TY  - JOUR
AU  - Vasiljević-Nedić, Bojana
AU  - Obradović, Milena
AU  - Bajuk-Bogdanović, Danica V.
AU  - Milojević-Rakić, Maja
AU  - Jovanović, Zoran M.
AU  - Gavrilov, Nemanja M.
AU  - Holclajtner-Antunović, Ivanka D.
PY  - 2019
UR  - https://linkinghub.elsevier.com/retrieve/pii/S1001074218314682
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/8217
AB  - Potassium tungstophosphate is supported on BEA zeolite by in situ synthesis for glyphosate removal. Spectroscopic measurements identified hydrogen bonding as a primal interaction of potassium salt and BEA zeolite. Composites are evaluated for glyphosate herbicide removal and adsorption process is analyzed using two isotherm models. Obtained adsorption capacities for all prepared composites lay between 45.2 and 92.2 mg of glyphosate per gram of investigated composite. Suspension acidity revealed that glyphosate is adsorbed mainly in the zwitter-ion form at the composite surface while the amount of potassium salt in the composites is crucial for the adsorption application. Exceptional adsorption behavior is postulated to come from a high degree of homogeneity among surface active sites which is confirmed by different experimental methods. Temperature programmed desorption of glyphosate coupled with mass spectrometer detected one broad, high-temperature peak which represents overlapped desorption processes from active sights of similar strength. Introduction of potassium tungstophosphate affects active sites present in BEA zeolite for glyphosate desorption and significantly increases the amount of adsorbed pesticide in comparison to BEA zeolite. Supporting of potassium tungstophosphate on BEA zeolite via in situ synthesis procedure enables the formation of highly efficient adsorbents and revealed their perspective environmental application. © 2019
T2  - Journal of Environmental Sciences
T1  - In situ synthesis of potassium tungstophosphate supported on BEA zeolite and perspective application for pesticide removal
VL  - 81
SP  - 136
EP  - 147
DO  - 10.1016/j.jes.2019.01.018
ER  - 

@article{
author = "Vasiljević-Nedić, Bojana and Obradović, Milena and Bajuk-Bogdanović, Danica V. and Milojević-Rakić, Maja and Jovanović, Zoran M. and Gavrilov, Nemanja M. and Holclajtner-Antunović, Ivanka D.",
year = "2019",
abstract = "Potassium tungstophosphate is supported on BEA zeolite by in situ synthesis for glyphosate removal. Spectroscopic measurements identified hydrogen bonding as a primal interaction of potassium salt and BEA zeolite. Composites are evaluated for glyphosate herbicide removal and adsorption process is analyzed using two isotherm models. Obtained adsorption capacities for all prepared composites lay between 45.2 and 92.2 mg of glyphosate per gram of investigated composite. Suspension acidity revealed that glyphosate is adsorbed mainly in the zwitter-ion form at the composite surface while the amount of potassium salt in the composites is crucial for the adsorption application. Exceptional adsorption behavior is postulated to come from a high degree of homogeneity among surface active sites which is confirmed by different experimental methods. Temperature programmed desorption of glyphosate coupled with mass spectrometer detected one broad, high-temperature peak which represents overlapped desorption processes from active sights of similar strength. Introduction of potassium tungstophosphate affects active sites present in BEA zeolite for glyphosate desorption and significantly increases the amount of adsorbed pesticide in comparison to BEA zeolite. Supporting of potassium tungstophosphate on BEA zeolite via in situ synthesis procedure enables the formation of highly efficient adsorbents and revealed their perspective environmental application. © 2019",
journal = "Journal of Environmental Sciences",
title = "In situ synthesis of potassium tungstophosphate supported on BEA zeolite and perspective application for pesticide removal",
volume = "81",
pages = "136-147",
doi = "10.1016/j.jes.2019.01.018"
}

Vasiljević-Nedić, B., Obradović, M., Bajuk-Bogdanović, D. V., Milojević-Rakić, M., Jovanović, Z. M., Gavrilov, N. M.,& Holclajtner-Antunović, I. D.. (2019). In situ synthesis of potassium tungstophosphate supported on BEA zeolite and perspective application for pesticide removal. in Journal of Environmental Sciences, 81, 136-147.
https://doi.org/10.1016/j.jes.2019.01.018

Vasiljević-Nedić B, Obradović M, Bajuk-Bogdanović DV, Milojević-Rakić M, Jovanović ZM, Gavrilov NM, Holclajtner-Antunović ID. In situ synthesis of potassium tungstophosphate supported on BEA zeolite and perspective application for pesticide removal. in Journal of Environmental Sciences. 2019;81:136-147.
doi:10.1016/j.jes.2019.01.018 .

Vasiljević-Nedić, Bojana, Obradović, Milena, Bajuk-Bogdanović, Danica V., Milojević-Rakić, Maja, Jovanović, Zoran M., Gavrilov, Nemanja M., Holclajtner-Antunović, Ivanka D., "In situ synthesis of potassium tungstophosphate supported on BEA zeolite and perspective application for pesticide removal" in Journal of Environmental Sciences, 81 (2019):136-147,
https://doi.org/10.1016/j.jes.2019.01.018 . .