Kasic, Vladan D.

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  • Kasic, Vladan D. (2)
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Author's Bibliography

Low-temperature Ni-As-Sb-S mineralization of the Pb(Ag)-Zn deposits within the Rogozna ore field, Serbo-Macedonian Metallogenic Province: Ore mineralogy, crystal chemistry and paragenetic relationships

Radosavljevic, Slobodan A.; Stojanovic, Jovica N.; Vuković, Nikola S.; Radosavljević-Mihajlović, Ana S.; Kasic, Vladan D.

(2015)

TY  - JOUR
AU  - Radosavljevic, Slobodan A.
AU  - Stojanovic, Jovica N.
AU  - Vuković, Nikola S.
AU  - Radosavljević-Mihajlović, Ana S.
AU  - Kasic, Vladan D.
PY  - 2015
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/363
AB  - The Rogozna ore field (ROF) belongs to the Serbo-Macedonian Metallogenic Province (SMMP), and covers a part of the western Dinarides rim and the Vardar ophiolite zone, situated within the Neogene volcanogenic-intrusive complex of calc-alkaline and shoshonitic rocks within the territories of Serbia and Kosovo. It is well-known for its Cu(Au, Pb, Zn) skarn mineralization and Pb(Ag)-Zn hydrothermal deposits and occurences. Mineral associations, deposition order and genesis of the ROF were discussed in detail. Complex ore parageneses were determined in the Crnac, Plalcaonica, and Kaludjer Pb(Ag)-Zn deposits and are composed of the following minerals: sulfides (pyrrhotite, chalcopyrrhotite, chalcopyrite, sphalerite, galena, pyrite, marcasite, millerite, bravoite), sulfosalts (arsenopolybasite, tetrahedrite, Ag-bearing tetrahedrite, Zn-bearing tetrahedrite, semseyite, heteromorphite, jamesonite, ferrokesterite), arsenides (nickeline), sulfarsenides and sulfantimonides (gersdorffite, Sb-bearing gersdorffite, Fe-bearing gersdorffite, As-bearing ullmannite, arsenopyrite), native metals (native Au, native Ag), oxides (Cr-spinel, rutile, anatase, leucoxene, magnetite, hematite) and gangue minerals (quartz, silicates, chalcedony, carbonates, monazite(Ce), barite, gypsum, anglesite, cerussite, smithsonite, zaratite, limonite). The high-, medium-, and low-temperature hydrothermal mineral assemblage occur throughout the Pb(Ag)-Zn deposits at Kaludjer-Crnac-Plakaonica ore system, in which the whole ore field as high- to medium-temperature hydrothermal formed at shallow to moderate depth. The following stages of ore mineral formation are recognized in the Pb-Zn mineral assemblage at the ROF: i) pre-ore; ii) high-temperature hydrothermal; iii) hypogene; iv) medium-temperature hydrothermal; v) low-temperature hydrothermal; and vi) supergene. Generally, there are two types of mineralization, brecciated ore veins with ribbon-like textures deposited in amphibolites or in contact with quarz latites, and impregnations within columnar ore bodies hosted in silicified and carbonated serpentinites (listwaenites). Ni-mineralization is represented by significant sulphide, arsenide, sulfarsenide, and sulfantimonide occurrences, but the most significant consists of gersdorffite-ullmannite series (GUS) minerals. It is the most developed in the Kaludjer deposit, much lesser at Plakaonica, whereas in the Crnac deposit it was not noted. The importance of the Ni mineralization is of scientific interest for now, as the attention has been directed only to the exploration of lead and zinc. However, it is believed that plans for the future will be focused on a detailed study of nickel. (C) 2014 Elsevier B.V. All rights reserved.
T2  - ORE Geology Reviews
T1  - Low-temperature Ni-As-Sb-S mineralization of the Pb(Ag)-Zn deposits within the Rogozna ore field, Serbo-Macedonian Metallogenic Province: Ore mineralogy, crystal chemistry and paragenetic relationships
VL  - 65
SP  - 213
EP  - 227
DO  - 10.1016/j.oregeorev.2014.09.029
ER  - 
@article{
author = "Radosavljevic, Slobodan A. and Stojanovic, Jovica N. and Vuković, Nikola S. and Radosavljević-Mihajlović, Ana S. and Kasic, Vladan D.",
year = "2015",
abstract = "The Rogozna ore field (ROF) belongs to the Serbo-Macedonian Metallogenic Province (SMMP), and covers a part of the western Dinarides rim and the Vardar ophiolite zone, situated within the Neogene volcanogenic-intrusive complex of calc-alkaline and shoshonitic rocks within the territories of Serbia and Kosovo. It is well-known for its Cu(Au, Pb, Zn) skarn mineralization and Pb(Ag)-Zn hydrothermal deposits and occurences. Mineral associations, deposition order and genesis of the ROF were discussed in detail. Complex ore parageneses were determined in the Crnac, Plalcaonica, and Kaludjer Pb(Ag)-Zn deposits and are composed of the following minerals: sulfides (pyrrhotite, chalcopyrrhotite, chalcopyrite, sphalerite, galena, pyrite, marcasite, millerite, bravoite), sulfosalts (arsenopolybasite, tetrahedrite, Ag-bearing tetrahedrite, Zn-bearing tetrahedrite, semseyite, heteromorphite, jamesonite, ferrokesterite), arsenides (nickeline), sulfarsenides and sulfantimonides (gersdorffite, Sb-bearing gersdorffite, Fe-bearing gersdorffite, As-bearing ullmannite, arsenopyrite), native metals (native Au, native Ag), oxides (Cr-spinel, rutile, anatase, leucoxene, magnetite, hematite) and gangue minerals (quartz, silicates, chalcedony, carbonates, monazite(Ce), barite, gypsum, anglesite, cerussite, smithsonite, zaratite, limonite). The high-, medium-, and low-temperature hydrothermal mineral assemblage occur throughout the Pb(Ag)-Zn deposits at Kaludjer-Crnac-Plakaonica ore system, in which the whole ore field as high- to medium-temperature hydrothermal formed at shallow to moderate depth. The following stages of ore mineral formation are recognized in the Pb-Zn mineral assemblage at the ROF: i) pre-ore; ii) high-temperature hydrothermal; iii) hypogene; iv) medium-temperature hydrothermal; v) low-temperature hydrothermal; and vi) supergene. Generally, there are two types of mineralization, brecciated ore veins with ribbon-like textures deposited in amphibolites or in contact with quarz latites, and impregnations within columnar ore bodies hosted in silicified and carbonated serpentinites (listwaenites). Ni-mineralization is represented by significant sulphide, arsenide, sulfarsenide, and sulfantimonide occurrences, but the most significant consists of gersdorffite-ullmannite series (GUS) minerals. It is the most developed in the Kaludjer deposit, much lesser at Plakaonica, whereas in the Crnac deposit it was not noted. The importance of the Ni mineralization is of scientific interest for now, as the attention has been directed only to the exploration of lead and zinc. However, it is believed that plans for the future will be focused on a detailed study of nickel. (C) 2014 Elsevier B.V. All rights reserved.",
journal = "ORE Geology Reviews",
title = "Low-temperature Ni-As-Sb-S mineralization of the Pb(Ag)-Zn deposits within the Rogozna ore field, Serbo-Macedonian Metallogenic Province: Ore mineralogy, crystal chemistry and paragenetic relationships",
volume = "65",
pages = "213-227",
doi = "10.1016/j.oregeorev.2014.09.029"
}
Radosavljevic, S. A., Stojanovic, J. N., Vuković, N. S., Radosavljević-Mihajlović, A. S.,& Kasic, V. D.. (2015). Low-temperature Ni-As-Sb-S mineralization of the Pb(Ag)-Zn deposits within the Rogozna ore field, Serbo-Macedonian Metallogenic Province: Ore mineralogy, crystal chemistry and paragenetic relationships. in ORE Geology Reviews, 65, 213-227.
https://doi.org/10.1016/j.oregeorev.2014.09.029
Radosavljevic SA, Stojanovic JN, Vuković NS, Radosavljević-Mihajlović AS, Kasic VD. Low-temperature Ni-As-Sb-S mineralization of the Pb(Ag)-Zn deposits within the Rogozna ore field, Serbo-Macedonian Metallogenic Province: Ore mineralogy, crystal chemistry and paragenetic relationships. in ORE Geology Reviews. 2015;65:213-227.
doi:10.1016/j.oregeorev.2014.09.029 .
Radosavljevic, Slobodan A., Stojanovic, Jovica N., Vuković, Nikola S., Radosavljević-Mihajlović, Ana S., Kasic, Vladan D., "Low-temperature Ni-As-Sb-S mineralization of the Pb(Ag)-Zn deposits within the Rogozna ore field, Serbo-Macedonian Metallogenic Province: Ore mineralogy, crystal chemistry and paragenetic relationships" in ORE Geology Reviews, 65 (2015):213-227,
https://doi.org/10.1016/j.oregeorev.2014.09.029 . .
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Polymetallic mineralization of the Boranja orefield, Podrinje Metallogenic District, Serbia: zonality, mineral associations and genetic features

Radosavljevic, Slobodan A.; Stojanovic, Jovica N.; Radosavljević-Mihajlović, Ana S.; Kasic, Vladan D.

(2013)

TY  - JOUR
AU  - Radosavljevic, Slobodan A.
AU  - Stojanovic, Jovica N.
AU  - Radosavljević-Mihajlović, Ana S.
AU  - Kasic, Vladan D.
PY  - 2013
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/5500
AB  - The Serbo-Macedonian Metallogenetic Province, part of the Alpine metallogenic belt, hosts several ore deposits in mainly three geotectonic units: the Vardar Zone, the Serbo-Macedonian massif, and to a lesser extend the Dinarides. This metallogenic province includes the most significant Pb-Zn and Sb deposits in Serbia, as well as smaller Bi, Mo, Cu, Fe, Sn, Au and minor U, Wand Hg deposits, which are genetically related to emplacement of granitoids. The Podrinje Metallogenic District belongs to the Serbo-Macedonian Metallogenetic Province and incorporates several smaller orefields: Cer (Northwest Serbia), Boranja (West Serbia), and Srebrenica (East Bosnia and Herzegovina). Polymetallic deposits in the Boranja orefield are genetically related to the emplacement of the Tertiary Boranja granodiorite complex. The orefield contains a large number of sulfide deposits with Pb-Zn, and Sb with subordinate Cu, As, Bi and Ag. Small magnetite deposits connected to pyrometasomatic (skarn) stage are also significant. Skarns are of calcic type, and were formed along contacts of Triassic limestones and quartz diorites. Ore minerals are similar among the various types of orebodies in the Boranja orefield and consist of sulfides, sulfosalts [Pb-Bi-(Ag)-Te-Cu, Pb-Sb-(As), Sb-Cu-(Ag, Fe, Zn)], tellurides, native metals and alloys, oxides and complex-oxides, and gangue minerals. Minerals of the Boranja orefield were formed in several successive stages, which together correspond to a single regional-scale mineralization event that is genetically related to the subvulcanic-plutonic intrusion of the Neogene-aged magmatic Boranja complex. This can be best demonstrated by the zonal arrangement of several metallic mineral associations [Fe-Cu(Bi) - GT Pb(Ag)-Zn - GT Sb(As) - GT CaF2(Pb-Zn)], with increasing distance from the Boranja granodiorite. Silver occurs as a minor metal principally as Ag-tetrahedrite, with subordinate native silver, Ag-bearing gold and pyrargyrite. Significant quantities of Ag can also be accommodated in galena as it is found to contain varied amounts of Ag, Bi and Sb (0.001-0.936, 0-3.345, and 0.012-0.510 wt%, respectively). The presence of both Ag and Bi in significant amounts in a Pb-rich sulfide system is essential for development of galena [solid solution alpha-(Pb-2, AgSb, AgBi)S-2]. This study demonstrates that silver, the most economic metal in Boranja orefield, is mainly accommodated in the galena structure, with lesser amounts present in the form of visible and/or invisible Pb-Bi-(Ag) sulfosalts.
T2  - Periodico di Mineralogia
T1  - Polymetallic mineralization of the Boranja orefield, Podrinje Metallogenic District, Serbia: zonality, mineral associations and genetic features
VL  - 82
IS  - 1
SP  - 61
EP  - 87
DO  - 10.2451/2013PM0004
ER  - 
@article{
author = "Radosavljevic, Slobodan A. and Stojanovic, Jovica N. and Radosavljević-Mihajlović, Ana S. and Kasic, Vladan D.",
year = "2013",
abstract = "The Serbo-Macedonian Metallogenetic Province, part of the Alpine metallogenic belt, hosts several ore deposits in mainly three geotectonic units: the Vardar Zone, the Serbo-Macedonian massif, and to a lesser extend the Dinarides. This metallogenic province includes the most significant Pb-Zn and Sb deposits in Serbia, as well as smaller Bi, Mo, Cu, Fe, Sn, Au and minor U, Wand Hg deposits, which are genetically related to emplacement of granitoids. The Podrinje Metallogenic District belongs to the Serbo-Macedonian Metallogenetic Province and incorporates several smaller orefields: Cer (Northwest Serbia), Boranja (West Serbia), and Srebrenica (East Bosnia and Herzegovina). Polymetallic deposits in the Boranja orefield are genetically related to the emplacement of the Tertiary Boranja granodiorite complex. The orefield contains a large number of sulfide deposits with Pb-Zn, and Sb with subordinate Cu, As, Bi and Ag. Small magnetite deposits connected to pyrometasomatic (skarn) stage are also significant. Skarns are of calcic type, and were formed along contacts of Triassic limestones and quartz diorites. Ore minerals are similar among the various types of orebodies in the Boranja orefield and consist of sulfides, sulfosalts [Pb-Bi-(Ag)-Te-Cu, Pb-Sb-(As), Sb-Cu-(Ag, Fe, Zn)], tellurides, native metals and alloys, oxides and complex-oxides, and gangue minerals. Minerals of the Boranja orefield were formed in several successive stages, which together correspond to a single regional-scale mineralization event that is genetically related to the subvulcanic-plutonic intrusion of the Neogene-aged magmatic Boranja complex. This can be best demonstrated by the zonal arrangement of several metallic mineral associations [Fe-Cu(Bi) - GT Pb(Ag)-Zn - GT Sb(As) - GT CaF2(Pb-Zn)], with increasing distance from the Boranja granodiorite. Silver occurs as a minor metal principally as Ag-tetrahedrite, with subordinate native silver, Ag-bearing gold and pyrargyrite. Significant quantities of Ag can also be accommodated in galena as it is found to contain varied amounts of Ag, Bi and Sb (0.001-0.936, 0-3.345, and 0.012-0.510 wt%, respectively). The presence of both Ag and Bi in significant amounts in a Pb-rich sulfide system is essential for development of galena [solid solution alpha-(Pb-2, AgSb, AgBi)S-2]. This study demonstrates that silver, the most economic metal in Boranja orefield, is mainly accommodated in the galena structure, with lesser amounts present in the form of visible and/or invisible Pb-Bi-(Ag) sulfosalts.",
journal = "Periodico di Mineralogia",
title = "Polymetallic mineralization of the Boranja orefield, Podrinje Metallogenic District, Serbia: zonality, mineral associations and genetic features",
volume = "82",
number = "1",
pages = "61-87",
doi = "10.2451/2013PM0004"
}
Radosavljevic, S. A., Stojanovic, J. N., Radosavljević-Mihajlović, A. S.,& Kasic, V. D.. (2013). Polymetallic mineralization of the Boranja orefield, Podrinje Metallogenic District, Serbia: zonality, mineral associations and genetic features. in Periodico di Mineralogia, 82(1), 61-87.
https://doi.org/10.2451/2013PM0004
Radosavljevic SA, Stojanovic JN, Radosavljević-Mihajlović AS, Kasic VD. Polymetallic mineralization of the Boranja orefield, Podrinje Metallogenic District, Serbia: zonality, mineral associations and genetic features. in Periodico di Mineralogia. 2013;82(1):61-87.
doi:10.2451/2013PM0004 .
Radosavljevic, Slobodan A., Stojanovic, Jovica N., Radosavljević-Mihajlović, Ana S., Kasic, Vladan D., "Polymetallic mineralization of the Boranja orefield, Podrinje Metallogenic District, Serbia: zonality, mineral associations and genetic features" in Periodico di Mineralogia, 82, no. 1 (2013):61-87,
https://doi.org/10.2451/2013PM0004 . .
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