Barudžija, Tanja

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Authority KeyName Variants
orcid::0000-0002-9240-9609
  • Barudžija, Tanja (65)
Projects
Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200017 (University of Belgrade, Institute of Nuclear Sciences 'Vinča', Belgrade-Vinča) Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200026 (University of Belgrade, Institute of Chemistry, Technology and Metallurgy - IChTM)
Magnetic and radionuclide labeled nanostructured materials for medical applications Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200135 (University of Belgrade, Faculty of Technology and Metallurgy)
New approach in designing materials for energy conversion and energy storage systems Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200175 (Institute of Technical Sciences of SASA, Belgrade)
Investigation of intermetallics and semiconductors and possible application in renewable energy sources Electrochemical synthesis and characterization of nanostructured functional materials for application in new technologies
Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200161 (University of Belgrade, Faculty of Pharmacy) Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200287 (Innovation Center of the Faculty of Technology and Metallurgy)
Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200288 (Innovation Center of the Faculty of Chemistry) Nanostructured Functional and Composite Materials in Catalytic and Sorption Processes
Ministry of Education, Science and Technological Development of the Republic of Serbia Bilateral Serbia-Slovenia [06-00-118/2018-09/32/02]
Bilateral Serbia-Slovenia [BI-RS/18-19-031] Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200325 (Military Technical Institute - MTI, Belgrade)
Optoelectronics nanodimension systems - the rout towards applications Ministry of Education, Science and Technological Development of the Republic of Serbia and German Academic Exchange Service (DAAD) - bilateral project (451-03-01971/2018-09/4)
Bilateral collaboration INCDIE ICPE-CA Bucharest JINR Dubna [04-4-1069-2009/2011, agreement no. 3887-4-09/11/2009] Bilateral Project [Bi-RS/1415-24]
Bilateral research project between Ministry of Education, Science and Technological Development of the Republic of Serbia and German Academic Exchange Service (DAAD) - [ID:451-03- 01344/2020-09/8] Bilateral research project (ID: 451-03-01971/201809/4) supported by the Ministry of Education, Science and Technological Development of the Republic of Serbia and German Academic Exchange Service (DAAD)
CENN Nanocenter for the use of Transmission Electron Microscope Jeol [JEM-2100] COST actions [CM1101, MP1106]
European Regional Development Fund [ITMS: 26220220179] NanoTBTech - Nanoparticles-based 2D thermal bioimaging technologies
The electrical breakdown of gases, surface processes and applications Dynamics of nonlinear physicochemical and biochemical systems with modeling and predicting of their behavior under nonequilibrium conditions
Size-, shape- and structure- dependent properties of nanoparticles and nanocomposites Transformation of Serbian Geospace - lessons from the past, contemporary problems and possible solutions

Author's Bibliography

Electrodeposition of copper on glassy carbon and palladium from choline chloride - ethylene glycol deep eutectic solvent

Cvetković, Vesna S.; Jović, Vladimir D.; Nikolić, Nebojša D.; Barudžija, Tanja; Dimitrijević, Silvana; Jovićević, Jovan N.

(2024)

TY  - JOUR
AU  - Cvetković, Vesna S.
AU  - Jović, Vladimir D.
AU  - Nikolić, Nebojša D.
AU  - Barudžija, Tanja
AU  - Dimitrijević, Silvana
AU  - Jovićević, Jovan N.
PY  - 2024
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/12936
AB  - Electrodeposition of copper from deep eutectic solvents (DES) based on a mixture of choline chloride and ethylene glycol containing CuCl2·2H2O at 50 °C and 80 °C was studied. Electrochemical reduction/oxidation of Cu(II)/Cu(0) on glassy carbon (GC) and palladium (Pd) electrodes was investigated by cyclic voltammetry (CV) and square wave voltammetry (SWV) emphasizing that this process takes place through two steps, Cu(II) ↔ Cu(I) and Cu(I) ↔ Cu(0). The CV results showed that in chloride-rich DES electrolytes, the increased presence of chloro ligands raises the overpotential required for Cu electrodeposition. The electrochemical impedance spectroscopy (EIS) results indicate simultaneous electrodeposition of Cu and electrosorption of large cations on electrodeposited Cu on both GC and Pd substrates. Scanning electron microscopy (SEM) results showed that Cu grains of approximately 1 μm were obtained by electrodeposition of Cu on both Pd and GC, whereby better coverage by electrodeposited Cu was obtained on Pd than on GC. Cu electrodeposited on Pd was relatively uniform and smooth, but porous, while Cu electrodeposited on GC was dispersed in small agglomerates. Energy-dispersive X-ray spectroscopy (EDS) of Cu electrodeposited on Pd detected the dominant presence of Cu with the possibility of the formation of CuPd alloy. The presence of CuPd alloy face-centred cubic structures is confirmed by X-ray diffraction (XRD) along with metallic Cu.
T2  - Journal of Electroanalytical Chemistry
T1  - Electrodeposition of copper on glassy carbon and palladium from choline chloride - ethylene glycol deep eutectic solvent
VL  - 958
SP  - 118161
DO  - 10.1016/j.jelechem.2024.118161
ER  - 
@article{
author = "Cvetković, Vesna S. and Jović, Vladimir D. and Nikolić, Nebojša D. and Barudžija, Tanja and Dimitrijević, Silvana and Jovićević, Jovan N.",
year = "2024",
abstract = "Electrodeposition of copper from deep eutectic solvents (DES) based on a mixture of choline chloride and ethylene glycol containing CuCl2·2H2O at 50 °C and 80 °C was studied. Electrochemical reduction/oxidation of Cu(II)/Cu(0) on glassy carbon (GC) and palladium (Pd) electrodes was investigated by cyclic voltammetry (CV) and square wave voltammetry (SWV) emphasizing that this process takes place through two steps, Cu(II) ↔ Cu(I) and Cu(I) ↔ Cu(0). The CV results showed that in chloride-rich DES electrolytes, the increased presence of chloro ligands raises the overpotential required for Cu electrodeposition. The electrochemical impedance spectroscopy (EIS) results indicate simultaneous electrodeposition of Cu and electrosorption of large cations on electrodeposited Cu on both GC and Pd substrates. Scanning electron microscopy (SEM) results showed that Cu grains of approximately 1 μm were obtained by electrodeposition of Cu on both Pd and GC, whereby better coverage by electrodeposited Cu was obtained on Pd than on GC. Cu electrodeposited on Pd was relatively uniform and smooth, but porous, while Cu electrodeposited on GC was dispersed in small agglomerates. Energy-dispersive X-ray spectroscopy (EDS) of Cu electrodeposited on Pd detected the dominant presence of Cu with the possibility of the formation of CuPd alloy. The presence of CuPd alloy face-centred cubic structures is confirmed by X-ray diffraction (XRD) along with metallic Cu.",
journal = "Journal of Electroanalytical Chemistry",
title = "Electrodeposition of copper on glassy carbon and palladium from choline chloride - ethylene glycol deep eutectic solvent",
volume = "958",
pages = "118161",
doi = "10.1016/j.jelechem.2024.118161"
}
Cvetković, V. S., Jović, V. D., Nikolić, N. D., Barudžija, T., Dimitrijević, S.,& Jovićević, J. N.. (2024). Electrodeposition of copper on glassy carbon and palladium from choline chloride - ethylene glycol deep eutectic solvent. in Journal of Electroanalytical Chemistry, 958, 118161.
https://doi.org/10.1016/j.jelechem.2024.118161
Cvetković VS, Jović VD, Nikolić ND, Barudžija T, Dimitrijević S, Jovićević JN. Electrodeposition of copper on glassy carbon and palladium from choline chloride - ethylene glycol deep eutectic solvent. in Journal of Electroanalytical Chemistry. 2024;958:118161.
doi:10.1016/j.jelechem.2024.118161 .
Cvetković, Vesna S., Jović, Vladimir D., Nikolić, Nebojša D., Barudžija, Tanja, Dimitrijević, Silvana, Jovićević, Jovan N., "Electrodeposition of copper on glassy carbon and palladium from choline chloride - ethylene glycol deep eutectic solvent" in Journal of Electroanalytical Chemistry, 958 (2024):118161,
https://doi.org/10.1016/j.jelechem.2024.118161 . .

Functional nano-silver decorated textiles for wearable electronics and electromagnetic interference shielding

Stupar, Stevan; Vuksanović, Marija M.; Mijin, Dušan Ž.; Bučko, Mihael M.; Joksimović, Vasilija J.; Barudžija, Tanja; Tanić, Milan N.

(2023)

TY  - JOUR
AU  - Stupar, Stevan
AU  - Vuksanović, Marija M.
AU  - Mijin, Dušan Ž.
AU  - Bučko, Mihael M.
AU  - Joksimović, Vasilija J.
AU  - Barudžija, Tanja
AU  - Tanić, Milan N.
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10606
AB  - The presented research focused on the metallization of polyester, cotton, and polyamide 6.6 fabrics using the silver conductive complex to allow electric conductivity through the fabric's surface and enhance the fabric's mechanical properties. The method used for the metallization of studied fabrics does not require the use of expensive toxic chemicals or electricity, making the process more economically acceptable. The signal attenuation was measured in frequency ranges of 1–4 and 5–12 GHz. After five cycles of metallization, the polyester fabric has higher EMI effectiveness, in a lower range was 45.44 and 57.25 dB. X-ray powder diffractometry (XRD) and infrared spectroscopy with Fourier transform infrared spectrophotometry (FT-IR) characterize the modified tissues. Scanning electron microscopy coupled with energy-dispersion spectroscopy (SEM-EDS) was used to determine layers' morphology and elemental composition. Also, the water and air permeability of modified textiles was determined.
T2  - Materials Today Communications
T1  - Functional nano-silver decorated textiles for wearable electronics and electromagnetic interference shielding
VL  - 34
SP  - 105312
DO  - 10.1016/j.mtcomm.2023.105312
ER  - 
@article{
author = "Stupar, Stevan and Vuksanović, Marija M. and Mijin, Dušan Ž. and Bučko, Mihael M. and Joksimović, Vasilija J. and Barudžija, Tanja and Tanić, Milan N.",
year = "2023",
abstract = "The presented research focused on the metallization of polyester, cotton, and polyamide 6.6 fabrics using the silver conductive complex to allow electric conductivity through the fabric's surface and enhance the fabric's mechanical properties. The method used for the metallization of studied fabrics does not require the use of expensive toxic chemicals or electricity, making the process more economically acceptable. The signal attenuation was measured in frequency ranges of 1–4 and 5–12 GHz. After five cycles of metallization, the polyester fabric has higher EMI effectiveness, in a lower range was 45.44 and 57.25 dB. X-ray powder diffractometry (XRD) and infrared spectroscopy with Fourier transform infrared spectrophotometry (FT-IR) characterize the modified tissues. Scanning electron microscopy coupled with energy-dispersion spectroscopy (SEM-EDS) was used to determine layers' morphology and elemental composition. Also, the water and air permeability of modified textiles was determined.",
journal = "Materials Today Communications",
title = "Functional nano-silver decorated textiles for wearable electronics and electromagnetic interference shielding",
volume = "34",
pages = "105312",
doi = "10.1016/j.mtcomm.2023.105312"
}
Stupar, S., Vuksanović, M. M., Mijin, D. Ž., Bučko, M. M., Joksimović, V. J., Barudžija, T.,& Tanić, M. N.. (2023). Functional nano-silver decorated textiles for wearable electronics and electromagnetic interference shielding. in Materials Today Communications, 34, 105312.
https://doi.org/10.1016/j.mtcomm.2023.105312
Stupar S, Vuksanović MM, Mijin DŽ, Bučko MM, Joksimović VJ, Barudžija T, Tanić MN. Functional nano-silver decorated textiles for wearable electronics and electromagnetic interference shielding. in Materials Today Communications. 2023;34:105312.
doi:10.1016/j.mtcomm.2023.105312 .
Stupar, Stevan, Vuksanović, Marija M., Mijin, Dušan Ž., Bučko, Mihael M., Joksimović, Vasilija J., Barudžija, Tanja, Tanić, Milan N., "Functional nano-silver decorated textiles for wearable electronics and electromagnetic interference shielding" in Materials Today Communications, 34 (2023):105312,
https://doi.org/10.1016/j.mtcomm.2023.105312 . .
5
4

Microwave-induced synthesis of zinc-phthalocyanine with improved photosensitizing potential

Vasiljević, Bojana; Milivojević, Dušan; Barudžija, Tanja; Budimir, Milica; Mijin, Dušan; Marinović-Cincović, Milena; Marinković, Dragana

(2023)

TY  - JOUR
AU  - Vasiljević, Bojana
AU  - Milivojević, Dušan
AU  - Barudžija, Tanja
AU  - Budimir, Milica
AU  - Mijin, Dušan
AU  - Marinović-Cincović, Milena
AU  - Marinković, Dragana
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/11349
AB  - In this paper, an efficient and environmentally friendly approach to the microwave-assisted synthesis of zinc
phthalocyanine (ZnPc) was developed to compare the features and changes in morphology, phase, and optical
properties with crystals obtained under conventional synthesis. Well-crystallized with high yield and purity ZnPc
in β-form was obtained by fast and efficient microwave-assisted procedure after five minutes of microwave
heating. Studies including electron paramagnet resonance (EPR) indicated the improved photosensitizing potential of microwave-produced crystals, creating viable candidates for photodynamic treatment. Gamma rays
aftereffect confirmed the stability of the ZnPc making them versatile in their application in medicine and sophisticated technology.
T2  - Materials Letters
T1  - Microwave-induced synthesis of zinc-phthalocyanine with improved photosensitizing potential
VL  - 350
SP  - 134911
DO  - 10.1016/j.matlet.2023.134911
ER  - 
@article{
author = "Vasiljević, Bojana and Milivojević, Dušan and Barudžija, Tanja and Budimir, Milica and Mijin, Dušan and Marinović-Cincović, Milena and Marinković, Dragana",
year = "2023",
abstract = "In this paper, an efficient and environmentally friendly approach to the microwave-assisted synthesis of zinc
phthalocyanine (ZnPc) was developed to compare the features and changes in morphology, phase, and optical
properties with crystals obtained under conventional synthesis. Well-crystallized with high yield and purity ZnPc
in β-form was obtained by fast and efficient microwave-assisted procedure after five minutes of microwave
heating. Studies including electron paramagnet resonance (EPR) indicated the improved photosensitizing potential of microwave-produced crystals, creating viable candidates for photodynamic treatment. Gamma rays
aftereffect confirmed the stability of the ZnPc making them versatile in their application in medicine and sophisticated technology.",
journal = "Materials Letters",
title = "Microwave-induced synthesis of zinc-phthalocyanine with improved photosensitizing potential",
volume = "350",
pages = "134911",
doi = "10.1016/j.matlet.2023.134911"
}
Vasiljević, B., Milivojević, D., Barudžija, T., Budimir, M., Mijin, D., Marinović-Cincović, M.,& Marinković, D.. (2023). Microwave-induced synthesis of zinc-phthalocyanine with improved photosensitizing potential. in Materials Letters, 350, 134911.
https://doi.org/10.1016/j.matlet.2023.134911
Vasiljević B, Milivojević D, Barudžija T, Budimir M, Mijin D, Marinović-Cincović M, Marinković D. Microwave-induced synthesis of zinc-phthalocyanine with improved photosensitizing potential. in Materials Letters. 2023;350:134911.
doi:10.1016/j.matlet.2023.134911 .
Vasiljević, Bojana, Milivojević, Dušan, Barudžija, Tanja, Budimir, Milica, Mijin, Dušan, Marinović-Cincović, Milena, Marinković, Dragana, "Microwave-induced synthesis of zinc-phthalocyanine with improved photosensitizing potential" in Materials Letters, 350 (2023):134911,
https://doi.org/10.1016/j.matlet.2023.134911 . .

Influence of grinding, pressing and sintering of the powder 50.0 wt% Fe, 47.0 wt% BaTiO3 and 3.0 wt% TiO2 on morphology, microstructure, magnetic and electric properties

Luković, Milentije; Spasojević-Savković, Milica; Kosić, Olivera; Barudžija, Tanja; Lojpur, Vesna; Maričić, Aleksa; Spasojević, Miroslav

(2023)

TY  - JOUR
AU  - Luković, Milentije
AU  - Spasojević-Savković, Milica
AU  - Kosić, Olivera
AU  - Barudžija, Tanja
AU  - Lojpur, Vesna
AU  - Maričić, Aleksa
AU  - Spasojević, Miroslav
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/12841
AB  - A mixture of 50.0 wt% Fe, 47.0 wt% BaTiO3, and 3.0 wt% TiO2 powders is milled and then pressed and sintered. Samples sintered from ground powders have a structure consisting of plates. They consist of the crystalline phase BaFe12O19 and crystalline and amorphous phases Fe, BaTiO3, and TiO2. Samples sintered from powders ground for more than 180 min are compact and composed of BaFe12O19 crystals embedded in an amorphous matrix consisting of amorphous BaTiO3 and TiO2 phases. Magnetization of a sample ground for 220 min gradually decreases with increasing temperature up to 440°C. This decrease result from the transition of ordered domains into chaotically directed domains. Above 440°C, the thermal energy is sufficiently large to destroy ordered paramagnetic ferromagnetic and weakly ferromagnetic domains. During sample cooling in the absence of an external magnetic field, the temperature dependence of magnetization is the same as that obtained during heating in the magnetic field. However, during the sample cooling in the magnetic field, substantially higher values of magnetization are obtained. Considerably higher magnetization of the cooled sample remains even after switching off the external magnetic field. The sintered sample, previously pressed in the magnetic field, has a higher dielectric constant than the sample pressed in the absence of the magnetic field. The dielectric constant decreases with increasing frequency.
T2  - Science of Sintering
T1  - Influence of grinding, pressing and sintering of the powder 50.0 wt% Fe, 47.0 wt% BaTiO3 and 3.0 wt% TiO2 on morphology, microstructure, magnetic and electric properties
IS  - InPress
SP  - 67
EP  - 67
DO  - 10.2298/SOS230915067L
ER  - 
@article{
author = "Luković, Milentije and Spasojević-Savković, Milica and Kosić, Olivera and Barudžija, Tanja and Lojpur, Vesna and Maričić, Aleksa and Spasojević, Miroslav",
year = "2023",
abstract = "A mixture of 50.0 wt% Fe, 47.0 wt% BaTiO3, and 3.0 wt% TiO2 powders is milled and then pressed and sintered. Samples sintered from ground powders have a structure consisting of plates. They consist of the crystalline phase BaFe12O19 and crystalline and amorphous phases Fe, BaTiO3, and TiO2. Samples sintered from powders ground for more than 180 min are compact and composed of BaFe12O19 crystals embedded in an amorphous matrix consisting of amorphous BaTiO3 and TiO2 phases. Magnetization of a sample ground for 220 min gradually decreases with increasing temperature up to 440°C. This decrease result from the transition of ordered domains into chaotically directed domains. Above 440°C, the thermal energy is sufficiently large to destroy ordered paramagnetic ferromagnetic and weakly ferromagnetic domains. During sample cooling in the absence of an external magnetic field, the temperature dependence of magnetization is the same as that obtained during heating in the magnetic field. However, during the sample cooling in the magnetic field, substantially higher values of magnetization are obtained. Considerably higher magnetization of the cooled sample remains even after switching off the external magnetic field. The sintered sample, previously pressed in the magnetic field, has a higher dielectric constant than the sample pressed in the absence of the magnetic field. The dielectric constant decreases with increasing frequency.",
journal = "Science of Sintering",
title = "Influence of grinding, pressing and sintering of the powder 50.0 wt% Fe, 47.0 wt% BaTiO3 and 3.0 wt% TiO2 on morphology, microstructure, magnetic and electric properties",
number = "InPress",
pages = "67-67",
doi = "10.2298/SOS230915067L"
}
Luković, M., Spasojević-Savković, M., Kosić, O., Barudžija, T., Lojpur, V., Maričić, A.,& Spasojević, M.. (2023). Influence of grinding, pressing and sintering of the powder 50.0 wt% Fe, 47.0 wt% BaTiO3 and 3.0 wt% TiO2 on morphology, microstructure, magnetic and electric properties. in Science of Sintering(InPress), 67-67.
https://doi.org/10.2298/SOS230915067L
Luković M, Spasojević-Savković M, Kosić O, Barudžija T, Lojpur V, Maričić A, Spasojević M. Influence of grinding, pressing and sintering of the powder 50.0 wt% Fe, 47.0 wt% BaTiO3 and 3.0 wt% TiO2 on morphology, microstructure, magnetic and electric properties. in Science of Sintering. 2023;(InPress):67-67.
doi:10.2298/SOS230915067L .
Luković, Milentije, Spasojević-Savković, Milica, Kosić, Olivera, Barudžija, Tanja, Lojpur, Vesna, Maričić, Aleksa, Spasojević, Miroslav, "Influence of grinding, pressing and sintering of the powder 50.0 wt% Fe, 47.0 wt% BaTiO3 and 3.0 wt% TiO2 on morphology, microstructure, magnetic and electric properties" in Science of Sintering, no. InPress (2023):67-67,
https://doi.org/10.2298/SOS230915067L . .

Seeded silicon nitride powders obtained by carbothermal reduction—nitridation of diatomite and various sources of carbon

Šaponjić, Aleksandra; Ilić, Svetlana; Barudžija, Tanja; Radosavljević-Mihajlović, Ana S.; Kokunešoski, Maja; Matović, Branko

(2023)

TY  - JOUR
AU  - Šaponjić, Aleksandra
AU  - Ilić, Svetlana
AU  - Barudžija, Tanja
AU  - Radosavljević-Mihajlović, Ana S.
AU  - Kokunešoski, Maja
AU  - Matović, Branko
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10852
AB  - In this paper, the effects of the addition of silicon nitride seeds on the phase composition, particle size, and shape of silicon nitride powders obtained by carbothermal reduction-nitridation were studied. Environmentally friendly natural raw material, diatomaceous earth, was used as a Si precursor. Three different carbon sources were used: activated carbon, carbonized sucrose, and carbon cryogel as reducing agents in the molar ratio C/SiO2 = 5. To obtain better-quality Si3N4 powder, the commercial α-Si3N4 powder was added into starting mixtures as seeds in four different quantities. The X-ray diffraction, specific surface area, infrared spectroscopy with Fourier transform, and scanning electron microscopy were employed to characterize the obtained powders. Sucrose as a carbon source enables a major reduction of SiO2 and the onset of β-Si3N4 crystallization at a lower temperature (1350 °C) as well as the complete absence of diatomaceous earth relics. It indicates that the carbothermal reduction-nitridation takes place faster in contrast to the other two carbon sources.
T2  - Journal of the Australian Ceramic Society
T1  - Seeded silicon nitride powders obtained by carbothermal reduction—nitridation of diatomite and various sources of carbon
VL  - 59
SP  - 823
EP  - 835
DO  - 10.1007/s41779-023-00876-w
ER  - 
@article{
author = "Šaponjić, Aleksandra and Ilić, Svetlana and Barudžija, Tanja and Radosavljević-Mihajlović, Ana S. and Kokunešoski, Maja and Matović, Branko",
year = "2023",
abstract = "In this paper, the effects of the addition of silicon nitride seeds on the phase composition, particle size, and shape of silicon nitride powders obtained by carbothermal reduction-nitridation were studied. Environmentally friendly natural raw material, diatomaceous earth, was used as a Si precursor. Three different carbon sources were used: activated carbon, carbonized sucrose, and carbon cryogel as reducing agents in the molar ratio C/SiO2 = 5. To obtain better-quality Si3N4 powder, the commercial α-Si3N4 powder was added into starting mixtures as seeds in four different quantities. The X-ray diffraction, specific surface area, infrared spectroscopy with Fourier transform, and scanning electron microscopy were employed to characterize the obtained powders. Sucrose as a carbon source enables a major reduction of SiO2 and the onset of β-Si3N4 crystallization at a lower temperature (1350 °C) as well as the complete absence of diatomaceous earth relics. It indicates that the carbothermal reduction-nitridation takes place faster in contrast to the other two carbon sources.",
journal = "Journal of the Australian Ceramic Society",
title = "Seeded silicon nitride powders obtained by carbothermal reduction—nitridation of diatomite and various sources of carbon",
volume = "59",
pages = "823-835",
doi = "10.1007/s41779-023-00876-w"
}
Šaponjić, A., Ilić, S., Barudžija, T., Radosavljević-Mihajlović, A. S., Kokunešoski, M.,& Matović, B.. (2023). Seeded silicon nitride powders obtained by carbothermal reduction—nitridation of diatomite and various sources of carbon. in Journal of the Australian Ceramic Society, 59, 823-835.
https://doi.org/10.1007/s41779-023-00876-w
Šaponjić A, Ilić S, Barudžija T, Radosavljević-Mihajlović AS, Kokunešoski M, Matović B. Seeded silicon nitride powders obtained by carbothermal reduction—nitridation of diatomite and various sources of carbon. in Journal of the Australian Ceramic Society. 2023;59:823-835.
doi:10.1007/s41779-023-00876-w .
Šaponjić, Aleksandra, Ilić, Svetlana, Barudžija, Tanja, Radosavljević-Mihajlović, Ana S., Kokunešoski, Maja, Matović, Branko, "Seeded silicon nitride powders obtained by carbothermal reduction—nitridation of diatomite and various sources of carbon" in Journal of the Australian Ceramic Society, 59 (2023):823-835,
https://doi.org/10.1007/s41779-023-00876-w . .

Evaluation of the antibacterial effectiveness of novel copper/polypyrrole nanocomposite

Mašojević, Dijana; Stamenović, Una; Otoničar, Mojca; Davidović, Slađana; Škapin, Srečo Davor; Barudžija, Tanja; Vodnik, Vesna

(2023)

TY  - JOUR
AU  - Mašojević, Dijana
AU  - Stamenović, Una
AU  - Otoničar, Mojca
AU  - Davidović, Slađana
AU  - Škapin, Srečo Davor
AU  - Barudžija, Tanja
AU  - Vodnik, Vesna
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10657
AB  - A novel and effective antibacterial agent based on a combination of copper nanoparticles (CuNPs) and polypyrrole (PPy) is presented. By using a straightforward in situ polymerization method in water, a copper/polypyrrole (Cu/PPy) nanocomposite with spherical CuNPs, around 25 nm in diameter, uniformly dispersed throughout a granular PPy matrix, was characterized and subjected to determination of antibacterial activity toward E. coli, and S. aureus. In this survey, the synergistic engagement of various features of CuNPs and PPy against bacteria was somewhat expected. After a 24 h interaction with S. aureus, already 2 ppm of Cu/PPy with only 9.45 wt% content of Cu is acting almost completely cidal, with 99.17 % bacterial growth inhibition, while 10 ppm has a cidal value of 99.99 % at the same time. Safe and environmentally acceptable concentrations of Cu/PPy indicate that it is convenient as an antibacterial agent for wider use.
T2  - Materials Letters
T1  - Evaluation of the antibacterial effectiveness of novel copper/polypyrrole nanocomposite
VL  - 338
SP  - 134051
DO  - 10.1016/j.matlet.2023.134051
ER  - 
@article{
author = "Mašojević, Dijana and Stamenović, Una and Otoničar, Mojca and Davidović, Slađana and Škapin, Srečo Davor and Barudžija, Tanja and Vodnik, Vesna",
year = "2023",
abstract = "A novel and effective antibacterial agent based on a combination of copper nanoparticles (CuNPs) and polypyrrole (PPy) is presented. By using a straightforward in situ polymerization method in water, a copper/polypyrrole (Cu/PPy) nanocomposite with spherical CuNPs, around 25 nm in diameter, uniformly dispersed throughout a granular PPy matrix, was characterized and subjected to determination of antibacterial activity toward E. coli, and S. aureus. In this survey, the synergistic engagement of various features of CuNPs and PPy against bacteria was somewhat expected. After a 24 h interaction with S. aureus, already 2 ppm of Cu/PPy with only 9.45 wt% content of Cu is acting almost completely cidal, with 99.17 % bacterial growth inhibition, while 10 ppm has a cidal value of 99.99 % at the same time. Safe and environmentally acceptable concentrations of Cu/PPy indicate that it is convenient as an antibacterial agent for wider use.",
journal = "Materials Letters",
title = "Evaluation of the antibacterial effectiveness of novel copper/polypyrrole nanocomposite",
volume = "338",
pages = "134051",
doi = "10.1016/j.matlet.2023.134051"
}
Mašojević, D., Stamenović, U., Otoničar, M., Davidović, S., Škapin, S. D., Barudžija, T.,& Vodnik, V.. (2023). Evaluation of the antibacterial effectiveness of novel copper/polypyrrole nanocomposite. in Materials Letters, 338, 134051.
https://doi.org/10.1016/j.matlet.2023.134051
Mašojević D, Stamenović U, Otoničar M, Davidović S, Škapin SD, Barudžija T, Vodnik V. Evaluation of the antibacterial effectiveness of novel copper/polypyrrole nanocomposite. in Materials Letters. 2023;338:134051.
doi:10.1016/j.matlet.2023.134051 .
Mašojević, Dijana, Stamenović, Una, Otoničar, Mojca, Davidović, Slađana, Škapin, Srečo Davor, Barudžija, Tanja, Vodnik, Vesna, "Evaluation of the antibacterial effectiveness of novel copper/polypyrrole nanocomposite" in Materials Letters, 338 (2023):134051,
https://doi.org/10.1016/j.matlet.2023.134051 . .
1
1

Influence of poly(vinyl alcohol)/poly(N-vinyl-2-pyrrolidone) polymer matrix composition on the bonding environment and characteristics of Ag nanoparticles produced by gamma irradiation

Nikolić, Nikolina; Spasojević, Jelena P.; Radosavljević, Aleksandra; Milošević, Milica V.; Barudžija, Tanja; Rakočević, Lazar; Kačarević-Popović, Zorica M.

(2023)

TY  - JOUR
AU  - Nikolić, Nikolina
AU  - Spasojević, Jelena P.
AU  - Radosavljević, Aleksandra
AU  - Milošević, Milica V.
AU  - Barudžija, Tanja
AU  - Rakočević, Lazar
AU  - Kačarević-Popović, Zorica M.
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10449
AB  - A series of silver nanoparticles (AgNPs)-poly(vinyl alcohol)/poly(N-vinyl-2-pyrrolidone) (PVA/PVP) hydrogel nanocomposites were synthesized by gamma irradiation to examine the matrix's impact on properties of Ag nanocrystals important for strain engineering in functional materials. SEM analysis and the swelling studies revealed nanocomposite morphology and fluid transport properties. UV–Vis absorption characterization of AgNPs has enabled an understanding of the cluster size effects. The gel content indicated inter-crosslinking of the two components of the polymer matrix, especially for equivalent (1:1) PVA/PVP ratio, affecting the investigated AgNPs structural parameters. The lattice parameters and the interface stress, analyzed using XRD, have the lowest negative magnitude from the bulk lattice constant for the PVA/PVP (2:1) and (1:1) ratio. The lowest values of the lattice strain and dislocation density, as mutually dependent parameters, are obtained in AgNPs embedded in a PVA/PVP (2:1) and (1:1) matrix. The XPS and FTIR data show a positive shift of the O1s and a redshift of the CO – Ag vibration band indicating charge transfer to the vacant orbital of Ag nanocrystals. The N atoms of the pyrrolidine ring are not directly involved in the electronic interactions, but over the p-π conjugation with carbonyl O. In addition, the tested Ag-(PVA/PVP) hydrogel nanocomposites showed significant potential as a broad-spectrum antibacterial material.
T2  - Radiation Physics and Chemistry
T1  - Influence of poly(vinyl alcohol)/poly(N-vinyl-2-pyrrolidone) polymer matrix composition on the bonding environment and characteristics of Ag nanoparticles produced by gamma irradiation
VL  - 202
SP  - 110564
DO  - 10.1016/j.radphyschem.2022.110564
ER  - 
@article{
author = "Nikolić, Nikolina and Spasojević, Jelena P. and Radosavljević, Aleksandra and Milošević, Milica V. and Barudžija, Tanja and Rakočević, Lazar and Kačarević-Popović, Zorica M.",
year = "2023",
abstract = "A series of silver nanoparticles (AgNPs)-poly(vinyl alcohol)/poly(N-vinyl-2-pyrrolidone) (PVA/PVP) hydrogel nanocomposites were synthesized by gamma irradiation to examine the matrix's impact on properties of Ag nanocrystals important for strain engineering in functional materials. SEM analysis and the swelling studies revealed nanocomposite morphology and fluid transport properties. UV–Vis absorption characterization of AgNPs has enabled an understanding of the cluster size effects. The gel content indicated inter-crosslinking of the two components of the polymer matrix, especially for equivalent (1:1) PVA/PVP ratio, affecting the investigated AgNPs structural parameters. The lattice parameters and the interface stress, analyzed using XRD, have the lowest negative magnitude from the bulk lattice constant for the PVA/PVP (2:1) and (1:1) ratio. The lowest values of the lattice strain and dislocation density, as mutually dependent parameters, are obtained in AgNPs embedded in a PVA/PVP (2:1) and (1:1) matrix. The XPS and FTIR data show a positive shift of the O1s and a redshift of the CO – Ag vibration band indicating charge transfer to the vacant orbital of Ag nanocrystals. The N atoms of the pyrrolidine ring are not directly involved in the electronic interactions, but over the p-π conjugation with carbonyl O. In addition, the tested Ag-(PVA/PVP) hydrogel nanocomposites showed significant potential as a broad-spectrum antibacterial material.",
journal = "Radiation Physics and Chemistry",
title = "Influence of poly(vinyl alcohol)/poly(N-vinyl-2-pyrrolidone) polymer matrix composition on the bonding environment and characteristics of Ag nanoparticles produced by gamma irradiation",
volume = "202",
pages = "110564",
doi = "10.1016/j.radphyschem.2022.110564"
}
Nikolić, N., Spasojević, J. P., Radosavljević, A., Milošević, M. V., Barudžija, T., Rakočević, L.,& Kačarević-Popović, Z. M.. (2023). Influence of poly(vinyl alcohol)/poly(N-vinyl-2-pyrrolidone) polymer matrix composition on the bonding environment and characteristics of Ag nanoparticles produced by gamma irradiation. in Radiation Physics and Chemistry, 202, 110564.
https://doi.org/10.1016/j.radphyschem.2022.110564
Nikolić N, Spasojević JP, Radosavljević A, Milošević MV, Barudžija T, Rakočević L, Kačarević-Popović ZM. Influence of poly(vinyl alcohol)/poly(N-vinyl-2-pyrrolidone) polymer matrix composition on the bonding environment and characteristics of Ag nanoparticles produced by gamma irradiation. in Radiation Physics and Chemistry. 2023;202:110564.
doi:10.1016/j.radphyschem.2022.110564 .
Nikolić, Nikolina, Spasojević, Jelena P., Radosavljević, Aleksandra, Milošević, Milica V., Barudžija, Tanja, Rakočević, Lazar, Kačarević-Popović, Zorica M., "Influence of poly(vinyl alcohol)/poly(N-vinyl-2-pyrrolidone) polymer matrix composition on the bonding environment and characteristics of Ag nanoparticles produced by gamma irradiation" in Radiation Physics and Chemistry, 202 (2023):110564,
https://doi.org/10.1016/j.radphyschem.2022.110564 . .
11
6

Enhancement of up-conversion luminescent characteristics of Yb3+/Ho3+ co-doped Bi3+ based SrGd2O4 nanoparticles

Stamenković, Tijana; Radmilović, Nadežda; Dinić, Ivana; Vuković, Marina; Barudžija, Tanja; Čebela, Maria; Lojpur, Vesna

(Belgrade : Institute for Multidisciplinary Research, 2023)

TY  - CONF
AU  - Stamenković, Tijana
AU  - Radmilović, Nadežda
AU  - Dinić, Ivana
AU  - Vuković, Marina
AU  - Barudžija, Tanja
AU  - Čebela, Maria
AU  - Lojpur, Vesna
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/11483
AB  - In this investigation, samples of SrGd2O4 doped with different Yb3+ (2, 4, 6 at.%) ions and constant Ho3+ (1 at.%) and Bi3+ (2 at.%) concentrations were prepared. The sol-gel method with glycine as a fuel and citric acid as a chelator was chosen for sample preparation. All samples were heated in the furnace for 1.5 h at 500 °C and then thermally treated for 2.5 h at 1000 °C. The pure orthorhombic lattice of SrGd2O4, space group Pnma, was revealed by X-ray diffraction (XRD) (JCPDS Card No.:01-072-6387). Transmission electron microscopy (TEM) discovered agglomerated clusters of spherical particles measuring around 150 nm in size. Including Bi3+ ions into the structure influenced the morphology of the sample showing fine packing of pyramidal-shaped nanoparticles. The uniform distribution of constitutive elements in the samples was confirmed by energy dispersive spectroscopy (EDS). Up-conversion emission properties were evaluated from photoluminescent emission spectra and intensity dependence on excitation power after excitation at 976 nm. Dominant green (550 nm), red (671 nm), and infrared (758 nm) 5F4, 5S2 → 5I8, 5F5 → 5I8, 5F4, 5S2 → 5I7 transition emissions, respectively, are detected in all samples. The sample co-doped with Bi3+ showed the most intense photoluminescent emission.
PB  - Belgrade : Institute for Multidisciplinary Research
C3  - Programme and the Book of Abstracts / 7th Conference of The Serbian Society for Ceramic Materials, 7CSCS-2023, June 14-16, 2023 Belgrade, Serbia
T1  - Enhancement of up-conversion luminescent characteristics of Yb3+/Ho3+ co-doped Bi3+ based SrGd2O4 nanoparticles
SP  - 113
EP  - 114
UR  - https://hdl.handle.net/21.15107/rcub_vinar_11483
ER  - 
@conference{
author = "Stamenković, Tijana and Radmilović, Nadežda and Dinić, Ivana and Vuković, Marina and Barudžija, Tanja and Čebela, Maria and Lojpur, Vesna",
year = "2023",
abstract = "In this investigation, samples of SrGd2O4 doped with different Yb3+ (2, 4, 6 at.%) ions and constant Ho3+ (1 at.%) and Bi3+ (2 at.%) concentrations were prepared. The sol-gel method with glycine as a fuel and citric acid as a chelator was chosen for sample preparation. All samples were heated in the furnace for 1.5 h at 500 °C and then thermally treated for 2.5 h at 1000 °C. The pure orthorhombic lattice of SrGd2O4, space group Pnma, was revealed by X-ray diffraction (XRD) (JCPDS Card No.:01-072-6387). Transmission electron microscopy (TEM) discovered agglomerated clusters of spherical particles measuring around 150 nm in size. Including Bi3+ ions into the structure influenced the morphology of the sample showing fine packing of pyramidal-shaped nanoparticles. The uniform distribution of constitutive elements in the samples was confirmed by energy dispersive spectroscopy (EDS). Up-conversion emission properties were evaluated from photoluminescent emission spectra and intensity dependence on excitation power after excitation at 976 nm. Dominant green (550 nm), red (671 nm), and infrared (758 nm) 5F4, 5S2 → 5I8, 5F5 → 5I8, 5F4, 5S2 → 5I7 transition emissions, respectively, are detected in all samples. The sample co-doped with Bi3+ showed the most intense photoluminescent emission.",
publisher = "Belgrade : Institute for Multidisciplinary Research",
journal = "Programme and the Book of Abstracts / 7th Conference of The Serbian Society for Ceramic Materials, 7CSCS-2023, June 14-16, 2023 Belgrade, Serbia",
title = "Enhancement of up-conversion luminescent characteristics of Yb3+/Ho3+ co-doped Bi3+ based SrGd2O4 nanoparticles",
pages = "113-114",
url = "https://hdl.handle.net/21.15107/rcub_vinar_11483"
}
Stamenković, T., Radmilović, N., Dinić, I., Vuković, M., Barudžija, T., Čebela, M.,& Lojpur, V.. (2023). Enhancement of up-conversion luminescent characteristics of Yb3+/Ho3+ co-doped Bi3+ based SrGd2O4 nanoparticles. in Programme and the Book of Abstracts / 7th Conference of The Serbian Society for Ceramic Materials, 7CSCS-2023, June 14-16, 2023 Belgrade, Serbia
Belgrade : Institute for Multidisciplinary Research., 113-114.
https://hdl.handle.net/21.15107/rcub_vinar_11483
Stamenković T, Radmilović N, Dinić I, Vuković M, Barudžija T, Čebela M, Lojpur V. Enhancement of up-conversion luminescent characteristics of Yb3+/Ho3+ co-doped Bi3+ based SrGd2O4 nanoparticles. in Programme and the Book of Abstracts / 7th Conference of The Serbian Society for Ceramic Materials, 7CSCS-2023, June 14-16, 2023 Belgrade, Serbia. 2023;:113-114.
https://hdl.handle.net/21.15107/rcub_vinar_11483 .
Stamenković, Tijana, Radmilović, Nadežda, Dinić, Ivana, Vuković, Marina, Barudžija, Tanja, Čebela, Maria, Lojpur, Vesna, "Enhancement of up-conversion luminescent characteristics of Yb3+/Ho3+ co-doped Bi3+ based SrGd2O4 nanoparticles" in Programme and the Book of Abstracts / 7th Conference of The Serbian Society for Ceramic Materials, 7CSCS-2023, June 14-16, 2023 Belgrade, Serbia (2023):113-114,
https://hdl.handle.net/21.15107/rcub_vinar_11483 .

Effect of Bi3+co-doping on the up-converting and photocatalytic properties of SrGd2O4:Yb3+/Ho3+ phase

Stamenković, Tijana; Dinić, Ivana; Vuković, Marina; Radmilović, Nadežda; Barudžija, Tanja; Tomić, Miloš; Mančić, Lidija; Lojpur, Vesna

(2023)

TY  - JOUR
AU  - Stamenković, Tijana
AU  - Dinić, Ivana
AU  - Vuković, Marina
AU  - Radmilović, Nadežda
AU  - Barudžija, Tanja
AU  - Tomić, Miloš
AU  - Mančić, Lidija
AU  - Lojpur, Vesna
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/11579
AB  - In this investigation, samples of strontium-gadolinium-oxide (SrGd2O4) doped with different Yb3+ (2, 4 and 6 at%) and constant Ho3+ (1 at%) contents and co-doped with Bi3+ (2 at%) were prepared using the glycine-assisted sol–gel method. The pure orthorhombic SrGd2O4 phase, space group Pnma, was revealed using X-ray diffraction in all samples. Transmission electron microscopy discovered agglomerated clusters of spherical particles measuring approximately 150 nm in size. The inclusion of Bi3+ ions into the structure influenced the morphology since the formation of larger grains was observed, with sizes reaching up to ∼1.7 μm. The uniform distribution of all constitutive elements was confirmed by energy-dispersive X-ray spectroscopy. In all samples, up-conversion emission spectra revealed two dominant green (540 and 550 nm), red (671 nm), and infrared (758 nm) emission lines, due to the 5F4,5S2→5I8, 5F5→5I8, and 5F4,5S2 → 5I7 transitions, respectively. The sample co-doped with Bi3+ showed the most intense photoluminescent emissions, shorter luminescence decay, and the highest quantum yield. Additionally, a significant decrease in the energy band gap value was detected using diffuse reflectance spectroscopy for this sample. Methylene blue was used as a test pollutant to investigate its photocatalytic efficiency under simulated sunlight irradiation. The results show that Bi3+ co-doping deteriorates the photocatalytic efficiency of the SrGd2O4:Yb3+/Ho3+ phase by reducing hydroxyl radical formation.
T2  - Ceramics International
T1  - Effect of Bi3+co-doping on the up-converting and photocatalytic properties of SrGd2O4:Yb3+/Ho3+ phase
DO  - 10.1016/j.ceramint.2023.09.103
ER  - 
@article{
author = "Stamenković, Tijana and Dinić, Ivana and Vuković, Marina and Radmilović, Nadežda and Barudžija, Tanja and Tomić, Miloš and Mančić, Lidija and Lojpur, Vesna",
year = "2023",
abstract = "In this investigation, samples of strontium-gadolinium-oxide (SrGd2O4) doped with different Yb3+ (2, 4 and 6 at%) and constant Ho3+ (1 at%) contents and co-doped with Bi3+ (2 at%) were prepared using the glycine-assisted sol–gel method. The pure orthorhombic SrGd2O4 phase, space group Pnma, was revealed using X-ray diffraction in all samples. Transmission electron microscopy discovered agglomerated clusters of spherical particles measuring approximately 150 nm in size. The inclusion of Bi3+ ions into the structure influenced the morphology since the formation of larger grains was observed, with sizes reaching up to ∼1.7 μm. The uniform distribution of all constitutive elements was confirmed by energy-dispersive X-ray spectroscopy. In all samples, up-conversion emission spectra revealed two dominant green (540 and 550 nm), red (671 nm), and infrared (758 nm) emission lines, due to the 5F4,5S2→5I8, 5F5→5I8, and 5F4,5S2 → 5I7 transitions, respectively. The sample co-doped with Bi3+ showed the most intense photoluminescent emissions, shorter luminescence decay, and the highest quantum yield. Additionally, a significant decrease in the energy band gap value was detected using diffuse reflectance spectroscopy for this sample. Methylene blue was used as a test pollutant to investigate its photocatalytic efficiency under simulated sunlight irradiation. The results show that Bi3+ co-doping deteriorates the photocatalytic efficiency of the SrGd2O4:Yb3+/Ho3+ phase by reducing hydroxyl radical formation.",
journal = "Ceramics International",
title = "Effect of Bi3+co-doping on the up-converting and photocatalytic properties of SrGd2O4:Yb3+/Ho3+ phase",
doi = "10.1016/j.ceramint.2023.09.103"
}
Stamenković, T., Dinić, I., Vuković, M., Radmilović, N., Barudžija, T., Tomić, M., Mančić, L.,& Lojpur, V.. (2023). Effect of Bi3+co-doping on the up-converting and photocatalytic properties of SrGd2O4:Yb3+/Ho3+ phase. in Ceramics International.
https://doi.org/10.1016/j.ceramint.2023.09.103
Stamenković T, Dinić I, Vuković M, Radmilović N, Barudžija T, Tomić M, Mančić L, Lojpur V. Effect of Bi3+co-doping on the up-converting and photocatalytic properties of SrGd2O4:Yb3+/Ho3+ phase. in Ceramics International. 2023;.
doi:10.1016/j.ceramint.2023.09.103 .
Stamenković, Tijana, Dinić, Ivana, Vuković, Marina, Radmilović, Nadežda, Barudžija, Tanja, Tomić, Miloš, Mančić, Lidija, Lojpur, Vesna, "Effect of Bi3+co-doping on the up-converting and photocatalytic properties of SrGd2O4:Yb3+/Ho3+ phase" in Ceramics International (2023),
https://doi.org/10.1016/j.ceramint.2023.09.103 . .

Copper Electrodeposition onto Palladium from a Deep Eutectic System Based on Choline Chloride

Cvetković, Vesna S.; Nikolić, Nebojša D.; Košević, Milica; Barudžija, Tanja; Dimitrijević, Silvana B.; Jovićević, Jovan N.

(Society of Chemists and Technologists of Macedonia, 2023)

TY  - CONF
AU  - Cvetković, Vesna S.
AU  - Nikolić, Nebojša D.
AU  - Košević, Milica
AU  - Barudžija, Tanja
AU  - Dimitrijević, Silvana B.
AU  - Jovićević, Jovan N.
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/11760
AB  - Recently, there has been an increasing interest in developing nonaqueous electrolytes which have been widely employed as an alternative media for a range of metals and metal alloys electrodepositions. A promising and new class of electrolytes among ionic liquids (Ils) are deep eutectic solvents (DESs)1 . The purpose of the copper deposition study from DESs is the application of copper coating and copper alloys in both, industry and fundamental research. In this work, the electrochemical deposition of copper onto palladium working substrate from ChCl/EG (1:2 ratio) DES electrolyte at 50°C was investigated. Additionally, the Cu(II) electroreduction process was studied by potentiodynamic measurements, cyclic voltammetry, chronoamperometry, in the electrolytes with different concentrations of Cu(II) ions ranging from 0.1 M to 0.5 M. The cyclic voltammetry results indicated that the bulk deposition of Cu(II) begins to occur at around –0.080 V vs. Cu. It was found that copper deposition onto the Pd cathode from ChCl:EG electrolyte under potentiostatic conditions is achievable. Data collected from X-ray diffraction (XRD) analysis proved that the cathodic deposits are composed of Cu and CuPd intermetallic. CuPd alloys with different Pd-Cu ratios were prepared by constant potential of –0.100 V vs. Cu from ChCl/EG containing 0.1 M and 0.5 M Cu(II). It is worth noting that the Xray data indicated that the composition of the produced Pd-Cu films could be varied by changing the concentration of Cu(II) ions in the electrolyte or changing the deposition mode.
PB  - Society of Chemists and Technologists of Macedonia
C3  - 26th Congress of the Society of Chemists and Technologists of Macedonia : the book of abstracts; September 20-23, Ohrid, Macedonia
T1  - Copper Electrodeposition onto Palladium from a Deep Eutectic System Based on Choline Chloride
SP  - 139
EP  - 139
UR  - https://hdl.handle.net/21.15107/rcub_vinar_11760
ER  - 
@conference{
author = "Cvetković, Vesna S. and Nikolić, Nebojša D. and Košević, Milica and Barudžija, Tanja and Dimitrijević, Silvana B. and Jovićević, Jovan N.",
year = "2023",
abstract = "Recently, there has been an increasing interest in developing nonaqueous electrolytes which have been widely employed as an alternative media for a range of metals and metal alloys electrodepositions. A promising and new class of electrolytes among ionic liquids (Ils) are deep eutectic solvents (DESs)1 . The purpose of the copper deposition study from DESs is the application of copper coating and copper alloys in both, industry and fundamental research. In this work, the electrochemical deposition of copper onto palladium working substrate from ChCl/EG (1:2 ratio) DES electrolyte at 50°C was investigated. Additionally, the Cu(II) electroreduction process was studied by potentiodynamic measurements, cyclic voltammetry, chronoamperometry, in the electrolytes with different concentrations of Cu(II) ions ranging from 0.1 M to 0.5 M. The cyclic voltammetry results indicated that the bulk deposition of Cu(II) begins to occur at around –0.080 V vs. Cu. It was found that copper deposition onto the Pd cathode from ChCl:EG electrolyte under potentiostatic conditions is achievable. Data collected from X-ray diffraction (XRD) analysis proved that the cathodic deposits are composed of Cu and CuPd intermetallic. CuPd alloys with different Pd-Cu ratios were prepared by constant potential of –0.100 V vs. Cu from ChCl/EG containing 0.1 M and 0.5 M Cu(II). It is worth noting that the Xray data indicated that the composition of the produced Pd-Cu films could be varied by changing the concentration of Cu(II) ions in the electrolyte or changing the deposition mode.",
publisher = "Society of Chemists and Technologists of Macedonia",
journal = "26th Congress of the Society of Chemists and Technologists of Macedonia : the book of abstracts; September 20-23, Ohrid, Macedonia",
title = "Copper Electrodeposition onto Palladium from a Deep Eutectic System Based on Choline Chloride",
pages = "139-139",
url = "https://hdl.handle.net/21.15107/rcub_vinar_11760"
}
Cvetković, V. S., Nikolić, N. D., Košević, M., Barudžija, T., Dimitrijević, S. B.,& Jovićević, J. N.. (2023). Copper Electrodeposition onto Palladium from a Deep Eutectic System Based on Choline Chloride. in 26th Congress of the Society of Chemists and Technologists of Macedonia : the book of abstracts; September 20-23, Ohrid, Macedonia
Society of Chemists and Technologists of Macedonia., 139-139.
https://hdl.handle.net/21.15107/rcub_vinar_11760
Cvetković VS, Nikolić ND, Košević M, Barudžija T, Dimitrijević SB, Jovićević JN. Copper Electrodeposition onto Palladium from a Deep Eutectic System Based on Choline Chloride. in 26th Congress of the Society of Chemists and Technologists of Macedonia : the book of abstracts; September 20-23, Ohrid, Macedonia. 2023;:139-139.
https://hdl.handle.net/21.15107/rcub_vinar_11760 .
Cvetković, Vesna S., Nikolić, Nebojša D., Košević, Milica, Barudžija, Tanja, Dimitrijević, Silvana B., Jovićević, Jovan N., "Copper Electrodeposition onto Palladium from a Deep Eutectic System Based on Choline Chloride" in 26th Congress of the Society of Chemists and Technologists of Macedonia : the book of abstracts; September 20-23, Ohrid, Macedonia (2023):139-139,
https://hdl.handle.net/21.15107/rcub_vinar_11760 .

Multispectral electromagnetic shielding and mechanical properties of carbon fabrics reinforced by silver deposition

Stupar, Stevan; Vuksanović, Marija M.; Mijin, Dušan Ž.; Milanović, Bojan C.; Joksimović, Vasilija J.; Barudžija, Tanja; Knežević, Marina R.

(2022)

TY  - JOUR
AU  - Stupar, Stevan
AU  - Vuksanović, Marija M.
AU  - Mijin, Dušan Ž.
AU  - Milanović, Bojan C.
AU  - Joksimović, Vasilija J.
AU  - Barudžija, Tanja
AU  - Knežević, Marina R.
PY  - 2022
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10369
AB  - Electromagnetic interference (EMI) has become a widespread modern environmental pollutant. There is an essential need for practical and applicable materials for its attenuation. Therefore, the presented research has focused on metallization of carbon fabric using the silver conductive complex solution to enhance the surface conductivity and mechanical properties of the fabric. With this amplification and improving the mentioned characteristics, lightweight and flexible modified carbon fibers can be applied in many environments. The modification has been performed in three steps: the silver conductive complex synthesis, carbon fabric immersion into a silver complex solution, treating with temperature for silver deposition by annealing. The method used for the metallization of carbon fabrics surface does not require expensive and toxic chemicals or electricity, making the process more ecologically and economically acceptable. One of the advantages of using the method for surface modification is the possibility of usage for other materials, not only for textiles and foils. The examination of the surface structure, electrical, EMI shielding characteristics, and mechanical properties of carbon fabrics modified by silver deposition contributes to the determination of multifunctional properties of materials. Also, the dependence on the improvement of multispectral electromagnetic interference shielding effectiveness (EMI SE) characteristics and mechanical properties of materials on the number of cycles has been determined. The most effective material was carbon fabric modified by five cycles, and average attenuation at an L and S bands was 49.67 dB, and a part of C and full X band was 51.07 dB, caused by better coverage by silver particles, increased density and porosity of deposited layer. Increasing the number of silver deposition cycles improves the physical properties of the modified carbon fabrics, where after five cycles the highest maximum force has been measured (2.26 kN). The material's morphology was studied by scanning electron microscopy with Energy-Dispersive X-ray Spectroscopy. The crystallographic phases of sintered particles were determined by X-ray diffraction. The crystallographic phases of sintered particles were determined by X-ray diffraction.
T2  - Materials Chemistry and Physics
T1  - Multispectral electromagnetic shielding and mechanical properties of carbon fabrics reinforced by silver deposition
VL  - 289
SP  - 126495
DO  - 10.1016/j.matchemphys.2022.126495
ER  - 
@article{
author = "Stupar, Stevan and Vuksanović, Marija M. and Mijin, Dušan Ž. and Milanović, Bojan C. and Joksimović, Vasilija J. and Barudžija, Tanja and Knežević, Marina R.",
year = "2022",
abstract = "Electromagnetic interference (EMI) has become a widespread modern environmental pollutant. There is an essential need for practical and applicable materials for its attenuation. Therefore, the presented research has focused on metallization of carbon fabric using the silver conductive complex solution to enhance the surface conductivity and mechanical properties of the fabric. With this amplification and improving the mentioned characteristics, lightweight and flexible modified carbon fibers can be applied in many environments. The modification has been performed in three steps: the silver conductive complex synthesis, carbon fabric immersion into a silver complex solution, treating with temperature for silver deposition by annealing. The method used for the metallization of carbon fabrics surface does not require expensive and toxic chemicals or electricity, making the process more ecologically and economically acceptable. One of the advantages of using the method for surface modification is the possibility of usage for other materials, not only for textiles and foils. The examination of the surface structure, electrical, EMI shielding characteristics, and mechanical properties of carbon fabrics modified by silver deposition contributes to the determination of multifunctional properties of materials. Also, the dependence on the improvement of multispectral electromagnetic interference shielding effectiveness (EMI SE) characteristics and mechanical properties of materials on the number of cycles has been determined. The most effective material was carbon fabric modified by five cycles, and average attenuation at an L and S bands was 49.67 dB, and a part of C and full X band was 51.07 dB, caused by better coverage by silver particles, increased density and porosity of deposited layer. Increasing the number of silver deposition cycles improves the physical properties of the modified carbon fabrics, where after five cycles the highest maximum force has been measured (2.26 kN). The material's morphology was studied by scanning electron microscopy with Energy-Dispersive X-ray Spectroscopy. The crystallographic phases of sintered particles were determined by X-ray diffraction. The crystallographic phases of sintered particles were determined by X-ray diffraction.",
journal = "Materials Chemistry and Physics",
title = "Multispectral electromagnetic shielding and mechanical properties of carbon fabrics reinforced by silver deposition",
volume = "289",
pages = "126495",
doi = "10.1016/j.matchemphys.2022.126495"
}
Stupar, S., Vuksanović, M. M., Mijin, D. Ž., Milanović, B. C., Joksimović, V. J., Barudžija, T.,& Knežević, M. R.. (2022). Multispectral electromagnetic shielding and mechanical properties of carbon fabrics reinforced by silver deposition. in Materials Chemistry and Physics, 289, 126495.
https://doi.org/10.1016/j.matchemphys.2022.126495
Stupar S, Vuksanović MM, Mijin DŽ, Milanović BC, Joksimović VJ, Barudžija T, Knežević MR. Multispectral electromagnetic shielding and mechanical properties of carbon fabrics reinforced by silver deposition. in Materials Chemistry and Physics. 2022;289:126495.
doi:10.1016/j.matchemphys.2022.126495 .
Stupar, Stevan, Vuksanović, Marija M., Mijin, Dušan Ž., Milanović, Bojan C., Joksimović, Vasilija J., Barudžija, Tanja, Knežević, Marina R., "Multispectral electromagnetic shielding and mechanical properties of carbon fabrics reinforced by silver deposition" in Materials Chemistry and Physics, 289 (2022):126495,
https://doi.org/10.1016/j.matchemphys.2022.126495 . .
12
10

Development of novel gamma radiation dosimeter based on metallophthalocyanine

Vasiljević, Bojana; Vujičić, Ivica; Barudžija, Tanja; Krstić, Maja; Budimir, Milica; Mijin, Dušan; Marinović-Cincović, Milena; Marinković, Dragana

(University of Szeged, 2022)

TY  - CONF
AU  - Vasiljević, Bojana
AU  - Vujičić, Ivica
AU  - Barudžija, Tanja
AU  - Krstić, Maja
AU  - Budimir, Milica
AU  - Mijin, Dušan
AU  - Marinović-Cincović, Milena
AU  - Marinković, Dragana
PY  - 2022
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/11471
AB  - In this study, zinc phthalocyanine was evaluated as a possible chemical dosimeter for gamma rays at low-medium dose ranges in solution form and PVA film. The zinc phthalocyanine was successfully synthesized with a high yield under microwave irradiation at 200 °C. The calibration curves of absorbance versus dose of gamma irradiation show excellent linearity over a wider dose range (1 - 25kGy). After being irradiated, the samples' color changed from blue to yellow.
PB  - University of Szeged
C3  - 28th International Symposium on Analytical and Environmental Problems : Proceedings book : November 14-15, Szeged, Hungary
T1  - Development of novel gamma radiation dosimeter based on metallophthalocyanine
SP  - 380
EP  - 376
UR  - https://hdl.handle.net/21.15107/rcub_vinar_11471
ER  - 
@conference{
author = "Vasiljević, Bojana and Vujičić, Ivica and Barudžija, Tanja and Krstić, Maja and Budimir, Milica and Mijin, Dušan and Marinović-Cincović, Milena and Marinković, Dragana",
year = "2022",
abstract = "In this study, zinc phthalocyanine was evaluated as a possible chemical dosimeter for gamma rays at low-medium dose ranges in solution form and PVA film. The zinc phthalocyanine was successfully synthesized with a high yield under microwave irradiation at 200 °C. The calibration curves of absorbance versus dose of gamma irradiation show excellent linearity over a wider dose range (1 - 25kGy). After being irradiated, the samples' color changed from blue to yellow.",
publisher = "University of Szeged",
journal = "28th International Symposium on Analytical and Environmental Problems : Proceedings book : November 14-15, Szeged, Hungary",
title = "Development of novel gamma radiation dosimeter based on metallophthalocyanine",
pages = "380-376",
url = "https://hdl.handle.net/21.15107/rcub_vinar_11471"
}
Vasiljević, B., Vujičić, I., Barudžija, T., Krstić, M., Budimir, M., Mijin, D., Marinović-Cincović, M.,& Marinković, D.. (2022). Development of novel gamma radiation dosimeter based on metallophthalocyanine. in 28th International Symposium on Analytical and Environmental Problems : Proceedings book : November 14-15, Szeged, Hungary
University of Szeged., 380-376.
https://hdl.handle.net/21.15107/rcub_vinar_11471
Vasiljević B, Vujičić I, Barudžija T, Krstić M, Budimir M, Mijin D, Marinović-Cincović M, Marinković D. Development of novel gamma radiation dosimeter based on metallophthalocyanine. in 28th International Symposium on Analytical and Environmental Problems : Proceedings book : November 14-15, Szeged, Hungary. 2022;:380-376.
https://hdl.handle.net/21.15107/rcub_vinar_11471 .
Vasiljević, Bojana, Vujičić, Ivica, Barudžija, Tanja, Krstić, Maja, Budimir, Milica, Mijin, Dušan, Marinović-Cincović, Milena, Marinković, Dragana, "Development of novel gamma radiation dosimeter based on metallophthalocyanine" in 28th International Symposium on Analytical and Environmental Problems : Proceedings book : November 14-15, Szeged, Hungary (2022):380-376,
https://hdl.handle.net/21.15107/rcub_vinar_11471 .

Optical properties of copper helical nanostructures: the effect of thickness on the SPR peak position

Potočnik, Jelena; Božinović, Nevena; Novaković, Mirjana M.; Barudžija, Tanja; Nenadović, Miloš; Popović, Maja

(2022)

TY  - JOUR
AU  - Potočnik, Jelena
AU  - Božinović, Nevena
AU  - Novaković, Mirjana M.
AU  - Barudžija, Tanja
AU  - Nenadović, Miloš
AU  - Popović, Maja
PY  - 2022
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10299
AB  - In this study, we have investigated the effect of thickness on the structural and optical properties of copper (Cu) helical nanostructures. Thin films with thicknesses of 160 nm, 280 nm, 450 nm, and 780 nm were obtained by e-beam glancing angle deposition. The morphology and the microstructure were studied by field emission scanning electron microscopy, x-ray diffraction and transmission electron microscopy, while for the optical analysis measurements spectroscopic ellipsometry was used. The results show that the deposited structures are porous with nanometer-sized crystallites preferentially oriented along (111) planes, as well as that the diameter of the helices increases with thickness. Detailed analyses of optical properties have demonstrated that the dielectric function of Cu structures is greatly influenced by the films thicknesses. With increasing thickness from 160 nm to 780 nm, the surface plasmon resonance peak was shifted from 1.31 eV to 1.05 eV, which was correlated with the growth mechanism and the size of deposited nanostructures.
T2  - Nanotechnology
T1  - Optical properties of copper helical nanostructures: the effect of thickness on the SPR peak position
VL  - 33
IS  - 34
SP  - 345710
DO  - 10.1088/1361-6528/ac705c
ER  - 
@article{
author = "Potočnik, Jelena and Božinović, Nevena and Novaković, Mirjana M. and Barudžija, Tanja and Nenadović, Miloš and Popović, Maja",
year = "2022",
abstract = "In this study, we have investigated the effect of thickness on the structural and optical properties of copper (Cu) helical nanostructures. Thin films with thicknesses of 160 nm, 280 nm, 450 nm, and 780 nm were obtained by e-beam glancing angle deposition. The morphology and the microstructure were studied by field emission scanning electron microscopy, x-ray diffraction and transmission electron microscopy, while for the optical analysis measurements spectroscopic ellipsometry was used. The results show that the deposited structures are porous with nanometer-sized crystallites preferentially oriented along (111) planes, as well as that the diameter of the helices increases with thickness. Detailed analyses of optical properties have demonstrated that the dielectric function of Cu structures is greatly influenced by the films thicknesses. With increasing thickness from 160 nm to 780 nm, the surface plasmon resonance peak was shifted from 1.31 eV to 1.05 eV, which was correlated with the growth mechanism and the size of deposited nanostructures.",
journal = "Nanotechnology",
title = "Optical properties of copper helical nanostructures: the effect of thickness on the SPR peak position",
volume = "33",
number = "34",
pages = "345710",
doi = "10.1088/1361-6528/ac705c"
}
Potočnik, J., Božinović, N., Novaković, M. M., Barudžija, T., Nenadović, M.,& Popović, M.. (2022). Optical properties of copper helical nanostructures: the effect of thickness on the SPR peak position. in Nanotechnology, 33(34), 345710.
https://doi.org/10.1088/1361-6528/ac705c
Potočnik J, Božinović N, Novaković MM, Barudžija T, Nenadović M, Popović M. Optical properties of copper helical nanostructures: the effect of thickness on the SPR peak position. in Nanotechnology. 2022;33(34):345710.
doi:10.1088/1361-6528/ac705c .
Potočnik, Jelena, Božinović, Nevena, Novaković, Mirjana M., Barudžija, Tanja, Nenadović, Miloš, Popović, Maja, "Optical properties of copper helical nanostructures: the effect of thickness on the SPR peak position" in Nanotechnology, 33, no. 34 (2022):345710,
https://doi.org/10.1088/1361-6528/ac705c . .
1
1

Fabrication of zigzag and square spiral Cu nanostructures: Influence of substrate rotation on the structural, optical and electrical properties

Potočnik, Jelena; Božinović, Nevena; Popović, Maja; Barudžija, Tanja; Nenadović, Miloš; Novaković, Mirjana M.

(2022)

TY  - JOUR
AU  - Potočnik, Jelena
AU  - Božinović, Nevena
AU  - Popović, Maja
AU  - Barudžija, Tanja
AU  - Nenadović, Miloš
AU  - Novaković, Mirjana M.
PY  - 2022
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10366
AB  - Copper (Cu) thin films were deposited by using glancing angle deposition in the form of zigzag and square spiral nanostructures. Thin films were fabricated under different azimuthal rotations (φ = 180°, 90°, 45°, 22.5° and 11°), to the thickness of approximately 300 nm. Morphological, chemical and structural properties were investigated by field-emission scanning electron microscopy, X-ray diffraction, X-ray photoelectron spectroscopy and high-resolution transmission electron microscopy. For the optical characterization of the samples spectroscopic ellipsometry was used, while the electrical properties were analyzed by four-point probe method. It was found that as the azimuthal rotation decreases, deposited nanostructures become more porous with larger number of grown arms. Both, optical and electrical analyses revealed that the properties of the obtained thin films are significantly influenced by growth mechanism. By decreasing the φ parameter, the surface plasmon resonance peak was shifted from 1038.9 nm to 1676.6 nm, which can be correlated with the porosity of Cu structures. Besides, it was found that the optical and electrical properties of the thin films are also strongly dependent on the concentration of defects.
T2  - Journal of Alloys and Compounds
T1  - Fabrication of zigzag and square spiral Cu nanostructures: Influence of substrate rotation on the structural, optical and electrical properties
VL  - 922
SP  - 166211
DO  - 10.1016/j.jallcom.2022.166211
ER  - 
@article{
author = "Potočnik, Jelena and Božinović, Nevena and Popović, Maja and Barudžija, Tanja and Nenadović, Miloš and Novaković, Mirjana M.",
year = "2022",
abstract = "Copper (Cu) thin films were deposited by using glancing angle deposition in the form of zigzag and square spiral nanostructures. Thin films were fabricated under different azimuthal rotations (φ = 180°, 90°, 45°, 22.5° and 11°), to the thickness of approximately 300 nm. Morphological, chemical and structural properties were investigated by field-emission scanning electron microscopy, X-ray diffraction, X-ray photoelectron spectroscopy and high-resolution transmission electron microscopy. For the optical characterization of the samples spectroscopic ellipsometry was used, while the electrical properties were analyzed by four-point probe method. It was found that as the azimuthal rotation decreases, deposited nanostructures become more porous with larger number of grown arms. Both, optical and electrical analyses revealed that the properties of the obtained thin films are significantly influenced by growth mechanism. By decreasing the φ parameter, the surface plasmon resonance peak was shifted from 1038.9 nm to 1676.6 nm, which can be correlated with the porosity of Cu structures. Besides, it was found that the optical and electrical properties of the thin films are also strongly dependent on the concentration of defects.",
journal = "Journal of Alloys and Compounds",
title = "Fabrication of zigzag and square spiral Cu nanostructures: Influence of substrate rotation on the structural, optical and electrical properties",
volume = "922",
pages = "166211",
doi = "10.1016/j.jallcom.2022.166211"
}
Potočnik, J., Božinović, N., Popović, M., Barudžija, T., Nenadović, M.,& Novaković, M. M.. (2022). Fabrication of zigzag and square spiral Cu nanostructures: Influence of substrate rotation on the structural, optical and electrical properties. in Journal of Alloys and Compounds, 922, 166211.
https://doi.org/10.1016/j.jallcom.2022.166211
Potočnik J, Božinović N, Popović M, Barudžija T, Nenadović M, Novaković MM. Fabrication of zigzag and square spiral Cu nanostructures: Influence of substrate rotation on the structural, optical and electrical properties. in Journal of Alloys and Compounds. 2022;922:166211.
doi:10.1016/j.jallcom.2022.166211 .
Potočnik, Jelena, Božinović, Nevena, Popović, Maja, Barudžija, Tanja, Nenadović, Miloš, Novaković, Mirjana M., "Fabrication of zigzag and square spiral Cu nanostructures: Influence of substrate rotation on the structural, optical and electrical properties" in Journal of Alloys and Compounds, 922 (2022):166211,
https://doi.org/10.1016/j.jallcom.2022.166211 . .

Silicon nitride based powders obtained by carbothermal reduction and nitridation of diatomite

Šaponjić, Aleksandra; Kokunešoski, Maja; Ilić, Svetlana; Radosavljević-Mihajlović, Ana S.; Barudžija, Tanja; Matović, Branko

(Belgrade : Society of Physical Chemists of Serbia, 2022)

TY  - CONF
AU  - Šaponjić, Aleksandra
AU  - Kokunešoski, Maja
AU  - Ilić, Svetlana
AU  - Radosavljević-Mihajlović, Ana S.
AU  - Barudžija, Tanja
AU  - Matović, Branko
PY  - 2022
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/11283
AB  - The possibilities of obtaining nanoparticles of non-oxide ceramic powders of silicon
nitride (Si3N4) by the method of carbothermal reduction and nitriding of diatomaceous
earth, a natural bio-amorphous raw material of low crystallinity, were investigated in this
paper. Activated carbon was used as a carbon source. In order to obtain better quality
Si3N4 powder in a faster and more efficient way, commercial α-Si3N4 powder was
introduced into starting mixtures. The starting mixtures of diatomaceous earth, activated
carbon, and differnt amounts of commercial α-Si3N4 powder (5, 10, 15, and 20) wt.%
were thermally treated for 2 h at 1350 and 1450 ºC. The obtained powders were
characterized by the following methods: X-ray diffraction (XRD), infrared spectroscopy
with Fourier transform (FTIR) and scanning electron microscopy (SEM).
PB  - Belgrade : Society of Physical Chemists of Serbia
C3  - PHYSICAL CHEMISTRY 2022 : 16th International Conference on Fundamental and Applied Aspects of Physical Chemistry : Proceedings, Vol. 2
T1  - Silicon nitride based powders obtained by carbothermal reduction and nitridation of diatomite
SP  - 370
EP  - 367
UR  - https://hdl.handle.net/21.15107/rcub_vinar_11283
ER  - 
@conference{
author = "Šaponjić, Aleksandra and Kokunešoski, Maja and Ilić, Svetlana and Radosavljević-Mihajlović, Ana S. and Barudžija, Tanja and Matović, Branko",
year = "2022",
abstract = "The possibilities of obtaining nanoparticles of non-oxide ceramic powders of silicon
nitride (Si3N4) by the method of carbothermal reduction and nitriding of diatomaceous
earth, a natural bio-amorphous raw material of low crystallinity, were investigated in this
paper. Activated carbon was used as a carbon source. In order to obtain better quality
Si3N4 powder in a faster and more efficient way, commercial α-Si3N4 powder was
introduced into starting mixtures. The starting mixtures of diatomaceous earth, activated
carbon, and differnt amounts of commercial α-Si3N4 powder (5, 10, 15, and 20) wt.%
were thermally treated for 2 h at 1350 and 1450 ºC. The obtained powders were
characterized by the following methods: X-ray diffraction (XRD), infrared spectroscopy
with Fourier transform (FTIR) and scanning electron microscopy (SEM).",
publisher = "Belgrade : Society of Physical Chemists of Serbia",
journal = "PHYSICAL CHEMISTRY 2022 : 16th International Conference on Fundamental and Applied Aspects of Physical Chemistry : Proceedings, Vol. 2",
title = "Silicon nitride based powders obtained by carbothermal reduction and nitridation of diatomite",
pages = "370-367",
url = "https://hdl.handle.net/21.15107/rcub_vinar_11283"
}
Šaponjić, A., Kokunešoski, M., Ilić, S., Radosavljević-Mihajlović, A. S., Barudžija, T.,& Matović, B.. (2022). Silicon nitride based powders obtained by carbothermal reduction and nitridation of diatomite. in PHYSICAL CHEMISTRY 2022 : 16th International Conference on Fundamental and Applied Aspects of Physical Chemistry : Proceedings, Vol. 2
Belgrade : Society of Physical Chemists of Serbia., 370-367.
https://hdl.handle.net/21.15107/rcub_vinar_11283
Šaponjić A, Kokunešoski M, Ilić S, Radosavljević-Mihajlović AS, Barudžija T, Matović B. Silicon nitride based powders obtained by carbothermal reduction and nitridation of diatomite. in PHYSICAL CHEMISTRY 2022 : 16th International Conference on Fundamental and Applied Aspects of Physical Chemistry : Proceedings, Vol. 2. 2022;:370-367.
https://hdl.handle.net/21.15107/rcub_vinar_11283 .
Šaponjić, Aleksandra, Kokunešoski, Maja, Ilić, Svetlana, Radosavljević-Mihajlović, Ana S., Barudžija, Tanja, Matović, Branko, "Silicon nitride based powders obtained by carbothermal reduction and nitridation of diatomite" in PHYSICAL CHEMISTRY 2022 : 16th International Conference on Fundamental and Applied Aspects of Physical Chemistry : Proceedings, Vol. 2 (2022):370-367,
https://hdl.handle.net/21.15107/rcub_vinar_11283 .

Infrared Photoluminescence of Nd-Doped Sesquioxide and Fluoride Nanocrystals: A Comparative Study

Gennari, Fulvia; Sekulić, Milica; Barudžija, Tanja; Antić, Željka; Dramićanin, Miroslav; Toncelli, Alessandra

(2022)

TY  - JOUR
AU  - Gennari, Fulvia
AU  - Sekulić, Milica
AU  - Barudžija, Tanja
AU  - Antić, Željka
AU  - Dramićanin, Miroslav
AU  - Toncelli, Alessandra
PY  - 2022
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10413
AB  - Lanthanide ions possess various emission channels in the near-infrared region that are well known in bulk crystals but are far less studied in samples with nanometric size. In this work, we present the infrared spectroscopic characterization of various Nd-doped fluoride and sesquioxide nanocrystals, namely Nd:Y2O3, Nd:Lu2O3, Nd:Sc2O3, Nd:YF3, and Nd:LuF3. Emissions from the three main emission bands in the near-infrared region have been observed and the emission cross-sections have been calculated. Moreover, another decay channel at around 2 μm has been observed and ascribed to the 4F3/2→4I15/2 transition. The lifetime of the 4F3/2 level has been measured under LED pumping. Emission cross-sections for the various compounds are calculated in the 1 μm, 900 nm, and 1.3 μm regions and are of the order of 10−20 cm2 in agreement with the literature results. Those in the 2 μm region are of the order of 10−21 cm2.
T2  - Crystals
T1  - Infrared Photoluminescence of Nd-Doped Sesquioxide and Fluoride Nanocrystals: A Comparative Study
VL  - 12
IS  - 8
SP  - 1071
DO  - 10.3390/cryst12081071
ER  - 
@article{
author = "Gennari, Fulvia and Sekulić, Milica and Barudžija, Tanja and Antić, Željka and Dramićanin, Miroslav and Toncelli, Alessandra",
year = "2022",
abstract = "Lanthanide ions possess various emission channels in the near-infrared region that are well known in bulk crystals but are far less studied in samples with nanometric size. In this work, we present the infrared spectroscopic characterization of various Nd-doped fluoride and sesquioxide nanocrystals, namely Nd:Y2O3, Nd:Lu2O3, Nd:Sc2O3, Nd:YF3, and Nd:LuF3. Emissions from the three main emission bands in the near-infrared region have been observed and the emission cross-sections have been calculated. Moreover, another decay channel at around 2 μm has been observed and ascribed to the 4F3/2→4I15/2 transition. The lifetime of the 4F3/2 level has been measured under LED pumping. Emission cross-sections for the various compounds are calculated in the 1 μm, 900 nm, and 1.3 μm regions and are of the order of 10−20 cm2 in agreement with the literature results. Those in the 2 μm region are of the order of 10−21 cm2.",
journal = "Crystals",
title = "Infrared Photoluminescence of Nd-Doped Sesquioxide and Fluoride Nanocrystals: A Comparative Study",
volume = "12",
number = "8",
pages = "1071",
doi = "10.3390/cryst12081071"
}
Gennari, F., Sekulić, M., Barudžija, T., Antić, Ž., Dramićanin, M.,& Toncelli, A.. (2022). Infrared Photoluminescence of Nd-Doped Sesquioxide and Fluoride Nanocrystals: A Comparative Study. in Crystals, 12(8), 1071.
https://doi.org/10.3390/cryst12081071
Gennari F, Sekulić M, Barudžija T, Antić Ž, Dramićanin M, Toncelli A. Infrared Photoluminescence of Nd-Doped Sesquioxide and Fluoride Nanocrystals: A Comparative Study. in Crystals. 2022;12(8):1071.
doi:10.3390/cryst12081071 .
Gennari, Fulvia, Sekulić, Milica, Barudžija, Tanja, Antić, Željka, Dramićanin, Miroslav, Toncelli, Alessandra, "Infrared Photoluminescence of Nd-Doped Sesquioxide and Fluoride Nanocrystals: A Comparative Study" in Crystals, 12, no. 8 (2022):1071,
https://doi.org/10.3390/cryst12081071 . .
1

Antimicrobial Nanocomposites Based on Oxidized Cotton Fabric and in situ Biosynthesized Copper Oxides Nanostructures Using Bearberry Leaves Extract

Krkobabić, Ana; Marković, Darka; Kovačević, Aleksandar; Tadić, Vanja; Radoičić, Marija B.; Barudžija, Tanja; Ilić-Tomić, Tatjana; Radetić, Maja M.

(2022)

TY  - JOUR
AU  - Krkobabić, Ana
AU  - Marković, Darka
AU  - Kovačević, Aleksandar
AU  - Tadić, Vanja
AU  - Radoičić, Marija B.
AU  - Barudžija, Tanja
AU  - Ilić-Tomić, Tatjana
AU  - Radetić, Maja M.
PY  - 2022
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10256
AB  - The aim of this study was to develop antimicrobial nanocomposite textile material comprising of Cu-based nanostructures synthesized on oxidized cotton fabric using Arctostaphylos uva-ursi (L.) Spreng., Ericaceae (bearberry leaves) as a green reducing agent for adsorbed Cu2+-ions. In order to provide sufficient number of carboxyl groups for complexation with Cu2+-ions a two-step oxidation process with NaIO4 and NaClO2 was carried out. The influence of NaIO4 concentration on content of carboxyl groups and Cu-based nanoparticles was studied by FTIR and AAS. HPLC analysis identified the gallic acid known as a reducing agent in bearberry leaves extract. FESEM and XRD analyses revealed that using bearberry leaves extract and gallic acid solution as reducing agents led to a formation of spherical Cu2O/CuO nanoparticles and CuO nanosheets, respectively. These nanoparticles and nanosheets provided excellent antibacterial activity against Gram-negative bacteria Escherichia coli and Gram-positive bacteria Staphylococcus aureus. Cytotoxicity on human keratinocyte cells was shown to depend on their copper content.
T2  - Fibers and Polymers
T1  - Antimicrobial Nanocomposites Based on Oxidized Cotton Fabric and in situ Biosynthesized Copper Oxides Nanostructures Using Bearberry Leaves Extract
VL  - 23
IS  - 4
SP  - 954
EP  - 966
DO  - 10.1007/s12221-022-4639-5
ER  - 
@article{
author = "Krkobabić, Ana and Marković, Darka and Kovačević, Aleksandar and Tadić, Vanja and Radoičić, Marija B. and Barudžija, Tanja and Ilić-Tomić, Tatjana and Radetić, Maja M.",
year = "2022",
abstract = "The aim of this study was to develop antimicrobial nanocomposite textile material comprising of Cu-based nanostructures synthesized on oxidized cotton fabric using Arctostaphylos uva-ursi (L.) Spreng., Ericaceae (bearberry leaves) as a green reducing agent for adsorbed Cu2+-ions. In order to provide sufficient number of carboxyl groups for complexation with Cu2+-ions a two-step oxidation process with NaIO4 and NaClO2 was carried out. The influence of NaIO4 concentration on content of carboxyl groups and Cu-based nanoparticles was studied by FTIR and AAS. HPLC analysis identified the gallic acid known as a reducing agent in bearberry leaves extract. FESEM and XRD analyses revealed that using bearberry leaves extract and gallic acid solution as reducing agents led to a formation of spherical Cu2O/CuO nanoparticles and CuO nanosheets, respectively. These nanoparticles and nanosheets provided excellent antibacterial activity against Gram-negative bacteria Escherichia coli and Gram-positive bacteria Staphylococcus aureus. Cytotoxicity on human keratinocyte cells was shown to depend on their copper content.",
journal = "Fibers and Polymers",
title = "Antimicrobial Nanocomposites Based on Oxidized Cotton Fabric and in situ Biosynthesized Copper Oxides Nanostructures Using Bearberry Leaves Extract",
volume = "23",
number = "4",
pages = "954-966",
doi = "10.1007/s12221-022-4639-5"
}
Krkobabić, A., Marković, D., Kovačević, A., Tadić, V., Radoičić, M. B., Barudžija, T., Ilić-Tomić, T.,& Radetić, M. M.. (2022). Antimicrobial Nanocomposites Based on Oxidized Cotton Fabric and in situ Biosynthesized Copper Oxides Nanostructures Using Bearberry Leaves Extract. in Fibers and Polymers, 23(4), 954-966.
https://doi.org/10.1007/s12221-022-4639-5
Krkobabić A, Marković D, Kovačević A, Tadić V, Radoičić MB, Barudžija T, Ilić-Tomić T, Radetić MM. Antimicrobial Nanocomposites Based on Oxidized Cotton Fabric and in situ Biosynthesized Copper Oxides Nanostructures Using Bearberry Leaves Extract. in Fibers and Polymers. 2022;23(4):954-966.
doi:10.1007/s12221-022-4639-5 .
Krkobabić, Ana, Marković, Darka, Kovačević, Aleksandar, Tadić, Vanja, Radoičić, Marija B., Barudžija, Tanja, Ilić-Tomić, Tatjana, Radetić, Maja M., "Antimicrobial Nanocomposites Based on Oxidized Cotton Fabric and in situ Biosynthesized Copper Oxides Nanostructures Using Bearberry Leaves Extract" in Fibers and Polymers, 23, no. 4 (2022):954-966,
https://doi.org/10.1007/s12221-022-4639-5 . .
3
1
3

Antibacterial activity of copper/polypyrrole nanocomposite

Mašojević, Dijana; Vodnik, Vesna; Spasojević, J.; Barudžija, Tanja; Otoničar, Mojca; Davidović, Slađana; Stamenović, Una

(Belgrade : Society of Physical Chemists of Serbia, 2022)

TY  - CONF
AU  - Mašojević, Dijana
AU  - Vodnik, Vesna
AU  - Spasojević, J.
AU  - Barudžija, Tanja
AU  - Otoničar, Mojca
AU  - Davidović, Slađana
AU  - Stamenović, Una
PY  - 2022
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/12535
AB  - A novel and favorable antibacterial agent as a combination of copper nanoparticles (CuNPs) and polypyrrole (PPy) is presented. By simple in situ polymerization method, copper/polypyrrole (Cu/PPy) nanocomposite with spherical CuNPs, around 25 nm in diameter, uniformly dispersed throughout PPy matrix with granular morphology, was characterized and subjected to determination of antibacterial activity toward bacteria Escherichia coli and Staphylococcus aureus. Knowing that when acting alone, CuNPs and PPy have already shown antimicrobial responce, their mutual and synergetic engagement against bacteria in this survey is somewhat expected. After a twenty-four-hour interaction with S. aureus, already 2 ppm of Cu/PPy with only 9.45 wt% content of Cu is acting almost completely cidal, with 99.17% of bacterial growth inhibition. Such nanocomposite could easily find application in water disinfection, soil sterilization and food preservation.
PB  - Belgrade : Society of Physical Chemists of Serbia
C3  - PHYSICAL CHEMISTRY 2022 : 16th International Conference on Fundamental and Applied Aspects of Physical Chemistry : Book of abstracts
T1  - Antibacterial activity of copper/polypyrrole nanocomposite
SP  - 174
EP  - 174
UR  - https://hdl.handle.net/21.15107/rcub_vinar_12535
ER  - 
@conference{
author = "Mašojević, Dijana and Vodnik, Vesna and Spasojević, J. and Barudžija, Tanja and Otoničar, Mojca and Davidović, Slađana and Stamenović, Una",
year = "2022",
abstract = "A novel and favorable antibacterial agent as a combination of copper nanoparticles (CuNPs) and polypyrrole (PPy) is presented. By simple in situ polymerization method, copper/polypyrrole (Cu/PPy) nanocomposite with spherical CuNPs, around 25 nm in diameter, uniformly dispersed throughout PPy matrix with granular morphology, was characterized and subjected to determination of antibacterial activity toward bacteria Escherichia coli and Staphylococcus aureus. Knowing that when acting alone, CuNPs and PPy have already shown antimicrobial responce, their mutual and synergetic engagement against bacteria in this survey is somewhat expected. After a twenty-four-hour interaction with S. aureus, already 2 ppm of Cu/PPy with only 9.45 wt% content of Cu is acting almost completely cidal, with 99.17% of bacterial growth inhibition. Such nanocomposite could easily find application in water disinfection, soil sterilization and food preservation.",
publisher = "Belgrade : Society of Physical Chemists of Serbia",
journal = "PHYSICAL CHEMISTRY 2022 : 16th International Conference on Fundamental and Applied Aspects of Physical Chemistry : Book of abstracts",
title = "Antibacterial activity of copper/polypyrrole nanocomposite",
pages = "174-174",
url = "https://hdl.handle.net/21.15107/rcub_vinar_12535"
}
Mašojević, D., Vodnik, V., Spasojević, J., Barudžija, T., Otoničar, M., Davidović, S.,& Stamenović, U.. (2022). Antibacterial activity of copper/polypyrrole nanocomposite. in PHYSICAL CHEMISTRY 2022 : 16th International Conference on Fundamental and Applied Aspects of Physical Chemistry : Book of abstracts
Belgrade : Society of Physical Chemists of Serbia., 174-174.
https://hdl.handle.net/21.15107/rcub_vinar_12535
Mašojević D, Vodnik V, Spasojević J, Barudžija T, Otoničar M, Davidović S, Stamenović U. Antibacterial activity of copper/polypyrrole nanocomposite. in PHYSICAL CHEMISTRY 2022 : 16th International Conference on Fundamental and Applied Aspects of Physical Chemistry : Book of abstracts. 2022;:174-174.
https://hdl.handle.net/21.15107/rcub_vinar_12535 .
Mašojević, Dijana, Vodnik, Vesna, Spasojević, J., Barudžija, Tanja, Otoničar, Mojca, Davidović, Slađana, Stamenović, Una, "Antibacterial activity of copper/polypyrrole nanocomposite" in PHYSICAL CHEMISTRY 2022 : 16th International Conference on Fundamental and Applied Aspects of Physical Chemistry : Book of abstracts (2022):174-174,
https://hdl.handle.net/21.15107/rcub_vinar_12535 .

Antibacterial activity of copper/polypyrrole nanocomposite

Mašojević, Dijana; Vodnik, Vesna; Spasojević, Jelena; Barudžija, Tanja; Otoničar, Mojca; Davidović, Slađana; Stamenović, Una

(Belgrade : Society of Physical Chemists of Serbia, 2022)

TY  - CONF
AU  - Mašojević, Dijana
AU  - Vodnik, Vesna
AU  - Spasojević, Jelena
AU  - Barudžija, Tanja
AU  - Otoničar, Mojca
AU  - Davidović, Slađana
AU  - Stamenović, Una
PY  - 2022
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/12536
AB  - A novel and favorable antibacterial agent as a combination of copper nanoparticles (CuNPs) and polypyrrole (PPy) is presented. By simple in situ polymerization method, copper/polypyrrole (Cu/PPy) nanocomposite with spherical CuNPs, around 25 nm in diameter, uniformly dispersed throughout PPy matrix with granular morphology, was characterized and subjected to determination of antibacterial activity toward bacteria Escherichia coli and Staphylococcus aureus. Knowing that when acting alone, CuNPs and PPy have already shown antimicrobial responce, their mutual and synergetic engagement against bacteria in this survey is somewhat expected. After a twenty-fourhour interaction with S. aureus, already 2 ppm of Cu/PPy with only 9.45 wt% content of Cu is acting almost completely cidal, with 99.17% of bacterial growth inhibition. Such nanocomposite could easily find application in water disinfection, soil sterilization and food preservation.
PB  - Belgrade : Society of Physical Chemists of Serbia
C3  - PHYSICAL CHEMISTRY 2022 : 16th International Conference on Fundamental and Applied Aspects of Physical Chemistry : Proceedings
T1  - Antibacterial activity of copper/polypyrrole nanocomposite
VL  - 2
SP  - 629
EP  - 632
UR  - https://hdl.handle.net/21.15107/rcub_vinar_12536
ER  - 
@conference{
author = "Mašojević, Dijana and Vodnik, Vesna and Spasojević, Jelena and Barudžija, Tanja and Otoničar, Mojca and Davidović, Slađana and Stamenović, Una",
year = "2022",
abstract = "A novel and favorable antibacterial agent as a combination of copper nanoparticles (CuNPs) and polypyrrole (PPy) is presented. By simple in situ polymerization method, copper/polypyrrole (Cu/PPy) nanocomposite with spherical CuNPs, around 25 nm in diameter, uniformly dispersed throughout PPy matrix with granular morphology, was characterized and subjected to determination of antibacterial activity toward bacteria Escherichia coli and Staphylococcus aureus. Knowing that when acting alone, CuNPs and PPy have already shown antimicrobial responce, their mutual and synergetic engagement against bacteria in this survey is somewhat expected. After a twenty-fourhour interaction with S. aureus, already 2 ppm of Cu/PPy with only 9.45 wt% content of Cu is acting almost completely cidal, with 99.17% of bacterial growth inhibition. Such nanocomposite could easily find application in water disinfection, soil sterilization and food preservation.",
publisher = "Belgrade : Society of Physical Chemists of Serbia",
journal = "PHYSICAL CHEMISTRY 2022 : 16th International Conference on Fundamental and Applied Aspects of Physical Chemistry : Proceedings",
title = "Antibacterial activity of copper/polypyrrole nanocomposite",
volume = "2",
pages = "629-632",
url = "https://hdl.handle.net/21.15107/rcub_vinar_12536"
}
Mašojević, D., Vodnik, V., Spasojević, J., Barudžija, T., Otoničar, M., Davidović, S.,& Stamenović, U.. (2022). Antibacterial activity of copper/polypyrrole nanocomposite. in PHYSICAL CHEMISTRY 2022 : 16th International Conference on Fundamental and Applied Aspects of Physical Chemistry : Proceedings
Belgrade : Society of Physical Chemists of Serbia., 2, 629-632.
https://hdl.handle.net/21.15107/rcub_vinar_12536
Mašojević D, Vodnik V, Spasojević J, Barudžija T, Otoničar M, Davidović S, Stamenović U. Antibacterial activity of copper/polypyrrole nanocomposite. in PHYSICAL CHEMISTRY 2022 : 16th International Conference on Fundamental and Applied Aspects of Physical Chemistry : Proceedings. 2022;2:629-632.
https://hdl.handle.net/21.15107/rcub_vinar_12536 .
Mašojević, Dijana, Vodnik, Vesna, Spasojević, Jelena, Barudžija, Tanja, Otoničar, Mojca, Davidović, Slađana, Stamenović, Una, "Antibacterial activity of copper/polypyrrole nanocomposite" in PHYSICAL CHEMISTRY 2022 : 16th International Conference on Fundamental and Applied Aspects of Physical Chemistry : Proceedings, 2 (2022):629-632,
https://hdl.handle.net/21.15107/rcub_vinar_12536 .

The Influence of a Binder in a Composite Electrode: The Case Study of Vanadyl Phosphate in Aqueous Electrolyte

Jugović, Dragana; Milović, Miloš; Barudžija, Tanja; Kuzmanović, Maja; Vujković, Milica; Mitrić, Miodrag

(2022)

TY  - JOUR
AU  - Jugović, Dragana
AU  - Milović, Miloš
AU  - Barudžija, Tanja
AU  - Kuzmanović, Maja
AU  - Vujković, Milica
AU  - Mitrić, Miodrag
PY  - 2022
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10577
AB  - Layered VOPO4·2H2O is synthesized by the sonochemical method. An X-ray powder diffraction is used to examine the crystal structure, while scanning electron microscopy is used to reveal the morphology of the powder. The crystal structure refinement is performed in the P4/nmmZ space group. The electrochemical intercalation of several cations (Na+, Mg2+, Ca2+, and Al3+) in saturated nitrate aqueous solutions is investigated. The most notable reversible activity is found for the cycling in aluminium nitrate aqueous solution in the voltage range from −0.1 to 0.8 V vs. SCE. During the preparation of the electrode, it is observed that the structure is prone to changes that have not been recorded in the literature so far. Namely, the use of conventional binder PVDF in NMP solution deteriorates the structure and lowers the powder’s crystallinity, while the use of Nafion solution causes the rearrangement of the atoms in a new crystal form that can be described in the monoclinic P21/c space group. Consequently, these structural changes affect electrochemical performances. The observed differences in electrochemical performances are a result of structural rearrangements.
T2  - Materials
T1  - The Influence of a Binder in a Composite Electrode: The Case Study of Vanadyl Phosphate in Aqueous Electrolyte
VL  - 15
IS  - 24
SP  - 9041
DO  - 10.3390/ma15249041
ER  - 
@article{
author = "Jugović, Dragana and Milović, Miloš and Barudžija, Tanja and Kuzmanović, Maja and Vujković, Milica and Mitrić, Miodrag",
year = "2022",
abstract = "Layered VOPO4·2H2O is synthesized by the sonochemical method. An X-ray powder diffraction is used to examine the crystal structure, while scanning electron microscopy is used to reveal the morphology of the powder. The crystal structure refinement is performed in the P4/nmmZ space group. The electrochemical intercalation of several cations (Na+, Mg2+, Ca2+, and Al3+) in saturated nitrate aqueous solutions is investigated. The most notable reversible activity is found for the cycling in aluminium nitrate aqueous solution in the voltage range from −0.1 to 0.8 V vs. SCE. During the preparation of the electrode, it is observed that the structure is prone to changes that have not been recorded in the literature so far. Namely, the use of conventional binder PVDF in NMP solution deteriorates the structure and lowers the powder’s crystallinity, while the use of Nafion solution causes the rearrangement of the atoms in a new crystal form that can be described in the monoclinic P21/c space group. Consequently, these structural changes affect electrochemical performances. The observed differences in electrochemical performances are a result of structural rearrangements.",
journal = "Materials",
title = "The Influence of a Binder in a Composite Electrode: The Case Study of Vanadyl Phosphate in Aqueous Electrolyte",
volume = "15",
number = "24",
pages = "9041",
doi = "10.3390/ma15249041"
}
Jugović, D., Milović, M., Barudžija, T., Kuzmanović, M., Vujković, M.,& Mitrić, M.. (2022). The Influence of a Binder in a Composite Electrode: The Case Study of Vanadyl Phosphate in Aqueous Electrolyte. in Materials, 15(24), 9041.
https://doi.org/10.3390/ma15249041
Jugović D, Milović M, Barudžija T, Kuzmanović M, Vujković M, Mitrić M. The Influence of a Binder in a Composite Electrode: The Case Study of Vanadyl Phosphate in Aqueous Electrolyte. in Materials. 2022;15(24):9041.
doi:10.3390/ma15249041 .
Jugović, Dragana, Milović, Miloš, Barudžija, Tanja, Kuzmanović, Maja, Vujković, Milica, Mitrić, Miodrag, "The Influence of a Binder in a Composite Electrode: The Case Study of Vanadyl Phosphate in Aqueous Electrolyte" in Materials, 15, no. 24 (2022):9041,
https://doi.org/10.3390/ma15249041 . .
1

Stimuli-responsive copolymeric hydrogels based on oligo(ethylene glycol) dimethacrylate for biomedical applications: An optimisation study of pH and thermoresponsive behaviour

Krstić, Marko Z.; Rogić Miladinović, Z.; Barudžija, Tanja; Mladenović, Aleksandar R.; Suljovrujić, Edin H.

(2022)

TY  - JOUR
AU  - Krstić, Marko Z.
AU  - Rogić Miladinović, Z.
AU  - Barudžija, Tanja
AU  - Mladenović, Aleksandar R.
AU  - Suljovrujić, Edin H.
PY  - 2022
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10097
AB  - Di(meth)acrylate (D(M)A) systems with pendant oligo(ethylene glycol) (OEG) chains are promising biomedical candidates. Homopolymeric P(OEG)D(M)A hydrogels have significant thermoresponsiveness demonstrated mainly at elevated temperatures which makes this class of materials unsuitable for bio-applications. Copolymerisation with less hydrophilic 2-hydroxyethyl methacrylate (HEMA) was performed in an effort to shift volume phase transition (VPT) closer to physiological temperatures and to widen their application as thermoresponsive materials. Various monomer-solvent mixtures, consisting of different mole ratios of OEGDMA and HEMA monomers (100/0, 50/50, 27.5/72.5, and 12.5/87.5) and water/ethanol as solvent, were exposed to gamma radiation up to 6, 12, 25, and 50 kGy. Furthermore, in an attempt to obtain multi- (thermo- and pH-) responsive hydrogels for biomedical applications new P(OEGDMA/HEMA/IA) terpolymers containing a small share (2.5, and 5 wt%) of itaconic acid (IA) were synthesised. The successful fabrication of the hydrogels was confirmed by gel measurements and FTIR spectroscopy. Swelling measurements indicated that obtained networks possessed tuneable thermal behaviour and swelling properties which could be significantly altered by hydrogel composition. The porous architecture was investigated using SEM, confirming swelling results. Cytotoxicity revealed relatively high cell viability for all hydrogels, indicating satisfactory in vitro biocompatibility. Therefore, new OEGDMA based hydrogels showed potential for biomedical applications.
T2  - Reactive and Functional Polymers
T1  - Stimuli-responsive copolymeric hydrogels based on oligo(ethylene glycol) dimethacrylate for biomedical applications: An optimisation study of pH and thermoresponsive behaviour
VL  - 170
SP  - 105140
DO  - 10.1016/j.reactfunctpolym.2021.105140
ER  - 
@article{
author = "Krstić, Marko Z. and Rogić Miladinović, Z. and Barudžija, Tanja and Mladenović, Aleksandar R. and Suljovrujić, Edin H.",
year = "2022",
abstract = "Di(meth)acrylate (D(M)A) systems with pendant oligo(ethylene glycol) (OEG) chains are promising biomedical candidates. Homopolymeric P(OEG)D(M)A hydrogels have significant thermoresponsiveness demonstrated mainly at elevated temperatures which makes this class of materials unsuitable for bio-applications. Copolymerisation with less hydrophilic 2-hydroxyethyl methacrylate (HEMA) was performed in an effort to shift volume phase transition (VPT) closer to physiological temperatures and to widen their application as thermoresponsive materials. Various monomer-solvent mixtures, consisting of different mole ratios of OEGDMA and HEMA monomers (100/0, 50/50, 27.5/72.5, and 12.5/87.5) and water/ethanol as solvent, were exposed to gamma radiation up to 6, 12, 25, and 50 kGy. Furthermore, in an attempt to obtain multi- (thermo- and pH-) responsive hydrogels for biomedical applications new P(OEGDMA/HEMA/IA) terpolymers containing a small share (2.5, and 5 wt%) of itaconic acid (IA) were synthesised. The successful fabrication of the hydrogels was confirmed by gel measurements and FTIR spectroscopy. Swelling measurements indicated that obtained networks possessed tuneable thermal behaviour and swelling properties which could be significantly altered by hydrogel composition. The porous architecture was investigated using SEM, confirming swelling results. Cytotoxicity revealed relatively high cell viability for all hydrogels, indicating satisfactory in vitro biocompatibility. Therefore, new OEGDMA based hydrogels showed potential for biomedical applications.",
journal = "Reactive and Functional Polymers",
title = "Stimuli-responsive copolymeric hydrogels based on oligo(ethylene glycol) dimethacrylate for biomedical applications: An optimisation study of pH and thermoresponsive behaviour",
volume = "170",
pages = "105140",
doi = "10.1016/j.reactfunctpolym.2021.105140"
}
Krstić, M. Z., Rogić Miladinović, Z., Barudžija, T., Mladenović, A. R.,& Suljovrujić, E. H.. (2022). Stimuli-responsive copolymeric hydrogels based on oligo(ethylene glycol) dimethacrylate for biomedical applications: An optimisation study of pH and thermoresponsive behaviour. in Reactive and Functional Polymers, 170, 105140.
https://doi.org/10.1016/j.reactfunctpolym.2021.105140
Krstić MZ, Rogić Miladinović Z, Barudžija T, Mladenović AR, Suljovrujić EH. Stimuli-responsive copolymeric hydrogels based on oligo(ethylene glycol) dimethacrylate for biomedical applications: An optimisation study of pH and thermoresponsive behaviour. in Reactive and Functional Polymers. 2022;170:105140.
doi:10.1016/j.reactfunctpolym.2021.105140 .
Krstić, Marko Z., Rogić Miladinović, Z., Barudžija, Tanja, Mladenović, Aleksandar R., Suljovrujić, Edin H., "Stimuli-responsive copolymeric hydrogels based on oligo(ethylene glycol) dimethacrylate for biomedical applications: An optimisation study of pH and thermoresponsive behaviour" in Reactive and Functional Polymers, 170 (2022):105140,
https://doi.org/10.1016/j.reactfunctpolym.2021.105140 . .
8
1
7

Influence of spray-drying process on properties of chitosan/xanthan gum polyelectrolyte complexes as carriers for oral delivery of ibuprofen

Ćirić, Ana; Milinković Budinčić, Jelena; Medarević, Đorđe; Dobričić, Vladimir; Rmandić, Milena; Barudžija, Tanja; Malenović, Anđelija; Petrović, Lidija; Đekić, Ljiljana

(2022)

TY  - JOUR
AU  - Ćirić, Ana
AU  - Milinković Budinčić, Jelena
AU  - Medarević, Đorđe
AU  - Dobričić, Vladimir
AU  - Rmandić, Milena
AU  - Barudžija, Tanja
AU  - Malenović, Anđelija
AU  - Petrović, Lidija
AU  - Đekić, Ljiljana
PY  - 2022
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10375
AB  - Polyelectrolyte complexes (PECs) are attractive carriers with recognized potential toenhance oral delivery of poorly soluble high-dosed low-molecular-weight drugs. The formulationof solid oral dosage forms requires the drying of PECs, which may affect their physicochemicaland biopharmaceutical properties. The aim of this study was to investigate the effect of spray-drying on the properties of ibuprofen-loaded chitosan/xanthan gum PECs and to assess the drugrelease kinetics from such PECs filled into hard capsules in comparison with corresponding PECswhich are dried under ambient conditions. The yield, ibuprofen content, entrapment efficiency,and residual moisture content of spray-dried PECs were lower than those of ambient-dried PECs.Better flowability of spray-dried PECs was attributed to the almost spherical particle shape,shown by scanning electron microscopy. DSC and PXRD analysis confirmed the amorphizationof ibuprofen during spray-drying. All the investigated PECs, obtained by drying under ambientconditions as well as by spray-drying, had high rehydration capacity both in 0.1 M hydrochloricacid (pH 1.2) and phosphate buffer pH 7.4. In vitro ibuprofen release from dried PECs wascontrolled during 12 h with the release of approximately 30% of entrapped ibuprofen. Spray-driedPECs provided better control of ibuprofen diffusion from the carrier compared to the ambient-dried ones.
T2  - Arhiv za farmaciju
T1  - Influence of spray-drying process on properties of chitosan/xanthan gum polyelectrolyte complexes as carriers for oral delivery of ibuprofen
T1  - Uticaj postupka sušenja raspršivanjem na svojstva polielektrolitnih kompleksa hitozana i ksantan gume kao nosača za peroralnu isporuku ibuprofena
VL  - 72
IS  - 1
SP  - 36
EP  - 60
DO  - 10.5937/arhfarm72-35133
ER  - 
@article{
author = "Ćirić, Ana and Milinković Budinčić, Jelena and Medarević, Đorđe and Dobričić, Vladimir and Rmandić, Milena and Barudžija, Tanja and Malenović, Anđelija and Petrović, Lidija and Đekić, Ljiljana",
year = "2022",
abstract = "Polyelectrolyte complexes (PECs) are attractive carriers with recognized potential toenhance oral delivery of poorly soluble high-dosed low-molecular-weight drugs. The formulationof solid oral dosage forms requires the drying of PECs, which may affect their physicochemicaland biopharmaceutical properties. The aim of this study was to investigate the effect of spray-drying on the properties of ibuprofen-loaded chitosan/xanthan gum PECs and to assess the drugrelease kinetics from such PECs filled into hard capsules in comparison with corresponding PECswhich are dried under ambient conditions. The yield, ibuprofen content, entrapment efficiency,and residual moisture content of spray-dried PECs were lower than those of ambient-dried PECs.Better flowability of spray-dried PECs was attributed to the almost spherical particle shape,shown by scanning electron microscopy. DSC and PXRD analysis confirmed the amorphizationof ibuprofen during spray-drying. All the investigated PECs, obtained by drying under ambientconditions as well as by spray-drying, had high rehydration capacity both in 0.1 M hydrochloricacid (pH 1.2) and phosphate buffer pH 7.4. In vitro ibuprofen release from dried PECs wascontrolled during 12 h with the release of approximately 30% of entrapped ibuprofen. Spray-driedPECs provided better control of ibuprofen diffusion from the carrier compared to the ambient-dried ones.",
journal = "Arhiv za farmaciju",
title = "Influence of spray-drying process on properties of chitosan/xanthan gum polyelectrolyte complexes as carriers for oral delivery of ibuprofen, Uticaj postupka sušenja raspršivanjem na svojstva polielektrolitnih kompleksa hitozana i ksantan gume kao nosača za peroralnu isporuku ibuprofena",
volume = "72",
number = "1",
pages = "36-60",
doi = "10.5937/arhfarm72-35133"
}
Ćirić, A., Milinković Budinčić, J., Medarević, Đ., Dobričić, V., Rmandić, M., Barudžija, T., Malenović, A., Petrović, L.,& Đekić, L.. (2022). Influence of spray-drying process on properties of chitosan/xanthan gum polyelectrolyte complexes as carriers for oral delivery of ibuprofen. in Arhiv za farmaciju, 72(1), 36-60.
https://doi.org/10.5937/arhfarm72-35133
Ćirić A, Milinković Budinčić J, Medarević Đ, Dobričić V, Rmandić M, Barudžija T, Malenović A, Petrović L, Đekić L. Influence of spray-drying process on properties of chitosan/xanthan gum polyelectrolyte complexes as carriers for oral delivery of ibuprofen. in Arhiv za farmaciju. 2022;72(1):36-60.
doi:10.5937/arhfarm72-35133 .
Ćirić, Ana, Milinković Budinčić, Jelena, Medarević, Đorđe, Dobričić, Vladimir, Rmandić, Milena, Barudžija, Tanja, Malenović, Anđelija, Petrović, Lidija, Đekić, Ljiljana, "Influence of spray-drying process on properties of chitosan/xanthan gum polyelectrolyte complexes as carriers for oral delivery of ibuprofen" in Arhiv za farmaciju, 72, no. 1 (2022):36-60,
https://doi.org/10.5937/arhfarm72-35133 . .
3
3

Evaluation of chitosan/xanthan gum polyelectrolyte complexes potential for pH-dependent oral delivery of escin

Ćirić, Ana; Milinković Budinčić, Jelena; Dobričić, Vladimir; Rmandić, Milena; Barudžija, Tanja; Malenović, Anđelija; Petrović, Lidija; Đekić, Ljiljana

(2022)

TY  - JOUR
AU  - Ćirić, Ana
AU  - Milinković Budinčić, Jelena
AU  - Dobričić, Vladimir
AU  - Rmandić, Milena
AU  - Barudžija, Tanja
AU  - Malenović, Anđelija
AU  - Petrović, Lidija
AU  - Đekić, Ljiljana
PY  - 2022
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10410
AB  - Escin is an amphiphilic and weakly acidic drug that oral administration may lead to the irritation of gastric mucosa. The entrapment of escin into chitosan (CH)/xanthan gum (XG)-based polyelectrolyte complexes (PECs) can facilitate controlled drug release which may be beneficial for the reduction of its side effects. This study aimed to investigate the influence of escin content and drying method on the formation, physicochemical, and controlled, pH-dependent drug release properties of CH/XG-based PECs. Measurements of transmittance, con- ductivity, and rheological characterization confirmed the formation of CH/XG-based PECs with escin entrapped at escin-to-polymers mass ratios 1:1, 1:2, and 1:4. Ambient-dried PECs had higher yield, entrapment efficiency, and escin content in comparison with spray-dried ones. FT-IR spectra confirmed the interactions between CH, XG, and escin, which were stronger in ambient-dried PECs. PXRD and DSC analyses showed the amorphous escin character in all dry PECs, regardless of the drying method. The most promising controlled and pH-dependent in vitro escin release was from the ambient-dried PEC at the escin-to-polymers mass ratio of 1:1. For that reason and due to the highest yield and entrapment efficiency, this carrier has the potential to prevent the irritation of gastric mucosa after oral administration of escin.
T2  - International Journal of Biological Macromolecules
T1  - Evaluation of chitosan/xanthan gum polyelectrolyte complexes potential for pH-dependent oral delivery of escin
VL  - 221
SP  - 48
EP  - 60
DO  - 10.1016/j.ijbiomac.2022.08.190
ER  - 
@article{
author = "Ćirić, Ana and Milinković Budinčić, Jelena and Dobričić, Vladimir and Rmandić, Milena and Barudžija, Tanja and Malenović, Anđelija and Petrović, Lidija and Đekić, Ljiljana",
year = "2022",
abstract = "Escin is an amphiphilic and weakly acidic drug that oral administration may lead to the irritation of gastric mucosa. The entrapment of escin into chitosan (CH)/xanthan gum (XG)-based polyelectrolyte complexes (PECs) can facilitate controlled drug release which may be beneficial for the reduction of its side effects. This study aimed to investigate the influence of escin content and drying method on the formation, physicochemical, and controlled, pH-dependent drug release properties of CH/XG-based PECs. Measurements of transmittance, con- ductivity, and rheological characterization confirmed the formation of CH/XG-based PECs with escin entrapped at escin-to-polymers mass ratios 1:1, 1:2, and 1:4. Ambient-dried PECs had higher yield, entrapment efficiency, and escin content in comparison with spray-dried ones. FT-IR spectra confirmed the interactions between CH, XG, and escin, which were stronger in ambient-dried PECs. PXRD and DSC analyses showed the amorphous escin character in all dry PECs, regardless of the drying method. The most promising controlled and pH-dependent in vitro escin release was from the ambient-dried PEC at the escin-to-polymers mass ratio of 1:1. For that reason and due to the highest yield and entrapment efficiency, this carrier has the potential to prevent the irritation of gastric mucosa after oral administration of escin.",
journal = "International Journal of Biological Macromolecules",
title = "Evaluation of chitosan/xanthan gum polyelectrolyte complexes potential for pH-dependent oral delivery of escin",
volume = "221",
pages = "48-60",
doi = "10.1016/j.ijbiomac.2022.08.190"
}
Ćirić, A., Milinković Budinčić, J., Dobričić, V., Rmandić, M., Barudžija, T., Malenović, A., Petrović, L.,& Đekić, L.. (2022). Evaluation of chitosan/xanthan gum polyelectrolyte complexes potential for pH-dependent oral delivery of escin. in International Journal of Biological Macromolecules, 221, 48-60.
https://doi.org/10.1016/j.ijbiomac.2022.08.190
Ćirić A, Milinković Budinčić J, Dobričić V, Rmandić M, Barudžija T, Malenović A, Petrović L, Đekić L. Evaluation of chitosan/xanthan gum polyelectrolyte complexes potential for pH-dependent oral delivery of escin. in International Journal of Biological Macromolecules. 2022;221:48-60.
doi:10.1016/j.ijbiomac.2022.08.190 .
Ćirić, Ana, Milinković Budinčić, Jelena, Dobričić, Vladimir, Rmandić, Milena, Barudžija, Tanja, Malenović, Anđelija, Petrović, Lidija, Đekić, Ljiljana, "Evaluation of chitosan/xanthan gum polyelectrolyte complexes potential for pH-dependent oral delivery of escin" in International Journal of Biological Macromolecules, 221 (2022):48-60,
https://doi.org/10.1016/j.ijbiomac.2022.08.190 . .
5
4

Influence of Rare Earth Oxide Concentration on Electrochemical Co-Deposition of Nd and Pr from NdF3-PrF3-LiF Based Melts

Cvetković, Vesna S.; Feldhaus, Dominic; Vukićević, Nataša M.; Milićević-Neumann, Ksenija; Barudžija, Tanja; Friedrich, Bernd; Jovićević, Jovan N.

(2022)

TY  - JOUR
AU  - Cvetković, Vesna S.
AU  - Feldhaus, Dominic
AU  - Vukićević, Nataša M.
AU  - Milićević-Neumann, Ksenija
AU  - Barudžija, Tanja
AU  - Friedrich, Bernd
AU  - Jovićević, Jovan N.
PY  - 2022
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10416
AB  - The impact of rare earth oxide (REO) concentration on the deposition process and selective recovery of the metal being deposited from a molten fluoride salt system was investigated by applying deposition of Nd and Pr and varying the concentration of REO added to the electrolyte. A ternary phase diagram for the liquidus temperature of the NdF3-PrF3-LiF system was constructed to better predict the optimal electrolyte constitution. Cyclic voltammetry was used to record three redox signals, reflecting the processes involving Nd(III)/Nd and Pr(III)/Pr transformations. A two-step red/ox process for Nd(III) ions and a single-step red/ox process for Pr(III) ions were confirmed by square-wave voltammetry. The cyclic voltammetry results indicated the possibility of neodymium and praseodymium co-deposition. In order to sustain higher co-deposition rates on the cathode and to avoid increased production of PFC greenhouse gases on the anode, a low-overpotential deposition technique was used for Nd and Pr electrodeposition from the electrolyte with varying Nd2O3 and Pr6O11 concentrations. Co-deposited neodymium and praseodymium metals were characterized by electron probe microanalysis (EPMA) and X-ray diffraction (XRD) analysis. After electrodeposition, concentration profiles of neodymium and praseodymium were recorded, starting from the cathode surface towards the electrolyte bulk. The working temperature of 1050 °C of the molten fluoride salt basic electrolyte, in line with the constructed phase diagram, was validated by improved co-deposition and led to a more effective deposition process.
T2  - Metals
T1  - Influence of Rare Earth Oxide Concentration on Electrochemical
Co-Deposition of Nd and Pr from NdF3-PrF3-LiF Based Melts
VL  - 12
IS  - 7
SP  - 1204
DO  - 10.3390/met12071204
ER  - 
@article{
author = "Cvetković, Vesna S. and Feldhaus, Dominic and Vukićević, Nataša M. and Milićević-Neumann, Ksenija and Barudžija, Tanja and Friedrich, Bernd and Jovićević, Jovan N.",
year = "2022",
abstract = "The impact of rare earth oxide (REO) concentration on the deposition process and selective recovery of the metal being deposited from a molten fluoride salt system was investigated by applying deposition of Nd and Pr and varying the concentration of REO added to the electrolyte. A ternary phase diagram for the liquidus temperature of the NdF3-PrF3-LiF system was constructed to better predict the optimal electrolyte constitution. Cyclic voltammetry was used to record three redox signals, reflecting the processes involving Nd(III)/Nd and Pr(III)/Pr transformations. A two-step red/ox process for Nd(III) ions and a single-step red/ox process for Pr(III) ions were confirmed by square-wave voltammetry. The cyclic voltammetry results indicated the possibility of neodymium and praseodymium co-deposition. In order to sustain higher co-deposition rates on the cathode and to avoid increased production of PFC greenhouse gases on the anode, a low-overpotential deposition technique was used for Nd and Pr electrodeposition from the electrolyte with varying Nd2O3 and Pr6O11 concentrations. Co-deposited neodymium and praseodymium metals were characterized by electron probe microanalysis (EPMA) and X-ray diffraction (XRD) analysis. After electrodeposition, concentration profiles of neodymium and praseodymium were recorded, starting from the cathode surface towards the electrolyte bulk. The working temperature of 1050 °C of the molten fluoride salt basic electrolyte, in line with the constructed phase diagram, was validated by improved co-deposition and led to a more effective deposition process.",
journal = "Metals",
title = "Influence of Rare Earth Oxide Concentration on Electrochemical
Co-Deposition of Nd and Pr from NdF3-PrF3-LiF Based Melts",
volume = "12",
number = "7",
pages = "1204",
doi = "10.3390/met12071204"
}
Cvetković, V. S., Feldhaus, D., Vukićević, N. M., Milićević-Neumann, K., Barudžija, T., Friedrich, B.,& Jovićević, J. N.. (2022). Influence of Rare Earth Oxide Concentration on Electrochemical
Co-Deposition of Nd and Pr from NdF3-PrF3-LiF Based Melts. in Metals, 12(7), 1204.
https://doi.org/10.3390/met12071204
Cvetković VS, Feldhaus D, Vukićević NM, Milićević-Neumann K, Barudžija T, Friedrich B, Jovićević JN. Influence of Rare Earth Oxide Concentration on Electrochemical
Co-Deposition of Nd and Pr from NdF3-PrF3-LiF Based Melts. in Metals. 2022;12(7):1204.
doi:10.3390/met12071204 .
Cvetković, Vesna S., Feldhaus, Dominic, Vukićević, Nataša M., Milićević-Neumann, Ksenija, Barudžija, Tanja, Friedrich, Bernd, Jovićević, Jovan N., "Influence of Rare Earth Oxide Concentration on Electrochemical
Co-Deposition of Nd and Pr from NdF3-PrF3-LiF Based Melts" in Metals, 12, no. 7 (2022):1204,
https://doi.org/10.3390/met12071204 . .
1
3
4

Electrochemical study of Nd and Pr co-deposition onto Mo and W from molten oxyfluorides

Cvetković, Vesna S.; Feldhaus, Dominic; Vukićević, Nataša M.; Barudžija, Tanja; Friedrich, Bernd; Jovićević, Jovan N.

(2021)

TY  - JOUR
AU  - Cvetković, Vesna S.
AU  - Feldhaus, Dominic
AU  - Vukićević, Nataša M.
AU  - Barudžija, Tanja
AU  - Friedrich, Bernd
AU  - Jovićević, Jovan N.
PY  - 2021
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/9947
AB  - Electrodeposition processes of neodymium and praseodymium in molten NdF3 + PrF3 + LiF + 1 wt.%Pr6O11 + 1 wt.%Nd2O3 and NdF3 + PrF3 + LiF + 2 wt.%Pr6O11 + 2 wt.%Nd2O3 electrolytes at 1323 K were investigated. Cyclic voltammetry, square wave voltammetry, and open circuit potentiometry were applied to study the electrochemical reduction of Nd(III) and Pr(III) ions on Mo and W cathodes. It was established that a critical condition for Nd and Pr co-deposition in oxyfluoride electrolytes was a constant praseodymium deposition overpotential of ≈−0.100 V, which was shown to result in co-deposition current densities approaching 6 mAcm−2 . Analysis of the results obtained by applied electrochemical techniques showed that praseodymium deposition proceeds as a one-step process involving exchange of three electrons (Pr(III)→Pr(0)) and that neodymium deposition is a two-step process: the first involves one electron exchange (Nd(III)→Nd(II)), and the second involves an exchange of two electrons (Nd(II)→Nd(0)). X-ray diffraction analyses confirmed the formation of metallic Nd and Pr on the working substrate. Keeping the anodic potential to the glassy carbon working anode low results in very low levels of carbon oxides, fluorine and fluorocarbon gas emissions, which should qualify the studied system as an environmentally friendly option for rare earth metal deposition. The newly reported data for Nd and Pr metals co-deposition provide valuable information for the recycling of neodymium-iron-boron magnets.
T2  - Metals
T1  - Electrochemical study of Nd and Pr co-deposition onto Mo and W from molten oxyfluorides
VL  - 11
IS  - 9
SP  - 1494
DO  - 10.3390/met11091494
ER  - 
@article{
author = "Cvetković, Vesna S. and Feldhaus, Dominic and Vukićević, Nataša M. and Barudžija, Tanja and Friedrich, Bernd and Jovićević, Jovan N.",
year = "2021",
abstract = "Electrodeposition processes of neodymium and praseodymium in molten NdF3 + PrF3 + LiF + 1 wt.%Pr6O11 + 1 wt.%Nd2O3 and NdF3 + PrF3 + LiF + 2 wt.%Pr6O11 + 2 wt.%Nd2O3 electrolytes at 1323 K were investigated. Cyclic voltammetry, square wave voltammetry, and open circuit potentiometry were applied to study the electrochemical reduction of Nd(III) and Pr(III) ions on Mo and W cathodes. It was established that a critical condition for Nd and Pr co-deposition in oxyfluoride electrolytes was a constant praseodymium deposition overpotential of ≈−0.100 V, which was shown to result in co-deposition current densities approaching 6 mAcm−2 . Analysis of the results obtained by applied electrochemical techniques showed that praseodymium deposition proceeds as a one-step process involving exchange of three electrons (Pr(III)→Pr(0)) and that neodymium deposition is a two-step process: the first involves one electron exchange (Nd(III)→Nd(II)), and the second involves an exchange of two electrons (Nd(II)→Nd(0)). X-ray diffraction analyses confirmed the formation of metallic Nd and Pr on the working substrate. Keeping the anodic potential to the glassy carbon working anode low results in very low levels of carbon oxides, fluorine and fluorocarbon gas emissions, which should qualify the studied system as an environmentally friendly option for rare earth metal deposition. The newly reported data for Nd and Pr metals co-deposition provide valuable information for the recycling of neodymium-iron-boron magnets.",
journal = "Metals",
title = "Electrochemical study of Nd and Pr co-deposition onto Mo and W from molten oxyfluorides",
volume = "11",
number = "9",
pages = "1494",
doi = "10.3390/met11091494"
}
Cvetković, V. S., Feldhaus, D., Vukićević, N. M., Barudžija, T., Friedrich, B.,& Jovićević, J. N.. (2021). Electrochemical study of Nd and Pr co-deposition onto Mo and W from molten oxyfluorides. in Metals, 11(9), 1494.
https://doi.org/10.3390/met11091494
Cvetković VS, Feldhaus D, Vukićević NM, Barudžija T, Friedrich B, Jovićević JN. Electrochemical study of Nd and Pr co-deposition onto Mo and W from molten oxyfluorides. in Metals. 2021;11(9):1494.
doi:10.3390/met11091494 .
Cvetković, Vesna S., Feldhaus, Dominic, Vukićević, Nataša M., Barudžija, Tanja, Friedrich, Bernd, Jovićević, Jovan N., "Electrochemical study of Nd and Pr co-deposition onto Mo and W from molten oxyfluorides" in Metals, 11, no. 9 (2021):1494,
https://doi.org/10.3390/met11091494 . .
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