphocytes

Pirković, Andrea; Lazić, Vesna; Spremo-Potparević, Biljana; Živković, Lada; Topalović, Dijana; Kuzman, Sanja; Antić-Stanković, Jelena; Božić, Dragana; Jovanović Krivokuća, Milica; Nedeljković, Jovan

(2023)

TY  - JOUR
AU  - Pirković, Andrea
AU  - Lazić, Vesna
AU  - Spremo-Potparević, Biljana
AU  - Živković, Lada
AU  - Topalović, Dijana
AU  - Kuzman, Sanja
AU  - Antić-Stanković, Jelena
AU  - Božić, Dragana
AU  - Jovanović Krivokuća, Milica
AU  - Nedeljković, Jovan
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/11219
AB  - Dry olive leaf extract (DOLE) and its active component oleuropein (OLE) were applied as reducing and stabilizing agents to prepare colloidal 20–25 nm silver nanoparticles (Ag NPs). The Ag NPs were characterized using transmission electron microscopy, X-ray diffraction analysis, and absorption spectroscopy. The cytotoxic actions of coated Ag NPs, and their inorganic and organic components, were examined against trophoblast cells and human peripheral blood lymphocytes (PBLs), Gram-positive, Gram-negative bacteria, and yeast. The genotoxic potential was evaluated in PBLs in vitro with the comet assay. Ag/DOLE and Ag/OLE induced cytotoxic effects in both types of cells after 24 h exposure when silver concentrations were 0.025–0.2 mM. However, the most pronounced cytotoxicity exhibits Ag/OLE. Both colloids also caused reduced ROS production in both cell types at 0.1 mM and 0.2 mM, while bare Ag NPs did not alter ROS levels at any of the conditions. Functionalized Ag/DOLE and Ag/OLE did not show genotoxic effects in PBLs, while bare AgNPs increased DNA damage significantly only at 0.2 mM. Regarding the antimicrobial effects, the Ag/OLE had MIC values for all evaluated microorganisms from 0.0625 to less than 0.0312 mM. Also, the antimicrobial effect of Ag/DOLE was significantly higher on Gram-negative bacteria and yeast than on Gram-positive bacteria. Obtained results indicate that Ag/OLE induced the most pronounced biological effects, beneficial for its application as an antimicrobial agent, but with potential risks from exposure to high concentrations that could induce cytotoxicity in healthy human cells.
T2  - Mutagenesis
T1  - Comparative analysis of Ag NPs functionalized with olive leaf extract and oleuropein and toxicity in human trophoblast cells and peripheral blood lymphocytes
VL  - 38
IS  - 3
SP  - 169
EP  - 181
DO  - 10.1093/mutage/gead013
ER  - 
@article{
author = "Pirković, Andrea and Lazić, Vesna and Spremo-Potparević, Biljana and Živković, Lada and Topalović, Dijana and Kuzman, Sanja and Antić-Stanković, Jelena and Božić, Dragana and Jovanović Krivokuća, Milica and Nedeljković, Jovan",
year = "2023",
abstract = "Dry olive leaf extract (DOLE) and its active component oleuropein (OLE) were applied as reducing and stabilizing agents to prepare colloidal 20–25 nm silver nanoparticles (Ag NPs). The Ag NPs were characterized using transmission electron microscopy, X-ray diffraction analysis, and absorption spectroscopy. The cytotoxic actions of coated Ag NPs, and their inorganic and organic components, were examined against trophoblast cells and human peripheral blood lymphocytes (PBLs), Gram-positive, Gram-negative bacteria, and yeast. The genotoxic potential was evaluated in PBLs in vitro with the comet assay. Ag/DOLE and Ag/OLE induced cytotoxic effects in both types of cells after 24 h exposure when silver concentrations were 0.025–0.2 mM. However, the most pronounced cytotoxicity exhibits Ag/OLE. Both colloids also caused reduced ROS production in both cell types at 0.1 mM and 0.2 mM, while bare Ag NPs did not alter ROS levels at any of the conditions. Functionalized Ag/DOLE and Ag/OLE did not show genotoxic effects in PBLs, while bare AgNPs increased DNA damage significantly only at 0.2 mM. Regarding the antimicrobial effects, the Ag/OLE had MIC values for all evaluated microorganisms from 0.0625 to less than 0.0312 mM. Also, the antimicrobial effect of Ag/DOLE was significantly higher on Gram-negative bacteria and yeast than on Gram-positive bacteria. Obtained results indicate that Ag/OLE induced the most pronounced biological effects, beneficial for its application as an antimicrobial agent, but with potential risks from exposure to high concentrations that could induce cytotoxicity in healthy human cells.",
journal = "Mutagenesis",
title = "Comparative analysis of Ag NPs functionalized with olive leaf extract and oleuropein and toxicity in human trophoblast cells and peripheral blood lymphocytes",
volume = "38",
number = "3",
pages = "169-181",
doi = "10.1093/mutage/gead013"
}
Pirković, A., Lazić, V., Spremo-Potparević, B., Živković, L., Topalović, D., Kuzman, S., Antić-Stanković, J., Božić, D., Jovanović Krivokuća, M.,& Nedeljković, J.. (2023). Comparative analysis of Ag NPs functionalized with olive leaf extract and oleuropein and toxicity in human trophoblast cells and peripheral blood lymphocytes. in Mutagenesis, 38(3), 169-181.
https://doi.org/10.1093/mutage/gead013
Pirković A, Lazić V, Spremo-Potparević B, Živković L, Topalović D, Kuzman S, Antić-Stanković J, Božić D, Jovanović Krivokuća M, Nedeljković J. Comparative analysis of Ag NPs functionalized with olive leaf extract and oleuropein and toxicity in human trophoblast cells and peripheral blood lymphocytes. in Mutagenesis. 2023;38(3):169-181.
doi:10.1093/mutage/gead013 .
Pirković, Andrea, Lazić, Vesna, Spremo-Potparević, Biljana, Živković, Lada, Topalović, Dijana, Kuzman, Sanja, Antić-Stanković, Jelena, Božić, Dragana, Jovanović Krivokuća, Milica, Nedeljković, Jovan, "Comparative analysis of Ag NPs functionalized with olive leaf extract and oleuropein and toxicity in human trophoblast cells and peripheral blood lymphocytes" in Mutagenesis, 38, no. 3 (2023):169-181,
https://doi.org/10.1093/mutage/gead013 . .
1

Photoactive graphene quantum dots/bacterial cellulose hydrogels: Structural, mechanical, and pro-oxidant study

Marković, Zoran M.; Zmejkoski, Danica; Budimir, Milica; Bugarova, Nikol; Kleinova, Angela; Kuzman, Sanja; Špitalsky, Zdeno; Pavlović, Vladimir B.; Milivojević, Dušan; Todorović-Marković, Biljana

(2022)

TY  - JOUR
AU  - Marković, Zoran M.
AU  - Zmejkoski, Danica
AU  - Budimir, Milica
AU  - Bugarova, Nikol
AU  - Kleinova, Angela
AU  - Kuzman, Sanja
AU  - Špitalsky, Zdeno
AU  - Pavlović, Vladimir B.
AU  - Milivojević, Dušan
AU  - Todorović-Marković, Biljana
PY  - 2022
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10634
AB  - Due to their unique structural properties bacterial cellulose (BC) hydrogels find possible usage in many fields such as cosmetology, food industry, or medicine. In this study, photoactive BC hydrogels are investigated through modifications of their structural, mechanical, and pro-oxidant properties resulting from graphene quantum dots (GQDs) encapsulation. Detailed structural analysis is conducted by atomic force microscopy, transmission electron microscopy and scanning electron microscopy, X-ray photoelectron spectroscopy, Fourier transform infrared spectroscopy, and X-ray diffraction method. Dynamic mechanical analysis is performed to study the changes in storage modulus, loss modulus and tan δ. Pro-oxidative properties of new designed composites are tested by electron paramagnetic resonance (EPR). Structural and mechanical analyses show successful encapsulation of GQDs into BC whereas EPR measurements indicate high potential of these composites for singlet oxygen production.
T2  - Journal of Applied Polymer Science
T1  - Photoactive graphene quantum dots/bacterial cellulose hydrogels: Structural, mechanical, and pro-oxidant study
VL  - 139
IS  - 16
SP  - 51996
DO  - 10.1002/app.51996
ER  - 
@article{
author = "Marković, Zoran M. and Zmejkoski, Danica and Budimir, Milica and Bugarova, Nikol and Kleinova, Angela and Kuzman, Sanja and Špitalsky, Zdeno and Pavlović, Vladimir B. and Milivojević, Dušan and Todorović-Marković, Biljana",
year = "2022",
abstract = "Due to their unique structural properties bacterial cellulose (BC) hydrogels find possible usage in many fields such as cosmetology, food industry, or medicine. In this study, photoactive BC hydrogels are investigated through modifications of their structural, mechanical, and pro-oxidant properties resulting from graphene quantum dots (GQDs) encapsulation. Detailed structural analysis is conducted by atomic force microscopy, transmission electron microscopy and scanning electron microscopy, X-ray photoelectron spectroscopy, Fourier transform infrared spectroscopy, and X-ray diffraction method. Dynamic mechanical analysis is performed to study the changes in storage modulus, loss modulus and tan δ. Pro-oxidative properties of new designed composites are tested by electron paramagnetic resonance (EPR). Structural and mechanical analyses show successful encapsulation of GQDs into BC whereas EPR measurements indicate high potential of these composites for singlet oxygen production.",
journal = "Journal of Applied Polymer Science",
title = "Photoactive graphene quantum dots/bacterial cellulose hydrogels: Structural, mechanical, and pro-oxidant study",
volume = "139",
number = "16",
pages = "51996",
doi = "10.1002/app.51996"
}
Marković, Z. M., Zmejkoski, D., Budimir, M., Bugarova, N., Kleinova, A., Kuzman, S., Špitalsky, Z., Pavlović, V. B., Milivojević, D.,& Todorović-Marković, B.. (2022). Photoactive graphene quantum dots/bacterial cellulose hydrogels: Structural, mechanical, and pro-oxidant study. in Journal of Applied Polymer Science, 139(16), 51996.
https://doi.org/10.1002/app.51996
Marković ZM, Zmejkoski D, Budimir M, Bugarova N, Kleinova A, Kuzman S, Špitalsky Z, Pavlović VB, Milivojević D, Todorović-Marković B. Photoactive graphene quantum dots/bacterial cellulose hydrogels: Structural, mechanical, and pro-oxidant study. in Journal of Applied Polymer Science. 2022;139(16):51996.
doi:10.1002/app.51996 .
Marković, Zoran M., Zmejkoski, Danica, Budimir, Milica, Bugarova, Nikol, Kleinova, Angela, Kuzman, Sanja, Špitalsky, Zdeno, Pavlović, Vladimir B., Milivojević, Dušan, Todorović-Marković, Biljana, "Photoactive graphene quantum dots/bacterial cellulose hydrogels: Structural, mechanical, and pro-oxidant study" in Journal of Applied Polymer Science, 139, no. 16 (2022):51996,
https://doi.org/10.1002/app.51996 . .
3
3

Mn5+-activated Ca6Ba(PO4)4O near-infrared phosphor and its application in luminescence thermometry

Dramićanin, Miroslav; Marciniak, Lukasz; Kuzman, Sanja; Piotrowski, Wojciech; Ristić, Zoran; Periša, Jovana; Evans, Ivana; Mitrić, Jelena; Đorđević, Vesna; Tadić, Julijana D.; Brik, Mikhail G.; Ma, Chong-Geng

(2022)

TY  - JOUR
AU  - Dramićanin, Miroslav
AU  - Marciniak, Lukasz
AU  - Kuzman, Sanja
AU  - Piotrowski, Wojciech
AU  - Ristić, Zoran
AU  - Periša, Jovana
AU  - Evans, Ivana
AU  - Mitrić, Jelena
AU  - Đorđević, Vesna
AU  - Tadić, Julijana D.
AU  - Brik, Mikhail G.
AU  - Ma, Chong-Geng
PY  - 2022
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10439
AB  - The near-infrared luminescence of Ca6Ba(PO4)4O:Mn5+ is demonstrated and explained. When excited into the broad and strong absorption band that spans the 500–1000 nm spectral range, this phosphor provides an ultranarrow (FWHM = 5 nm) emission centered at 1140 nm that originates from a spin-forbidden 1E → 3A2 transition with a 37.5% internal quantum efficiency and an excited-state lifetime of about 350 μs. We derived the crystal field and Racah parameters and calculated the appropriate Tanabe–Sugano diagram for this phosphor. We found that 1E emission quenches due to the thermally-assisted cross-over with the 3T2 state and that the relatively high Debye temperature of 783 K of Ca6Ba(PO4)4O facilitates efficient emission. Since Ca6Ba(PO4)4O also provides efficient yellow emission of the Eu2+ dopant, we calculated and explained its electronic band structure, the partial and total density of states, effective Mulliken charges of all ions, elastic constants, Debye temperature, and vibrational spectra. Finally, we demonstrated the application of phosphor in a luminescence intensity ratio thermometry and obtained a relative sensitivity of 1.92%K−1 and a temperature resolution of 0.2 K in the range of physiological temperatures.
T2  - Light: Science & Applications
T1  - Mn5+-activated Ca6Ba(PO4)4O near-infrared phosphor and its application in luminescence thermometry
VL  - 11
IS  - 1
SP  - 279
DO  - 10.1038/s41377-022-00958-7
ER  - 
@article{
author = "Dramićanin, Miroslav and Marciniak, Lukasz and Kuzman, Sanja and Piotrowski, Wojciech and Ristić, Zoran and Periša, Jovana and Evans, Ivana and Mitrić, Jelena and Đorđević, Vesna and Tadić, Julijana D. and Brik, Mikhail G. and Ma, Chong-Geng",
year = "2022",
abstract = "The near-infrared luminescence of Ca6Ba(PO4)4O:Mn5+ is demonstrated and explained. When excited into the broad and strong absorption band that spans the 500–1000 nm spectral range, this phosphor provides an ultranarrow (FWHM = 5 nm) emission centered at 1140 nm that originates from a spin-forbidden 1E → 3A2 transition with a 37.5% internal quantum efficiency and an excited-state lifetime of about 350 μs. We derived the crystal field and Racah parameters and calculated the appropriate Tanabe–Sugano diagram for this phosphor. We found that 1E emission quenches due to the thermally-assisted cross-over with the 3T2 state and that the relatively high Debye temperature of 783 K of Ca6Ba(PO4)4O facilitates efficient emission. Since Ca6Ba(PO4)4O also provides efficient yellow emission of the Eu2+ dopant, we calculated and explained its electronic band structure, the partial and total density of states, effective Mulliken charges of all ions, elastic constants, Debye temperature, and vibrational spectra. Finally, we demonstrated the application of phosphor in a luminescence intensity ratio thermometry and obtained a relative sensitivity of 1.92%K−1 and a temperature resolution of 0.2 K in the range of physiological temperatures.",
journal = "Light: Science & Applications",
title = "Mn5+-activated Ca6Ba(PO4)4O near-infrared phosphor and its application in luminescence thermometry",
volume = "11",
number = "1",
pages = "279",
doi = "10.1038/s41377-022-00958-7"
}
Dramićanin, M., Marciniak, L., Kuzman, S., Piotrowski, W., Ristić, Z., Periša, J., Evans, I., Mitrić, J., Đorđević, V., Tadić, J. D., Brik, M. G.,& Ma, C.. (2022). Mn5+-activated Ca6Ba(PO4)4O near-infrared phosphor and its application in luminescence thermometry. in Light: Science & Applications, 11(1), 279.
https://doi.org/10.1038/s41377-022-00958-7
Dramićanin M, Marciniak L, Kuzman S, Piotrowski W, Ristić Z, Periša J, Evans I, Mitrić J, Đorđević V, Tadić JD, Brik MG, Ma C. Mn5+-activated Ca6Ba(PO4)4O near-infrared phosphor and its application in luminescence thermometry. in Light: Science & Applications. 2022;11(1):279.
doi:10.1038/s41377-022-00958-7 .
Dramićanin, Miroslav, Marciniak, Lukasz, Kuzman, Sanja, Piotrowski, Wojciech, Ristić, Zoran, Periša, Jovana, Evans, Ivana, Mitrić, Jelena, Đorđević, Vesna, Tadić, Julijana D., Brik, Mikhail G., Ma, Chong-Geng, "Mn5+-activated Ca6Ba(PO4)4O near-infrared phosphor and its application in luminescence thermometry" in Light: Science & Applications, 11, no. 1 (2022):279,
https://doi.org/10.1038/s41377-022-00958-7 . .
4
33
31

Multiple temperature readings from Ca6Ba(PO4)4O:Mn5+ steady-state nearinfrared emission in a physiological temperature range

Kuzman, Sanja; Ristić, Zoran; Antić, Željka; Đačanin Far, Ljubica; Dramićanin, Miroslav

(Society for science development of Serbia, Belgrade, 2022)

TY  - CONF
AU  - Kuzman, Sanja
AU  - Ristić, Zoran
AU  - Antić, Željka
AU  - Đačanin Far, Ljubica
AU  - Dramićanin, Miroslav
PY  - 2022
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/11340
AB  - The Mn5+-activated Ca6Ba(PO4)4O phosphor is described in this paper as a versatile nearinfrared luminescence thermometry probe in a physiological temperature range. It is focused on several steady-state approaches to luminescence thermometry operating entirely in the first (excitation ex=635 nm) and the second (emission) biological transparency windows. This material was synthesized by a solid-state reaction using CaCO3, BaCO3, (NH4)H2PO4 and MnO as precursor materials. Starting chemicals were thoroughly mixed in an agate mortar for 1 hour with an appropriate amount of etanol. A mixture of the raw materials was heated at 600⁰C for 6 hours, ground in an agate mortar, and further calcinated at 1280⁰C for 10h. The exploited features of Ca6Ba(PO4)4O:Mn5+ emission spectra were (Figure 1): i) luminescence intensity ratio (LIR) between spin-allowed 3T2 → 3A2 and spin forbidden 1E → 3A2 (Sr MAX=2.04%K-1 @ 20 oC, dT<0.36 K); ii) LIR between Stokes peak corresponding to the bending deformation vibronic mode (O-Mn-O) and spin forbidden 1E → 3A2 (Sr MAX=0.57 %K-1 @ 100 oC, dT<2 K above 50 oC); iii) LIR between Stokes and Anti-Stokes peaks corresponding to the bending deformation vibronic mode (O-Mn-O) (Sr MAX=0.52 %K-1 @ 100 oC, dT3 K); iv) red-shift of the position of the 1E → 3A2 peak (Sa=0.21 cm-1K -1, dT<0.33 K) and v) the broadening of the full with at half maximum (FWHM) of the same peak with the temperature increase (Sr MAX=0.34 %K-1 @ 100 oC, dT<0.38 K). The steady-state approach facilitated quick measurements of emission spectra and, consequently, a large number of acquired spectra (50) for each temperature point, which were used to experimentally determine the temperature resolution for each thermometry method.
PB  - Society for science development of Serbia, Belgrade
C3  - The 6th International Conference on the Physics of Optical Materials and Devices & The 5th International Workshop of Persistent and Photostimulable Phosphors
T1  - Multiple temperature readings from Ca6Ba(PO4)4O:Mn5+ steady-state nearinfrared emission in a physiological temperature range
UR  - https://hdl.handle.net/21.15107/rcub_vinar_11340
ER  - 
@conference{
author = "Kuzman, Sanja and Ristić, Zoran and Antić, Željka and Đačanin Far, Ljubica and Dramićanin, Miroslav",
year = "2022",
abstract = "The Mn5+-activated Ca6Ba(PO4)4O phosphor is described in this paper as a versatile nearinfrared luminescence thermometry probe in a physiological temperature range. It is focused on several steady-state approaches to luminescence thermometry operating entirely in the first (excitation ex=635 nm) and the second (emission) biological transparency windows. This material was synthesized by a solid-state reaction using CaCO3, BaCO3, (NH4)H2PO4 and MnO as precursor materials. Starting chemicals were thoroughly mixed in an agate mortar for 1 hour with an appropriate amount of etanol. A mixture of the raw materials was heated at 600⁰C for 6 hours, ground in an agate mortar, and further calcinated at 1280⁰C for 10h. The exploited features of Ca6Ba(PO4)4O:Mn5+ emission spectra were (Figure 1): i) luminescence intensity ratio (LIR) between spin-allowed 3T2 → 3A2 and spin forbidden 1E → 3A2 (Sr MAX=2.04%K-1 @ 20 oC, dT<0.36 K); ii) LIR between Stokes peak corresponding to the bending deformation vibronic mode (O-Mn-O) and spin forbidden 1E → 3A2 (Sr MAX=0.57 %K-1 @ 100 oC, dT<2 K above 50 oC); iii) LIR between Stokes and Anti-Stokes peaks corresponding to the bending deformation vibronic mode (O-Mn-O) (Sr MAX=0.52 %K-1 @ 100 oC, dT3 K); iv) red-shift of the position of the 1E → 3A2 peak (Sa=0.21 cm-1K -1, dT<0.33 K) and v) the broadening of the full with at half maximum (FWHM) of the same peak with the temperature increase (Sr MAX=0.34 %K-1 @ 100 oC, dT<0.38 K). The steady-state approach facilitated quick measurements of emission spectra and, consequently, a large number of acquired spectra (50) for each temperature point, which were used to experimentally determine the temperature resolution for each thermometry method.",
publisher = "Society for science development of Serbia, Belgrade",
journal = "The 6th International Conference on the Physics of Optical Materials and Devices & The 5th International Workshop of Persistent and Photostimulable Phosphors",
title = "Multiple temperature readings from Ca6Ba(PO4)4O:Mn5+ steady-state nearinfrared emission in a physiological temperature range",
url = "https://hdl.handle.net/21.15107/rcub_vinar_11340"
}
Kuzman, S., Ristić, Z., Antić, Ž., Đačanin Far, L.,& Dramićanin, M.. (2022). Multiple temperature readings from Ca6Ba(PO4)4O:Mn5+ steady-state nearinfrared emission in a physiological temperature range. in The 6th International Conference on the Physics of Optical Materials and Devices & The 5th International Workshop of Persistent and Photostimulable Phosphors
Society for science development of Serbia, Belgrade..
https://hdl.handle.net/21.15107/rcub_vinar_11340
Kuzman S, Ristić Z, Antić Ž, Đačanin Far L, Dramićanin M. Multiple temperature readings from Ca6Ba(PO4)4O:Mn5+ steady-state nearinfrared emission in a physiological temperature range. in The 6th International Conference on the Physics of Optical Materials and Devices & The 5th International Workshop of Persistent and Photostimulable Phosphors. 2022;.
https://hdl.handle.net/21.15107/rcub_vinar_11340 .
Kuzman, Sanja, Ristić, Zoran, Antić, Željka, Đačanin Far, Ljubica, Dramićanin, Miroslav, "Multiple temperature readings from Ca6Ba(PO4)4O:Mn5+ steady-state nearinfrared emission in a physiological temperature range" in The 6th International Conference on the Physics of Optical Materials and Devices & The 5th International Workshop of Persistent and Photostimulable Phosphors (2022),
https://hdl.handle.net/21.15107/rcub_vinar_11340 .

Highly sensitive temperature reading from intensity ratio of Eu3+ And Mn4+emissions in Y3Al5O12 nanocrystals

Periša, Jovana; Đorđević, Vesna R.; Ristić, Zoran; Medić, Mina M.; Kuzman, Sanja; Antić, Željka; Dramićanin, Miroslav

(2022)

TY  - JOUR
AU  - Periša, Jovana
AU  - Đorđević, Vesna R.
AU  - Ristić, Zoran
AU  - Medić, Mina M.
AU  - Kuzman, Sanja
AU  - Antić, Željka
AU  - Dramićanin, Miroslav
PY  - 2022
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10104
AB  - Potential of Eu3+, Mn4+ co-doped YAG for dual-activated luminescence intensity ratio thermometry is investigated. The samples were prepared by modified Pechini method and cubic structure confirmed by X-ray diffraction with average crystallite size of ∼ 20 nm. Scanning electron microscopy revealed different sized chunks composed of ellipsoidal-shaped particles bellow 50 nm. Temperature-dependent photoluminescent emission spectra (λex = 465 nm, 98–473 K temperature range) of co-doped samples consist of emission bands in the red spectral region originating from both Eu3+and Mn4+transitions. Concentration of Mn4+ and Eu3+ is optimized to be 0.5mol% and 3mol%. Observed suppression of Eu3+ emission indicate an efficient (∼97%) energy transfer from Eu3+ to Mn4+. Using luminescence intensity ratio as the ratio between the integrated intensities of the Eu3+ 5D0→7F1 transition and the Mn4+ 2E→4A2 manyfold, maximal absolute and relative sensitivities of SAmax = 19.2mK−1 at 351 K and SRmax = 5.06%K − 1 at 321 K were calculated.
T2  - Materials Research Bulletin
T1  - Highly sensitive temperature reading from intensity ratio of Eu3+ And Mn4+emissions in Y3Al5O12 nanocrystals
VL  - 149
SP  - 111708
DO  - 10.1016/j.materresbull.2021.111708
ER  - 
@article{
author = "Periša, Jovana and Đorđević, Vesna R. and Ristić, Zoran and Medić, Mina M. and Kuzman, Sanja and Antić, Željka and Dramićanin, Miroslav",
year = "2022",
abstract = "Potential of Eu3+, Mn4+ co-doped YAG for dual-activated luminescence intensity ratio thermometry is investigated. The samples were prepared by modified Pechini method and cubic structure confirmed by X-ray diffraction with average crystallite size of ∼ 20 nm. Scanning electron microscopy revealed different sized chunks composed of ellipsoidal-shaped particles bellow 50 nm. Temperature-dependent photoluminescent emission spectra (λex = 465 nm, 98–473 K temperature range) of co-doped samples consist of emission bands in the red spectral region originating from both Eu3+and Mn4+transitions. Concentration of Mn4+ and Eu3+ is optimized to be 0.5mol% and 3mol%. Observed suppression of Eu3+ emission indicate an efficient (∼97%) energy transfer from Eu3+ to Mn4+. Using luminescence intensity ratio as the ratio between the integrated intensities of the Eu3+ 5D0→7F1 transition and the Mn4+ 2E→4A2 manyfold, maximal absolute and relative sensitivities of SAmax = 19.2mK−1 at 351 K and SRmax = 5.06%K − 1 at 321 K were calculated.",
journal = "Materials Research Bulletin",
title = "Highly sensitive temperature reading from intensity ratio of Eu3+ And Mn4+emissions in Y3Al5O12 nanocrystals",
volume = "149",
pages = "111708",
doi = "10.1016/j.materresbull.2021.111708"
}
Periša, J., Đorđević, V. R., Ristić, Z., Medić, M. M., Kuzman, S., Antić, Ž.,& Dramićanin, M.. (2022). Highly sensitive temperature reading from intensity ratio of Eu3+ And Mn4+emissions in Y3Al5O12 nanocrystals. in Materials Research Bulletin, 149, 111708.
https://doi.org/10.1016/j.materresbull.2021.111708
Periša J, Đorđević VR, Ristić Z, Medić MM, Kuzman S, Antić Ž, Dramićanin M. Highly sensitive temperature reading from intensity ratio of Eu3+ And Mn4+emissions in Y3Al5O12 nanocrystals. in Materials Research Bulletin. 2022;149:111708.
doi:10.1016/j.materresbull.2021.111708 .
Periša, Jovana, Đorđević, Vesna R., Ristić, Zoran, Medić, Mina M., Kuzman, Sanja, Antić, Željka, Dramićanin, Miroslav, "Highly sensitive temperature reading from intensity ratio of Eu3+ And Mn4+emissions in Y3Al5O12 nanocrystals" in Materials Research Bulletin, 149 (2022):111708,
https://doi.org/10.1016/j.materresbull.2021.111708 . .
1
9
7

Temperature dependence of the Cr3+-DOPED Mg2TiO4 near-infrared emission

Ristić, Zoran; Đorđević, Vesna R.; Medić, Mina M.; Kuzman, Sanja; Brik, Mikhail G.; Antić, Željka; Dramićanin, Miroslav

(2021)

TY  - JOUR
AU  - Ristić, Zoran
AU  - Đorđević, Vesna R.
AU  - Medić, Mina M.
AU  - Kuzman, Sanja
AU  - Brik, Mikhail G.
AU  - Antić, Željka
AU  - Dramićanin, Miroslav
PY  - 2021
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/9910
AB  - This paper presents the Cr3+-activated Mg2TiO4 phosphor temperature dependance of its near infrared luminescence and its potential in the optical thermometry applications. In this respect, temperature dependences of three emission features were tested over the broad temperature range (10–500 K): (i) the luminescence intensity ratio (LIR) between emissions from 4T2→4A2 and 2E→4A2 transitions, (ii) the emission lifetime, and (iii) the shift of the 2E→4A2 emission band. We observed that LIR follows the Boltzmann equation for T > 300 K with the maximal value of relative sensitivity of 1.73 %K−1. The lifetime value of the 2E→4A2 transition strongly decreases with temperature with a maximal relative sensitivity of about 0.75 %K−1 at around 430K. Finally, the shift of the emission band is about 65 cm−1 over the complete temperature range.
T2  - Optical Materials
T1  - Temperature dependence of the Cr3+-DOPED Mg2TiO4 near-infrared emission
VL  - 120
SP  - 111468
DO  - 10.1016/j.optmat.2021.111468
ER  - 
@article{
author = "Ristić, Zoran and Đorđević, Vesna R. and Medić, Mina M. and Kuzman, Sanja and Brik, Mikhail G. and Antić, Željka and Dramićanin, Miroslav",
year = "2021",
abstract = "This paper presents the Cr3+-activated Mg2TiO4 phosphor temperature dependance of its near infrared luminescence and its potential in the optical thermometry applications. In this respect, temperature dependences of three emission features were tested over the broad temperature range (10–500 K): (i) the luminescence intensity ratio (LIR) between emissions from 4T2→4A2 and 2E→4A2 transitions, (ii) the emission lifetime, and (iii) the shift of the 2E→4A2 emission band. We observed that LIR follows the Boltzmann equation for T > 300 K with the maximal value of relative sensitivity of 1.73 %K−1. The lifetime value of the 2E→4A2 transition strongly decreases with temperature with a maximal relative sensitivity of about 0.75 %K−1 at around 430K. Finally, the shift of the emission band is about 65 cm−1 over the complete temperature range.",
journal = "Optical Materials",
title = "Temperature dependence of the Cr3+-DOPED Mg2TiO4 near-infrared emission",
volume = "120",
pages = "111468",
doi = "10.1016/j.optmat.2021.111468"
}
Ristić, Z., Đorđević, V. R., Medić, M. M., Kuzman, S., Brik, M. G., Antić, Ž.,& Dramićanin, M.. (2021). Temperature dependence of the Cr3+-DOPED Mg2TiO4 near-infrared emission. in Optical Materials, 120, 111468.
https://doi.org/10.1016/j.optmat.2021.111468
Ristić Z, Đorđević VR, Medić MM, Kuzman S, Brik MG, Antić Ž, Dramićanin M. Temperature dependence of the Cr3+-DOPED Mg2TiO4 near-infrared emission. in Optical Materials. 2021;120:111468.
doi:10.1016/j.optmat.2021.111468 .
Ristić, Zoran, Đorđević, Vesna R., Medić, Mina M., Kuzman, Sanja, Brik, Mikhail G., Antić, Željka, Dramićanin, Miroslav, "Temperature dependence of the Cr3+-DOPED Mg2TiO4 near-infrared emission" in Optical Materials, 120 (2021):111468,
https://doi.org/10.1016/j.optmat.2021.111468 . .
17
2
16

Sensitive temperature reading from intensity ratio of Cr3+ and defects’ emissions in MgTiO3:Cr3+

Ćirić, Aleksandar; Periša, Jovana; Medić, Mina M.; Kuzman, Sanja; Ristić, Zoran; Antić, Željka; Dramićanin, Miroslav

(2021)

TY  - JOUR
AU  - Ćirić, Aleksandar
AU  - Periša, Jovana
AU  - Medić, Mina M.
AU  - Kuzman, Sanja
AU  - Ristić, Zoran
AU  - Antić, Željka
AU  - Dramićanin, Miroslav
PY  - 2021
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/9907
AB  - The luminescence thermometry based on the intensity ratio of Cr3+ and host emissions in the Cr3+ activated MgTiO3 phosphor powder is demonstrated over the 100–350 K temperature range. Phosphor was prepared by a two-step procedure based on the sol-gel and molten salt methods. Rhombohedral crystal structure of the material is confirmed by X-ray diffraction analysis, and the mean crystallite size of the powder was calculated to be ~ 32 nm. Morphology was investigated using scanning electron microscopy showing ellipsoidal, densely packed grains with 100 nm–150 nm average size. Photoluminescence emission spectra recorded under 385 nm excitation showed the broad host emission centered at ~ 485 nm and the Cr3+ emission around ~ 700 nm. The temperature-dependent emission spectra showed that host-emission intensity is almost temperature invariant, while the intensity of the Cr3+ emission rapidly decreases from 200 K to 350 K. Such behavior theoretically modelled and further applied for the ratiometric luminescence temperature sensing showed the maximal relative sensitivity of ~ 2.6% K-1, temperature resolution of 0.3 K, and excellent repeatability.
T2  - Ceramics International
T1  - Sensitive temperature reading from intensity ratio of Cr3+ and defects’ emissions in MgTiO3:Cr3+
VL  - 47
IS  - 22
SP  - 31915
EP  - 31919
DO  - 10.1016/j.ceramint.2021.08.077
ER  - 
@article{
author = "Ćirić, Aleksandar and Periša, Jovana and Medić, Mina M. and Kuzman, Sanja and Ristić, Zoran and Antić, Željka and Dramićanin, Miroslav",
year = "2021",
abstract = "The luminescence thermometry based on the intensity ratio of Cr3+ and host emissions in the Cr3+ activated MgTiO3 phosphor powder is demonstrated over the 100–350 K temperature range. Phosphor was prepared by a two-step procedure based on the sol-gel and molten salt methods. Rhombohedral crystal structure of the material is confirmed by X-ray diffraction analysis, and the mean crystallite size of the powder was calculated to be ~ 32 nm. Morphology was investigated using scanning electron microscopy showing ellipsoidal, densely packed grains with 100 nm–150 nm average size. Photoluminescence emission spectra recorded under 385 nm excitation showed the broad host emission centered at ~ 485 nm and the Cr3+ emission around ~ 700 nm. The temperature-dependent emission spectra showed that host-emission intensity is almost temperature invariant, while the intensity of the Cr3+ emission rapidly decreases from 200 K to 350 K. Such behavior theoretically modelled and further applied for the ratiometric luminescence temperature sensing showed the maximal relative sensitivity of ~ 2.6% K-1, temperature resolution of 0.3 K, and excellent repeatability.",
journal = "Ceramics International",
title = "Sensitive temperature reading from intensity ratio of Cr3+ and defects’ emissions in MgTiO3:Cr3+",
volume = "47",
number = "22",
pages = "31915-31919",
doi = "10.1016/j.ceramint.2021.08.077"
}
Ćirić, A., Periša, J., Medić, M. M., Kuzman, S., Ristić, Z., Antić, Ž.,& Dramićanin, M.. (2021). Sensitive temperature reading from intensity ratio of Cr3+ and defects’ emissions in MgTiO3:Cr3+. in Ceramics International, 47(22), 31915-31919.
https://doi.org/10.1016/j.ceramint.2021.08.077
Ćirić A, Periša J, Medić MM, Kuzman S, Ristić Z, Antić Ž, Dramićanin M. Sensitive temperature reading from intensity ratio of Cr3+ and defects’ emissions in MgTiO3:Cr3+. in Ceramics International. 2021;47(22):31915-31919.
doi:10.1016/j.ceramint.2021.08.077 .
Ćirić, Aleksandar, Periša, Jovana, Medić, Mina M., Kuzman, Sanja, Ristić, Zoran, Antić, Željka, Dramićanin, Miroslav, "Sensitive temperature reading from intensity ratio of Cr3+ and defects’ emissions in MgTiO3:Cr3+" in Ceramics International, 47, no. 22 (2021):31915-31919,
https://doi.org/10.1016/j.ceramint.2021.08.077 . .
10
10

Bactericidal and antioxidant bacterial cellulose hydrogels doped with chitosan as potential urinary tract infection biomedical agent

Zmejkoski, Danica; Marković, Zoran M.; Zdravković, Nemanja M.; Trišić, Dijana; Budimir, Milica; Kuzman, Sanja; Kozyrovska, Natalia O.; Orlovska, Iryna V.; Bugárová, Nikol; Petrović, Đorđe; Kováčová, Mária; Kleinová, Angela; Špitalský, Zdeno; Pavlović, Vladimir B.; Todorović-Marković, Biljana

(2021)

TY  - JOUR
AU  - Zmejkoski, Danica
AU  - Marković, Zoran M.
AU  - Zdravković, Nemanja M.
AU  - Trišić, Dijana
AU  - Budimir, Milica
AU  - Kuzman, Sanja
AU  - Kozyrovska, Natalia O.
AU  - Orlovska, Iryna V.
AU  - Bugárová, Nikol
AU  - Petrović, Đorđe
AU  - Kováčová, Mária
AU  - Kleinová, Angela
AU  - Špitalský, Zdeno
AU  - Pavlović, Vladimir B.
AU  - Todorović-Marković, Biljana
PY  - 2021
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/9143
AB  - Therapy of bacterial urinary tract infections (UTIs) and catheter associated urinary tract infections (CAUTIs) is still a great challenge because of the resistance of bacteria to nowadays used antibiotics and encrustation of catheters. Bacterial cellulose (BC) as a biocompatible material with a high porosity allows incorporation of different materials in its three dimensional network structure. In this work a low molecular weight chitosan (Chi) polymer is incorporated in BC with different concentrations. Different characterization techniques are used to investigate structural and optical properties of these composites. Radical scavenging activity test shows moderate antioxidant activity of these biocompatible composites whereasin vitrorelease test shows that 13.3% of chitosan is released after 72 h. Antibacterial testing of BC-Chi composites conducted on Gram-positive and Gram-negative bacteria causing UTIs and CAUTIs (Escherichia coli,Pseudomonas aeruginosa,Klebsiella pneumoniae) and encrustation (Proteus mirabilis) show bactericidal effect. The morphology analysis of bacteria after the application of BC-Chi shows that they are flattened with a rough surface, with a tendency to agglomerate and with decreased length and width. All obtained results show that BC-Chi composites might be considered as potential biomedical agents in treatment of UTIs and CAUTIs and as a urinary catheter coating in encrustation prevention.
T2  - RSC Advances
T1  - Bactericidal and antioxidant bacterial cellulose hydrogels doped with chitosan as potential urinary tract infection biomedical agent
VL  - 11
IS  - 15
SP  - 8559
EP  - 8568
DO  - 10.1039/D0RA10782D
ER  - 
@article{
author = "Zmejkoski, Danica and Marković, Zoran M. and Zdravković, Nemanja M. and Trišić, Dijana and Budimir, Milica and Kuzman, Sanja and Kozyrovska, Natalia O. and Orlovska, Iryna V. and Bugárová, Nikol and Petrović, Đorđe and Kováčová, Mária and Kleinová, Angela and Špitalský, Zdeno and Pavlović, Vladimir B. and Todorović-Marković, Biljana",
year = "2021",
abstract = "Therapy of bacterial urinary tract infections (UTIs) and catheter associated urinary tract infections (CAUTIs) is still a great challenge because of the resistance of bacteria to nowadays used antibiotics and encrustation of catheters. Bacterial cellulose (BC) as a biocompatible material with a high porosity allows incorporation of different materials in its three dimensional network structure. In this work a low molecular weight chitosan (Chi) polymer is incorporated in BC with different concentrations. Different characterization techniques are used to investigate structural and optical properties of these composites. Radical scavenging activity test shows moderate antioxidant activity of these biocompatible composites whereasin vitrorelease test shows that 13.3% of chitosan is released after 72 h. Antibacterial testing of BC-Chi composites conducted on Gram-positive and Gram-negative bacteria causing UTIs and CAUTIs (Escherichia coli,Pseudomonas aeruginosa,Klebsiella pneumoniae) and encrustation (Proteus mirabilis) show bactericidal effect. The morphology analysis of bacteria after the application of BC-Chi shows that they are flattened with a rough surface, with a tendency to agglomerate and with decreased length and width. All obtained results show that BC-Chi composites might be considered as potential biomedical agents in treatment of UTIs and CAUTIs and as a urinary catheter coating in encrustation prevention.",
journal = "RSC Advances",
title = "Bactericidal and antioxidant bacterial cellulose hydrogels doped with chitosan as potential urinary tract infection biomedical agent",
volume = "11",
number = "15",
pages = "8559-8568",
doi = "10.1039/D0RA10782D"
}
Zmejkoski, D., Marković, Z. M., Zdravković, N. M., Trišić, D., Budimir, M., Kuzman, S., Kozyrovska, N. O., Orlovska, I. V., Bugárová, N., Petrović, Đ., Kováčová, M., Kleinová, A., Špitalský, Z., Pavlović, V. B.,& Todorović-Marković, B.. (2021). Bactericidal and antioxidant bacterial cellulose hydrogels doped with chitosan as potential urinary tract infection biomedical agent. in RSC Advances, 11(15), 8559-8568.
https://doi.org/10.1039/D0RA10782D
Zmejkoski D, Marković ZM, Zdravković NM, Trišić D, Budimir M, Kuzman S, Kozyrovska NO, Orlovska IV, Bugárová N, Petrović Đ, Kováčová M, Kleinová A, Špitalský Z, Pavlović VB, Todorović-Marković B. Bactericidal and antioxidant bacterial cellulose hydrogels doped with chitosan as potential urinary tract infection biomedical agent. in RSC Advances. 2021;11(15):8559-8568.
doi:10.1039/D0RA10782D .
Zmejkoski, Danica, Marković, Zoran M., Zdravković, Nemanja M., Trišić, Dijana, Budimir, Milica, Kuzman, Sanja, Kozyrovska, Natalia O., Orlovska, Iryna V., Bugárová, Nikol, Petrović, Đorđe, Kováčová, Mária, Kleinová, Angela, Špitalský, Zdeno, Pavlović, Vladimir B., Todorović-Marković, Biljana, "Bactericidal and antioxidant bacterial cellulose hydrogels doped with chitosan as potential urinary tract infection biomedical agent" in RSC Advances, 11, no. 15 (2021):8559-8568,
https://doi.org/10.1039/D0RA10782D . .
11
2
7

Photoactive and antioxidant nanochitosan dots/biocellulose hydrogels for wound healing treatment

Zmejkoski, Danica; Marković, Zoran M.; Budimir, Milica; Zdravković, Nemanja M.; Trišić, Dijana ; Bugárová, Nikol; Danko, Martin; Kozyrovska, Natalia O.; Špitalský, Zdeno; Kleinová, Angela; Kuzman, Sanja; Pavlović, Vladimir B.; Todorović-Marković, Biljana

(2021)

TY  - JOUR
AU  - Zmejkoski, Danica
AU  - Marković, Zoran M.
AU  - Budimir, Milica
AU  - Zdravković, Nemanja M.
AU  - Trišić, Dijana 
AU  - Bugárová, Nikol
AU  - Danko, Martin
AU  - Kozyrovska, Natalia O.
AU  - Špitalský, Zdeno
AU  - Kleinová, Angela
AU  - Kuzman, Sanja
AU  - Pavlović, Vladimir B.
AU  - Todorović-Marković, Biljana
PY  - 2021
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/9566
AB  - Bacterial infection and their resistance to known antibiotics delays wound healing. In this study, nanochitosan dots (nChiD) produced by gamma irradiation have been encapsulated in bacterial cellulose (BC) polymer matrix to study the antibacterial potentials of these nanocomposites and their possible usage in wound healing treatment (scratch assay). Detailed analyses show that nChiDs have disc-like shape and average diameter in the range of 40 to 60 nm depending of the applied dose. All nChiDs as well as BC-nChiD nanocomposites emit green photoluminescence independently on the excitation wavelengths. The new designed nanocomposites do not have a cytotoxic effect; antioxidant analysis shows their moderate radical scavenging activity whereas antibacterial properties show significant growth inhibition of strains mostly found in difficult-to-heal wounds. The obtained results confirm that new designed BC-nChiD nanocomposites might be potential agent in wound healing treatment. © 2021 Elsevier B.V.
T2  - Materials Science and Engineering: C
T1  - Photoactive and antioxidant nanochitosan dots/biocellulose hydrogels for wound healing treatment
VL  - 122
SP  - 111925
DO  - 10.1016/j.msec.2021.111925
ER  - 
@article{
author = "Zmejkoski, Danica and Marković, Zoran M. and Budimir, Milica and Zdravković, Nemanja M. and Trišić, Dijana  and Bugárová, Nikol and Danko, Martin and Kozyrovska, Natalia O. and Špitalský, Zdeno and Kleinová, Angela and Kuzman, Sanja and Pavlović, Vladimir B. and Todorović-Marković, Biljana",
year = "2021",
abstract = "Bacterial infection and their resistance to known antibiotics delays wound healing. In this study, nanochitosan dots (nChiD) produced by gamma irradiation have been encapsulated in bacterial cellulose (BC) polymer matrix to study the antibacterial potentials of these nanocomposites and their possible usage in wound healing treatment (scratch assay). Detailed analyses show that nChiDs have disc-like shape and average diameter in the range of 40 to 60 nm depending of the applied dose. All nChiDs as well as BC-nChiD nanocomposites emit green photoluminescence independently on the excitation wavelengths. The new designed nanocomposites do not have a cytotoxic effect; antioxidant analysis shows their moderate radical scavenging activity whereas antibacterial properties show significant growth inhibition of strains mostly found in difficult-to-heal wounds. The obtained results confirm that new designed BC-nChiD nanocomposites might be potential agent in wound healing treatment. © 2021 Elsevier B.V.",
journal = "Materials Science and Engineering: C",
title = "Photoactive and antioxidant nanochitosan dots/biocellulose hydrogels for wound healing treatment",
volume = "122",
pages = "111925",
doi = "10.1016/j.msec.2021.111925"
}
Zmejkoski, D., Marković, Z. M., Budimir, M., Zdravković, N. M., Trišić, D., Bugárová, N., Danko, M., Kozyrovska, N. O., Špitalský, Z., Kleinová, A., Kuzman, S., Pavlović, V. B.,& Todorović-Marković, B.. (2021). Photoactive and antioxidant nanochitosan dots/biocellulose hydrogels for wound healing treatment. in Materials Science and Engineering: C, 122, 111925.
https://doi.org/10.1016/j.msec.2021.111925
Zmejkoski D, Marković ZM, Budimir M, Zdravković NM, Trišić D, Bugárová N, Danko M, Kozyrovska NO, Špitalský Z, Kleinová A, Kuzman S, Pavlović VB, Todorović-Marković B. Photoactive and antioxidant nanochitosan dots/biocellulose hydrogels for wound healing treatment. in Materials Science and Engineering: C. 2021;122:111925.
doi:10.1016/j.msec.2021.111925 .
Zmejkoski, Danica, Marković, Zoran M., Budimir, Milica, Zdravković, Nemanja M., Trišić, Dijana , Bugárová, Nikol, Danko, Martin, Kozyrovska, Natalia O., Špitalský, Zdeno, Kleinová, Angela, Kuzman, Sanja, Pavlović, Vladimir B., Todorović-Marković, Biljana, "Photoactive and antioxidant nanochitosan dots/biocellulose hydrogels for wound healing treatment" in Materials Science and Engineering: C, 122 (2021):111925,
https://doi.org/10.1016/j.msec.2021.111925 . .
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21

Supersensitive Sm2+ ‐Activated Al2O3 Thermometric Coatings for High‐Resolution Multiple Temperature Read‐Outs from Luminescence

Ćirić, Aleksandar; Stojadinović, Stevan; Ristić, Zoran; Zeković, Ivana Lj.; Kuzman, Sanja; Antić, Željka; Dramićanin, Miroslav

(2021)

TY  - JOUR
AU  - Ćirić, Aleksandar
AU  - Stojadinović, Stevan
AU  - Ristić, Zoran
AU  - Zeković, Ivana Lj.
AU  - Kuzman, Sanja
AU  - Antić, Željka
AU  - Dramićanin, Miroslav
PY  - 2021
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/9140
AB  - The introduction of additional functionalities to materials is exceptionally important as it opens new applications for them. Aluminum, one of the most abundant and important materials, is coated with luminescent Sm2+-doped γ-aluminium oxide to impart thermometric functionality. Considering the potential industrial applications, two of the most widely used aluminum alloys, 6061 and 7075, are also coated. For this purpose, plasma electrolytic oxidation (PEO), an effective technique for producing hard ceramic coatings on various metal surfaces, is used. It is shown that thermometric coatings can be produced on aluminum in one-step process by adding the raw precursor to the electrolyte. The valence reduction of Ln3+ to Ln2+ is achieved during the PEO process. The intense and broad (orange to deep red) emission from the coating shows supersensitivity to temperature changes over the 100–648 K range. The temperature is obtained from the coating emission using i) the emission intensity ratio method, ii) emission lifetime, and iii) emission band position with sensitivities of 4.8% K−1, 1.2% K−1, and 8 cm−1 K−1, respectively. Several applications would benefit from the thermometric coating's excellent temperature resolution of 0.04 K and the choice of three temperature read-outs that facilitate the coating's use in different luminescence thermometry setups. © 2021 Wiley-VCH GmbH
T2  - Advanced Materials Technologies
T1  - Supersensitive Sm2+ ‐Activated Al2O3 Thermometric Coatings for High‐Resolution Multiple Temperature Read‐Outs from Luminescence
VL  - 6
IS  - 4
SP  - 2001201
DO  - 10.1002/admt.202001201
ER  - 
@article{
author = "Ćirić, Aleksandar and Stojadinović, Stevan and Ristić, Zoran and Zeković, Ivana Lj. and Kuzman, Sanja and Antić, Željka and Dramićanin, Miroslav",
year = "2021",
abstract = "The introduction of additional functionalities to materials is exceptionally important as it opens new applications for them. Aluminum, one of the most abundant and important materials, is coated with luminescent Sm2+-doped γ-aluminium oxide to impart thermometric functionality. Considering the potential industrial applications, two of the most widely used aluminum alloys, 6061 and 7075, are also coated. For this purpose, plasma electrolytic oxidation (PEO), an effective technique for producing hard ceramic coatings on various metal surfaces, is used. It is shown that thermometric coatings can be produced on aluminum in one-step process by adding the raw precursor to the electrolyte. The valence reduction of Ln3+ to Ln2+ is achieved during the PEO process. The intense and broad (orange to deep red) emission from the coating shows supersensitivity to temperature changes over the 100–648 K range. The temperature is obtained from the coating emission using i) the emission intensity ratio method, ii) emission lifetime, and iii) emission band position with sensitivities of 4.8% K−1, 1.2% K−1, and 8 cm−1 K−1, respectively. Several applications would benefit from the thermometric coating's excellent temperature resolution of 0.04 K and the choice of three temperature read-outs that facilitate the coating's use in different luminescence thermometry setups. © 2021 Wiley-VCH GmbH",
journal = "Advanced Materials Technologies",
title = "Supersensitive Sm2+ ‐Activated Al2O3 Thermometric Coatings for High‐Resolution Multiple Temperature Read‐Outs from Luminescence",
volume = "6",
number = "4",
pages = "2001201",
doi = "10.1002/admt.202001201"
}
Ćirić, A., Stojadinović, S., Ristić, Z., Zeković, I. Lj., Kuzman, S., Antić, Ž.,& Dramićanin, M.. (2021). Supersensitive Sm2+ ‐Activated Al2O3 Thermometric Coatings for High‐Resolution Multiple Temperature Read‐Outs from Luminescence. in Advanced Materials Technologies, 6(4), 2001201.
https://doi.org/10.1002/admt.202001201
Ćirić A, Stojadinović S, Ristić Z, Zeković IL, Kuzman S, Antić Ž, Dramićanin M. Supersensitive Sm2+ ‐Activated Al2O3 Thermometric Coatings for High‐Resolution Multiple Temperature Read‐Outs from Luminescence. in Advanced Materials Technologies. 2021;6(4):2001201.
doi:10.1002/admt.202001201 .
Ćirić, Aleksandar, Stojadinović, Stevan, Ristić, Zoran, Zeković, Ivana Lj., Kuzman, Sanja, Antić, Željka, Dramićanin, Miroslav, "Supersensitive Sm2+ ‐Activated Al2O3 Thermometric Coatings for High‐Resolution Multiple Temperature Read‐Outs from Luminescence" in Advanced Materials Technologies, 6, no. 4 (2021):2001201,
https://doi.org/10.1002/admt.202001201 . .
3
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21

Triple-temperature readout in luminescence thermometry with Cr3+-doped Mg2SiO4 operating from cryogenic to physiologically relevant temperatures

Ristić, Zoran; Đorđević, Vesna R.; Medić, Mina M.; Kuzman, Sanja; Sekulić, Milica; Antić, Željka; Dramićanin, Miroslav

(2021)

TY  - JOUR
AU  - Ristić, Zoran
AU  - Đorđević, Vesna R.
AU  - Medić, Mina M.
AU  - Kuzman, Sanja
AU  - Sekulić, Milica
AU  - Antić, Željka
AU  - Dramićanin, Miroslav
PY  - 2021
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/9624
AB  - Cr3+-doped Mg2SiO4 orthorhombic nanoparticles are synthesized by a combustion method. The 3d3 electron configuration of the Cr3+ ion results in the deep-red emission from optical transitions between d-d orbitals. Two overlapping emissions from the Cr3+ spin-forbidden 2Eg→ 4A2g and the spin-allowed 4T2g→ 4A2g electronic transitions are influenced by the strong crystal field in Mg2SiO4 and, thus, are suitable for ratiometric luminescence thermometry. The temperature-induced changes in Cr3+-doped Mg2SiO4 emission are tested for use in luminescence thermometry from cryogenic to physiologically relevant temperatures (10-350 K) by three approaches: (a) temperature-induced changes of emission intensity; (b) temperature-dependent luminescence lifetime; and (c) temperature-induced changes of emission band position. The second approach offers applicable thermometry at cryogenic temperatures, starting from temperatures as low as 50 K, while all three approaches offer applicable thermometry at physiologically relevant temperatures with relative sensitivities of 0.7% K-1 for emission intensity, 0.8% K-1 for lifetime and 0.85% K-1 for band position at 310 K. © 2021 IOP Publishing Ltd.
T2  - Measurement Science and Technology
T1  - Triple-temperature readout in luminescence thermometry with Cr3+-doped Mg2SiO4 operating from cryogenic to physiologically relevant temperatures
VL  - 32
IS  - 5
SP  - 054004
DO  - 10.1088/1361-6501/abdc9a
ER  - 
@article{
author = "Ristić, Zoran and Đorđević, Vesna R. and Medić, Mina M. and Kuzman, Sanja and Sekulić, Milica and Antić, Željka and Dramićanin, Miroslav",
year = "2021",
abstract = "Cr3+-doped Mg2SiO4 orthorhombic nanoparticles are synthesized by a combustion method. The 3d3 electron configuration of the Cr3+ ion results in the deep-red emission from optical transitions between d-d orbitals. Two overlapping emissions from the Cr3+ spin-forbidden 2Eg→ 4A2g and the spin-allowed 4T2g→ 4A2g electronic transitions are influenced by the strong crystal field in Mg2SiO4 and, thus, are suitable for ratiometric luminescence thermometry. The temperature-induced changes in Cr3+-doped Mg2SiO4 emission are tested for use in luminescence thermometry from cryogenic to physiologically relevant temperatures (10-350 K) by three approaches: (a) temperature-induced changes of emission intensity; (b) temperature-dependent luminescence lifetime; and (c) temperature-induced changes of emission band position. The second approach offers applicable thermometry at cryogenic temperatures, starting from temperatures as low as 50 K, while all three approaches offer applicable thermometry at physiologically relevant temperatures with relative sensitivities of 0.7% K-1 for emission intensity, 0.8% K-1 for lifetime and 0.85% K-1 for band position at 310 K. © 2021 IOP Publishing Ltd.",
journal = "Measurement Science and Technology",
title = "Triple-temperature readout in luminescence thermometry with Cr3+-doped Mg2SiO4 operating from cryogenic to physiologically relevant temperatures",
volume = "32",
number = "5",
pages = "054004",
doi = "10.1088/1361-6501/abdc9a"
}
Ristić, Z., Đorđević, V. R., Medić, M. M., Kuzman, S., Sekulić, M., Antić, Ž.,& Dramićanin, M.. (2021). Triple-temperature readout in luminescence thermometry with Cr3+-doped Mg2SiO4 operating from cryogenic to physiologically relevant temperatures. in Measurement Science and Technology, 32(5), 054004.
https://doi.org/10.1088/1361-6501/abdc9a
Ristić Z, Đorđević VR, Medić MM, Kuzman S, Sekulić M, Antić Ž, Dramićanin M. Triple-temperature readout in luminescence thermometry with Cr3+-doped Mg2SiO4 operating from cryogenic to physiologically relevant temperatures. in Measurement Science and Technology. 2021;32(5):054004.
doi:10.1088/1361-6501/abdc9a .
Ristić, Zoran, Đorđević, Vesna R., Medić, Mina M., Kuzman, Sanja, Sekulić, Milica, Antić, Željka, Dramićanin, Miroslav, "Triple-temperature readout in luminescence thermometry with Cr3+-doped Mg2SiO4 operating from cryogenic to physiologically relevant temperatures" in Measurement Science and Technology, 32, no. 5 (2021):054004,
https://doi.org/10.1088/1361-6501/abdc9a . .
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22

Making Nd3+ a Sensitive Luminescent Thermometer for Physiological Temperatures—An Account of Pitfalls in Boltzmann Thermometry

Suta, Markus; Antić, Željka; Đorđević, Vesna R.; Kuzman, Sanja; Dramićanin, Miroslav; Meijerink, Andries

(2020)

TY  - JOUR
AU  - Suta, Markus
AU  - Antić, Željka
AU  - Đorđević, Vesna R.
AU  - Kuzman, Sanja
AU  - Dramićanin, Miroslav
AU  - Meijerink, Andries
PY  - 2020
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/8909
AB  - Ratiometric luminescence thermometry employing luminescence within the biological transparency windows provides high potential for biothermal imaging. Nd3+ is a promising candidate for that purpose due to its intense radiative transitions within biological windows (BWs) I and II and the simultaneous efficient excitability within BW I. This makes Nd3+ almost unique among all lanthanides. Typically, emission from the two 4F3/2 crystal field levels is used for thermometry but the small ~100 cm−1 energy separation limits the sensitivity. A higher sensitivity for physiological temperatures is possible using the luminescence intensity ratio (LIR) of the emissive transitions from the 4F5/2 and 4F3/2 excited spin-orbit levels. Herein, we demonstrate and discuss various pitfalls that can occur in Boltzmann thermometry if this particular LIR is used for physiological temperature sensing. Both microcrystalline, dilute (0.1%) Nd3+-doped LaPO4 and LaPO4: x% Nd3+ (x = 2, 5, 10, 25, 100) nanocrystals serve as an illustrative example. Besides structural and optical characterization of those luminescent thermometers, the impact and consequences of the Nd3+ concentration on their luminescence and performance as Boltzmann-based thermometers are analyzed. For low Nd3+ concentrations, Boltzmann equilibrium starts just around 300 K. At higher Nd3+ concentrations, cross-relaxation processes enhance the decay rates of the 4F3/2 and 4F5/2 levels making the decay faster than the equilibration rates between the levels. It is shown that the onset of the useful temperature sensing range shifts to higher temperatures, even above ~ 450 K for Nd concentrations over 5%. A microscopic explanation for pitfalls in Boltzmann thermometry with Nd3+ is finally given and guidelines for the usability of this lanthanide ion in the field of physiological temperature sensing are elaborated. Insight in competition between thermal coupling through non-radiative transitions and population decay through cross-relaxation of the 4F5/2 and 4F3/2 spin-orbit levels of Nd3+ makes it possible to tailor the thermometric performance of Nd3+ to enable physiological temperature sensing.
T2  - Nanomaterials
T1  - Making Nd3+ a Sensitive Luminescent Thermometer for Physiological Temperatures—An Account of Pitfalls in Boltzmann Thermometry
VL  - 10
IS  - 3
SP  - 543
DO  - 10.3390/nano10030543
ER  - 
@article{
author = "Suta, Markus and Antić, Željka and Đorđević, Vesna R. and Kuzman, Sanja and Dramićanin, Miroslav and Meijerink, Andries",
year = "2020",
abstract = "Ratiometric luminescence thermometry employing luminescence within the biological transparency windows provides high potential for biothermal imaging. Nd3+ is a promising candidate for that purpose due to its intense radiative transitions within biological windows (BWs) I and II and the simultaneous efficient excitability within BW I. This makes Nd3+ almost unique among all lanthanides. Typically, emission from the two 4F3/2 crystal field levels is used for thermometry but the small ~100 cm−1 energy separation limits the sensitivity. A higher sensitivity for physiological temperatures is possible using the luminescence intensity ratio (LIR) of the emissive transitions from the 4F5/2 and 4F3/2 excited spin-orbit levels. Herein, we demonstrate and discuss various pitfalls that can occur in Boltzmann thermometry if this particular LIR is used for physiological temperature sensing. Both microcrystalline, dilute (0.1%) Nd3+-doped LaPO4 and LaPO4: x% Nd3+ (x = 2, 5, 10, 25, 100) nanocrystals serve as an illustrative example. Besides structural and optical characterization of those luminescent thermometers, the impact and consequences of the Nd3+ concentration on their luminescence and performance as Boltzmann-based thermometers are analyzed. For low Nd3+ concentrations, Boltzmann equilibrium starts just around 300 K. At higher Nd3+ concentrations, cross-relaxation processes enhance the decay rates of the 4F3/2 and 4F5/2 levels making the decay faster than the equilibration rates between the levels. It is shown that the onset of the useful temperature sensing range shifts to higher temperatures, even above ~ 450 K for Nd concentrations over 5%. A microscopic explanation for pitfalls in Boltzmann thermometry with Nd3+ is finally given and guidelines for the usability of this lanthanide ion in the field of physiological temperature sensing are elaborated. Insight in competition between thermal coupling through non-radiative transitions and population decay through cross-relaxation of the 4F5/2 and 4F3/2 spin-orbit levels of Nd3+ makes it possible to tailor the thermometric performance of Nd3+ to enable physiological temperature sensing.",
journal = "Nanomaterials",
title = "Making Nd3+ a Sensitive Luminescent Thermometer for Physiological Temperatures—An Account of Pitfalls in Boltzmann Thermometry",
volume = "10",
number = "3",
pages = "543",
doi = "10.3390/nano10030543"
}
Suta, M., Antić, Ž., Đorđević, V. R., Kuzman, S., Dramićanin, M.,& Meijerink, A.. (2020). Making Nd3+ a Sensitive Luminescent Thermometer for Physiological Temperatures—An Account of Pitfalls in Boltzmann Thermometry. in Nanomaterials, 10(3), 543.
https://doi.org/10.3390/nano10030543
Suta M, Antić Ž, Đorđević VR, Kuzman S, Dramićanin M, Meijerink A. Making Nd3+ a Sensitive Luminescent Thermometer for Physiological Temperatures—An Account of Pitfalls in Boltzmann Thermometry. in Nanomaterials. 2020;10(3):543.
doi:10.3390/nano10030543 .
Suta, Markus, Antić, Željka, Đorđević, Vesna R., Kuzman, Sanja, Dramićanin, Miroslav, Meijerink, Andries, "Making Nd3+ a Sensitive Luminescent Thermometer for Physiological Temperatures—An Account of Pitfalls in Boltzmann Thermometry" in Nanomaterials, 10, no. 3 (2020):543,
https://doi.org/10.3390/nano10030543 . .
5
91
46
84

Ratiometric temperature measurement using negative thermal quenching of intrinsic BiFeO3 semiconductor nanoparticles

Antić, Željka; Prashanthi, Kovur; Kuzman, Sanja; Periša, Jovana; Ristić, Zoran; Palkar, Vaijayanti R.; Dramićanin, Miroslav

(2020)

TY  - JOUR
AU  - Antić, Željka
AU  - Prashanthi, Kovur
AU  - Kuzman, Sanja
AU  - Periša, Jovana
AU  - Ristić, Zoran
AU  - Palkar, Vaijayanti R.
AU  - Dramićanin, Miroslav
PY  - 2020
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/8998
AB  - A strategy for optical nanothermometry using the negative thermal quenching behavior of intrinsic BiFeO3semiconductor nanoparticles has been reported here. X-ray diffraction measurement shows polycrystalline BiFeO3nanoparticles with a rhombohedral distorted perovskite structure. Transmission electron microscopy shows agglomerated crystalline nanoparticles around 20 nm in size. Photoluminescence measurements show that intensity of the defect level emission increases significantly with temperature, while the intensity of near band emission and other defect levels emissions show an opposite trend. The most important figures of merit for luminescence nanothermometry: the absolute (Sa) and the relative sensor sensitivity (Sr) and the temperature resolution (?Tm) were effectively resolved and calculated. The relative sensitivity and temperature resolution values are found to be 2.5% K-1and 0.2 K, respectively which are among the highest reported values observed so far for semiconductors.
T2  - RSC Advances
T1  - Ratiometric temperature measurement using negative thermal quenching of intrinsic BiFeO3 semiconductor nanoparticles
VL  - 10
IS  - 29
SP  - 16982
EP  - 16986
DO  - 10.1039/D0RA01896A
ER  - 
@article{
author = "Antić, Željka and Prashanthi, Kovur and Kuzman, Sanja and Periša, Jovana and Ristić, Zoran and Palkar, Vaijayanti R. and Dramićanin, Miroslav",
year = "2020",
abstract = "A strategy for optical nanothermometry using the negative thermal quenching behavior of intrinsic BiFeO3semiconductor nanoparticles has been reported here. X-ray diffraction measurement shows polycrystalline BiFeO3nanoparticles with a rhombohedral distorted perovskite structure. Transmission electron microscopy shows agglomerated crystalline nanoparticles around 20 nm in size. Photoluminescence measurements show that intensity of the defect level emission increases significantly with temperature, while the intensity of near band emission and other defect levels emissions show an opposite trend. The most important figures of merit for luminescence nanothermometry: the absolute (Sa) and the relative sensor sensitivity (Sr) and the temperature resolution (?Tm) were effectively resolved and calculated. The relative sensitivity and temperature resolution values are found to be 2.5% K-1and 0.2 K, respectively which are among the highest reported values observed so far for semiconductors.",
journal = "RSC Advances",
title = "Ratiometric temperature measurement using negative thermal quenching of intrinsic BiFeO3 semiconductor nanoparticles",
volume = "10",
number = "29",
pages = "16982-16986",
doi = "10.1039/D0RA01896A"
}
Antić, Ž., Prashanthi, K., Kuzman, S., Periša, J., Ristić, Z., Palkar, V. R.,& Dramićanin, M.. (2020). Ratiometric temperature measurement using negative thermal quenching of intrinsic BiFeO3 semiconductor nanoparticles. in RSC Advances, 10(29), 16982-16986.
https://doi.org/10.1039/D0RA01896A
Antić Ž, Prashanthi K, Kuzman S, Periša J, Ristić Z, Palkar VR, Dramićanin M. Ratiometric temperature measurement using negative thermal quenching of intrinsic BiFeO3 semiconductor nanoparticles. in RSC Advances. 2020;10(29):16982-16986.
doi:10.1039/D0RA01896A .
Antić, Željka, Prashanthi, Kovur, Kuzman, Sanja, Periša, Jovana, Ristić, Zoran, Palkar, Vaijayanti R., Dramićanin, Miroslav, "Ratiometric temperature measurement using negative thermal quenching of intrinsic BiFeO3 semiconductor nanoparticles" in RSC Advances, 10, no. 29 (2020):16982-16986,
https://doi.org/10.1039/D0RA01896A . .

Surface Plasmon Enhancement of Eu3+ Emission Intensity in LaPO4/Ag Nanoparticles

Kuzman, Sanja; Periša, Jovana; Đorđević, Vesna R.; Zeković, Ivana Lj.; Vukoje, Ivana D.; Antić, Željka; Dramićanin, Miroslav

(2020)

TY  - JOUR
AU  - Kuzman, Sanja
AU  - Periša, Jovana
AU  - Đorđević, Vesna R.
AU  - Zeković, Ivana Lj.
AU  - Vukoje, Ivana D.
AU  - Antić, Željka
AU  - Dramićanin, Miroslav
PY  - 2020
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/9098
AB  - A promising way to improve the performance of luminescent materials is to combine them with noble metal nanoparticles. Herein, a set of silver/europium-doped lanthanum orthophosphate (Ag/La0.95Eu0.05PO4) nanostructures with different concentrations of silver nanoparticles were prepared and investigated. The presented overlap between the strongest europium (Eu3+) excitation line and the broad silver nanoparticle surface plasmon resonance makes the combination prospective for coupling. X-ray powder diffraction confirmed the monoclinic monazite structure. The transmission electron microscopy revealed particles with a rod-like shape and ~4 aspect ratio. Photoluminescence spectra show characteristic Eu3+ ion red emission. One of the requirements for an enhanced luminescence effect is the precise control of the distance between the noble metal nanoparticles and the emitter ion. The distance is indirectly varied throughout the change of Ag nanoparticle concentration in the La0.95Eu0.05PO4 host. The emission intensity increases with the increase in Ag nanoparticles up to 0.6 mol %, after which the luminescence decreases due to the nanoparticles’ close packing and aggregation leading to the displacement of La0.95Eu0.05PO4 from the vicinity of the metal particles and reabsorption of the emitted light. The emission intensity of La0.95Eu0.05PO4 increases more than three times when the Eu3+ excitation is supported by the localized surface plasmon resonance in the Ag/La0.95Eu0.05PO4 nanostructures.
T2  - Materials
T1  - Surface Plasmon Enhancement of Eu3+ Emission Intensity in LaPO4/Ag Nanoparticles
VL  - 13
IS  - 14
SP  - 3071
DO  - 10.3390/ma13143071
ER  - 
@article{
author = "Kuzman, Sanja and Periša, Jovana and Đorđević, Vesna R. and Zeković, Ivana Lj. and Vukoje, Ivana D. and Antić, Željka and Dramićanin, Miroslav",
year = "2020",
abstract = "A promising way to improve the performance of luminescent materials is to combine them with noble metal nanoparticles. Herein, a set of silver/europium-doped lanthanum orthophosphate (Ag/La0.95Eu0.05PO4) nanostructures with different concentrations of silver nanoparticles were prepared and investigated. The presented overlap between the strongest europium (Eu3+) excitation line and the broad silver nanoparticle surface plasmon resonance makes the combination prospective for coupling. X-ray powder diffraction confirmed the monoclinic monazite structure. The transmission electron microscopy revealed particles with a rod-like shape and ~4 aspect ratio. Photoluminescence spectra show characteristic Eu3+ ion red emission. One of the requirements for an enhanced luminescence effect is the precise control of the distance between the noble metal nanoparticles and the emitter ion. The distance is indirectly varied throughout the change of Ag nanoparticle concentration in the La0.95Eu0.05PO4 host. The emission intensity increases with the increase in Ag nanoparticles up to 0.6 mol %, after which the luminescence decreases due to the nanoparticles’ close packing and aggregation leading to the displacement of La0.95Eu0.05PO4 from the vicinity of the metal particles and reabsorption of the emitted light. The emission intensity of La0.95Eu0.05PO4 increases more than three times when the Eu3+ excitation is supported by the localized surface plasmon resonance in the Ag/La0.95Eu0.05PO4 nanostructures.",
journal = "Materials",
title = "Surface Plasmon Enhancement of Eu3+ Emission Intensity in LaPO4/Ag Nanoparticles",
volume = "13",
number = "14",
pages = "3071",
doi = "10.3390/ma13143071"
}
Kuzman, S., Periša, J., Đorđević, V. R., Zeković, I. Lj., Vukoje, I. D., Antić, Ž.,& Dramićanin, M.. (2020). Surface Plasmon Enhancement of Eu3+ Emission Intensity in LaPO4/Ag Nanoparticles. in Materials, 13(14), 3071.
https://doi.org/10.3390/ma13143071
Kuzman S, Periša J, Đorđević VR, Zeković IL, Vukoje ID, Antić Ž, Dramićanin M. Surface Plasmon Enhancement of Eu3+ Emission Intensity in LaPO4/Ag Nanoparticles. in Materials. 2020;13(14):3071.
doi:10.3390/ma13143071 .
Kuzman, Sanja, Periša, Jovana, Đorđević, Vesna R., Zeković, Ivana Lj., Vukoje, Ivana D., Antić, Željka, Dramićanin, Miroslav, "Surface Plasmon Enhancement of Eu3+ Emission Intensity in LaPO4/Ag Nanoparticles" in Materials, 13, no. 14 (2020):3071,
https://doi.org/10.3390/ma13143071 . .
3
3
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4

Structural and Luminescent Properties of Y2Mo4O15:Eu3+ Red Phosphor Calcined at Different Temperatures

Papan, Jelena; Ristić, Zoran; Ćirić, Aleksandar; Kuzman, Sanja; Dramićanin, Miroslav

(2020)

TY  - JOUR
AU  - Papan, Jelena
AU  - Ristić, Zoran
AU  - Ćirić, Aleksandar
AU  - Kuzman, Sanja
AU  - Dramićanin, Miroslav
PY  - 2020
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/8901
AB  - The red phosphor Y2Mo4O15:Eu3+ calcined at different temperatures is obtained by a solid-state method, and is investigated in this article. Usage of solid-state method with the combination of five different calcination temperatures (500, 550, 600, 650, and 700 °C) leads to the formation of pure monoclinic phase in all samples apart from the one calcined at the lowest temperature. Crystallite size obtained by Rietveld refinement is in the range of 38–55 nm. Scanning electron microscopy analysis confirms the presence of agglomerates. Luminescence emission spectra and emission decay curves are measured for all pure samples, and parameters derived from these measurements are used for Judd–Ofelt analysis. International commission on illumination (CIE) chromaticity diagram confirms the presence of pure red emission and high quantum efficiency. © 2019 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
T2  - Physica Status Solidi. B: Basic Research
T1  - Structural and Luminescent Properties of Y2Mo4O15:Eu3+ Red Phosphor Calcined at Different Temperatures
VL  - 257
IS  - 8
SP  - 1900454
DO  - 10.1002/pssb.201900454
ER  - 
@article{
author = "Papan, Jelena and Ristić, Zoran and Ćirić, Aleksandar and Kuzman, Sanja and Dramićanin, Miroslav",
year = "2020",
abstract = "The red phosphor Y2Mo4O15:Eu3+ calcined at different temperatures is obtained by a solid-state method, and is investigated in this article. Usage of solid-state method with the combination of five different calcination temperatures (500, 550, 600, 650, and 700 °C) leads to the formation of pure monoclinic phase in all samples apart from the one calcined at the lowest temperature. Crystallite size obtained by Rietveld refinement is in the range of 38–55 nm. Scanning electron microscopy analysis confirms the presence of agglomerates. Luminescence emission spectra and emission decay curves are measured for all pure samples, and parameters derived from these measurements are used for Judd–Ofelt analysis. International commission on illumination (CIE) chromaticity diagram confirms the presence of pure red emission and high quantum efficiency. © 2019 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim",
journal = "Physica Status Solidi. B: Basic Research",
title = "Structural and Luminescent Properties of Y2Mo4O15:Eu3+ Red Phosphor Calcined at Different Temperatures",
volume = "257",
number = "8",
pages = "1900454",
doi = "10.1002/pssb.201900454"
}
Papan, J., Ristić, Z., Ćirić, A., Kuzman, S.,& Dramićanin, M.. (2020). Structural and Luminescent Properties of Y2Mo4O15:Eu3+ Red Phosphor Calcined at Different Temperatures. in Physica Status Solidi. B: Basic Research, 257(8), 1900454.
https://doi.org/10.1002/pssb.201900454
Papan J, Ristić Z, Ćirić A, Kuzman S, Dramićanin M. Structural and Luminescent Properties of Y2Mo4O15:Eu3+ Red Phosphor Calcined at Different Temperatures. in Physica Status Solidi. B: Basic Research. 2020;257(8):1900454.
doi:10.1002/pssb.201900454 .
Papan, Jelena, Ristić, Zoran, Ćirić, Aleksandar, Kuzman, Sanja, Dramićanin, Miroslav, "Structural and Luminescent Properties of Y2Mo4O15:Eu3+ Red Phosphor Calcined at Different Temperatures" in Physica Status Solidi. B: Basic Research, 257, no. 8 (2020):1900454,
https://doi.org/10.1002/pssb.201900454 . .
2
2
2

Luminescence Thermometry Using Dy3+-Activated Na0.25K0.25Bi0.5TiO3 Powders

Kuzman, Sanja; Medić, Mina M.; Đorđević, Vesna R.; Zeković, Ivana Lj.; Ristić, Zoran; Đačanin Far, Ljubica; Dramićanin, Miroslav

(2020)

TY  - JOUR
AU  - Kuzman, Sanja
AU  - Medić, Mina M.
AU  - Đorđević, Vesna R.
AU  - Zeković, Ivana Lj.
AU  - Ristić, Zoran
AU  - Đačanin Far, Ljubica
AU  - Dramićanin, Miroslav
PY  - 2020
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/8936
AB  - When activated by Dy3+, Na0.25K0.25Bi0.50TiO3 (NKBT), piezoelectric powders show strong luminescence in the blue and yellow spectral range. Emissions of this material can be effectively utilized for both luminescence intensity ratio and lifetime-based readouts of temperature. Photoluminescence measurements over a temperature range of 293–483 K show that the luminescence intensity ratio temperature readout has maximal relative sensitivity of 1.93% K−1 at 380 K, while the relative sensitivity of the lifetime temperature readout reaches 1.1% K−1 at 480 K. For this study, materials were synthesized by a solid-state reaction using TiO2, Bi2O3, Na2CO3, K2CO3 and Dy2O3 as precursors. X-ray diffraction measurements showed that the NKBT sample crystallized in the A-site substituted distorted perovskite rhombohedral structure (R3c symmetry). The photoluminescence spectra showed characteristic emission bands of Dy3+ ions centered at 457 nm (4I15/2 → 6H15/2), 478 nm (4F9/2 → 6H15/2), 574 nm (4F9/2 → 6H13/2) and 663 nm (4F9/2 → 6H11/2). The ratio of emissions from 4F9/2 and 4I15/2 excited states to the 6H15/2 ground state was used as a luminescence intensity ratio indicator of temperature, while the decay of emission from 4F9/2 → 6H13/2 transition was used as a lifetime indicator of temperature. CIE coordinates x = 0.326 and y = 0.361 calculated from room temperature emission spectra show the perspective of this material for use in white light emission devices.
T2  - Journal of Electronic Materials
T1  - Luminescence Thermometry Using Dy3+-Activated Na0.25K0.25Bi0.5TiO3 Powders
VL  - 49
IS  - 6
SP  - 4002
EP  - 4009
DO  - 10.1007/s11664-020-08109-7
ER  - 
@article{
author = "Kuzman, Sanja and Medić, Mina M. and Đorđević, Vesna R. and Zeković, Ivana Lj. and Ristić, Zoran and Đačanin Far, Ljubica and Dramićanin, Miroslav",
year = "2020",
abstract = "When activated by Dy3+, Na0.25K0.25Bi0.50TiO3 (NKBT), piezoelectric powders show strong luminescence in the blue and yellow spectral range. Emissions of this material can be effectively utilized for both luminescence intensity ratio and lifetime-based readouts of temperature. Photoluminescence measurements over a temperature range of 293–483 K show that the luminescence intensity ratio temperature readout has maximal relative sensitivity of 1.93% K−1 at 380 K, while the relative sensitivity of the lifetime temperature readout reaches 1.1% K−1 at 480 K. For this study, materials were synthesized by a solid-state reaction using TiO2, Bi2O3, Na2CO3, K2CO3 and Dy2O3 as precursors. X-ray diffraction measurements showed that the NKBT sample crystallized in the A-site substituted distorted perovskite rhombohedral structure (R3c symmetry). The photoluminescence spectra showed characteristic emission bands of Dy3+ ions centered at 457 nm (4I15/2 → 6H15/2), 478 nm (4F9/2 → 6H15/2), 574 nm (4F9/2 → 6H13/2) and 663 nm (4F9/2 → 6H11/2). The ratio of emissions from 4F9/2 and 4I15/2 excited states to the 6H15/2 ground state was used as a luminescence intensity ratio indicator of temperature, while the decay of emission from 4F9/2 → 6H13/2 transition was used as a lifetime indicator of temperature. CIE coordinates x = 0.326 and y = 0.361 calculated from room temperature emission spectra show the perspective of this material for use in white light emission devices.",
journal = "Journal of Electronic Materials",
title = "Luminescence Thermometry Using Dy3+-Activated Na0.25K0.25Bi0.5TiO3 Powders",
volume = "49",
number = "6",
pages = "4002-4009",
doi = "10.1007/s11664-020-08109-7"
}
Kuzman, S., Medić, M. M., Đorđević, V. R., Zeković, I. Lj., Ristić, Z., Đačanin Far, L.,& Dramićanin, M.. (2020). Luminescence Thermometry Using Dy3+-Activated Na0.25K0.25Bi0.5TiO3 Powders. in Journal of Electronic Materials, 49(6), 4002-4009.
https://doi.org/10.1007/s11664-020-08109-7
Kuzman S, Medić MM, Đorđević VR, Zeković IL, Ristić Z, Đačanin Far L, Dramićanin M. Luminescence Thermometry Using Dy3+-Activated Na0.25K0.25Bi0.5TiO3 Powders. in Journal of Electronic Materials. 2020;49(6):4002-4009.
doi:10.1007/s11664-020-08109-7 .
Kuzman, Sanja, Medić, Mina M., Đorđević, Vesna R., Zeković, Ivana Lj., Ristić, Zoran, Đačanin Far, Ljubica, Dramićanin, Miroslav, "Luminescence Thermometry Using Dy3+-Activated Na0.25K0.25Bi0.5TiO3 Powders" in Journal of Electronic Materials, 49, no. 6 (2020):4002-4009,
https://doi.org/10.1007/s11664-020-08109-7 . .
4
1
4

Non-isothermal crystallization kinetics of the heavy-group lanthanide dititanates

Milićević, Bojana R.; Kuzman, Sanja; Porobić, Slavica; Marinović-Cincović, Milena; Dramićanin, Miroslav

(2017)

TY  - JOUR
AU  - Milićević, Bojana R.
AU  - Kuzman, Sanja
AU  - Porobić, Slavica
AU  - Marinović-Cincović, Milena
AU  - Dramićanin, Miroslav
PY  - 2017
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/7198
AB  - The systematic investigation of crystallization kinetics of heavy-group lanthanide dititanate pyrochlores, HL2Ti2O7 (HL=Lu, Tm, Er, Ho, Y, Dy, and Tb) is presented. Materials are prepared by the Pechini-type polymerized complex route, and their thermal properties were studied by differential thermal analysis under non-isothermal conditions. For this group, the crystallization temperature became larger with increasing the ionic radius of lanthanides, from 1066 K for Lu2Ti2O7 to 1125 K for Tb2Ti2O7. The linear dependence of crystallization temperature on radius of heavy lanthanide ions is found to follows T-c [K] = 168.86 + 920.89 x r(ion) [angstrom] semi-empirical equation. Apparent activation energies of crystallization were obtained from calculations based on the Arrhenius equation, isoconversional method and PerezMaqueda method, and are similar to 805 kJ mol(-1) calculated by three different methods. The crystallization kinetics followed the so-called Avrami Erofeev (A3) model, as confirmed using several criteria, namely, the Malek, master plot, and Perez-Maqueda methods. The crystallization mechanism of all lanthanide dititanate pyrochlores is found to be the same, and the crystallization process involves a constant rate of nucleation and two-dimensional growth of nuclei. (C) 2017 Elsevier B.V. All rights reserved.
T2  - Optical Materials
T1  - Non-isothermal crystallization kinetics of the heavy-group lanthanide dititanates
VL  - 74
SP  - 86
EP  - 92
DO  - 10.1016/j.optmat.2017.03.058
ER  - 
@article{
author = "Milićević, Bojana R. and Kuzman, Sanja and Porobić, Slavica and Marinović-Cincović, Milena and Dramićanin, Miroslav",
year = "2017",
abstract = "The systematic investigation of crystallization kinetics of heavy-group lanthanide dititanate pyrochlores, HL2Ti2O7 (HL=Lu, Tm, Er, Ho, Y, Dy, and Tb) is presented. Materials are prepared by the Pechini-type polymerized complex route, and their thermal properties were studied by differential thermal analysis under non-isothermal conditions. For this group, the crystallization temperature became larger with increasing the ionic radius of lanthanides, from 1066 K for Lu2Ti2O7 to 1125 K for Tb2Ti2O7. The linear dependence of crystallization temperature on radius of heavy lanthanide ions is found to follows T-c [K] = 168.86 + 920.89 x r(ion) [angstrom] semi-empirical equation. Apparent activation energies of crystallization were obtained from calculations based on the Arrhenius equation, isoconversional method and PerezMaqueda method, and are similar to 805 kJ mol(-1) calculated by three different methods. The crystallization kinetics followed the so-called Avrami Erofeev (A3) model, as confirmed using several criteria, namely, the Malek, master plot, and Perez-Maqueda methods. The crystallization mechanism of all lanthanide dititanate pyrochlores is found to be the same, and the crystallization process involves a constant rate of nucleation and two-dimensional growth of nuclei. (C) 2017 Elsevier B.V. All rights reserved.",
journal = "Optical Materials",
title = "Non-isothermal crystallization kinetics of the heavy-group lanthanide dititanates",
volume = "74",
pages = "86-92",
doi = "10.1016/j.optmat.2017.03.058"
}
Milićević, B. R., Kuzman, S., Porobić, S., Marinović-Cincović, M.,& Dramićanin, M.. (2017). Non-isothermal crystallization kinetics of the heavy-group lanthanide dititanates. in Optical Materials, 74, 86-92.
https://doi.org/10.1016/j.optmat.2017.03.058
Milićević BR, Kuzman S, Porobić S, Marinović-Cincović M, Dramićanin M. Non-isothermal crystallization kinetics of the heavy-group lanthanide dititanates. in Optical Materials. 2017;74:86-92.
doi:10.1016/j.optmat.2017.03.058 .
Milićević, Bojana R., Kuzman, Sanja, Porobić, Slavica, Marinović-Cincović, Milena, Dramićanin, Miroslav, "Non-isothermal crystallization kinetics of the heavy-group lanthanide dititanates" in Optical Materials, 74 (2017):86-92,
https://doi.org/10.1016/j.optmat.2017.03.058 . .
7
4
8

White- and blue-light-emitting dysprosium(III) and terbium(III)-doped gadolinium titanate phosphors

Antić, Željka; Kuzman, Sanja; Đorđević, Vesna R.; Dramićanin, Miroslav; Thundat, Thomas

(2017)

TY  - JOUR
AU  - Antić, Željka
AU  - Kuzman, Sanja
AU  - Đorđević, Vesna R.
AU  - Dramićanin, Miroslav
AU  - Thundat, Thomas
PY  - 2017
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/1571
AB  - Here we report the synthesis and structural, morphological, and photoluminescence analysis of white- and blue-light-emitting Dy3+- and Tm3+-doped Gd2Ti2O7 nanophosphors. Single-phase cubic Gd2Ti2O7 nanopowders consist of compact, dense aggregates of nanoparticles with an average size of similar to 25 nm for Dy3+-doped and similar to 50 nm for Tm3+-doped samples. The photoluminescence results indicated that ultraviolet (UV) light excitation of the Dy3+-doped sample resulted in direct generation of white light, while a dominant yellow emission was obtained under blue-light excitation. Intense blue light was obtained for Tm3+-doped Gd2Ti2O7 under UV excitation suggesting that this material could be used as a blue phosphor.
T2  - Luminescence
T1  - White- and blue-light-emitting dysprosium(III) and terbium(III)-doped gadolinium titanate phosphors
VL  - 32
IS  - 4
SP  - 539
EP  - 544
DO  - 10.1002/bio.3210
ER  - 
@article{
author = "Antić, Željka and Kuzman, Sanja and Đorđević, Vesna R. and Dramićanin, Miroslav and Thundat, Thomas",
year = "2017",
abstract = "Here we report the synthesis and structural, morphological, and photoluminescence analysis of white- and blue-light-emitting Dy3+- and Tm3+-doped Gd2Ti2O7 nanophosphors. Single-phase cubic Gd2Ti2O7 nanopowders consist of compact, dense aggregates of nanoparticles with an average size of similar to 25 nm for Dy3+-doped and similar to 50 nm for Tm3+-doped samples. The photoluminescence results indicated that ultraviolet (UV) light excitation of the Dy3+-doped sample resulted in direct generation of white light, while a dominant yellow emission was obtained under blue-light excitation. Intense blue light was obtained for Tm3+-doped Gd2Ti2O7 under UV excitation suggesting that this material could be used as a blue phosphor.",
journal = "Luminescence",
title = "White- and blue-light-emitting dysprosium(III) and terbium(III)-doped gadolinium titanate phosphors",
volume = "32",
number = "4",
pages = "539-544",
doi = "10.1002/bio.3210"
}
Antić, Ž., Kuzman, S., Đorđević, V. R., Dramićanin, M.,& Thundat, T.. (2017). White- and blue-light-emitting dysprosium(III) and terbium(III)-doped gadolinium titanate phosphors. in Luminescence, 32(4), 539-544.
https://doi.org/10.1002/bio.3210
Antić Ž, Kuzman S, Đorđević VR, Dramićanin M, Thundat T. White- and blue-light-emitting dysprosium(III) and terbium(III)-doped gadolinium titanate phosphors. in Luminescence. 2017;32(4):539-544.
doi:10.1002/bio.3210 .
Antić, Željka, Kuzman, Sanja, Đorđević, Vesna R., Dramićanin, Miroslav, Thundat, Thomas, "White- and blue-light-emitting dysprosium(III) and terbium(III)-doped gadolinium titanate phosphors" in Luminescence, 32, no. 4 (2017):539-544,
https://doi.org/10.1002/bio.3210 . .
4
3
4

Contactless Temperature Sensing via Luminescence

Dramićanin, Miroslav; Antić, Željka; Kuzman, Sanja; Thundat, Thomas

(2016)

TY  - CONF
AU  - Dramićanin, Miroslav
AU  - Antić, Željka
AU  - Kuzman, Sanja
AU  - Thundat, Thomas
PY  - 2016
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/7134
T1  - Contactless Temperature Sensing via Luminescence
UR  - https://hdl.handle.net/21.15107/rcub_vinar_7134
ER  - 
@conference{
author = "Dramićanin, Miroslav and Antić, Željka and Kuzman, Sanja and Thundat, Thomas",
year = "2016",
title = "Contactless Temperature Sensing via Luminescence",
url = "https://hdl.handle.net/21.15107/rcub_vinar_7134"
}
Dramićanin, M., Antić, Ž., Kuzman, S.,& Thundat, T.. (2016). Contactless Temperature Sensing via Luminescence. .
https://hdl.handle.net/21.15107/rcub_vinar_7134
Dramićanin M, Antić Ž, Kuzman S, Thundat T. Contactless Temperature Sensing via Luminescence. 2016;.
https://hdl.handle.net/21.15107/rcub_vinar_7134 .
Dramićanin, Miroslav, Antić, Željka, Kuzman, Sanja, Thundat, Thomas, "Contactless Temperature Sensing via Luminescence" (2016),
https://hdl.handle.net/21.15107/rcub_vinar_7134 .

Ratiometric luminescence thermometry with different combinations of emissions from Eu3+ doped Gd2Ti2O7 nanoparticles

Lojpur, Vesna; Ćulubrk, Sanja; Dramićanin, Miroslav

(2016)

TY  - JOUR
AU  - Lojpur, Vesna
AU  - Ćulubrk, Sanja
AU  - Dramićanin, Miroslav
PY  - 2016
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/7086
AB  - Herein, Eu3+ doped Gd2Ti2O7 nanoparticles were tested for application in ratiometric luminescence thermometry. It is shown that two combinations of emissions: one that uses two emissions of Eu3+ ions and one that uses one emission of Eu3+ ions and trap emission of Gd2Ti2O7 provide thermometry over the 303-423 K temperature range with relative sensitivities between 0.14% K-1 and 0.95% K-1. Thermometry based on two Eu3+ emissions from D-5(0) to D-5(1) levels has a higher relative sensitivity, but lower absolute sensitivity than thermometry based on one Eu3+ emission and trap emission of Gd2Ti2O7. The tested material is prepared by Pechini-type polymerized complex route and is composed of agglomerated nanoparticles of similar to 30-50 nm in size with pure-phase cubic structure (space group Fd-3m) as evidenced from electron microscopy and X-ray diffraction measurements. (C) 2015 Elsevier B.V. All rights reserved.
T2  - Journal of Luminescence
T1  - Ratiometric luminescence thermometry with different combinations of emissions from Eu3+ doped Gd2Ti2O7 nanoparticles
VL  - 169
SP  - 534
EP  - 538
DO  - 10.1016/j.jlumin.2015.01.027
ER  - 
@article{
author = "Lojpur, Vesna and Ćulubrk, Sanja and Dramićanin, Miroslav",
year = "2016",
abstract = "Herein, Eu3+ doped Gd2Ti2O7 nanoparticles were tested for application in ratiometric luminescence thermometry. It is shown that two combinations of emissions: one that uses two emissions of Eu3+ ions and one that uses one emission of Eu3+ ions and trap emission of Gd2Ti2O7 provide thermometry over the 303-423 K temperature range with relative sensitivities between 0.14% K-1 and 0.95% K-1. Thermometry based on two Eu3+ emissions from D-5(0) to D-5(1) levels has a higher relative sensitivity, but lower absolute sensitivity than thermometry based on one Eu3+ emission and trap emission of Gd2Ti2O7. The tested material is prepared by Pechini-type polymerized complex route and is composed of agglomerated nanoparticles of similar to 30-50 nm in size with pure-phase cubic structure (space group Fd-3m) as evidenced from electron microscopy and X-ray diffraction measurements. (C) 2015 Elsevier B.V. All rights reserved.",
journal = "Journal of Luminescence",
title = "Ratiometric luminescence thermometry with different combinations of emissions from Eu3+ doped Gd2Ti2O7 nanoparticles",
volume = "169",
pages = "534-538",
doi = "10.1016/j.jlumin.2015.01.027"
}
Lojpur, V., Ćulubrk, S.,& Dramićanin, M.. (2016). Ratiometric luminescence thermometry with different combinations of emissions from Eu3+ doped Gd2Ti2O7 nanoparticles. in Journal of Luminescence, 169, 534-538.
https://doi.org/10.1016/j.jlumin.2015.01.027
Lojpur V, Ćulubrk S, Dramićanin M. Ratiometric luminescence thermometry with different combinations of emissions from Eu3+ doped Gd2Ti2O7 nanoparticles. in Journal of Luminescence. 2016;169:534-538.
doi:10.1016/j.jlumin.2015.01.027 .
Lojpur, Vesna, Ćulubrk, Sanja, Dramićanin, Miroslav, "Ratiometric luminescence thermometry with different combinations of emissions from Eu3+ doped Gd2Ti2O7 nanoparticles" in Journal of Luminescence, 169 (2016):534-538,
https://doi.org/10.1016/j.jlumin.2015.01.027 . .
57
42
55

Luminescence thermometry with Eu3+ doped GdAlO3

Lojpur, Vesna; Ćulubrk, Sanja; Medić, Mina M.; Dramićanin, Miroslav

(Elsevier, 2016)

TY  - JOUR
AU  - Lojpur, Vesna
AU  - Ćulubrk, Sanja
AU  - Medić, Mina M.
AU  - Dramićanin, Miroslav
PY  - 2016
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/878
AB  - Eu3+ doped GdAlO3 powder synthesized by solid state reaction was investigated for application in luminescence thermometry. Phase composition of material was confirmed by X-ray powder diffraction analysis. The photoluminescence emission spectra were collected under excitation of 399 rim, while elevating the temperature of the sample from the room temperature to 793 K. Emissions from D-5(1) - GT F-7(1) and D-5(0) - GT F-7(2) characteristic transitions of Eu3+ ions are selected for the temperature-dependence study using the fluorescence intensity ratio method. Emission decay curves measured at the strongest emission peak centered at 614 nm were recorded in a same temperature range. Data analysis showed that thermometry by fluorescence intensity ratio method can be used over the temperature region 293-793 K with the maximal relative sensitivity of 2.96% K-1 (at 293 K). Temporal dependence of emission (lifetime) provides temperature sensing from 620 to 793 K with the maximal relative sensitivity of 2.28% K-1. (C) 2015 Elsevier B.V. All rights reserved.
PB  - Elsevier
T2  - Journal of Luminescence
T1  - Luminescence thermometry with Eu3+ doped GdAlO3
VL  - 170
IS  - SI
SP  - 467
EP  - 471
DO  - 10.1016/j.jlumin.2015.06.032
ER  - 
@article{
author = "Lojpur, Vesna and Ćulubrk, Sanja and Medić, Mina M. and Dramićanin, Miroslav",
year = "2016",
abstract = "Eu3+ doped GdAlO3 powder synthesized by solid state reaction was investigated for application in luminescence thermometry. Phase composition of material was confirmed by X-ray powder diffraction analysis. The photoluminescence emission spectra were collected under excitation of 399 rim, while elevating the temperature of the sample from the room temperature to 793 K. Emissions from D-5(1) - GT F-7(1) and D-5(0) - GT F-7(2) characteristic transitions of Eu3+ ions are selected for the temperature-dependence study using the fluorescence intensity ratio method. Emission decay curves measured at the strongest emission peak centered at 614 nm were recorded in a same temperature range. Data analysis showed that thermometry by fluorescence intensity ratio method can be used over the temperature region 293-793 K with the maximal relative sensitivity of 2.96% K-1 (at 293 K). Temporal dependence of emission (lifetime) provides temperature sensing from 620 to 793 K with the maximal relative sensitivity of 2.28% K-1. (C) 2015 Elsevier B.V. All rights reserved.",
publisher = "Elsevier",
journal = "Journal of Luminescence",
title = "Luminescence thermometry with Eu3+ doped GdAlO3",
volume = "170",
number = "SI",
pages = "467-471",
doi = "10.1016/j.jlumin.2015.06.032"
}
Lojpur, V., Ćulubrk, S., Medić, M. M.,& Dramićanin, M.. (2016). Luminescence thermometry with Eu3+ doped GdAlO3. in Journal of Luminescence
Elsevier., 170(SI), 467-471.
https://doi.org/10.1016/j.jlumin.2015.06.032
Lojpur V, Ćulubrk S, Medić MM, Dramićanin M. Luminescence thermometry with Eu3+ doped GdAlO3. in Journal of Luminescence. 2016;170(SI):467-471.
doi:10.1016/j.jlumin.2015.06.032 .
Lojpur, Vesna, Ćulubrk, Sanja, Medić, Mina M., Dramićanin, Miroslav, "Luminescence thermometry with Eu3+ doped GdAlO3" in Journal of Luminescence, 170, no. SI (2016):467-471,
https://doi.org/10.1016/j.jlumin.2015.06.032 . .
57
39
55

Pulsed Laser Deposited Dysprosium-Doped Gadolinium-Vanadate Thin Films for Noncontact, Self-Referencing Luminescence Thermometry

Antić, Željka; Dramićanin, Miroslav; Prashanthi, Kovur; Jovanović, Dragana J.; Kuzman, Sanja; Thundat, Thomas

(2016)

TY  - JOUR
AU  - Antić, Željka
AU  - Dramićanin, Miroslav
AU  - Prashanthi, Kovur
AU  - Jovanović, Dragana J.
AU  - Kuzman, Sanja
AU  - Thundat, Thomas
PY  - 2016
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/1255
AB  - Lanthanide-doped vanadate thin films offer (i) a promising platform for luminescence-based noncontact temperature sensing; (ii) ratiometric/self-referencing absolute measurements; (iii) exceptional repeatability and reversibility for multirun uses and a long life cycle; (iv) 2% K-1 maximum temperature sensitivity (among the highest recorded for inorganic nanothermometers); (v) a temperature resolution greater than 0.5 K; and (vi) the potential for high-resolution 2D temperature mapping.
T2  - Advanced Materials
T1  - Pulsed Laser Deposited Dysprosium-Doped Gadolinium-Vanadate Thin Films for Noncontact, Self-Referencing Luminescence Thermometry
VL  - 28
IS  - 35
SP  - 7745
DO  - 10.1002/adma.201601176
ER  - 
@article{
author = "Antić, Željka and Dramićanin, Miroslav and Prashanthi, Kovur and Jovanović, Dragana J. and Kuzman, Sanja and Thundat, Thomas",
year = "2016",
abstract = "Lanthanide-doped vanadate thin films offer (i) a promising platform for luminescence-based noncontact temperature sensing; (ii) ratiometric/self-referencing absolute measurements; (iii) exceptional repeatability and reversibility for multirun uses and a long life cycle; (iv) 2% K-1 maximum temperature sensitivity (among the highest recorded for inorganic nanothermometers); (v) a temperature resolution greater than 0.5 K; and (vi) the potential for high-resolution 2D temperature mapping.",
journal = "Advanced Materials",
title = "Pulsed Laser Deposited Dysprosium-Doped Gadolinium-Vanadate Thin Films for Noncontact, Self-Referencing Luminescence Thermometry",
volume = "28",
number = "35",
pages = "7745",
doi = "10.1002/adma.201601176"
}
Antić, Ž., Dramićanin, M., Prashanthi, K., Jovanović, D. J., Kuzman, S.,& Thundat, T.. (2016). Pulsed Laser Deposited Dysprosium-Doped Gadolinium-Vanadate Thin Films for Noncontact, Self-Referencing Luminescence Thermometry. in Advanced Materials, 28(35), 7745.
https://doi.org/10.1002/adma.201601176
Antić Ž, Dramićanin M, Prashanthi K, Jovanović DJ, Kuzman S, Thundat T. Pulsed Laser Deposited Dysprosium-Doped Gadolinium-Vanadate Thin Films for Noncontact, Self-Referencing Luminescence Thermometry. in Advanced Materials. 2016;28(35):7745.
doi:10.1002/adma.201601176 .
Antić, Željka, Dramićanin, Miroslav, Prashanthi, Kovur, Jovanović, Dragana J., Kuzman, Sanja, Thundat, Thomas, "Pulsed Laser Deposited Dysprosium-Doped Gadolinium-Vanadate Thin Films for Noncontact, Self-Referencing Luminescence Thermometry" in Advanced Materials, 28, no. 35 (2016):7745,
https://doi.org/10.1002/adma.201601176 . .
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Effect of annealing conditions on structural and luminescencent properties of Eu3+-doped Gd2Ti2O7 thin films

Antić, Željka; Prashanthi, Kovur; Ćulubrk, Sanja; Vuković, Katarina; Dramićanin, Miroslav; Thundat, Thomas

(Elsevier, 2016)

TY  - JOUR
AU  - Antić, Željka
AU  - Prashanthi, Kovur
AU  - Ćulubrk, Sanja
AU  - Vuković, Katarina
AU  - Dramićanin, Miroslav
AU  - Thundat, Thomas
PY  - 2016
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/935
AB  - Here we report on preparation of Eu3+-doped Gd(2)Ti(2)O(7)pyrochlore luminescent thin films by pulsed laser deposition technique and their structural, morphological and optical characterization. The influence of annealing temperature and background gas (air vs. argon) on film photoluminescence is examined fort he optimization of post-deposition annealing conditions. As-deposited amorphous films become pure pyrochlore crystalline after calcination at temperatures higher than 1000 degrees C. Atomic force microscopy showed increase in the grain size from similar to 20 nm in the as-deposited to similar to 60 nm in the crystalline sample annealed at 1100 degrees C. Scanning electron microscopy showed dense films with the uniform thickness of about 700 nm. Luminescence spectra of crystalline films were complex and composed of better resolved emission lines than in the amorphous sample. Emission spectra showed that symmetry of Eu3+ sites become disturbed in annealed films due to the extrinsic thermal stress. Films treated in argon displayed similar emission and excitation spectral features like air-treated ones, but with better resolved emissionlines. Calculated quantum efficiency of emission showed that optimization of annealing conditions led to an enhancement of films luminescence. The highest quantum efficiency of emission and the longestlife time is found for the sample annealed at 1100 degrees C in presence of argon. Crown Copyright (C) 2015 Published by Elsevier B. V. All rights reserved.
PB  - Elsevier
T2  - Applied Surface Science
T1  - Effect of annealing conditions on structural and luminescencent properties of Eu3+-doped Gd2Ti2O7 thin films
VL  - 364
SP  - 273
EP  - 279
DO  - 10.1016/j.apsusc.2015.12.137
ER  - 
@article{
author = "Antić, Željka and Prashanthi, Kovur and Ćulubrk, Sanja and Vuković, Katarina and Dramićanin, Miroslav and Thundat, Thomas",
year = "2016",
abstract = "Here we report on preparation of Eu3+-doped Gd(2)Ti(2)O(7)pyrochlore luminescent thin films by pulsed laser deposition technique and their structural, morphological and optical characterization. The influence of annealing temperature and background gas (air vs. argon) on film photoluminescence is examined fort he optimization of post-deposition annealing conditions. As-deposited amorphous films become pure pyrochlore crystalline after calcination at temperatures higher than 1000 degrees C. Atomic force microscopy showed increase in the grain size from similar to 20 nm in the as-deposited to similar to 60 nm in the crystalline sample annealed at 1100 degrees C. Scanning electron microscopy showed dense films with the uniform thickness of about 700 nm. Luminescence spectra of crystalline films were complex and composed of better resolved emission lines than in the amorphous sample. Emission spectra showed that symmetry of Eu3+ sites become disturbed in annealed films due to the extrinsic thermal stress. Films treated in argon displayed similar emission and excitation spectral features like air-treated ones, but with better resolved emissionlines. Calculated quantum efficiency of emission showed that optimization of annealing conditions led to an enhancement of films luminescence. The highest quantum efficiency of emission and the longestlife time is found for the sample annealed at 1100 degrees C in presence of argon. Crown Copyright (C) 2015 Published by Elsevier B. V. All rights reserved.",
publisher = "Elsevier",
journal = "Applied Surface Science",
title = "Effect of annealing conditions on structural and luminescencent properties of Eu3+-doped Gd2Ti2O7 thin films",
volume = "364",
pages = "273-279",
doi = "10.1016/j.apsusc.2015.12.137"
}
Antić, Ž., Prashanthi, K., Ćulubrk, S., Vuković, K., Dramićanin, M.,& Thundat, T.. (2016). Effect of annealing conditions on structural and luminescencent properties of Eu3+-doped Gd2Ti2O7 thin films. in Applied Surface Science
Elsevier., 364, 273-279.
https://doi.org/10.1016/j.apsusc.2015.12.137
Antić Ž, Prashanthi K, Ćulubrk S, Vuković K, Dramićanin M, Thundat T. Effect of annealing conditions on structural and luminescencent properties of Eu3+-doped Gd2Ti2O7 thin films. in Applied Surface Science. 2016;364:273-279.
doi:10.1016/j.apsusc.2015.12.137 .
Antić, Željka, Prashanthi, Kovur, Ćulubrk, Sanja, Vuković, Katarina, Dramićanin, Miroslav, Thundat, Thomas, "Effect of annealing conditions on structural and luminescencent properties of Eu3+-doped Gd2Ti2O7 thin films" in Applied Surface Science, 364 (2016):273-279,
https://doi.org/10.1016/j.apsusc.2015.12.137 . .
10
6
10

Non-contact thermometry with Dy3+ doped Gd2Ti2O7 nano-powders

Ćulubrk, Sanja; Lojpur, Vesna; Ahrenkiel, Scott Phillip; Nedeljković, Jovan; Dramićanin, Miroslav

(Elsevier, 2016)

TY  - JOUR
AU  - Ćulubrk, Sanja
AU  - Lojpur, Vesna
AU  - Ahrenkiel, Scott Phillip
AU  - Nedeljković, Jovan
AU  - Dramićanin, Miroslav
PY  - 2016
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/877
AB  - The performance of Dy3+ doped Gd2Ti2O7 nano-powders for luminescence temperature sensing was tested over a temperature range from 293 to 443 K. The Dy3+ ions were incorporated into Gd2Ti2O7 nanocrystals using a hydrolytic sal-gel route. Microstructural characterization of the obtained material was performed using transmission electron microscopy and X-ray diffraction measurements. Luminescence spectra of Dy3+ doped Gd2Ti2O7 nano-powders consists of two distinct spectral regions: the highenergy region associated with the trap emission of the Gd2Ti2O7 host and the low-energy region with well-resolved emission peaks of the Dy3+ ions. The ratio between intensities of two Dy3+ emission lines, as well as the ratio between intensities of trap emission of host and Dy3+ emission show strong temperature dependence and are tested for temperature sensing. In both cases, ratiometric measurements provide comparable quality of temperature sensing, and when they are combined the relative sensor sensitivities were found to be higher than 0.9% K-1 over given temperature range. The fluorescence quenching of Dy3+ ions was discussed in terms of simple theoretical models. (C) 2015 Elsevier B.V. All rights reserved.
PB  - Elsevier
T2  - Journal of Luminescence
T1  - Non-contact thermometry with Dy3+ doped Gd2Ti2O7 nano-powders
VL  - 170
IS  - SI
SP  - 395
EP  - 400
DO  - 10.1016/j.jlumin.2015.06.006
ER  - 
@article{
author = "Ćulubrk, Sanja and Lojpur, Vesna and Ahrenkiel, Scott Phillip and Nedeljković, Jovan and Dramićanin, Miroslav",
year = "2016",
abstract = "The performance of Dy3+ doped Gd2Ti2O7 nano-powders for luminescence temperature sensing was tested over a temperature range from 293 to 443 K. The Dy3+ ions were incorporated into Gd2Ti2O7 nanocrystals using a hydrolytic sal-gel route. Microstructural characterization of the obtained material was performed using transmission electron microscopy and X-ray diffraction measurements. Luminescence spectra of Dy3+ doped Gd2Ti2O7 nano-powders consists of two distinct spectral regions: the highenergy region associated with the trap emission of the Gd2Ti2O7 host and the low-energy region with well-resolved emission peaks of the Dy3+ ions. The ratio between intensities of two Dy3+ emission lines, as well as the ratio between intensities of trap emission of host and Dy3+ emission show strong temperature dependence and are tested for temperature sensing. In both cases, ratiometric measurements provide comparable quality of temperature sensing, and when they are combined the relative sensor sensitivities were found to be higher than 0.9% K-1 over given temperature range. The fluorescence quenching of Dy3+ ions was discussed in terms of simple theoretical models. (C) 2015 Elsevier B.V. All rights reserved.",
publisher = "Elsevier",
journal = "Journal of Luminescence",
title = "Non-contact thermometry with Dy3+ doped Gd2Ti2O7 nano-powders",
volume = "170",
number = "SI",
pages = "395-400",
doi = "10.1016/j.jlumin.2015.06.006"
}
Ćulubrk, S., Lojpur, V., Ahrenkiel, S. P., Nedeljković, J.,& Dramićanin, M.. (2016). Non-contact thermometry with Dy3+ doped Gd2Ti2O7 nano-powders. in Journal of Luminescence
Elsevier., 170(SI), 395-400.
https://doi.org/10.1016/j.jlumin.2015.06.006
Ćulubrk S, Lojpur V, Ahrenkiel SP, Nedeljković J, Dramićanin M. Non-contact thermometry with Dy3+ doped Gd2Ti2O7 nano-powders. in Journal of Luminescence. 2016;170(SI):395-400.
doi:10.1016/j.jlumin.2015.06.006 .
Ćulubrk, Sanja, Lojpur, Vesna, Ahrenkiel, Scott Phillip, Nedeljković, Jovan, Dramićanin, Miroslav, "Non-contact thermometry with Dy3+ doped Gd2Ti2O7 nano-powders" in Journal of Luminescence, 170, no. SI (2016):395-400,
https://doi.org/10.1016/j.jlumin.2015.06.006 . .
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