Vuković, Jovana S.

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  • Vuković, Jovana S. (1)
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Removal of Pb2+ from aqueous solution by P(HEA/IA) hydrogels

Antić, Katarina M.; Babić, Marija M.; Vuković, Jovana S.; Onjia, Antonije E.; Filipović, Jovanka M.; Tomić, Simonida Lj.

(2016)

TY  - JOUR
AU  - Antić, Katarina M.
AU  - Babić, Marija M.
AU  - Vuković, Jovana S.
AU  - Onjia, Antonije E.
AU  - Filipović, Jovanka M.
AU  - Tomić, Simonida Lj.
PY  - 2016
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/1394
AB  - A series of poly(2-hydroxyethyl acrylate-co-itaconic acid), P(HEA/IA), hydrogels with different HEA/IA ratio, were synthesized using free radical crosslinking/copolymerization and investigated as sorbents for Pb2+ from aqueous solutions. Hydrogels were characterized using DMA, FTIR, DSC, SEM and AFM. The adsorption was found to be highly dependent on hydrogel composition, solution pH, sorbent weight, ionic strength and contact time. Five isotherm models, Langmuir, Freundlich, Redlich-Peterson, Temkin and Dubinin-Radushkevich, were applied to the sorption data. The best fit was obtained with Redlich-Peterson isotherm. The separation factor, RL, value indicated favorable sorption for Pb2+. The maximum sorption capacities were 392.2 and 409.8 mg/g for P(HEA/2IA) and P(HEA/10IA), respectively. Kinetic data showed best fit with pseudo-second-order model. Thermodynamic studies revealed that the reaction was exothermic and proceeds with a decrease in entropy. Moreover, P(HEA/IA) hydrogel showed the most pronounced sorption toward Pb2+ from environment containing Cu2+, Zn2+, Cd2+, Ni2+ and Co2+. Sorption/desorption experiments, showed that the P(HEA/IA) hydrogels could be reused without significant loss of the initial properties even after three adsorption-desorption cycles.
T2  - Hemijska industrija
T1  - Removal of Pb2+ from aqueous solution by P(HEA/IA) hydrogels
VL  - 70
IS  - 6
SP  - 695
EP  - 705
DO  - 10.2298/HEMIND151225006A
ER  - 
@article{
author = "Antić, Katarina M. and Babić, Marija M. and Vuković, Jovana S. and Onjia, Antonije E. and Filipović, Jovanka M. and Tomić, Simonida Lj.",
year = "2016",
abstract = "A series of poly(2-hydroxyethyl acrylate-co-itaconic acid), P(HEA/IA), hydrogels with different HEA/IA ratio, were synthesized using free radical crosslinking/copolymerization and investigated as sorbents for Pb2+ from aqueous solutions. Hydrogels were characterized using DMA, FTIR, DSC, SEM and AFM. The adsorption was found to be highly dependent on hydrogel composition, solution pH, sorbent weight, ionic strength and contact time. Five isotherm models, Langmuir, Freundlich, Redlich-Peterson, Temkin and Dubinin-Radushkevich, were applied to the sorption data. The best fit was obtained with Redlich-Peterson isotherm. The separation factor, RL, value indicated favorable sorption for Pb2+. The maximum sorption capacities were 392.2 and 409.8 mg/g for P(HEA/2IA) and P(HEA/10IA), respectively. Kinetic data showed best fit with pseudo-second-order model. Thermodynamic studies revealed that the reaction was exothermic and proceeds with a decrease in entropy. Moreover, P(HEA/IA) hydrogel showed the most pronounced sorption toward Pb2+ from environment containing Cu2+, Zn2+, Cd2+, Ni2+ and Co2+. Sorption/desorption experiments, showed that the P(HEA/IA) hydrogels could be reused without significant loss of the initial properties even after three adsorption-desorption cycles.",
journal = "Hemijska industrija",
title = "Removal of Pb2+ from aqueous solution by P(HEA/IA) hydrogels",
volume = "70",
number = "6",
pages = "695-705",
doi = "10.2298/HEMIND151225006A"
}
Antić, K. M., Babić, M. M., Vuković, J. S., Onjia, A. E., Filipović, J. M.,& Tomić, S. Lj.. (2016). Removal of Pb2+ from aqueous solution by P(HEA/IA) hydrogels. in Hemijska industrija, 70(6), 695-705.
https://doi.org/10.2298/HEMIND151225006A
Antić KM, Babić MM, Vuković JS, Onjia AE, Filipović JM, Tomić SL. Removal of Pb2+ from aqueous solution by P(HEA/IA) hydrogels. in Hemijska industrija. 2016;70(6):695-705.
doi:10.2298/HEMIND151225006A .
Antić, Katarina M., Babić, Marija M., Vuković, Jovana S., Onjia, Antonije E., Filipović, Jovanka M., Tomić, Simonida Lj., "Removal of Pb2+ from aqueous solution by P(HEA/IA) hydrogels" in Hemijska industrija, 70, no. 6 (2016):695-705,
https://doi.org/10.2298/HEMIND151225006A . .
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