@conference{
author = "Janković, Bojan and Janković, Marija and Cvetković, Slobodan and Manić, Nebojša and Pijović-Radovanović, Milena and Perendija, Jovana and Cvetinović, Dejan",
year = "2023",
abstract = "Biomasa se smatra važnim obnovljivim resursom, koji igra ključnu ulogu u razvoju održivih energetskih sistema. Biomasa se može pretvoriti u energiju ili vredne hemikalije sagorevanjem, utečnjavanjem, pirolizom i gasifikacijom. Među ovim procesima, termička gasifikacija ‛razlaže’ biomasu u lake hemijske vrste na visokim temperaturama, koje se mogu primeniti na biomasu sa najvećom raznovrsnošću. Kao krajnji (ciljni) proizvod gasifikacije biomase, singas ili gas bogat vodonikom (H2), su veoma važni međuproizvodi u petrohemijskoj industriji. Međutim, problematični katran koji se proizvodi tokom gasifikacije mogao bi da donese niz problema. Katalitička gasifikacija biomase je obećavajuća strategija za značajno ublažavanje ovih problema. Katalizatori na bazi prelaznih metala za katalitičku gasifikaciju biomase proučavani su poslednjih decenija. U ovom pregledu se razmatraju različiti katalizatori prelaznih metala za gasifikaciju biomase, uključujući monometalne i bimetalne katalizatore na bazi nikla (Ni) i druge katalizatore na bazi Fe i Pt. Performanse ovih katalizatora su bile procenjene na osnovu primenjenih parametara reakcije, kvaliteta proizvedenog singasa i učinkovitosti u smanjenju katrana. Sumirane su primena DFT (‛funkcionalne teorije gustine’) proračuna i AI (‛veštačke inteligencije’) za proučavanje mehanizama gasifikacije biomase, a takođe je bio i razmatran uzrok deaktivacije katalizatora i regeneracije istrošenih katalizatora. Isto tako, u ovom pregledu, razmotren je potencijal razvoja katalitičke gasifikacije biomase u Republici Srbiji., Biomass is considered as an important renewable resource, which plays a key role in the development of sustainable energy systems. Biomass can be converted into energy or valuable chemicals by combustion, liquefaction, pyrolysis and gasification. Among these processes, thermal gasification “decomposes” biomass into the light chemical species at high temperatures, which can be applied to biomass with the greatest diversity. As the final (target) product of biomass gasification, syngas or gas rich in hydrogen (H2), are very important intermediate products in the petrochemical industry. However, the problematic tar produced during gasification could bring a number of problems. Catalytic biomass gasification is a promising strategy to significantly alleviate these problems. Transition metal-based catalysts for catalytic biomass gasification have been studied in recent decades. This review discusses various transition metal catalysts for biomass gasification, including nickel (Ni)-based monometallic and bimetallic catalysts and other Fe- and Pt-based catalysts. The performance of these catalysts is evaluated based on the applied reaction parameters, the quality of the syngas produced, and the tar reduction performance. Applications of DFT (‛Density Functional Theory’) calculations and AI (‛Artificial Intelligence’) to study biomass gasification mechanisms are summarized, and the cause of catalyst deactivation and regeneration of spent catalysts are also discussed. Likewise, in this review, the development potential of catalytic gasification of biomass in the Republic of Serbia was considered.",
publisher = "Belgrade : Society of Thermal Engineers of Serbia",
journal = "International Conference Power Plants 2023 : Proceedings",
title = "Pregled katalitičke gasifikacije biomase pogodne za industriju u Republici Srbiji, Overview of catalytic gasification of biomass suitable for industry in the Republic of Serbia",
pages = "910-921",
url = "https://hdl.handle.net/21.15107/rcub_vinar_12363"
}
