TY  - JOUR
AU  - Tot, Nataša
AU  - Despotović, Vesna
AU  - Panić, Sanja
AU  - Kordić, Branko
AU  - Finčur, Nina
AU  - Prekodravac, Jovana
AU  - Jakimov, Dimitar
AU  - Putnik, Predrag
AU  - Abramović, Biljana
AU  - Šojić Merkulov, Daniela
PY  - 2024
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/13126
AB  - This study aimed to compare the effectiveness of adsorption and photocatalysis techniques at removing the herbicide clomazone (CLO) and the antidepressant known as amitriptyline (AMI) from water. This study employed kinetic models to analyze the removal processes and assess the potential toxicity of the treated water. The structure and morphology of the prepared multi-walled carbon nanotubes were characterized as adsorbents by transmission electron microscopy, X-ray diffraction, Fourier transform infrared techniques, and Raman spectroscopy. The adsorption kinetics of CLO and AMI were studied on the pristine and functionalized multi-walled carbon nanotubes. Kinetic studies were performed by modeling the obtained experimental data using three kinetic models: pseudo-first-order, pseudo-second-order, and Elovich kinetic models. On the other hand, the efficiency of CLO and AMI photodegradation was examined as a function of the type of irradiation (UV and simulated solar irradiation) and type of TiO2 photocatalyst (Aeroxide and Kronos). Under the experimental conditions employed, the reaction followed pseudo-first-order kinetics. Additionally, in order to assess the toxicity of water containing CLO, AMI, and their intermediates, toxicity assessments were conducted using human fetal lung fibroblast cells. The results obtained indicate the effectiveness of both methods and provide valuable insights into their removal mechanisms, contributing to the advancement of sustainable water treatment strategies.
T2  - Materials
T1  - Comparative Study on the Removal Efficiency of Clomazone and Amitriptyline via Adsorption and Photocatalysis in Aqueous Media: Kinetic Models and Toxicity Assessment
VL  - 17
IS  - 6
SP  - 1369
DO  - 10.3390/ma17061369
ER  - 

@article{
author = "Tot, Nataša and Despotović, Vesna and Panić, Sanja and Kordić, Branko and Finčur, Nina and Prekodravac, Jovana and Jakimov, Dimitar and Putnik, Predrag and Abramović, Biljana and Šojić Merkulov, Daniela",
year = "2024",
abstract = "This study aimed to compare the effectiveness of adsorption and photocatalysis techniques at removing the herbicide clomazone (CLO) and the antidepressant known as amitriptyline (AMI) from water. This study employed kinetic models to analyze the removal processes and assess the potential toxicity of the treated water. The structure and morphology of the prepared multi-walled carbon nanotubes were characterized as adsorbents by transmission electron microscopy, X-ray diffraction, Fourier transform infrared techniques, and Raman spectroscopy. The adsorption kinetics of CLO and AMI were studied on the pristine and functionalized multi-walled carbon nanotubes. Kinetic studies were performed by modeling the obtained experimental data using three kinetic models: pseudo-first-order, pseudo-second-order, and Elovich kinetic models. On the other hand, the efficiency of CLO and AMI photodegradation was examined as a function of the type of irradiation (UV and simulated solar irradiation) and type of TiO2 photocatalyst (Aeroxide and Kronos). Under the experimental conditions employed, the reaction followed pseudo-first-order kinetics. Additionally, in order to assess the toxicity of water containing CLO, AMI, and their intermediates, toxicity assessments were conducted using human fetal lung fibroblast cells. The results obtained indicate the effectiveness of both methods and provide valuable insights into their removal mechanisms, contributing to the advancement of sustainable water treatment strategies.",
journal = "Materials",
title = "Comparative Study on the Removal Efficiency of Clomazone and Amitriptyline via Adsorption and Photocatalysis in Aqueous Media: Kinetic Models and Toxicity Assessment",
volume = "17",
number = "6",
pages = "1369",
doi = "10.3390/ma17061369"
}

Tot, N., Despotović, V., Panić, S., Kordić, B., Finčur, N., Prekodravac, J., Jakimov, D., Putnik, P., Abramović, B.,& Šojić Merkulov, D.. (2024). Comparative Study on the Removal Efficiency of Clomazone and Amitriptyline via Adsorption and Photocatalysis in Aqueous Media: Kinetic Models and Toxicity Assessment. in Materials, 17(6), 1369.
https://doi.org/10.3390/ma17061369

Tot N, Despotović V, Panić S, Kordić B, Finčur N, Prekodravac J, Jakimov D, Putnik P, Abramović B, Šojić Merkulov D. Comparative Study on the Removal Efficiency of Clomazone and Amitriptyline via Adsorption and Photocatalysis in Aqueous Media: Kinetic Models and Toxicity Assessment. in Materials. 2024;17(6):1369.
doi:10.3390/ma17061369 .

Tot, Nataša, Despotović, Vesna, Panić, Sanja, Kordić, Branko, Finčur, Nina, Prekodravac, Jovana, Jakimov, Dimitar, Putnik, Predrag, Abramović, Biljana, Šojić Merkulov, Daniela, "Comparative Study on the Removal Efficiency of Clomazone and Amitriptyline via Adsorption and Photocatalysis in Aqueous Media: Kinetic Models and Toxicity Assessment" in Materials, 17, no. 6 (2024):1369,
https://doi.org/10.3390/ma17061369 . .

TY  - CONF
AU  - Čomor, Mirjana
AU  - Abazović, Nadica
AU  - Savić, T. D.
AU  - Šojić Merkulov, Daniela
AU  - Despotović, Vesna
AU  - Armaković, Sanja
AU  - Finčur, Nina
AU  - Lazarević, Marina
AU  - Uzelac, Maria
AU  - Abramović, Biljana
PY  - 2021
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/12379
AB  - Hydrothermally synthesized zirconia nanopowders: pure and doped with Si4+ ions were spectroscopically characterized and used as photocatalysts for degradation of herbicides sulcotrione and fluroxypyr. Zirconia is wide band gap ceramic (Eg ~ 5 eV) however, synthesized nanopowders showed unexpected, modest absorbance in visible light range. That fact inspired photocatalytical degradation of herbicides with wide utilization, using solar irradiation (SI) in laboratory conditions. In the scope of this study, degradation of herbicides was only slightly achieved (irradiation time 2h).
C3  - PHYSICAL CHEMISTRY 2021 : 15th international conference on fundamental and applied aspects of physical chemistry
T1  - Zirconia based photocatalysts in degradation of selected herbicides
SP  - 147
EP  - 150
UR  - https://hdl.handle.net/21.15107/rcub_vinar_10711
ER  - 

@conference{
author = "Čomor, Mirjana and Abazović, Nadica and Savić, T. D. and Šojić Merkulov, Daniela and Despotović, Vesna and Armaković, Sanja and Finčur, Nina and Lazarević, Marina and Uzelac, Maria and Abramović, Biljana",
year = "2021",
abstract = "Hydrothermally synthesized zirconia nanopowders: pure and doped with Si4+ ions were spectroscopically characterized and used as photocatalysts for degradation of herbicides sulcotrione and fluroxypyr. Zirconia is wide band gap ceramic (Eg ~ 5 eV) however, synthesized nanopowders showed unexpected, modest absorbance in visible light range. That fact inspired photocatalytical degradation of herbicides with wide utilization, using solar irradiation (SI) in laboratory conditions. In the scope of this study, degradation of herbicides was only slightly achieved (irradiation time 2h).",
journal = "PHYSICAL CHEMISTRY 2021 : 15th international conference on fundamental and applied aspects of physical chemistry",
title = "Zirconia based photocatalysts in degradation of selected herbicides",
pages = "147-150",
url = "https://hdl.handle.net/21.15107/rcub_vinar_10711"
}

Čomor, M., Abazović, N., Savić, T. D., Šojić Merkulov, D., Despotović, V., Armaković, S., Finčur, N., Lazarević, M., Uzelac, M.,& Abramović, B.. (2021). Zirconia based photocatalysts in degradation of selected herbicides. in PHYSICAL CHEMISTRY 2021 : 15th international conference on fundamental and applied aspects of physical chemistry, 147-150.
https://hdl.handle.net/21.15107/rcub_vinar_10711

Čomor M, Abazović N, Savić TD, Šojić Merkulov D, Despotović V, Armaković S, Finčur N, Lazarević M, Uzelac M, Abramović B. Zirconia based photocatalysts in degradation of selected herbicides. in PHYSICAL CHEMISTRY 2021 : 15th international conference on fundamental and applied aspects of physical chemistry. 2021;:147-150.
https://hdl.handle.net/21.15107/rcub_vinar_10711 .

Čomor, Mirjana, Abazović, Nadica, Savić, T. D., Šojić Merkulov, Daniela, Despotović, Vesna, Armaković, Sanja, Finčur, Nina, Lazarević, Marina, Uzelac, Maria, Abramović, Biljana, "Zirconia based photocatalysts in degradation of selected herbicides" in PHYSICAL CHEMISTRY 2021 : 15th international conference on fundamental and applied aspects of physical chemistry (2021):147-150,
https://hdl.handle.net/21.15107/rcub_vinar_10711 .