TY  - JOUR
AU  - Dojčinović, Biljana P.
AU  - Jančar, Boštjan
AU  - Bessais, Lotfi
AU  - Kremenović, Aleksandar S.
AU  - Jović-Jovičić, Nataša P.
AU  - Banković, Predrag T.
AU  - Stanković, Dalibor M.
AU  - Ognjanović, Miloš
AU  - Antić, Bratislav
PY  - 2019
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/8612
AB  - Herein we report effects of partial substitution of Fe3+ by Y3+ in magnetite (Fe3O4) on morphology and inorganic arsenic species adsorption efficiency of the Fe3-xYxO4 nanoparticles formed. The series of Fe3-xYxO4 (x = 0.00, 0.042 and 0.084, labeled as Y00, Y05 and Y10, respectively) was synthesized using co-precipitation followed by microwave-hydrothermal treatment (MW) at 200 degrees C. With increase of yttrium content (x value), both the morphological inhomogeneity of the samples and the fraction of spinel nanorods as compared to spinel pseudospherical particles increased. By both transmission electron microscopy and x-ray powder diffraction analyses, it was determined that the direction of growth of the spinel nanorods is along the [110] crystallographic direction. The Fe3-xYxO4 affinities of adsorption toward the inorganic arsenic species, As(III) (arsenite, AsO33-) and As(V) (arsenate, AsO43-), were investigated. Increased Y3+ content related to changes in sample morphology was followed by a decrease of As(III) removal efficiency and vice versa for As(V). The increase in Y3+ content, in addition to increasing the adsorption capacity for As(V), significantly expanded the optimum pH range for the maximum removal and decreased the contact time for necessary 50% removal (t(1/2)) of As(V) (Y00: pH 2-3, t(1/2) = 3.12 min; Y05: pH 2-6, t(1/2) = 2.12 min and Y10: pH 2-10, t(1/2) = 1.12 min). The results point to incorporation of Y3+ in the crystal lattice of magnetite, inducing nanorod spinel structure formation with significant changes in sorption properties important for the removal of inorganic arsenic from waters.
T2  - Nanotechnology
T1  - Differently shaped nanocrystalline (Fe, Y)3O4 and its adsorption efficiency toward inorganic arsenic species
VL  - 30
IS  - 47
SP  - 475702
DO  - 10.1088/1361-6528/ab3ca2
ER  - 

@article{
author = "Dojčinović, Biljana P. and Jančar, Boštjan and Bessais, Lotfi and Kremenović, Aleksandar S. and Jović-Jovičić, Nataša P. and Banković, Predrag T. and Stanković, Dalibor M. and Ognjanović, Miloš and Antić, Bratislav",
year = "2019",
abstract = "Herein we report effects of partial substitution of Fe3+ by Y3+ in magnetite (Fe3O4) on morphology and inorganic arsenic species adsorption efficiency of the Fe3-xYxO4 nanoparticles formed. The series of Fe3-xYxO4 (x = 0.00, 0.042 and 0.084, labeled as Y00, Y05 and Y10, respectively) was synthesized using co-precipitation followed by microwave-hydrothermal treatment (MW) at 200 degrees C. With increase of yttrium content (x value), both the morphological inhomogeneity of the samples and the fraction of spinel nanorods as compared to spinel pseudospherical particles increased. By both transmission electron microscopy and x-ray powder diffraction analyses, it was determined that the direction of growth of the spinel nanorods is along the [110] crystallographic direction. The Fe3-xYxO4 affinities of adsorption toward the inorganic arsenic species, As(III) (arsenite, AsO33-) and As(V) (arsenate, AsO43-), were investigated. Increased Y3+ content related to changes in sample morphology was followed by a decrease of As(III) removal efficiency and vice versa for As(V). The increase in Y3+ content, in addition to increasing the adsorption capacity for As(V), significantly expanded the optimum pH range for the maximum removal and decreased the contact time for necessary 50% removal (t(1/2)) of As(V) (Y00: pH 2-3, t(1/2) = 3.12 min; Y05: pH 2-6, t(1/2) = 2.12 min and Y10: pH 2-10, t(1/2) = 1.12 min). The results point to incorporation of Y3+ in the crystal lattice of magnetite, inducing nanorod spinel structure formation with significant changes in sorption properties important for the removal of inorganic arsenic from waters.",
journal = "Nanotechnology",
title = "Differently shaped nanocrystalline (Fe, Y)3O4 and its adsorption efficiency toward inorganic arsenic species",
volume = "30",
number = "47",
pages = "475702",
doi = "10.1088/1361-6528/ab3ca2"
}

Dojčinović, B. P., Jančar, B., Bessais, L., Kremenović, A. S., Jović-Jovičić, N. P., Banković, P. T., Stanković, D. M., Ognjanović, M.,& Antić, B.. (2019). Differently shaped nanocrystalline (Fe, Y)3O4 and its adsorption efficiency toward inorganic arsenic species. in Nanotechnology, 30(47), 475702.
https://doi.org/10.1088/1361-6528/ab3ca2

Dojčinović BP, Jančar B, Bessais L, Kremenović AS, Jović-Jovičić NP, Banković PT, Stanković DM, Ognjanović M, Antić B. Differently shaped nanocrystalline (Fe, Y)3O4 and its adsorption efficiency toward inorganic arsenic species. in Nanotechnology. 2019;30(47):475702.
doi:10.1088/1361-6528/ab3ca2 .

Dojčinović, Biljana P., Jančar, Boštjan, Bessais, Lotfi, Kremenović, Aleksandar S., Jović-Jovičić, Nataša P., Banković, Predrag T., Stanković, Dalibor M., Ognjanović, Miloš, Antić, Bratislav, "Differently shaped nanocrystalline (Fe, Y)3O4 and its adsorption efficiency toward inorganic arsenic species" in Nanotechnology, 30, no. 47 (2019):475702,
https://doi.org/10.1088/1361-6528/ab3ca2 . .

TY  - JOUR
AU  - Antić, Bratislav
AU  - Perović, Marija M.
AU  - Kremenović, Aleksandar S.
AU  - Blanuša, Jovan
AU  - Spasojević, Vojislav
AU  - Vulić, Predrag J.
AU  - Bessais, Lotfi
AU  - Božin, Emil S.
PY  - 2013
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/5305
AB  - The evolution of the magnetic state, crystal structure and microstructure parameters of nanocrystalline zinc-ferrite, tuned by thermal annealing of similar to 4 nm nanoparticles, was systematically studied by complementary characterization methods. Structural analysis of neutron and synchrotron x-ray radiation data revealed a mixed cation distribution in the nanoparticle samples, with the degree of inversion systematically decreasing from 0.25 in an as-prepared nanocrystalline sample to a non-inverted spinel structure with a normal cation distribution in the bulk counterpart. The results of DC magnetization and Mossbauer spectroscopy experiments indicated a superparamagnetic relaxation in similar to 4 nm nanoparticles, albeit with different freezing temperatures T-f of 27.5 K and 46 K, respectively. The quadrupole splitting parameter decreases with the annealing temperature due to cation redistribution between the tetrahedral and octahedral sites of the spinel structure and the associated defects. DC magnetization measurements indicated the existence of significant interparticle interactions among nanoparticles (superspins). Additional confirmation for the presence of interparticle interactions was found from the fit of the Tf(H) dependence to the AT line, from which a value of the anisotropy constant of K-eff = 5.6 x 10(5) erg cm(-3) was deduced. Further evidence for strong interparticle interactions was found from AC susceptibility measurements, where the frequency dependence of the freezing temperature T-f(f) was satisfactory described by both Vogel-Fulcher and dynamic scaling theory, both applicable for interacting systems. The parameters obtained from these fits suggest collective freezing of magnetic moments at T-f.
T2  - Journal of Physics: Condensed Matter
T1  - An integrated study of thermal treatment effects on the microstructure and magnetic properties of Zn-ferrite nanoparticles
VL  - 25
IS  - 8
DO  - 10.1088/0953-8984/25/8/086001
ER  - 

@article{
author = "Antić, Bratislav and Perović, Marija M. and Kremenović, Aleksandar S. and Blanuša, Jovan and Spasojević, Vojislav and Vulić, Predrag J. and Bessais, Lotfi and Božin, Emil S.",
year = "2013",
abstract = "The evolution of the magnetic state, crystal structure and microstructure parameters of nanocrystalline zinc-ferrite, tuned by thermal annealing of similar to 4 nm nanoparticles, was systematically studied by complementary characterization methods. Structural analysis of neutron and synchrotron x-ray radiation data revealed a mixed cation distribution in the nanoparticle samples, with the degree of inversion systematically decreasing from 0.25 in an as-prepared nanocrystalline sample to a non-inverted spinel structure with a normal cation distribution in the bulk counterpart. The results of DC magnetization and Mossbauer spectroscopy experiments indicated a superparamagnetic relaxation in similar to 4 nm nanoparticles, albeit with different freezing temperatures T-f of 27.5 K and 46 K, respectively. The quadrupole splitting parameter decreases with the annealing temperature due to cation redistribution between the tetrahedral and octahedral sites of the spinel structure and the associated defects. DC magnetization measurements indicated the existence of significant interparticle interactions among nanoparticles (superspins). Additional confirmation for the presence of interparticle interactions was found from the fit of the Tf(H) dependence to the AT line, from which a value of the anisotropy constant of K-eff = 5.6 x 10(5) erg cm(-3) was deduced. Further evidence for strong interparticle interactions was found from AC susceptibility measurements, where the frequency dependence of the freezing temperature T-f(f) was satisfactory described by both Vogel-Fulcher and dynamic scaling theory, both applicable for interacting systems. The parameters obtained from these fits suggest collective freezing of magnetic moments at T-f.",
journal = "Journal of Physics: Condensed Matter",
title = "An integrated study of thermal treatment effects on the microstructure and magnetic properties of Zn-ferrite nanoparticles",
volume = "25",
number = "8",
doi = "10.1088/0953-8984/25/8/086001"
}

Antić, B., Perović, M. M., Kremenović, A. S., Blanuša, J., Spasojević, V., Vulić, P. J., Bessais, L.,& Božin, E. S.. (2013). An integrated study of thermal treatment effects on the microstructure and magnetic properties of Zn-ferrite nanoparticles. in Journal of Physics: Condensed Matter, 25(8).
https://doi.org/10.1088/0953-8984/25/8/086001

Antić B, Perović MM, Kremenović AS, Blanuša J, Spasojević V, Vulić PJ, Bessais L, Božin ES. An integrated study of thermal treatment effects on the microstructure and magnetic properties of Zn-ferrite nanoparticles. in Journal of Physics: Condensed Matter. 2013;25(8).
doi:10.1088/0953-8984/25/8/086001 .

Antić, Bratislav, Perović, Marija M., Kremenović, Aleksandar S., Blanuša, Jovan, Spasojević, Vojislav, Vulić, Predrag J., Bessais, Lotfi, Božin, Emil S., "An integrated study of thermal treatment effects on the microstructure and magnetic properties of Zn-ferrite nanoparticles" in Journal of Physics: Condensed Matter, 25, no. 8 (2013),
https://doi.org/10.1088/0953-8984/25/8/086001 . .

TY  - JOUR
AU  - Vučinić-Vasić, Milica
AU  - Božin, Emil S.
AU  - Bessais, Lotfi
AU  - Stojanovic, G.
AU  - Kozmidis-Luburic, U.
AU  - Abeykoon, M.
AU  - Jančar, Boštjan
AU  - Meden, A.
AU  - Kremenović, Aleksandar S.
AU  - Antić, Bratislav
PY  - 2013
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/5555
AB  - Evolution of the structural and magnetic properties of ZnFe1.95Yb0.05O4 nanoparticles, prepared via a high-energy ball milling route and exposed to further thermal annealing/heating, was assessed in detail and correlation of these properties explored. inversion, heating of the sample to similar to 500 degrees C is found to rapidly alter the cation distribution from mixed to normal, in agreement with the known cation preferences. Under the same conditions the crystallite size only slowly grows. By further thermal treatment appreciably. An interrelationship among the lattice parameter, octahedral site occupancy, and crystallite size has been established. The observations are (a) both the site occupancy of Fe3+ at octahedral 16d spinel sites (N-16d(Fe3+)) and the cubic lattice parameter rapidly increase with an initial increase of the crystallite size, (b) the lattice parameter increases with increasing occupancy, N-16d(Fe3+), and (c) there appears to be a critical nanoparticle diameter (approximately 15 nm) above which both the site occupancy and lattice parameter values are saturated. The magnetic behavior of the annealed samples appears to be correlated to the evolution of both the cation distribution and crystallite size, as follows. As-prepared samples and those annealed at lower temperatures show superparamagnetic behavior at room temperature, presumably as a consequence of the Fe3+ distribution and strong Fe3+(8a)-O-Fe3+(16d) superexchange interactions. Samples with a nanopartide diameter greater than 12 nm and with almost normal distributions exhibit the paramagnetic state. The coercive field is found to decrease with an increase of the crystallite size. Partial Yb3+/Fe3+ substitution is found to increase the inversion parameter and saturation magnetization. Detailed knowledge of the thermal evolution of structural/microstructural parameters allows control over the cation distribution and crystallite size and hence the magnetic properties of nanoferrites.
T2  - Journal of Physical Chemistry. C
T1  - Thermal Evolution of Cation Distribution/Crystallite Size and Their Correlation with the Magnetic State of Yb-Substituted Zinc Ferrite Nanoparticles
VL  - 117
IS  - 23
SP  - 12358
EP  - 12365
DO  - 10.1021/jp403459t
ER  - 

@article{
author = "Vučinić-Vasić, Milica and Božin, Emil S. and Bessais, Lotfi and Stojanovic, G. and Kozmidis-Luburic, U. and Abeykoon, M. and Jančar, Boštjan and Meden, A. and Kremenović, Aleksandar S. and Antić, Bratislav",
year = "2013",
abstract = "Evolution of the structural and magnetic properties of ZnFe1.95Yb0.05O4 nanoparticles, prepared via a high-energy ball milling route and exposed to further thermal annealing/heating, was assessed in detail and correlation of these properties explored. inversion, heating of the sample to similar to 500 degrees C is found to rapidly alter the cation distribution from mixed to normal, in agreement with the known cation preferences. Under the same conditions the crystallite size only slowly grows. By further thermal treatment appreciably. An interrelationship among the lattice parameter, octahedral site occupancy, and crystallite size has been established. The observations are (a) both the site occupancy of Fe3+ at octahedral 16d spinel sites (N-16d(Fe3+)) and the cubic lattice parameter rapidly increase with an initial increase of the crystallite size, (b) the lattice parameter increases with increasing occupancy, N-16d(Fe3+), and (c) there appears to be a critical nanoparticle diameter (approximately 15 nm) above which both the site occupancy and lattice parameter values are saturated. The magnetic behavior of the annealed samples appears to be correlated to the evolution of both the cation distribution and crystallite size, as follows. As-prepared samples and those annealed at lower temperatures show superparamagnetic behavior at room temperature, presumably as a consequence of the Fe3+ distribution and strong Fe3+(8a)-O-Fe3+(16d) superexchange interactions. Samples with a nanopartide diameter greater than 12 nm and with almost normal distributions exhibit the paramagnetic state. The coercive field is found to decrease with an increase of the crystallite size. Partial Yb3+/Fe3+ substitution is found to increase the inversion parameter and saturation magnetization. Detailed knowledge of the thermal evolution of structural/microstructural parameters allows control over the cation distribution and crystallite size and hence the magnetic properties of nanoferrites.",
journal = "Journal of Physical Chemistry. C",
title = "Thermal Evolution of Cation Distribution/Crystallite Size and Their Correlation with the Magnetic State of Yb-Substituted Zinc Ferrite Nanoparticles",
volume = "117",
number = "23",
pages = "12358-12365",
doi = "10.1021/jp403459t"
}

Vučinić-Vasić, M., Božin, E. S., Bessais, L., Stojanovic, G., Kozmidis-Luburic, U., Abeykoon, M., Jančar, B., Meden, A., Kremenović, A. S.,& Antić, B.. (2013). Thermal Evolution of Cation Distribution/Crystallite Size and Their Correlation with the Magnetic State of Yb-Substituted Zinc Ferrite Nanoparticles. in Journal of Physical Chemistry. C, 117(23), 12358-12365.
https://doi.org/10.1021/jp403459t

Vučinić-Vasić M, Božin ES, Bessais L, Stojanovic G, Kozmidis-Luburic U, Abeykoon M, Jančar B, Meden A, Kremenović AS, Antić B. Thermal Evolution of Cation Distribution/Crystallite Size and Their Correlation with the Magnetic State of Yb-Substituted Zinc Ferrite Nanoparticles. in Journal of Physical Chemistry. C. 2013;117(23):12358-12365.
doi:10.1021/jp403459t .

Vučinić-Vasić, Milica, Božin, Emil S., Bessais, Lotfi, Stojanovic, G., Kozmidis-Luburic, U., Abeykoon, M., Jančar, Boštjan, Meden, A., Kremenović, Aleksandar S., Antić, Bratislav, "Thermal Evolution of Cation Distribution/Crystallite Size and Their Correlation with the Magnetic State of Yb-Substituted Zinc Ferrite Nanoparticles" in Journal of Physical Chemistry. C, 117, no. 23 (2013):12358-12365,
https://doi.org/10.1021/jp403459t . .