Ranđelović, Marjan S.

Link to this page

Authority KeyName Variants
664f49d7-7014-4039-8dc1-742f6f2732c2
  • Ranđelović, Marjan S. (25)
  • Ranđelović, Marjan (6)
Projects
Advanced technologies for monitoring and environmental protection from chemical pollutants and radiation burden Synthesis, processing and characterization of nanostructured materials for application in the field of energy, mechanical engineering, environmental protection and biomedicine
Development and characterization of novel biosorbent for natural and waste water treatment Combinatorial libraries of heterogeneous catalysts, natural products, and their derivatives and analogues: the way to biologically active compounds
Physics and Chemistry with Ion Beams Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200017 (University of Belgrade, Institute of Nuclear Sciences 'Vinča', Belgrade-Vinča)
DAAD foundation through a multilateral project "International Masters and Postgraduate Programme in Materials Science and Catalysis" (MatCatNet) German-Serbian bilateral project DAAD PPP Serbien [Project no. 57512952]
Grant Agency of the Czech Republic [P206/12/G151] Horizon 2020 [Grant No. 823717—ESTEEM3]
Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200175 (Institute of Technical Sciences of SASA, Belgrade) Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200288 (Innovation Center of the Faculty of Chemistry)
Materials of Reduced Dimensions for Efficient Light Harvesting and Energy conversion Studies on plant pathogens, arthropods, weeds, and pesticides with a view to developing the methods of biorational plant protection and safe food production
Institute of Physics Belgrade, through Ministry of Education, Science, and Technological Development of the Republic of Serbia Institute Vinča Belgrade, through Ministry of Education, Science, and Technological Development of the Republic of Serbia
Ministry of Education, Science and Technological Development of the Republic of Serbia Ministry of Education, Science and Technological Development of the Republic of Serbia [Grants no. 1702201 and 1702313]
Ministry of Science and Technological Development of the Republic of Serbia [TR19031] NATO [SPS G5550]
Serbian Academy of Sciences and Arts Serbian Academy of Sciences and Arts, DAAD fellowship [A/10/05029]
Serbian Ministry of Education, Science and Technological Development The project of Serbian Academy of Sciences and Arts

Author's Bibliography

Synthesis, Characterization, and Electronic Properties of ZnO/ZnS Core/Shell Nanostructures Investigated Using a Multidisciplinary Approach

Zagorac, Jelena B.; Zagorac, Dejan; Šrot, Vesna; Ranđelović, Marjan; Pejić, Milan; van Aken, Peter A.; Matović, Branko; Schön, Christian J.

(2023)

TY  - JOUR
AU  - Zagorac, Jelena B.
AU  - Zagorac, Dejan
AU  - Šrot, Vesna
AU  - Ranđelović, Marjan
AU  - Pejić, Milan
AU  - van Aken, Peter A.
AU  - Matović, Branko
AU  - Schön, Christian J.
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10592
AB  - ZnO/ZnS core/shell nanostructures, which are studied for diverse possible applications, ranging from semiconductors, photovoltaics, and light-emitting diodes (LED), to solar cells, infrared detectors, and thermoelectrics, were synthesized and characterized by XRD, HR-(S)TEM, and analytical TEM (EDX and EELS). Moreover, band-gap measurements of the ZnO/ZnS core/shell nanostructures have been performed using UV/Vis DRS. The experimental results were combined with theoretical modeling of ZnO/ZnS (hetero)structures and band structure calculations for ZnO/ZnS systems, yielding more insights into the properties of the nanoparticles. The ab initio calculations were performed using hybrid PBE0 and HSE06 functionals. The synthesized and characterized ZnO/ZnS core/shell materials show a unique three-phase composition, where the ZnO phase is dominant in the core region and, interestingly, the auxiliary ZnS compound occurs in two phases as wurtzite and sphalerite in the shell region. Moreover, theoretical ab initio calculations show advanced semiconducting properties and possible band-gap tuning in such ZnO/ZnS structures.
T2  - Materials
T1  - Synthesis, Characterization, and Electronic Properties of ZnO/ZnS Core/Shell Nanostructures Investigated Using a Multidisciplinary Approach
VL  - 16
IS  - 1
SP  - 326
DO  - 10.3390/ma16010326
ER  - 
@article{
author = "Zagorac, Jelena B. and Zagorac, Dejan and Šrot, Vesna and Ranđelović, Marjan and Pejić, Milan and van Aken, Peter A. and Matović, Branko and Schön, Christian J.",
year = "2023",
abstract = "ZnO/ZnS core/shell nanostructures, which are studied for diverse possible applications, ranging from semiconductors, photovoltaics, and light-emitting diodes (LED), to solar cells, infrared detectors, and thermoelectrics, were synthesized and characterized by XRD, HR-(S)TEM, and analytical TEM (EDX and EELS). Moreover, band-gap measurements of the ZnO/ZnS core/shell nanostructures have been performed using UV/Vis DRS. The experimental results were combined with theoretical modeling of ZnO/ZnS (hetero)structures and band structure calculations for ZnO/ZnS systems, yielding more insights into the properties of the nanoparticles. The ab initio calculations were performed using hybrid PBE0 and HSE06 functionals. The synthesized and characterized ZnO/ZnS core/shell materials show a unique three-phase composition, where the ZnO phase is dominant in the core region and, interestingly, the auxiliary ZnS compound occurs in two phases as wurtzite and sphalerite in the shell region. Moreover, theoretical ab initio calculations show advanced semiconducting properties and possible band-gap tuning in such ZnO/ZnS structures.",
journal = "Materials",
title = "Synthesis, Characterization, and Electronic Properties of ZnO/ZnS Core/Shell Nanostructures Investigated Using a Multidisciplinary Approach",
volume = "16",
number = "1",
pages = "326",
doi = "10.3390/ma16010326"
}
Zagorac, J. B., Zagorac, D., Šrot, V., Ranđelović, M., Pejić, M., van Aken, P. A., Matović, B.,& Schön, C. J.. (2023). Synthesis, Characterization, and Electronic Properties of ZnO/ZnS Core/Shell Nanostructures Investigated Using a Multidisciplinary Approach. in Materials, 16(1), 326.
https://doi.org/10.3390/ma16010326
Zagorac JB, Zagorac D, Šrot V, Ranđelović M, Pejić M, van Aken PA, Matović B, Schön CJ. Synthesis, Characterization, and Electronic Properties of ZnO/ZnS Core/Shell Nanostructures Investigated Using a Multidisciplinary Approach. in Materials. 2023;16(1):326.
doi:10.3390/ma16010326 .
Zagorac, Jelena B., Zagorac, Dejan, Šrot, Vesna, Ranđelović, Marjan, Pejić, Milan, van Aken, Peter A., Matović, Branko, Schön, Christian J., "Synthesis, Characterization, and Electronic Properties of ZnO/ZnS Core/Shell Nanostructures Investigated Using a Multidisciplinary Approach" in Materials, 16, no. 1 (2023):326,
https://doi.org/10.3390/ma16010326 . .
2

Photocatalytic ability of visible-light-responsive hybrid ZrO2 particles

Zarubica, Aleksandra; Sredojević, Dušan; Ljupković, Radomir; Ranđelović, Marjan; Murafa, Natalija; Stoiljković, Milovan; Lazić, Vesna; Nedeljković, Jovan

(2023)

TY  - JOUR
AU  - Zarubica, Aleksandra
AU  - Sredojević, Dušan
AU  - Ljupković, Radomir
AU  - Ranđelović, Marjan
AU  - Murafa, Natalija
AU  - Stoiljković, Milovan
AU  - Lazić, Vesna
AU  - Nedeljković, Jovan
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10874
AB  - The interfacial charge transfer (ICT) complex formation between zirconium dioxide (ZrO2), the material absorbing below 250 nm, and 5-aminosalicylic acid (5-ASA) leads to the formation of visible-light-absorbing inorganic–organic hybrids. The free amino groups, present on the hybrid's surface after the ICT complex formation, were used to reduce silver ions and link silver particles to ZrO2. The prepared samples were characterized by using transmission electron microscopy, X-ray diffraction analysis, and nitrogen adsorption–desorption isotherms. Density functional theory (DFT) calculations using a cluster model are applied to explain optical changes in hybrids, i.e., absorption redshift induced by the ICT complex formation. Decolorization of an organic dye crystal violet (CV), under ultraviolet-C or visible light, was used to compare the photocatalytic ability of the prepared samples. The ICT complex formation transformed ZrO2 into a hybrid material able to induce photocatalytic reactions under exclusive visible light excitation.
T2  - Sustainable Energy and Fuels
T1  - Photocatalytic ability of visible-light-responsive hybrid ZrO2 particles
VL  - 7
IS  - 9
SP  - 2279
EP  - 2287
DO  - 10.1039/D3SE00175J
ER  - 
@article{
author = "Zarubica, Aleksandra and Sredojević, Dušan and Ljupković, Radomir and Ranđelović, Marjan and Murafa, Natalija and Stoiljković, Milovan and Lazić, Vesna and Nedeljković, Jovan",
year = "2023",
abstract = "The interfacial charge transfer (ICT) complex formation between zirconium dioxide (ZrO2), the material absorbing below 250 nm, and 5-aminosalicylic acid (5-ASA) leads to the formation of visible-light-absorbing inorganic–organic hybrids. The free amino groups, present on the hybrid's surface after the ICT complex formation, were used to reduce silver ions and link silver particles to ZrO2. The prepared samples were characterized by using transmission electron microscopy, X-ray diffraction analysis, and nitrogen adsorption–desorption isotherms. Density functional theory (DFT) calculations using a cluster model are applied to explain optical changes in hybrids, i.e., absorption redshift induced by the ICT complex formation. Decolorization of an organic dye crystal violet (CV), under ultraviolet-C or visible light, was used to compare the photocatalytic ability of the prepared samples. The ICT complex formation transformed ZrO2 into a hybrid material able to induce photocatalytic reactions under exclusive visible light excitation.",
journal = "Sustainable Energy and Fuels",
title = "Photocatalytic ability of visible-light-responsive hybrid ZrO2 particles",
volume = "7",
number = "9",
pages = "2279-2287",
doi = "10.1039/D3SE00175J"
}
Zarubica, A., Sredojević, D., Ljupković, R., Ranđelović, M., Murafa, N., Stoiljković, M., Lazić, V.,& Nedeljković, J.. (2023). Photocatalytic ability of visible-light-responsive hybrid ZrO2 particles. in Sustainable Energy and Fuels, 7(9), 2279-2287.
https://doi.org/10.1039/D3SE00175J
Zarubica A, Sredojević D, Ljupković R, Ranđelović M, Murafa N, Stoiljković M, Lazić V, Nedeljković J. Photocatalytic ability of visible-light-responsive hybrid ZrO2 particles. in Sustainable Energy and Fuels. 2023;7(9):2279-2287.
doi:10.1039/D3SE00175J .
Zarubica, Aleksandra, Sredojević, Dušan, Ljupković, Radomir, Ranđelović, Marjan, Murafa, Natalija, Stoiljković, Milovan, Lazić, Vesna, Nedeljković, Jovan, "Photocatalytic ability of visible-light-responsive hybrid ZrO2 particles" in Sustainable Energy and Fuels, 7, no. 9 (2023):2279-2287,
https://doi.org/10.1039/D3SE00175J . .
1
1

Characterization and photocatalytic activity of newly synthesized Er and Yb doped SrGd2O4 nanophosphorus

Stamenković, Tijana; Ranđelović, Marjan; Čebela, Maria; Vuković, Marina; Dinić, Ivana; Mančić, Lidija; Lojpur, Vesna

(Belgrade : Institute for Multidisciplinary Research, 2023)

TY  - CONF
AU  - Stamenković, Tijana
AU  - Ranđelović, Marjan
AU  - Čebela, Maria
AU  - Vuković, Marina
AU  - Dinić, Ivana
AU  - Mančić, Lidija
AU  - Lojpur, Vesna
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/11484
AB  - The aim of this research was to investigate for the first-time photocatalytic degradation of methylene blue over SrGd2O4 powders co-doped with constant Er3+ (0.5 at.%) and different Yb3+ (1, 2.5 and 5 at.%) concentrations. Samples were successfully prepared via sol-gel assisted combustion method. They exhibit photoluminescence properties which are manifested as red emission at 661 nm (4F9/2 → 4I15/2) and two green emissions at 551 and 523 nm (4S3/2 → 4I15/2 and 2H11/2 → 4I15/2). X-ray Powder Diffraction pattern proved that all samples crystallize as a pure orthorhombic phase. Scanning electron microscopy was used for morphology characterization and it revealed the existence of porous agglomerated round-shaped particles. Energy dispersive X-ray spectroscopy showed the presence of dopant ions and even distribution of all constituting elements. To calculate the energy band gap, UV-VIS diffuse reflectance spectroscopy was performed and a value of 4.3 eV was obtained, as well as the four additional values from the bands at lower energies. Photocatalytic degradation of methylene blue was monitored using UV-VIS absorption spectroscopy. Obtained results were promising since after 4 h of exposure to the simulating Sun irradiation, more than 50% of the starting dye concentration was mineralized.
PB  - Belgrade : Institute for Multidisciplinary Research
C3  - Programme and the Book of Abstracts / 7th Conference of The Serbian Society for Ceramic Materials, 7CSCS-2023, June 14-16, 2023 Belgrade, Serbia
T1  - Characterization and photocatalytic activity of newly synthesized Er and Yb doped SrGd2O4 nanophosphorus
SP  - 107
EP  - 107
UR  - https://hdl.handle.net/21.15107/rcub_vinar_11484
ER  - 
@conference{
author = "Stamenković, Tijana and Ranđelović, Marjan and Čebela, Maria and Vuković, Marina and Dinić, Ivana and Mančić, Lidija and Lojpur, Vesna",
year = "2023",
abstract = "The aim of this research was to investigate for the first-time photocatalytic degradation of methylene blue over SrGd2O4 powders co-doped with constant Er3+ (0.5 at.%) and different Yb3+ (1, 2.5 and 5 at.%) concentrations. Samples were successfully prepared via sol-gel assisted combustion method. They exhibit photoluminescence properties which are manifested as red emission at 661 nm (4F9/2 → 4I15/2) and two green emissions at 551 and 523 nm (4S3/2 → 4I15/2 and 2H11/2 → 4I15/2). X-ray Powder Diffraction pattern proved that all samples crystallize as a pure orthorhombic phase. Scanning electron microscopy was used for morphology characterization and it revealed the existence of porous agglomerated round-shaped particles. Energy dispersive X-ray spectroscopy showed the presence of dopant ions and even distribution of all constituting elements. To calculate the energy band gap, UV-VIS diffuse reflectance spectroscopy was performed and a value of 4.3 eV was obtained, as well as the four additional values from the bands at lower energies. Photocatalytic degradation of methylene blue was monitored using UV-VIS absorption spectroscopy. Obtained results were promising since after 4 h of exposure to the simulating Sun irradiation, more than 50% of the starting dye concentration was mineralized.",
publisher = "Belgrade : Institute for Multidisciplinary Research",
journal = "Programme and the Book of Abstracts / 7th Conference of The Serbian Society for Ceramic Materials, 7CSCS-2023, June 14-16, 2023 Belgrade, Serbia",
title = "Characterization and photocatalytic activity of newly synthesized Er and Yb doped SrGd2O4 nanophosphorus",
pages = "107-107",
url = "https://hdl.handle.net/21.15107/rcub_vinar_11484"
}
Stamenković, T., Ranđelović, M., Čebela, M., Vuković, M., Dinić, I., Mančić, L.,& Lojpur, V.. (2023). Characterization and photocatalytic activity of newly synthesized Er and Yb doped SrGd2O4 nanophosphorus. in Programme and the Book of Abstracts / 7th Conference of The Serbian Society for Ceramic Materials, 7CSCS-2023, June 14-16, 2023 Belgrade, Serbia
Belgrade : Institute for Multidisciplinary Research., 107-107.
https://hdl.handle.net/21.15107/rcub_vinar_11484
Stamenković T, Ranđelović M, Čebela M, Vuković M, Dinić I, Mančić L, Lojpur V. Characterization and photocatalytic activity of newly synthesized Er and Yb doped SrGd2O4 nanophosphorus. in Programme and the Book of Abstracts / 7th Conference of The Serbian Society for Ceramic Materials, 7CSCS-2023, June 14-16, 2023 Belgrade, Serbia. 2023;:107-107.
https://hdl.handle.net/21.15107/rcub_vinar_11484 .
Stamenković, Tijana, Ranđelović, Marjan, Čebela, Maria, Vuković, Marina, Dinić, Ivana, Mančić, Lidija, Lojpur, Vesna, "Characterization and photocatalytic activity of newly synthesized Er and Yb doped SrGd2O4 nanophosphorus" in Programme and the Book of Abstracts / 7th Conference of The Serbian Society for Ceramic Materials, 7CSCS-2023, June 14-16, 2023 Belgrade, Serbia (2023):107-107,
https://hdl.handle.net/21.15107/rcub_vinar_11484 .

Yb3+/Tm3+ doped SrGd2O4 as photoluminescent and photocatalytic material

Stamenković, Tijana; Ranđelović, Marjan; Dinić, Ivana; Mančić, Lidija; Lojpur, Vesna

(Belgrade : Institute of Technical Sciences of SASA, 2023)

TY  - CONF
AU  - Stamenković, Tijana
AU  - Ranđelović, Marjan
AU  - Dinić, Ivana
AU  - Mančić, Lidija
AU  - Lojpur, Vesna
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/12318
AB  - In this work we present new up-conversion materials, consisted of SrGd2O4 doped with different concentration of Yb3+ (2, 4, 6 at%) ions and constant concentration of Tm3+ (1 at%), prepared by the combustion method. X-ray powder diffraction (XRPD) showed that assynthesized nanoparticles have orthorhombic structure (Pnma), assigned to the JCPDS Card No:01-072-6387. Scanning electron microscopy (SEM) revealed that obtained nanostructure is composed of porous agglomerated nanoparticles, while energy dispersive spectroscopy (EDS) confirmed presence and uniform distribution of all constituting elements accross the sample. Luminescent properties were evaluated and discovered two blue emission bands at 450 nm and 474 nm, and one red emission band at 650 nm. The sample co-doped with 4 at% Tm3+ showed the most intense photoluminescent emission, and because of that was used in the photocatalytic exiperiment. UV-VIS Diffuse Reflectance Spectroscopy was performed in order to examine materials bandgap, and value of 4.3 eV was obtained as well as the additional values from the bands at lower energies, which indicate potentially good photocatalytic properties. X-ray photoelectron spectroscopy (XPS) revealed presence of OHgroups on the surface which also have positive impact on the photocatalytic performances of the material. UV-VIS Absorption Spectroscopy was used to measure changes of the methylene blue concentration during the photocatalytic degradation process. After 4 h of exposure to the simulating Sun irradiation, the results indicate successful dye decomposition rate. Reaction parameters (MB concentration and catalyst mass) were altered in order to achieve the best photocatalytic performances of this newly synthesized materials.
PB  - Belgrade : Institute of Technical Sciences of SASA
C3  - 21st Young Researchers' Conference Materials Sciences and Engineering : program and the book of abstracts
T1  - Yb3+/Tm3+ doped SrGd2O4 as photoluminescent and photocatalytic material
SP  - 45
EP  - 45
UR  - https://hdl.handle.net/21.15107/rcub_vinar_12318
ER  - 
@conference{
author = "Stamenković, Tijana and Ranđelović, Marjan and Dinić, Ivana and Mančić, Lidija and Lojpur, Vesna",
year = "2023",
abstract = "In this work we present new up-conversion materials, consisted of SrGd2O4 doped with different concentration of Yb3+ (2, 4, 6 at%) ions and constant concentration of Tm3+ (1 at%), prepared by the combustion method. X-ray powder diffraction (XRPD) showed that assynthesized nanoparticles have orthorhombic structure (Pnma), assigned to the JCPDS Card No:01-072-6387. Scanning electron microscopy (SEM) revealed that obtained nanostructure is composed of porous agglomerated nanoparticles, while energy dispersive spectroscopy (EDS) confirmed presence and uniform distribution of all constituting elements accross the sample. Luminescent properties were evaluated and discovered two blue emission bands at 450 nm and 474 nm, and one red emission band at 650 nm. The sample co-doped with 4 at% Tm3+ showed the most intense photoluminescent emission, and because of that was used in the photocatalytic exiperiment. UV-VIS Diffuse Reflectance Spectroscopy was performed in order to examine materials bandgap, and value of 4.3 eV was obtained as well as the additional values from the bands at lower energies, which indicate potentially good photocatalytic properties. X-ray photoelectron spectroscopy (XPS) revealed presence of OHgroups on the surface which also have positive impact on the photocatalytic performances of the material. UV-VIS Absorption Spectroscopy was used to measure changes of the methylene blue concentration during the photocatalytic degradation process. After 4 h of exposure to the simulating Sun irradiation, the results indicate successful dye decomposition rate. Reaction parameters (MB concentration and catalyst mass) were altered in order to achieve the best photocatalytic performances of this newly synthesized materials.",
publisher = "Belgrade : Institute of Technical Sciences of SASA",
journal = "21st Young Researchers' Conference Materials Sciences and Engineering : program and the book of abstracts",
title = "Yb3+/Tm3+ doped SrGd2O4 as photoluminescent and photocatalytic material",
pages = "45-45",
url = "https://hdl.handle.net/21.15107/rcub_vinar_12318"
}
Stamenković, T., Ranđelović, M., Dinić, I., Mančić, L.,& Lojpur, V.. (2023). Yb3+/Tm3+ doped SrGd2O4 as photoluminescent and photocatalytic material. in 21st Young Researchers' Conference Materials Sciences and Engineering : program and the book of abstracts
Belgrade : Institute of Technical Sciences of SASA., 45-45.
https://hdl.handle.net/21.15107/rcub_vinar_12318
Stamenković T, Ranđelović M, Dinić I, Mančić L, Lojpur V. Yb3+/Tm3+ doped SrGd2O4 as photoluminescent and photocatalytic material. in 21st Young Researchers' Conference Materials Sciences and Engineering : program and the book of abstracts. 2023;:45-45.
https://hdl.handle.net/21.15107/rcub_vinar_12318 .
Stamenković, Tijana, Ranđelović, Marjan, Dinić, Ivana, Mančić, Lidija, Lojpur, Vesna, "Yb3+/Tm3+ doped SrGd2O4 as photoluminescent and photocatalytic material" in 21st Young Researchers' Conference Materials Sciences and Engineering : program and the book of abstracts (2023):45-45,
https://hdl.handle.net/21.15107/rcub_vinar_12318 .

Electromagnetic characterization of Ni0.5Zn0.3Co0.2Fe2O4 bulk ceramics in the 1 MHz-12 GHz frequency range

Zarubica, Aleksandra R.; Krstić, Jugoslav B.; Popović, Dejan; Krstić, Aleksandra; Ljupković, Radomir; Ranđelović, Marjan S.; Matović, Branko

(2021)

TY  - JOUR
AU  - Zarubica, Aleksandra R.
AU  - Krstić, Jugoslav B.
AU  - Popović, Dejan
AU  - Krstić, Aleksandra
AU  - Ljupković, Radomir
AU  - Ranđelović, Marjan S.
AU  - Matović, Branko
PY  - 2021
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/9900
AB  - In this paper, NiZnCo ferrite was produced by solid state synthesis, calcination at 1000 °C and sintering at 1250 °C in air atmosphere. The microstructure and phases of the sintered sample were analysed by scanning electron microscopy and X-ray diffraction, respectively. The magnetic properties of the ferrite were evaluated by magnetization and magnetostriction measurements. The complex magnetic permeability and complex permittivity were also measured between 1 MHz-12 GHz and the reflection loss (RL) was calculated in the 100 MHz-12 GHz frequency range. The results show that the ferrite sample presents magnetostrictive behaviour and a saturation magnetization of 71 Am2/kg. Complex permittivity measurements indicate that the material has dielectric behaviour in the whole frequency range studied, with ε′ varying between 7-40, and magnetic behaviour in frequencies between 1 MHz-5 GHz. The minimum RL was found at frequencies between 2.4-3.3 GHz and the calculated RL value for a thickness of 3 mm was lower than −10 dB in frequencies between 2.3-7.3 GHz. These results indicate potential application as microwave absorber in the S band.
T2  - Processing and Application of Ceramics
T1  - Electromagnetic characterization of Ni0.5Zn0.3Co0.2Fe2O4 bulk ceramics in the 1 MHz-12 GHz frequency range
VL  - 15
IS  - 2
SP  - 136
DO  - 10.2298/PAC2102111Z
ER  - 
@article{
author = "Zarubica, Aleksandra R. and Krstić, Jugoslav B. and Popović, Dejan and Krstić, Aleksandra and Ljupković, Radomir and Ranđelović, Marjan S. and Matović, Branko",
year = "2021",
abstract = "In this paper, NiZnCo ferrite was produced by solid state synthesis, calcination at 1000 °C and sintering at 1250 °C in air atmosphere. The microstructure and phases of the sintered sample were analysed by scanning electron microscopy and X-ray diffraction, respectively. The magnetic properties of the ferrite were evaluated by magnetization and magnetostriction measurements. The complex magnetic permeability and complex permittivity were also measured between 1 MHz-12 GHz and the reflection loss (RL) was calculated in the 100 MHz-12 GHz frequency range. The results show that the ferrite sample presents magnetostrictive behaviour and a saturation magnetization of 71 Am2/kg. Complex permittivity measurements indicate that the material has dielectric behaviour in the whole frequency range studied, with ε′ varying between 7-40, and magnetic behaviour in frequencies between 1 MHz-5 GHz. The minimum RL was found at frequencies between 2.4-3.3 GHz and the calculated RL value for a thickness of 3 mm was lower than −10 dB in frequencies between 2.3-7.3 GHz. These results indicate potential application as microwave absorber in the S band.",
journal = "Processing and Application of Ceramics",
title = "Electromagnetic characterization of Ni0.5Zn0.3Co0.2Fe2O4 bulk ceramics in the 1 MHz-12 GHz frequency range",
volume = "15",
number = "2",
pages = "136",
doi = "10.2298/PAC2102111Z"
}
Zarubica, A. R., Krstić, J. B., Popović, D., Krstić, A., Ljupković, R., Ranđelović, M. S.,& Matović, B.. (2021). Electromagnetic characterization of Ni0.5Zn0.3Co0.2Fe2O4 bulk ceramics in the 1 MHz-12 GHz frequency range. in Processing and Application of Ceramics, 15(2), 136.
https://doi.org/10.2298/PAC2102111Z
Zarubica AR, Krstić JB, Popović D, Krstić A, Ljupković R, Ranđelović MS, Matović B. Electromagnetic characterization of Ni0.5Zn0.3Co0.2Fe2O4 bulk ceramics in the 1 MHz-12 GHz frequency range. in Processing and Application of Ceramics. 2021;15(2):136.
doi:10.2298/PAC2102111Z .
Zarubica, Aleksandra R., Krstić, Jugoslav B., Popović, Dejan, Krstić, Aleksandra, Ljupković, Radomir, Ranđelović, Marjan S., Matović, Branko, "Electromagnetic characterization of Ni0.5Zn0.3Co0.2Fe2O4 bulk ceramics in the 1 MHz-12 GHz frequency range" in Processing and Application of Ceramics, 15, no. 2 (2021):136,
https://doi.org/10.2298/PAC2102111Z . .
1

Phonons investigation of ZnO@ZnS core-shell nanostructures with active layer

Hadžić, Branka B.; Matović, Branko; Ranđelović, Marjan S.; Kostić, Radmila; Romčević, Maja J.; Trajić, Jelena; Paunović, Novica; Romčević, Nebojša Ž.

(2021)

TY  - JOUR
AU  - Hadžić, Branka B.
AU  - Matović, Branko
AU  - Ranđelović, Marjan S.
AU  - Kostić, Radmila
AU  - Romčević, Maja J.
AU  - Trajić, Jelena
AU  - Paunović, Novica
AU  - Romčević, Nebojša Ž.
PY  - 2021
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/9788
AB  - In the present work experimental study of the ZnO@ZnS core-shell nanostructure with an active layer obtained by conversion of zinc oxide powders with H2S is reported. Тhe prepared structures were characterized by scanning electron microscopy, X-ray diffraction, Raman spectroscopy, and far-infrared spectroscopy. Top surface optical phonon (TSO) in ZnO, characteristic for the cylindrical nano-objects, the surface optical phonon (SOP) mode of ZnS, and SOP modes in ZnO@ZnS core-shell nanostructure are registered. Local mode of oxygen in ZnS and gap mode of sulfur in ZnO are also registered. This result is due to the existence of an active layer in the space between ZnO core and ZnS shell, which is very important for the application of these materials as thermoelectrics. © 2020 John Wiley & Sons, Ltd.
T2  - Journal of Raman Spectroscopy
T1  - Phonons investigation of ZnO@ZnS core-shell nanostructures with active layer
VL  - 52
IS  - 3
SP  - 616
EP  - 625
DO  - 10.1002/jrs.6058
ER  - 
@article{
author = "Hadžić, Branka B. and Matović, Branko and Ranđelović, Marjan S. and Kostić, Radmila and Romčević, Maja J. and Trajić, Jelena and Paunović, Novica and Romčević, Nebojša Ž.",
year = "2021",
abstract = "In the present work experimental study of the ZnO@ZnS core-shell nanostructure with an active layer obtained by conversion of zinc oxide powders with H2S is reported. Тhe prepared structures were characterized by scanning electron microscopy, X-ray diffraction, Raman spectroscopy, and far-infrared spectroscopy. Top surface optical phonon (TSO) in ZnO, characteristic for the cylindrical nano-objects, the surface optical phonon (SOP) mode of ZnS, and SOP modes in ZnO@ZnS core-shell nanostructure are registered. Local mode of oxygen in ZnS and gap mode of sulfur in ZnO are also registered. This result is due to the existence of an active layer in the space between ZnO core and ZnS shell, which is very important for the application of these materials as thermoelectrics. © 2020 John Wiley & Sons, Ltd.",
journal = "Journal of Raman Spectroscopy",
title = "Phonons investigation of ZnO@ZnS core-shell nanostructures with active layer",
volume = "52",
number = "3",
pages = "616-625",
doi = "10.1002/jrs.6058"
}
Hadžić, B. B., Matović, B., Ranđelović, M. S., Kostić, R., Romčević, M. J., Trajić, J., Paunović, N.,& Romčević, N. Ž.. (2021). Phonons investigation of ZnO@ZnS core-shell nanostructures with active layer. in Journal of Raman Spectroscopy, 52(3), 616-625.
https://doi.org/10.1002/jrs.6058
Hadžić BB, Matović B, Ranđelović MS, Kostić R, Romčević MJ, Trajić J, Paunović N, Romčević NŽ. Phonons investigation of ZnO@ZnS core-shell nanostructures with active layer. in Journal of Raman Spectroscopy. 2021;52(3):616-625.
doi:10.1002/jrs.6058 .
Hadžić, Branka B., Matović, Branko, Ranđelović, Marjan S., Kostić, Radmila, Romčević, Maja J., Trajić, Jelena, Paunović, Novica, Romčević, Nebojša Ž., "Phonons investigation of ZnO@ZnS core-shell nanostructures with active layer" in Journal of Raman Spectroscopy, 52, no. 3 (2021):616-625,
https://doi.org/10.1002/jrs.6058 . .
4
1
4

Effective determination of clomazone and oxyfluorfen in aqueous samples by differential pulse stripping voltammetry

Momčilović, Milan Z.; Ranđelović, Marjan; Milićević, Jelena S.; Bojić, Aleksandar

(2021)

TY  - CONF
AU  - Momčilović, Milan Z.
AU  - Ranđelović, Marjan
AU  - Milićević, Jelena S.
AU  - Bojić, Aleksandar
PY  - 2021
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10762
AB  - Two novel types of electrochemical sensors were obtained by chemical deposition of Pt and MoO2 nanoparticles onto multi walled carbon nano tubes (MWCNT) and used for determination of frequently used pesticides clomazone and oxyfluorfen in aqueous media via differential pulse stripping voltammetry (DPSV). Clomazone was determined in 0.1 M phosphate buffer solution at pH 7.0 in the concentration range 0.61-20.56 ng cm-3, with LOQ = 0.61 and LOD = 0.38 ng cm-3. Oxyfluorfen was determined with good reproducibility (RSD <2.4%) in the concentration range 2.5-34.5 ng cm-3, with r = 0.99 and a LOQ of 1.5 ng cm-3. Results were in the same range measured by HPLC/DAD, which was used as comparative method. Structural characterization of the dopped MWCNT performed by Raman spectroscopy, field emission scanning electron microscopy (FE-SEM), high-resolution transmission electron (HR-TEM), and X-ray crystallography revealed a preserved MWCNT structure decorated with well dispersed species of the platinum and MoO2 nanoparticles.
C3  - Technics. Technologies. Education. Safety. 2021 - Proceedings
T1  - Effective determination of clomazone and oxyfluorfen in aqueous samples by differential pulse stripping voltammetry
VL  - 2
SP  - 88
EP  - 90
UR  - https://hdl.handle.net/21.15107/rcub_vinar_10762
ER  - 
@conference{
author = "Momčilović, Milan Z. and Ranđelović, Marjan and Milićević, Jelena S. and Bojić, Aleksandar",
year = "2021",
abstract = "Two novel types of electrochemical sensors were obtained by chemical deposition of Pt and MoO2 nanoparticles onto multi walled carbon nano tubes (MWCNT) and used for determination of frequently used pesticides clomazone and oxyfluorfen in aqueous media via differential pulse stripping voltammetry (DPSV). Clomazone was determined in 0.1 M phosphate buffer solution at pH 7.0 in the concentration range 0.61-20.56 ng cm-3, with LOQ = 0.61 and LOD = 0.38 ng cm-3. Oxyfluorfen was determined with good reproducibility (RSD <2.4%) in the concentration range 2.5-34.5 ng cm-3, with r = 0.99 and a LOQ of 1.5 ng cm-3. Results were in the same range measured by HPLC/DAD, which was used as comparative method. Structural characterization of the dopped MWCNT performed by Raman spectroscopy, field emission scanning electron microscopy (FE-SEM), high-resolution transmission electron (HR-TEM), and X-ray crystallography revealed a preserved MWCNT structure decorated with well dispersed species of the platinum and MoO2 nanoparticles.",
journal = "Technics. Technologies. Education. Safety. 2021 - Proceedings",
title = "Effective determination of clomazone and oxyfluorfen in aqueous samples by differential pulse stripping voltammetry",
volume = "2",
pages = "88-90",
url = "https://hdl.handle.net/21.15107/rcub_vinar_10762"
}
Momčilović, M. Z., Ranđelović, M., Milićević, J. S.,& Bojić, A.. (2021). Effective determination of clomazone and oxyfluorfen in aqueous samples by differential pulse stripping voltammetry. in Technics. Technologies. Education. Safety. 2021 - Proceedings, 2, 88-90.
https://hdl.handle.net/21.15107/rcub_vinar_10762
Momčilović MZ, Ranđelović M, Milićević JS, Bojić A. Effective determination of clomazone and oxyfluorfen in aqueous samples by differential pulse stripping voltammetry. in Technics. Technologies. Education. Safety. 2021 - Proceedings. 2021;2:88-90.
https://hdl.handle.net/21.15107/rcub_vinar_10762 .
Momčilović, Milan Z., Ranđelović, Marjan, Milićević, Jelena S., Bojić, Aleksandar, "Effective determination of clomazone and oxyfluorfen in aqueous samples by differential pulse stripping voltammetry" in Technics. Technologies. Education. Safety. 2021 - Proceedings, 2 (2021):88-90,
https://hdl.handle.net/21.15107/rcub_vinar_10762 .

Multiwalled carbon nanotubes modified with MoO2 nanoparticles for voltammetric determination of the pesticide oxyfluorfen

Milićević, Jelena S.; Ranđelović, Marjan S.; Momčilović, Milan Z.; Zarubica, Aleksandra R.; Mofarah, Sajjad S.; Matović, Branko; Sorrel, Charles C.

(2020)

TY  - JOUR
AU  - Milićević, Jelena S.
AU  - Ranđelović, Marjan S.
AU  - Momčilović, Milan Z.
AU  - Zarubica, Aleksandra R.
AU  - Mofarah, Sajjad S.
AU  - Matović, Branko
AU  - Sorrel, Charles C.
PY  - 2020
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/9068
AB  - A glassy carbon electrode was functionalized by MoO2 nanoparticle–decorated multiwalled carbon nanotubes (MWCNTs) and examined as a working electrode in oxyfluorfen (OXY) detection by differential pulse stripping voltammetry (DPSV). Measurement parameters were as follows: initial potential − 0.1 V, end potential + 0.5 V, accumulation potential − 0.15 V, accumulation time 80 s, and scan rate 50 mV s−1. A stripping potential of + 0.315 V vs. Ag/AgCl was employed. The pPesticide oxyfluorfen was determined in model samples by DPSV with good reproducibility (RSD <2.4%) in the concentration range 2.5 to 34.5 ng mL−1, with r = 0.99 and a limit of detection of 1.5 ng mL−1. These results are in the same range as those of HPLC/DAD, which is used as the comparative method. Recovery for OXY determination in a real river water sample was 102%. Analyses in Briton-Robinson buffer has shown to be pH dependent with the best response at pH 6.0. Structural characterization of MoO2-MWCNT by Raman spectroscopy, field emission scanning electron microscopy, high-resolution transmission electron microscopy, and X-ray crystallography revealed a preserved MWCNT structure decorated with firmly attached clusters of MoO2 nanoparticles.
T2  - Microchimica Acta
T1  - Multiwalled carbon nanotubes modified with MoO2 nanoparticles for voltammetric determination of the pesticide oxyfluorfen
VL  - 187
IS  - 8
SP  - 429
DO  - 10.1007/s00604-020-04406-4
ER  - 
@article{
author = "Milićević, Jelena S. and Ranđelović, Marjan S. and Momčilović, Milan Z. and Zarubica, Aleksandra R. and Mofarah, Sajjad S. and Matović, Branko and Sorrel, Charles C.",
year = "2020",
abstract = "A glassy carbon electrode was functionalized by MoO2 nanoparticle–decorated multiwalled carbon nanotubes (MWCNTs) and examined as a working electrode in oxyfluorfen (OXY) detection by differential pulse stripping voltammetry (DPSV). Measurement parameters were as follows: initial potential − 0.1 V, end potential + 0.5 V, accumulation potential − 0.15 V, accumulation time 80 s, and scan rate 50 mV s−1. A stripping potential of + 0.315 V vs. Ag/AgCl was employed. The pPesticide oxyfluorfen was determined in model samples by DPSV with good reproducibility (RSD <2.4%) in the concentration range 2.5 to 34.5 ng mL−1, with r = 0.99 and a limit of detection of 1.5 ng mL−1. These results are in the same range as those of HPLC/DAD, which is used as the comparative method. Recovery for OXY determination in a real river water sample was 102%. Analyses in Briton-Robinson buffer has shown to be pH dependent with the best response at pH 6.0. Structural characterization of MoO2-MWCNT by Raman spectroscopy, field emission scanning electron microscopy, high-resolution transmission electron microscopy, and X-ray crystallography revealed a preserved MWCNT structure decorated with firmly attached clusters of MoO2 nanoparticles.",
journal = "Microchimica Acta",
title = "Multiwalled carbon nanotubes modified with MoO2 nanoparticles for voltammetric determination of the pesticide oxyfluorfen",
volume = "187",
number = "8",
pages = "429",
doi = "10.1007/s00604-020-04406-4"
}
Milićević, J. S., Ranđelović, M. S., Momčilović, M. Z., Zarubica, A. R., Mofarah, S. S., Matović, B.,& Sorrel, C. C.. (2020). Multiwalled carbon nanotubes modified with MoO2 nanoparticles for voltammetric determination of the pesticide oxyfluorfen. in Microchimica Acta, 187(8), 429.
https://doi.org/10.1007/s00604-020-04406-4
Milićević JS, Ranđelović MS, Momčilović MZ, Zarubica AR, Mofarah SS, Matović B, Sorrel CC. Multiwalled carbon nanotubes modified with MoO2 nanoparticles for voltammetric determination of the pesticide oxyfluorfen. in Microchimica Acta. 2020;187(8):429.
doi:10.1007/s00604-020-04406-4 .
Milićević, Jelena S., Ranđelović, Marjan S., Momčilović, Milan Z., Zarubica, Aleksandra R., Mofarah, Sajjad S., Matović, Branko, Sorrel, Charles C., "Multiwalled carbon nanotubes modified with MoO2 nanoparticles for voltammetric determination of the pesticide oxyfluorfen" in Microchimica Acta, 187, no. 8 (2020):429,
https://doi.org/10.1007/s00604-020-04406-4 . .
7
5

Electrochemistry of hydrogen peroxide reduction reaction on carbon paste electrodes modified by Ag- and Pt-supported carbon microspheres

Ranđelović, Marjan S.; Momčilović, Milan Z.; Enke, Dirk; Mirčeski, Valentin

(2019)

TY  - JOUR
AU  - Ranđelović, Marjan S.
AU  - Momčilović, Milan Z.
AU  - Enke, Dirk
AU  - Mirčeski, Valentin
PY  - 2019
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/8543
AB  - A simple and facile hydrothermal methodology for preparation of carbon microspheres supported with silver or platinum is presented. Electrocatalytic properties of modified carbon microspheres are tested against the electrochemical reduction reaction of hydrogen peroxide. As revealed by transmission electron microscopy, silver and platinum are immobilized on the surface of carbon microspheres in a form of nanoparticles. In addition, scanning electron microscopy reveals coexistence of smooth surface spherical-shaped carbon microspheres together with clusters that resemble a bunch-of-grapes. Carbon paste electrodes in combination with cyclic and square-wave voltammetry are used to study electrocatalytic properties of carbon microspheres. Voltammetric data are analyzed in light of the theory for simple irreversible electrode reaction. Correlation between experimental and theoretical data implies the highest electrocatalytic effect in the case of silver-modified carbon microspheres, though the electrode mechanism is more complex than theoretically predicted. © 2019, Springer-Verlag GmbH Germany, part of Springer Nature.
T2  - Journal of Solid State Electrochemistry
T1  - Electrochemistry of hydrogen peroxide reduction reaction on carbon paste electrodes modified by Ag- and Pt-supported carbon microspheres
VL  - 23
IS  - 4
SP  - 1257
EP  - 1267
DO  - 10.1007/s10008-019-04226-4
ER  - 
@article{
author = "Ranđelović, Marjan S. and Momčilović, Milan Z. and Enke, Dirk and Mirčeski, Valentin",
year = "2019",
abstract = "A simple and facile hydrothermal methodology for preparation of carbon microspheres supported with silver or platinum is presented. Electrocatalytic properties of modified carbon microspheres are tested against the electrochemical reduction reaction of hydrogen peroxide. As revealed by transmission electron microscopy, silver and platinum are immobilized on the surface of carbon microspheres in a form of nanoparticles. In addition, scanning electron microscopy reveals coexistence of smooth surface spherical-shaped carbon microspheres together with clusters that resemble a bunch-of-grapes. Carbon paste electrodes in combination with cyclic and square-wave voltammetry are used to study electrocatalytic properties of carbon microspheres. Voltammetric data are analyzed in light of the theory for simple irreversible electrode reaction. Correlation between experimental and theoretical data implies the highest electrocatalytic effect in the case of silver-modified carbon microspheres, though the electrode mechanism is more complex than theoretically predicted. © 2019, Springer-Verlag GmbH Germany, part of Springer Nature.",
journal = "Journal of Solid State Electrochemistry",
title = "Electrochemistry of hydrogen peroxide reduction reaction on carbon paste electrodes modified by Ag- and Pt-supported carbon microspheres",
volume = "23",
number = "4",
pages = "1257-1267",
doi = "10.1007/s10008-019-04226-4"
}
Ranđelović, M. S., Momčilović, M. Z., Enke, D.,& Mirčeski, V.. (2019). Electrochemistry of hydrogen peroxide reduction reaction on carbon paste electrodes modified by Ag- and Pt-supported carbon microspheres. in Journal of Solid State Electrochemistry, 23(4), 1257-1267.
https://doi.org/10.1007/s10008-019-04226-4
Ranđelović MS, Momčilović MZ, Enke D, Mirčeski V. Electrochemistry of hydrogen peroxide reduction reaction on carbon paste electrodes modified by Ag- and Pt-supported carbon microspheres. in Journal of Solid State Electrochemistry. 2019;23(4):1257-1267.
doi:10.1007/s10008-019-04226-4 .
Ranđelović, Marjan S., Momčilović, Milan Z., Enke, Dirk, Mirčeski, Valentin, "Electrochemistry of hydrogen peroxide reduction reaction on carbon paste electrodes modified by Ag- and Pt-supported carbon microspheres" in Journal of Solid State Electrochemistry, 23, no. 4 (2019):1257-1267,
https://doi.org/10.1007/s10008-019-04226-4 . .
9
7
9

Voltammetric sensor based on Pt nanoparticles suported MWCNT for determination of pesticide clomazone in water samples

Ranđelović, Marjan S.; Momčilović, Milan Z.; Milićević, Jelena S.; Đurović-Pejčev, Rada; Mofarah, Sajjad S.; Sorrel, Charles C.

(2019)

TY  - JOUR
AU  - Ranđelović, Marjan S.
AU  - Momčilović, Milan Z.
AU  - Milićević, Jelena S.
AU  - Đurović-Pejčev, Rada
AU  - Mofarah, Sajjad S.
AU  - Sorrel, Charles C.
PY  - 2019
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/8619
AB  - Novel electrochemical sensor based on Pt supported multiwalled carbon nanotubes is used for determination of pesticide clomazone in aqueous media via differential pulse stripping voltammetry (DPSV). Since clomazone is stable and readily soluble in water, it is often found in water sources. Hence, its determination in the environment is of utmost importance. Herein, clomazone is determined in 0.1 M phosphate buffer solution at pH 7.0 in the concentration range of 0.61–20.56 ng cm−3, with LOQ = 0.61 and LOD = 0.38. These results are in the same range with HPLC/DAD, which is used as comparative method. It is shown that DPSV is a facile and efficient way for determination of clomazone in contrast to precise but field-impractical HPLC. Mechanistic approach in explaining electrode processes is correlated to structural aspects of the synthesized sensor. HRTEM data reveals a uniform distribution of Pt nanoparticles on the MWCNT support as a source of crucial, structural and electronic changes. Furthermore, characterisation of Raman results indicates the existence of structural defects, which is believed to be the leading reason for improvement in sensing response. © 2019 Taiwan Institute of Chemical Engineers
T2  - Journal of the Taiwan Institute of Chemical Engineers
T1  - Voltammetric sensor based on Pt nanoparticles suported MWCNT for determination of pesticide clomazone in water samples
VL  - 105
SP  - 115
EP  - 123
DO  - 10.1016/j.jtice.2019.10.013
ER  - 
@article{
author = "Ranđelović, Marjan S. and Momčilović, Milan Z. and Milićević, Jelena S. and Đurović-Pejčev, Rada and Mofarah, Sajjad S. and Sorrel, Charles C.",
year = "2019",
abstract = "Novel electrochemical sensor based on Pt supported multiwalled carbon nanotubes is used for determination of pesticide clomazone in aqueous media via differential pulse stripping voltammetry (DPSV). Since clomazone is stable and readily soluble in water, it is often found in water sources. Hence, its determination in the environment is of utmost importance. Herein, clomazone is determined in 0.1 M phosphate buffer solution at pH 7.0 in the concentration range of 0.61–20.56 ng cm−3, with LOQ = 0.61 and LOD = 0.38. These results are in the same range with HPLC/DAD, which is used as comparative method. It is shown that DPSV is a facile and efficient way for determination of clomazone in contrast to precise but field-impractical HPLC. Mechanistic approach in explaining electrode processes is correlated to structural aspects of the synthesized sensor. HRTEM data reveals a uniform distribution of Pt nanoparticles on the MWCNT support as a source of crucial, structural and electronic changes. Furthermore, characterisation of Raman results indicates the existence of structural defects, which is believed to be the leading reason for improvement in sensing response. © 2019 Taiwan Institute of Chemical Engineers",
journal = "Journal of the Taiwan Institute of Chemical Engineers",
title = "Voltammetric sensor based on Pt nanoparticles suported MWCNT for determination of pesticide clomazone in water samples",
volume = "105",
pages = "115-123",
doi = "10.1016/j.jtice.2019.10.013"
}
Ranđelović, M. S., Momčilović, M. Z., Milićević, J. S., Đurović-Pejčev, R., Mofarah, S. S.,& Sorrel, C. C.. (2019). Voltammetric sensor based on Pt nanoparticles suported MWCNT for determination of pesticide clomazone in water samples. in Journal of the Taiwan Institute of Chemical Engineers, 105, 115-123.
https://doi.org/10.1016/j.jtice.2019.10.013
Ranđelović MS, Momčilović MZ, Milićević JS, Đurović-Pejčev R, Mofarah SS, Sorrel CC. Voltammetric sensor based on Pt nanoparticles suported MWCNT for determination of pesticide clomazone in water samples. in Journal of the Taiwan Institute of Chemical Engineers. 2019;105:115-123.
doi:10.1016/j.jtice.2019.10.013 .
Ranđelović, Marjan S., Momčilović, Milan Z., Milićević, Jelena S., Đurović-Pejčev, Rada, Mofarah, Sajjad S., Sorrel, Charles C., "Voltammetric sensor based on Pt nanoparticles suported MWCNT for determination of pesticide clomazone in water samples" in Journal of the Taiwan Institute of Chemical Engineers, 105 (2019):115-123,
https://doi.org/10.1016/j.jtice.2019.10.013 . .
12
6
13

Exploring electrochemical and sorptive aspects of interaction between dissolved sulfides and novel Fe-enriched aluminosilicate composites

Ranđelović, Marjan S.; Momčilović, Milan Z.; Purenović, Jelena M.; Dornberg, Gregor; Barascu, Andrei; Enke, Dirk; Zarubica, Aleksandra R.

(2018)

TY  - JOUR
AU  - Ranđelović, Marjan S.
AU  - Momčilović, Milan Z.
AU  - Purenović, Jelena M.
AU  - Dornberg, Gregor
AU  - Barascu, Andrei
AU  - Enke, Dirk
AU  - Zarubica, Aleksandra R.
PY  - 2018
UR  - http://linkinghub.elsevier.com/retrieve/pii/S092777571830284X
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/7742
AB  - Three types of functional ceramic composites were designed, synthesized and probed for effective sulfide removal from aqueous solutions. The main goal was to examine complex influence of graphite, surpluses of Fe (similar to 4%) and micro-additions of Cu (similar to 0.2%) on the functional features of the composites. The structural, textural, morphological and surface characteristics of the composites were examined in detail by XRD, nitrogen sorption, SEM and FTIR. It has been shown that all composites are solid heterogeneous systems containing amorphous and crystalline phases (graphite, hematite, montmorillonite, quartz, etc.) with pronounced redox activity in contact with sulfide aqueous solutions. Great enhancment of sulfide consumption was detected for composites which contained graphite and it was established that reaction kinetics is fitted to irreversible second-order batch reaction with two reactants. After the treatment of 1 mM S2- solution, using composite dossage of 1 g/dm(3), concentration dropped down to 0.02 mM. In addition, cyclic voltammetry at 50 mV/s revealed the key role of dopants in electrochemical aspect of the process. Obvious boost of S2- uptake is ascribed to numerous electrochemical, chemical and sorption processes on the composite's developed surface.
T2  - Colloids and Surfaces. A: Physicochemical and Engineering Aspects
T1  - Exploring electrochemical and sorptive aspects of interaction between dissolved sulfides and novel Fe-enriched aluminosilicate composites
VL  - 549
SP  - 196
EP  - 204
DO  - 10.1016/j.colsurfa.2018.04.014
ER  - 
@article{
author = "Ranđelović, Marjan S. and Momčilović, Milan Z. and Purenović, Jelena M. and Dornberg, Gregor and Barascu, Andrei and Enke, Dirk and Zarubica, Aleksandra R.",
year = "2018",
abstract = "Three types of functional ceramic composites were designed, synthesized and probed for effective sulfide removal from aqueous solutions. The main goal was to examine complex influence of graphite, surpluses of Fe (similar to 4%) and micro-additions of Cu (similar to 0.2%) on the functional features of the composites. The structural, textural, morphological and surface characteristics of the composites were examined in detail by XRD, nitrogen sorption, SEM and FTIR. It has been shown that all composites are solid heterogeneous systems containing amorphous and crystalline phases (graphite, hematite, montmorillonite, quartz, etc.) with pronounced redox activity in contact with sulfide aqueous solutions. Great enhancment of sulfide consumption was detected for composites which contained graphite and it was established that reaction kinetics is fitted to irreversible second-order batch reaction with two reactants. After the treatment of 1 mM S2- solution, using composite dossage of 1 g/dm(3), concentration dropped down to 0.02 mM. In addition, cyclic voltammetry at 50 mV/s revealed the key role of dopants in electrochemical aspect of the process. Obvious boost of S2- uptake is ascribed to numerous electrochemical, chemical and sorption processes on the composite's developed surface.",
journal = "Colloids and Surfaces. A: Physicochemical and Engineering Aspects",
title = "Exploring electrochemical and sorptive aspects of interaction between dissolved sulfides and novel Fe-enriched aluminosilicate composites",
volume = "549",
pages = "196-204",
doi = "10.1016/j.colsurfa.2018.04.014"
}
Ranđelović, M. S., Momčilović, M. Z., Purenović, J. M., Dornberg, G., Barascu, A., Enke, D.,& Zarubica, A. R.. (2018). Exploring electrochemical and sorptive aspects of interaction between dissolved sulfides and novel Fe-enriched aluminosilicate composites. in Colloids and Surfaces. A: Physicochemical and Engineering Aspects, 549, 196-204.
https://doi.org/10.1016/j.colsurfa.2018.04.014
Ranđelović MS, Momčilović MZ, Purenović JM, Dornberg G, Barascu A, Enke D, Zarubica AR. Exploring electrochemical and sorptive aspects of interaction between dissolved sulfides and novel Fe-enriched aluminosilicate composites. in Colloids and Surfaces. A: Physicochemical and Engineering Aspects. 2018;549:196-204.
doi:10.1016/j.colsurfa.2018.04.014 .
Ranđelović, Marjan S., Momčilović, Milan Z., Purenović, Jelena M., Dornberg, Gregor, Barascu, Andrei, Enke, Dirk, Zarubica, Aleksandra R., "Exploring electrochemical and sorptive aspects of interaction between dissolved sulfides and novel Fe-enriched aluminosilicate composites" in Colloids and Surfaces. A: Physicochemical and Engineering Aspects, 549 (2018):196-204,
https://doi.org/10.1016/j.colsurfa.2018.04.014 . .

Physicochemically modified peat by thermal and oxidation processes as an active material for purification of wastewaters from certain hazardous pollutants

Purenović, Jelena M.; Ranđelović, Marjan S.; Momčilović, Milan Z.; Purenović, Milovan M.; Stanković, Novica J.; Anđelković, Ljiljana N.

(2017)

TY  - JOUR
AU  - Purenović, Jelena M.
AU  - Ranđelović, Marjan S.
AU  - Momčilović, Milan Z.
AU  - Purenović, Milovan M.
AU  - Stanković, Novica J.
AU  - Anđelković, Ljiljana N.
PY  - 2017
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/1363
AB  - The physicochemical modification of peat through thermal and oxidation processes was carried out, in order to obtain new, inexpensive and active material for purification of different types of waters. During the modification, surface chemical compounds of Shilov type were formed. Batch adsorption properties and suitability of physicochemically modified peat (PCMP) for odor removal were tested in aqueous solutions of H2S and colloidal sulphur. Additionally, PCMP was tested in the removal of As(V) which is hazardous ingredient in contaminated waters. Possible mechanisms of pollutants binding include interactions, which lead to formation of adducts and clathrates. All these processes are elucidated in detail. The results showed that the obtained material can be used for the removal of sulphide, colloidal sulphur and As(V) from different types of waters.
T2  - Hemijska industrija
T1  - Physicochemically modified peat by thermal and oxidation processes as an active material for purification of wastewaters from certain hazardous pollutants
VL  - 71
IS  - 4
SP  - 299
EP  - 306
DO  - 10.2298/HEMIND160522040P
ER  - 
@article{
author = "Purenović, Jelena M. and Ranđelović, Marjan S. and Momčilović, Milan Z. and Purenović, Milovan M. and Stanković, Novica J. and Anđelković, Ljiljana N.",
year = "2017",
abstract = "The physicochemical modification of peat through thermal and oxidation processes was carried out, in order to obtain new, inexpensive and active material for purification of different types of waters. During the modification, surface chemical compounds of Shilov type were formed. Batch adsorption properties and suitability of physicochemically modified peat (PCMP) for odor removal were tested in aqueous solutions of H2S and colloidal sulphur. Additionally, PCMP was tested in the removal of As(V) which is hazardous ingredient in contaminated waters. Possible mechanisms of pollutants binding include interactions, which lead to formation of adducts and clathrates. All these processes are elucidated in detail. The results showed that the obtained material can be used for the removal of sulphide, colloidal sulphur and As(V) from different types of waters.",
journal = "Hemijska industrija",
title = "Physicochemically modified peat by thermal and oxidation processes as an active material for purification of wastewaters from certain hazardous pollutants",
volume = "71",
number = "4",
pages = "299-306",
doi = "10.2298/HEMIND160522040P"
}
Purenović, J. M., Ranđelović, M. S., Momčilović, M. Z., Purenović, M. M., Stanković, N. J.,& Anđelković, L. N.. (2017). Physicochemically modified peat by thermal and oxidation processes as an active material for purification of wastewaters from certain hazardous pollutants. in Hemijska industrija, 71(4), 299-306.
https://doi.org/10.2298/HEMIND160522040P
Purenović JM, Ranđelović MS, Momčilović MZ, Purenović MM, Stanković NJ, Anđelković LN. Physicochemically modified peat by thermal and oxidation processes as an active material for purification of wastewaters from certain hazardous pollutants. in Hemijska industrija. 2017;71(4):299-306.
doi:10.2298/HEMIND160522040P .
Purenović, Jelena M., Ranđelović, Marjan S., Momčilović, Milan Z., Purenović, Milovan M., Stanković, Novica J., Anđelković, Ljiljana N., "Physicochemically modified peat by thermal and oxidation processes as an active material for purification of wastewaters from certain hazardous pollutants" in Hemijska industrija, 71, no. 4 (2017):299-306,
https://doi.org/10.2298/HEMIND160522040P . .

Electrocatalitic behaviour of serpentinite modified carbon paste electrode

Ranđelović, Marjan S.; Momčilović, Milan Z.; Nikolić, Goran; Đorđević, Jelena S.

(2017)

TY  - JOUR
AU  - Ranđelović, Marjan S.
AU  - Momčilović, Milan Z.
AU  - Nikolić, Goran
AU  - Đorđević, Jelena S.
PY  - 2017
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/1754
AB  - Electrochemistry of carbon paste electrode which contained serpentinite powder and graphite in 1:1 weight ratio was examined in three-electrode cell regarding its electrocatalytic and sensing properties. For this purpose, red-ox reactions of potassium ferrocyanide in aqueous solutions as benchmark media and pesticide tebufenozide (TBF) were examined. Serpentinite characterization performed by XRPD, SEM/EDX, and FTIR confirmed the structure typical for this mineral rock. Voltammetric analyses have in all cases shown that serpentinite modified carbon paste electrode (S-CPE) possess superior electrocatalytic activity in contrast to bare CPE for the red-ox reactions of K-4[Fe(CN)(6)]. The enlargement of the peak currents, higher electroactive surface area, and the decline of the peak-to-peak separation are a proof of reversible and faster electron transfer kinetics for S-CPE. The effect of pH on the electrochemical behaviour of TBF was investigated in Britton-Robinson buffer solutions in range from 2.0 to 7.0 and showed the best analytical performance at pH 5.0. The oxidation peak of TBF appeared at + 0.5 V vs. Ag/AgCl under conditions optimized for the determination of TBF in the differential pulse stripping voltammetry: initial potential + 0.1 V, end potential + 0.9 V, accumulation potential -0.35 V, accumulation time 120 s, and the scan rate 50 my s(-1).
T2  - Journal of Electroanalytical Chemistry
T1  - Electrocatalitic behaviour of serpentinite modified carbon paste electrode
VL  - 801
SP  - 338
EP  - 344
DO  - 10.1016/j.jelechem.2017.08.011
ER  - 
@article{
author = "Ranđelović, Marjan S. and Momčilović, Milan Z. and Nikolić, Goran and Đorđević, Jelena S.",
year = "2017",
abstract = "Electrochemistry of carbon paste electrode which contained serpentinite powder and graphite in 1:1 weight ratio was examined in three-electrode cell regarding its electrocatalytic and sensing properties. For this purpose, red-ox reactions of potassium ferrocyanide in aqueous solutions as benchmark media and pesticide tebufenozide (TBF) were examined. Serpentinite characterization performed by XRPD, SEM/EDX, and FTIR confirmed the structure typical for this mineral rock. Voltammetric analyses have in all cases shown that serpentinite modified carbon paste electrode (S-CPE) possess superior electrocatalytic activity in contrast to bare CPE for the red-ox reactions of K-4[Fe(CN)(6)]. The enlargement of the peak currents, higher electroactive surface area, and the decline of the peak-to-peak separation are a proof of reversible and faster electron transfer kinetics for S-CPE. The effect of pH on the electrochemical behaviour of TBF was investigated in Britton-Robinson buffer solutions in range from 2.0 to 7.0 and showed the best analytical performance at pH 5.0. The oxidation peak of TBF appeared at + 0.5 V vs. Ag/AgCl under conditions optimized for the determination of TBF in the differential pulse stripping voltammetry: initial potential + 0.1 V, end potential + 0.9 V, accumulation potential -0.35 V, accumulation time 120 s, and the scan rate 50 my s(-1).",
journal = "Journal of Electroanalytical Chemistry",
title = "Electrocatalitic behaviour of serpentinite modified carbon paste electrode",
volume = "801",
pages = "338-344",
doi = "10.1016/j.jelechem.2017.08.011"
}
Ranđelović, M. S., Momčilović, M. Z., Nikolić, G.,& Đorđević, J. S.. (2017). Electrocatalitic behaviour of serpentinite modified carbon paste electrode. in Journal of Electroanalytical Chemistry, 801, 338-344.
https://doi.org/10.1016/j.jelechem.2017.08.011
Ranđelović MS, Momčilović MZ, Nikolić G, Đorđević JS. Electrocatalitic behaviour of serpentinite modified carbon paste electrode. in Journal of Electroanalytical Chemistry. 2017;801:338-344.
doi:10.1016/j.jelechem.2017.08.011 .
Ranđelović, Marjan S., Momčilović, Milan Z., Nikolić, Goran, Đorđević, Jelena S., "Electrocatalitic behaviour of serpentinite modified carbon paste electrode" in Journal of Electroanalytical Chemistry, 801 (2017):338-344,
https://doi.org/10.1016/j.jelechem.2017.08.011 . .
7
3
7

Electrochemical behaviour of serpentinite and forsterite in ferri/ferro cyanide benchmark redox system

Momčilović, Milan; Đorđević, Jelena S.; Zarubica, Aleksandra; Ranđelović, Marjan

(2017)

TY  - CONF
AU  - Momčilović, Milan
AU  - Đorđević, Jelena S.
AU  - Zarubica, Aleksandra
AU  - Ranđelović, Marjan
PY  - 2017
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10766
AB  - Serpentinite rock collected near Kopaonik Mountain in Serbia is considered as a multiphase assemblage mostly consisting of mineral lizardite. Forsterite has been obtained by chemical-thermal treatment of grounded sample of serpentinite. Electrochemical features of these two materials were investigated by using modified carbon paste electrode (CPE) which included mixing analytes, graphite powder and parafin oil as a binder and packing the mixture in a Teflon holder. Morphological and structural characteristics of the samples were analyzed by SEM and XRD techniques which revealed presence of certain crystal phases and agregates of irregular shapes sized from 10 to 40 μm. Cyclic voltammetry was employed to study their electrochemical characteristics. The peak current height and peak-to-peak separation showed that the electrochemical reaction is quasi-reversible. Kinetic parameters were derived from Tafel analysis. Calculated kinetic parameters indicated prominent electrocatalytic effect of the minerals for ferri/ferro cyanide redox reaction in aquaeous solution
C3  - 4th Conference of the Serbian Society for Ceramic Materials
T1  - Electrochemical behaviour of serpentinite and forsterite in ferri/ferro cyanide benchmark redox system
SP  - 94
UR  - https://hdl.handle.net/21.15107/rcub_vinar_10766
ER  - 
@conference{
author = "Momčilović, Milan and Đorđević, Jelena S. and Zarubica, Aleksandra and Ranđelović, Marjan",
year = "2017",
abstract = "Serpentinite rock collected near Kopaonik Mountain in Serbia is considered as a multiphase assemblage mostly consisting of mineral lizardite. Forsterite has been obtained by chemical-thermal treatment of grounded sample of serpentinite. Electrochemical features of these two materials were investigated by using modified carbon paste electrode (CPE) which included mixing analytes, graphite powder and parafin oil as a binder and packing the mixture in a Teflon holder. Morphological and structural characteristics of the samples were analyzed by SEM and XRD techniques which revealed presence of certain crystal phases and agregates of irregular shapes sized from 10 to 40 μm. Cyclic voltammetry was employed to study their electrochemical characteristics. The peak current height and peak-to-peak separation showed that the electrochemical reaction is quasi-reversible. Kinetic parameters were derived from Tafel analysis. Calculated kinetic parameters indicated prominent electrocatalytic effect of the minerals for ferri/ferro cyanide redox reaction in aquaeous solution",
journal = "4th Conference of the Serbian Society for Ceramic Materials",
title = "Electrochemical behaviour of serpentinite and forsterite in ferri/ferro cyanide benchmark redox system",
pages = "94",
url = "https://hdl.handle.net/21.15107/rcub_vinar_10766"
}
Momčilović, M., Đorđević, J. S., Zarubica, A.,& Ranđelović, M.. (2017). Electrochemical behaviour of serpentinite and forsterite in ferri/ferro cyanide benchmark redox system. in 4th Conference of the Serbian Society for Ceramic Materials, 94.
https://hdl.handle.net/21.15107/rcub_vinar_10766
Momčilović M, Đorđević JS, Zarubica A, Ranđelović M. Electrochemical behaviour of serpentinite and forsterite in ferri/ferro cyanide benchmark redox system. in 4th Conference of the Serbian Society for Ceramic Materials. 2017;:94.
https://hdl.handle.net/21.15107/rcub_vinar_10766 .
Momčilović, Milan, Đorđević, Jelena S., Zarubica, Aleksandra, Ranđelović, Marjan, "Electrochemical behaviour of serpentinite and forsterite in ferri/ferro cyanide benchmark redox system" in 4th Conference of the Serbian Society for Ceramic Materials (2017):94,
https://hdl.handle.net/21.15107/rcub_vinar_10766 .

Decolorization of crystal violet over TiO2 and TiO2 doped with zirconia photocatalysts

Vasić, Marija B.; Ranđelović, Marjan S.; Mitrović, Jelena Z.; Stojkovć, Nikola I.; Matović, Branko; Zarubica, Aleksandra R.

(2017)

TY  - JOUR
AU  - Vasić, Marija B.
AU  - Ranđelović, Marjan S.
AU  - Mitrović, Jelena Z.
AU  - Stojkovć, Nikola I.
AU  - Matović, Branko
AU  - Zarubica, Aleksandra R.
PY  - 2017
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/1671
AB  - Titania based catalyst and TiO2 doped with zirconia were prepared by modified sol-gel method. The synthesized catalysts samples were characterized by BET, XRD, SEM and FTIR techniques. Photocatalytic activity was tested in the reaction of crystal violet (CV) dye decolorization/decomposition under UV light irradiation. The effect of several operational parameters, such as catalyst dosage, initial dye concentrations, duration of UV irradiation treatment and number of reaction cycles were also considered. The obtained results indicated faster dye decolorization with the increase of the catalyst amount and a decrease of initial CV concentrations. An influence of doping with zirconia on the physico-chemical properties of bare titania was studied. The doping procedure had affected photocatalytic properties of the final catalytic material, and had improved photocatalytic performances of doped catalyst on crystal violet decolorization/degradation in comparison to bare titania.
T2  - Hemijska industrija
T1  - Decolorization of crystal violet over TiO2 and TiO2 doped with zirconia photocatalysts
VL  - 71
IS  - 3
SP  - 259
EP  - 269
DO  - 10.2298/HEMIND160521036V
ER  - 
@article{
author = "Vasić, Marija B. and Ranđelović, Marjan S. and Mitrović, Jelena Z. and Stojkovć, Nikola I. and Matović, Branko and Zarubica, Aleksandra R.",
year = "2017",
abstract = "Titania based catalyst and TiO2 doped with zirconia were prepared by modified sol-gel method. The synthesized catalysts samples were characterized by BET, XRD, SEM and FTIR techniques. Photocatalytic activity was tested in the reaction of crystal violet (CV) dye decolorization/decomposition under UV light irradiation. The effect of several operational parameters, such as catalyst dosage, initial dye concentrations, duration of UV irradiation treatment and number of reaction cycles were also considered. The obtained results indicated faster dye decolorization with the increase of the catalyst amount and a decrease of initial CV concentrations. An influence of doping with zirconia on the physico-chemical properties of bare titania was studied. The doping procedure had affected photocatalytic properties of the final catalytic material, and had improved photocatalytic performances of doped catalyst on crystal violet decolorization/degradation in comparison to bare titania.",
journal = "Hemijska industrija",
title = "Decolorization of crystal violet over TiO2 and TiO2 doped with zirconia photocatalysts",
volume = "71",
number = "3",
pages = "259-269",
doi = "10.2298/HEMIND160521036V"
}
Vasić, M. B., Ranđelović, M. S., Mitrović, J. Z., Stojkovć, N. I., Matović, B.,& Zarubica, A. R.. (2017). Decolorization of crystal violet over TiO2 and TiO2 doped with zirconia photocatalysts. in Hemijska industrija, 71(3), 259-269.
https://doi.org/10.2298/HEMIND160521036V
Vasić MB, Ranđelović MS, Mitrović JZ, Stojkovć NI, Matović B, Zarubica AR. Decolorization of crystal violet over TiO2 and TiO2 doped with zirconia photocatalysts. in Hemijska industrija. 2017;71(3):259-269.
doi:10.2298/HEMIND160521036V .
Vasić, Marija B., Ranđelović, Marjan S., Mitrović, Jelena Z., Stojkovć, Nikola I., Matović, Branko, Zarubica, Aleksandra R., "Decolorization of crystal violet over TiO2 and TiO2 doped with zirconia photocatalysts" in Hemijska industrija, 71, no. 3 (2017):259-269,
https://doi.org/10.2298/HEMIND160521036V . .
2
2
3

Morpho-structural, adsorption and electrochemical characteristics of serpentinite

Momčilović, Milan Z.; Ranđelović, Marjan S.; Purenović, Milovan M.; Đorđević, Jelena S.; Onjia, Antonije E.; Matović, Branko

(Elsevier, 2016)

TY  - JOUR
AU  - Momčilović, Milan Z.
AU  - Ranđelović, Marjan S.
AU  - Purenović, Milovan M.
AU  - Đorđević, Jelena S.
AU  - Onjia, Antonije E.
AU  - Matović, Branko
PY  - 2016
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/1015
AB  - Pollution control and water purification are the main concerns associated with hazardous component eliminations from wastewaters which have inspired the research, among the others, on various clay minerals as useful adsorbents. The aim of this study was to examine morphological, structural, adsorption, and electrochemical characteristics of serpentinite in order to check its potential for removal of cadmium and textile dyes from synthetic waters. SEM technique has provided a detailed insight into the surface morphology of serpentinite indicating irregularly shaped particles and lamellar aggregates which are characteristic of lizardite mineral. Crystal phases detected in composition of serpentinite by using XRD technique are lizardite and tiny amount of periclase. Serpentinite adsorption characteristics were investigated towards Cd2+ and anionic textile dyes (Procion red MX-5B, Procion orange and Ramazol black) in aqueous solutions. The main goal of the study was the reliable removal of hazardous Cd2+ at low initial concentrations (up to 200 mu g/dm(3)). Textile dyes were taken as the models of anionic organic pollutants in water. All the adsorption experiments were carried out in batch conditions by varying initial parameters such as concentration of pollutant, contact time, mass of adsorbent and pH. Based on the obtained results, serpentinite has proven to be efficient adsorbent with removal efficiency over 98% for the selected pollutants. Native serpentinite was further modified in order to obtain forsterite. Electrochemical characteristics of serpentinite and forsterite were examined by using cyclic voltammetry of solution of 0.1 M H2SO4 as acidic supporting electrolyte and K-4[Fe(CN)(6)] which was chosen as a redox model compound. Due to its specific structure, surface groups, morphology, and non-stoichiometric composition, serpentinite and forsterite exhibited prominent electrocatalytic activity. (C) 2016 Elsevier B.V. All rights reserved.
PB  - Elsevier
T2  - Separation and Purification Technology
T1  - Morpho-structural, adsorption and electrochemical characteristics of serpentinite
VL  - 163
SP  - 72
EP  - 78
DO  - 10.1016/j.seppur.2016.02.042
ER  - 
@article{
author = "Momčilović, Milan Z. and Ranđelović, Marjan S. and Purenović, Milovan M. and Đorđević, Jelena S. and Onjia, Antonije E. and Matović, Branko",
year = "2016",
abstract = "Pollution control and water purification are the main concerns associated with hazardous component eliminations from wastewaters which have inspired the research, among the others, on various clay minerals as useful adsorbents. The aim of this study was to examine morphological, structural, adsorption, and electrochemical characteristics of serpentinite in order to check its potential for removal of cadmium and textile dyes from synthetic waters. SEM technique has provided a detailed insight into the surface morphology of serpentinite indicating irregularly shaped particles and lamellar aggregates which are characteristic of lizardite mineral. Crystal phases detected in composition of serpentinite by using XRD technique are lizardite and tiny amount of periclase. Serpentinite adsorption characteristics were investigated towards Cd2+ and anionic textile dyes (Procion red MX-5B, Procion orange and Ramazol black) in aqueous solutions. The main goal of the study was the reliable removal of hazardous Cd2+ at low initial concentrations (up to 200 mu g/dm(3)). Textile dyes were taken as the models of anionic organic pollutants in water. All the adsorption experiments were carried out in batch conditions by varying initial parameters such as concentration of pollutant, contact time, mass of adsorbent and pH. Based on the obtained results, serpentinite has proven to be efficient adsorbent with removal efficiency over 98% for the selected pollutants. Native serpentinite was further modified in order to obtain forsterite. Electrochemical characteristics of serpentinite and forsterite were examined by using cyclic voltammetry of solution of 0.1 M H2SO4 as acidic supporting electrolyte and K-4[Fe(CN)(6)] which was chosen as a redox model compound. Due to its specific structure, surface groups, morphology, and non-stoichiometric composition, serpentinite and forsterite exhibited prominent electrocatalytic activity. (C) 2016 Elsevier B.V. All rights reserved.",
publisher = "Elsevier",
journal = "Separation and Purification Technology",
title = "Morpho-structural, adsorption and electrochemical characteristics of serpentinite",
volume = "163",
pages = "72-78",
doi = "10.1016/j.seppur.2016.02.042"
}
Momčilović, M. Z., Ranđelović, M. S., Purenović, M. M., Đorđević, J. S., Onjia, A. E.,& Matović, B.. (2016). Morpho-structural, adsorption and electrochemical characteristics of serpentinite. in Separation and Purification Technology
Elsevier., 163, 72-78.
https://doi.org/10.1016/j.seppur.2016.02.042
Momčilović MZ, Ranđelović MS, Purenović MM, Đorđević JS, Onjia AE, Matović B. Morpho-structural, adsorption and electrochemical characteristics of serpentinite. in Separation and Purification Technology. 2016;163:72-78.
doi:10.1016/j.seppur.2016.02.042 .
Momčilović, Milan Z., Ranđelović, Marjan S., Purenović, Milovan M., Đorđević, Jelena S., Onjia, Antonije E., Matović, Branko, "Morpho-structural, adsorption and electrochemical characteristics of serpentinite" in Separation and Purification Technology, 163 (2016):72-78,
https://doi.org/10.1016/j.seppur.2016.02.042 . .
16
12
20

The acid-base, morphological and structural properties of new biosorbent obtained by oxidative hydrothermal treatment of peat

Ranđelović, Marjan S.; Momčilović, Milan Z.; Purenović, Milovan M.; Zarubica, Aleksandra R.; Bojić, Aleksandar Lj.

(Springer, 2016)

TY  - JOUR
AU  - Ranđelović, Marjan S.
AU  - Momčilović, Milan Z.
AU  - Purenović, Milovan M.
AU  - Zarubica, Aleksandra R.
AU  - Bojić, Aleksandar Lj.
PY  - 2016
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/1076
AB  - Samples of natural peat (NP) were hydrothermally treated at different temperatures in oxidative and acidic aqueous medium to tailor their acid-base, adsorption, morphological and other properties. The obtained materials were thoroughly characterized by SEM, XRD and FTIR techniques, followed by determination of pH(pzc), examination of adsorption characteristics and the extent of organic matter leaching in water. Acid-base characteristics of these materials were examined by potentiometric and conductometric titration of corresponding aqueous suspensions. Experimental potentiometric data were interpreted using ProtoFit software (NEM, non-electrostatic model) which provided pKa values and concentrations of surface sites which are compared with corresponding values obtained by conductometric titration method. There are two main types of surface groups (carboxylic and phenolic) that are dominant in the materials and determine their acid-base behavior in the aqueous medium. Temperature during oxidative hydrothermal treatment has no significant effect on the total number of surface groups, but influences the ratio of carboxylic and phenol-type groups. Hence, acid-base properties of peat can be tailored, which is useful in designing and improving adsorptive characteristics of peat for the preferential removal of certain pollutants from water.
PB  - Springer
T2  - Environmental Earth Sciences
T1  - The acid-base, morphological and structural properties of new biosorbent obtained by oxidative hydrothermal treatment of peat
VL  - 75
IS  - 9
DO  - 10.1007/s12665-016-5242-0
ER  - 
@article{
author = "Ranđelović, Marjan S. and Momčilović, Milan Z. and Purenović, Milovan M. and Zarubica, Aleksandra R. and Bojić, Aleksandar Lj.",
year = "2016",
abstract = "Samples of natural peat (NP) were hydrothermally treated at different temperatures in oxidative and acidic aqueous medium to tailor their acid-base, adsorption, morphological and other properties. The obtained materials were thoroughly characterized by SEM, XRD and FTIR techniques, followed by determination of pH(pzc), examination of adsorption characteristics and the extent of organic matter leaching in water. Acid-base characteristics of these materials were examined by potentiometric and conductometric titration of corresponding aqueous suspensions. Experimental potentiometric data were interpreted using ProtoFit software (NEM, non-electrostatic model) which provided pKa values and concentrations of surface sites which are compared with corresponding values obtained by conductometric titration method. There are two main types of surface groups (carboxylic and phenolic) that are dominant in the materials and determine their acid-base behavior in the aqueous medium. Temperature during oxidative hydrothermal treatment has no significant effect on the total number of surface groups, but influences the ratio of carboxylic and phenol-type groups. Hence, acid-base properties of peat can be tailored, which is useful in designing and improving adsorptive characteristics of peat for the preferential removal of certain pollutants from water.",
publisher = "Springer",
journal = "Environmental Earth Sciences",
title = "The acid-base, morphological and structural properties of new biosorbent obtained by oxidative hydrothermal treatment of peat",
volume = "75",
number = "9",
doi = "10.1007/s12665-016-5242-0"
}
Ranđelović, M. S., Momčilović, M. Z., Purenović, M. M., Zarubica, A. R.,& Bojić, A. Lj.. (2016). The acid-base, morphological and structural properties of new biosorbent obtained by oxidative hydrothermal treatment of peat. in Environmental Earth Sciences
Springer., 75(9).
https://doi.org/10.1007/s12665-016-5242-0
Ranđelović MS, Momčilović MZ, Purenović MM, Zarubica AR, Bojić AL. The acid-base, morphological and structural properties of new biosorbent obtained by oxidative hydrothermal treatment of peat. in Environmental Earth Sciences. 2016;75(9).
doi:10.1007/s12665-016-5242-0 .
Ranđelović, Marjan S., Momčilović, Milan Z., Purenović, Milovan M., Zarubica, Aleksandra R., Bojić, Aleksandar Lj., "The acid-base, morphological and structural properties of new biosorbent obtained by oxidative hydrothermal treatment of peat" in Environmental Earth Sciences, 75, no. 9 (2016),
https://doi.org/10.1007/s12665-016-5242-0 . .
4
4
3

Degradation of crystal violet over heterogeneous TiO2-based catalysts: The effect of process parameters

Vasić, Marija B.; Ranđelović, Marjan S.; Momčilović, Milan Z.; Matović, Branko; Zarubica, Aleksandra R.

(2016)

TY  - JOUR
AU  - Vasić, Marija B.
AU  - Ranđelović, Marjan S.
AU  - Momčilović, Milan Z.
AU  - Matović, Branko
AU  - Zarubica, Aleksandra R.
PY  - 2016
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/1329
AB  - In this study, modified sol-gel method was employed to synthesize the pure and Zr-doped titania catalysts. Brunauer-Emmett-Teller (BET) method was applied to determine porosity, X-ray diffraction (XRD) analysis was used to study crystal structure, scanning electron microscopy (SEM) was used to investigate morphology and Fourier transform infrared spectroscopy (FTIR) was used to examine surface properties/total acidity of the obtained catalysts samples. Photocatalytic activity was tested in the reaction of crystal violet (CV) dye decolourization/degradation under UV light irradiation. The effects of several photocatalysis operational parameters were considered, such as catalyst dosage, initial dye concentrations, duration of UV irradiation treatment, as well as catalysts calcination temperatures and dopant amounts. The obtained results indicated faster dye decolourization/degradation with the increase of the catalyst dosage and the decrease of initial CV concentrations. The Zr-doping affects photocatalytic properties, i.e. CV decolourization/degradation of the prepared catalytic materials. Thus, addition of 5 wt.% of ZrO2 to titania increases photocatalytic effect for similar to 15% and addition of 10 wt.% of ZrO2 improves the photocatalytic efficiency of titania for nearly 30%.
T2  - Processing and Application of Ceramics
T1  - Degradation of crystal violet over heterogeneous TiO2-based catalysts: The effect of process parameters
VL  - 10
IS  - 3
SP  - 189
EP  - 198
DO  - 10.2298/PAC1603189V
ER  - 
@article{
author = "Vasić, Marija B. and Ranđelović, Marjan S. and Momčilović, Milan Z. and Matović, Branko and Zarubica, Aleksandra R.",
year = "2016",
abstract = "In this study, modified sol-gel method was employed to synthesize the pure and Zr-doped titania catalysts. Brunauer-Emmett-Teller (BET) method was applied to determine porosity, X-ray diffraction (XRD) analysis was used to study crystal structure, scanning electron microscopy (SEM) was used to investigate morphology and Fourier transform infrared spectroscopy (FTIR) was used to examine surface properties/total acidity of the obtained catalysts samples. Photocatalytic activity was tested in the reaction of crystal violet (CV) dye decolourization/degradation under UV light irradiation. The effects of several photocatalysis operational parameters were considered, such as catalyst dosage, initial dye concentrations, duration of UV irradiation treatment, as well as catalysts calcination temperatures and dopant amounts. The obtained results indicated faster dye decolourization/degradation with the increase of the catalyst dosage and the decrease of initial CV concentrations. The Zr-doping affects photocatalytic properties, i.e. CV decolourization/degradation of the prepared catalytic materials. Thus, addition of 5 wt.% of ZrO2 to titania increases photocatalytic effect for similar to 15% and addition of 10 wt.% of ZrO2 improves the photocatalytic efficiency of titania for nearly 30%.",
journal = "Processing and Application of Ceramics",
title = "Degradation of crystal violet over heterogeneous TiO2-based catalysts: The effect of process parameters",
volume = "10",
number = "3",
pages = "189-198",
doi = "10.2298/PAC1603189V"
}
Vasić, M. B., Ranđelović, M. S., Momčilović, M. Z., Matović, B.,& Zarubica, A. R.. (2016). Degradation of crystal violet over heterogeneous TiO2-based catalysts: The effect of process parameters. in Processing and Application of Ceramics, 10(3), 189-198.
https://doi.org/10.2298/PAC1603189V
Vasić MB, Ranđelović MS, Momčilović MZ, Matović B, Zarubica AR. Degradation of crystal violet over heterogeneous TiO2-based catalysts: The effect of process parameters. in Processing and Application of Ceramics. 2016;10(3):189-198.
doi:10.2298/PAC1603189V .
Vasić, Marija B., Ranđelović, Marjan S., Momčilović, Milan Z., Matović, Branko, Zarubica, Aleksandra R., "Degradation of crystal violet over heterogeneous TiO2-based catalysts: The effect of process parameters" in Processing and Application of Ceramics, 10, no. 3 (2016):189-198,
https://doi.org/10.2298/PAC1603189V . .
11
4
11

Cyclic voltammetry as a tool for model testing of catalytic Pt- and Ag-doped carbon microspheres

Ranđelović, Marjan S.; Momčilović, Milan Z.; Matović, Branko; Babić, Biljana M.; Barek, Jiri

(Elsevier, 2015)

TY  - JOUR
AU  - Ranđelović, Marjan S.
AU  - Momčilović, Milan Z.
AU  - Matović, Branko
AU  - Babić, Biljana M.
AU  - Barek, Jiri
PY  - 2015
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/850
AB  - This paper deals with comparison of modified carbon electrodes prepared from Pt- and Ag-doped carbon microspheres using cyclic voltammetry of [Fe(CN)(6)](3-)/[Fe(CN)(6)](4-) redox pair as a probe under various experimental conditions. Spherical particles ranging from 0.5 to 8 mu m in average as evidenced by SEM showed slight influence of dopant nature onto their microstructure. FTIR analysis revealed that the involvement of metal species in the carbon structure was followed by their subsequent reduction and rising of oxidized carbon functionalities in the spectra. Electrochemical study showed that all the examined electrodes performed reversible processes with chemically stable generated products and no side chemical reactions. Among them, Pt-doped electrode showed superior electrocatalytic behavior in terms of heterogeneous transfer rate constant and other kinetic parameters. Since minimal addition of Pt in the hydrothermal synthesis resulted in powerful electrocatalytic effect as precious advantage, benevolent impact of carbon microspheres as catalyst support was put into focus of this research. (C) 2015 Elsevier B.V. All rights reserved.
PB  - Elsevier
T2  - Journal of Electroanalytical Chemistry
T1  - Cyclic voltammetry as a tool for model testing of catalytic Pt- and Ag-doped carbon microspheres
VL  - 757
SP  - 176
EP  - 182
DO  - 10.1016/j.jelechem.2015.09.035
ER  - 
@article{
author = "Ranđelović, Marjan S. and Momčilović, Milan Z. and Matović, Branko and Babić, Biljana M. and Barek, Jiri",
year = "2015",
abstract = "This paper deals with comparison of modified carbon electrodes prepared from Pt- and Ag-doped carbon microspheres using cyclic voltammetry of [Fe(CN)(6)](3-)/[Fe(CN)(6)](4-) redox pair as a probe under various experimental conditions. Spherical particles ranging from 0.5 to 8 mu m in average as evidenced by SEM showed slight influence of dopant nature onto their microstructure. FTIR analysis revealed that the involvement of metal species in the carbon structure was followed by their subsequent reduction and rising of oxidized carbon functionalities in the spectra. Electrochemical study showed that all the examined electrodes performed reversible processes with chemically stable generated products and no side chemical reactions. Among them, Pt-doped electrode showed superior electrocatalytic behavior in terms of heterogeneous transfer rate constant and other kinetic parameters. Since minimal addition of Pt in the hydrothermal synthesis resulted in powerful electrocatalytic effect as precious advantage, benevolent impact of carbon microspheres as catalyst support was put into focus of this research. (C) 2015 Elsevier B.V. All rights reserved.",
publisher = "Elsevier",
journal = "Journal of Electroanalytical Chemistry",
title = "Cyclic voltammetry as a tool for model testing of catalytic Pt- and Ag-doped carbon microspheres",
volume = "757",
pages = "176-182",
doi = "10.1016/j.jelechem.2015.09.035"
}
Ranđelović, M. S., Momčilović, M. Z., Matović, B., Babić, B. M.,& Barek, J.. (2015). Cyclic voltammetry as a tool for model testing of catalytic Pt- and Ag-doped carbon microspheres. in Journal of Electroanalytical Chemistry
Elsevier., 757, 176-182.
https://doi.org/10.1016/j.jelechem.2015.09.035
Ranđelović MS, Momčilović MZ, Matović B, Babić BM, Barek J. Cyclic voltammetry as a tool for model testing of catalytic Pt- and Ag-doped carbon microspheres. in Journal of Electroanalytical Chemistry. 2015;757:176-182.
doi:10.1016/j.jelechem.2015.09.035 .
Ranđelović, Marjan S., Momčilović, Milan Z., Matović, Branko, Babić, Biljana M., Barek, Jiri, "Cyclic voltammetry as a tool for model testing of catalytic Pt- and Ag-doped carbon microspheres" in Journal of Electroanalytical Chemistry, 757 (2015):176-182,
https://doi.org/10.1016/j.jelechem.2015.09.035 . .
5
5
6

Application of Minkowski layer for intergranular fractal surfaces of multiphase active microalloyed and alloyed aluminium-silicate ceramics

Purenović, Jelena M.; Ranđelović, Marjan S.; Matović, Branko; Purenović, Milovan M.

(2015)

TY  - JOUR
AU  - Purenović, Jelena M.
AU  - Ranđelović, Marjan S.
AU  - Matović, Branko
AU  - Purenović, Milovan M.
PY  - 2015
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/424
AB  - Microalloyed and alloyed aluminium-silicate ceramics represents multiphase and multifunctional solid-solid system. The microstructure of aluminium-silicate ceramics matrix is arranged with favorable relationship between crystallinity and amorphousness. Numbered physical processes and interactions take place in very complex intergranular and interphase areas, making new boundaries and regions with fractal nature. Fractal nature of grains contours, macro, mezzo and micro pores and nanostructure phases at grain boundaries make this ceramics an active dielectric material. The synergistic effect of additives, dislocations and impurities leads to dislocations movement at grain boundaries and fragmentation of existing grains in a large number of micrograins with distinct fractal nature. Hence, permanent change of micromorphology occurs in intergranular area. Fractal analysis of intergranular microstructure has included application of Minkowski layer, correlated with fractal dimension. It represents convex layer of grains contour roughness and irregularity, determined in accordance with grain contours fractality. The introduction of fractal microstructure analysis allows better interpretation of many physical and physico-chemical processes, bearing in mind that Minkowski layer defines grains contact probability. (C) 2015 Elsevier B.V. All rights reserved.
T2  - Applied Surface Science
T1  - Application of Minkowski layer for intergranular fractal surfaces of multiphase active microalloyed and alloyed aluminium-silicate ceramics
VL  - 332
SP  - 440
EP  - 455
DO  - 10.1016/j.apsusc.2015.01.162
ER  - 
@article{
author = "Purenović, Jelena M. and Ranđelović, Marjan S. and Matović, Branko and Purenović, Milovan M.",
year = "2015",
abstract = "Microalloyed and alloyed aluminium-silicate ceramics represents multiphase and multifunctional solid-solid system. The microstructure of aluminium-silicate ceramics matrix is arranged with favorable relationship between crystallinity and amorphousness. Numbered physical processes and interactions take place in very complex intergranular and interphase areas, making new boundaries and regions with fractal nature. Fractal nature of grains contours, macro, mezzo and micro pores and nanostructure phases at grain boundaries make this ceramics an active dielectric material. The synergistic effect of additives, dislocations and impurities leads to dislocations movement at grain boundaries and fragmentation of existing grains in a large number of micrograins with distinct fractal nature. Hence, permanent change of micromorphology occurs in intergranular area. Fractal analysis of intergranular microstructure has included application of Minkowski layer, correlated with fractal dimension. It represents convex layer of grains contour roughness and irregularity, determined in accordance with grain contours fractality. The introduction of fractal microstructure analysis allows better interpretation of many physical and physico-chemical processes, bearing in mind that Minkowski layer defines grains contact probability. (C) 2015 Elsevier B.V. All rights reserved.",
journal = "Applied Surface Science",
title = "Application of Minkowski layer for intergranular fractal surfaces of multiphase active microalloyed and alloyed aluminium-silicate ceramics",
volume = "332",
pages = "440-455",
doi = "10.1016/j.apsusc.2015.01.162"
}
Purenović, J. M., Ranđelović, M. S., Matović, B.,& Purenović, M. M.. (2015). Application of Minkowski layer for intergranular fractal surfaces of multiphase active microalloyed and alloyed aluminium-silicate ceramics. in Applied Surface Science, 332, 440-455.
https://doi.org/10.1016/j.apsusc.2015.01.162
Purenović JM, Ranđelović MS, Matović B, Purenović MM. Application of Minkowski layer for intergranular fractal surfaces of multiphase active microalloyed and alloyed aluminium-silicate ceramics. in Applied Surface Science. 2015;332:440-455.
doi:10.1016/j.apsusc.2015.01.162 .
Purenović, Jelena M., Ranđelović, Marjan S., Matović, Branko, Purenović, Milovan M., "Application of Minkowski layer for intergranular fractal surfaces of multiphase active microalloyed and alloyed aluminium-silicate ceramics" in Applied Surface Science, 332 (2015):440-455,
https://doi.org/10.1016/j.apsusc.2015.01.162 . .
1
1

Synthesis and characterization of resorcinol formaldehyde carbon cryogel as efficient sorbent for imidacloprid removal

Momčilović, Milan Z.; Ranđelović, Marjan S.; Purenović, Milovan M.; Onjia, Antonije E.; Babić, Biljana M.; Matović, Branko

(2014)

TY  - JOUR
AU  - Momčilović, Milan Z.
AU  - Ranđelović, Marjan S.
AU  - Purenović, Milovan M.
AU  - Onjia, Antonije E.
AU  - Babić, Biljana M.
AU  - Matović, Branko
PY  - 2014
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/211
AB  - Carbon cryogel (CC) has been prepared through sol gel polycondensation of resorcinol with formaldehyde in basic aqueous solution followed by freeze-drying and carbonization. Porous properties of CC analyzed by gravimetric McBain method confirmed the expected surface area and degree of mesoporosity. Obtained powdered material was used for the removal of pesticide imidacloprid from aqueous solutions under regular batch adsorption procedure. A set of several isotherm models including Langmuir, Freundlich, Temkin, Dubinin-Radushkevich, Brouers-Sotolongo, Redlich-Peterson, Sips, Toth, Jovanovic, Hurkins-Jura, Halsey and Radke-Prausnitz model was used for nonlinear fitting of equilibrium data. Several models fitted with quite high correlation coefficients. Bangham and Elovich model fitted suitably for kinetic study indicating that pesticide diffusion into carbons pores is important step which dictates the process rate. Suitability of kinetic models decreased with the increase in adsorbent dosage. Imidacloprid uptake was not influenced by the solution pH.
T2  - Desalination and Water Treatment
T1  - Synthesis and characterization of resorcinol formaldehyde carbon cryogel as efficient sorbent for imidacloprid removal
VL  - 52
IS  - 37-39
SP  - 7306
EP  - 7316
DO  - 10.1080/19443994.2013.836993
ER  - 
@article{
author = "Momčilović, Milan Z. and Ranđelović, Marjan S. and Purenović, Milovan M. and Onjia, Antonije E. and Babić, Biljana M. and Matović, Branko",
year = "2014",
abstract = "Carbon cryogel (CC) has been prepared through sol gel polycondensation of resorcinol with formaldehyde in basic aqueous solution followed by freeze-drying and carbonization. Porous properties of CC analyzed by gravimetric McBain method confirmed the expected surface area and degree of mesoporosity. Obtained powdered material was used for the removal of pesticide imidacloprid from aqueous solutions under regular batch adsorption procedure. A set of several isotherm models including Langmuir, Freundlich, Temkin, Dubinin-Radushkevich, Brouers-Sotolongo, Redlich-Peterson, Sips, Toth, Jovanovic, Hurkins-Jura, Halsey and Radke-Prausnitz model was used for nonlinear fitting of equilibrium data. Several models fitted with quite high correlation coefficients. Bangham and Elovich model fitted suitably for kinetic study indicating that pesticide diffusion into carbons pores is important step which dictates the process rate. Suitability of kinetic models decreased with the increase in adsorbent dosage. Imidacloprid uptake was not influenced by the solution pH.",
journal = "Desalination and Water Treatment",
title = "Synthesis and characterization of resorcinol formaldehyde carbon cryogel as efficient sorbent for imidacloprid removal",
volume = "52",
number = "37-39",
pages = "7306-7316",
doi = "10.1080/19443994.2013.836993"
}
Momčilović, M. Z., Ranđelović, M. S., Purenović, M. M., Onjia, A. E., Babić, B. M.,& Matović, B.. (2014). Synthesis and characterization of resorcinol formaldehyde carbon cryogel as efficient sorbent for imidacloprid removal. in Desalination and Water Treatment, 52(37-39), 7306-7316.
https://doi.org/10.1080/19443994.2013.836993
Momčilović MZ, Ranđelović MS, Purenović MM, Onjia AE, Babić BM, Matović B. Synthesis and characterization of resorcinol formaldehyde carbon cryogel as efficient sorbent for imidacloprid removal. in Desalination and Water Treatment. 2014;52(37-39):7306-7316.
doi:10.1080/19443994.2013.836993 .
Momčilović, Milan Z., Ranđelović, Marjan S., Purenović, Milovan M., Onjia, Antonije E., Babić, Biljana M., Matović, Branko, "Synthesis and characterization of resorcinol formaldehyde carbon cryogel as efficient sorbent for imidacloprid removal" in Desalination and Water Treatment, 52, no. 37-39 (2014):7306-7316,
https://doi.org/10.1080/19443994.2013.836993 . .
9
10
11

Study on the efficient removal of clopyralid from water using a resorcinol-formaldehyde carbon cryogel

Momčilović, Milan Z.; Ranđelović, Marjan S.; Onjia, Antonije E.; Zarubica, Aleksandra R.; Babić, Biljana M.; Matović, Branko

(2014)

TY  - JOUR
AU  - Momčilović, Milan Z.
AU  - Ranđelović, Marjan S.
AU  - Onjia, Antonije E.
AU  - Zarubica, Aleksandra R.
AU  - Babić, Biljana M.
AU  - Matović, Branko
PY  - 2014
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/5984
AB  - A resorcinol-formaldehyde carbon cryogel was prepared, characterized and used for the removal of the commonly used herbicide clopyralid from aqueous solutions under varying experimental conditions. The carbon exhibited a relatively high specific surface area, significant mesoporosity and an amorphous structure. The following isotherm models were used to interpret the equilibrium data: the Langmuir, Freundlich, Temkin, Dubinin-Radushkevich, Jovanovic, Hurkins-Jura and the Helsey Model. Several models fitted the data well although the calculated values for q(max) poorly correlated with the experimentally obtained data. The pseudo-first and pseudo-second-order kinetic models, the models of Elovich, Bangham and the intraparticle diffusion model were employed for fitting the kinetic data. The rate of the process was fast at the beginning, although the adsorption equilibrium was not attained before 24 h. The adsorption was found to be pH dependent and favored in acidic solutions.
T2  - Journal of the Serbian Chemical Society
T1  - Study on the efficient removal of clopyralid from water using a resorcinol-formaldehyde carbon cryogel
VL  - 79
IS  - 4
SP  - 481
EP  - 494
DO  - 10.2298/JSC130611151M
ER  - 
@article{
author = "Momčilović, Milan Z. and Ranđelović, Marjan S. and Onjia, Antonije E. and Zarubica, Aleksandra R. and Babić, Biljana M. and Matović, Branko",
year = "2014",
abstract = "A resorcinol-formaldehyde carbon cryogel was prepared, characterized and used for the removal of the commonly used herbicide clopyralid from aqueous solutions under varying experimental conditions. The carbon exhibited a relatively high specific surface area, significant mesoporosity and an amorphous structure. The following isotherm models were used to interpret the equilibrium data: the Langmuir, Freundlich, Temkin, Dubinin-Radushkevich, Jovanovic, Hurkins-Jura and the Helsey Model. Several models fitted the data well although the calculated values for q(max) poorly correlated with the experimentally obtained data. The pseudo-first and pseudo-second-order kinetic models, the models of Elovich, Bangham and the intraparticle diffusion model were employed for fitting the kinetic data. The rate of the process was fast at the beginning, although the adsorption equilibrium was not attained before 24 h. The adsorption was found to be pH dependent and favored in acidic solutions.",
journal = "Journal of the Serbian Chemical Society",
title = "Study on the efficient removal of clopyralid from water using a resorcinol-formaldehyde carbon cryogel",
volume = "79",
number = "4",
pages = "481-494",
doi = "10.2298/JSC130611151M"
}
Momčilović, M. Z., Ranđelović, M. S., Onjia, A. E., Zarubica, A. R., Babić, B. M.,& Matović, B.. (2014). Study on the efficient removal of clopyralid from water using a resorcinol-formaldehyde carbon cryogel. in Journal of the Serbian Chemical Society, 79(4), 481-494.
https://doi.org/10.2298/JSC130611151M
Momčilović MZ, Ranđelović MS, Onjia AE, Zarubica AR, Babić BM, Matović B. Study on the efficient removal of clopyralid from water using a resorcinol-formaldehyde carbon cryogel. in Journal of the Serbian Chemical Society. 2014;79(4):481-494.
doi:10.2298/JSC130611151M .
Momčilović, Milan Z., Ranđelović, Marjan S., Onjia, Antonije E., Zarubica, Aleksandra R., Babić, Biljana M., Matović, Branko, "Study on the efficient removal of clopyralid from water using a resorcinol-formaldehyde carbon cryogel" in Journal of the Serbian Chemical Society, 79, no. 4 (2014):481-494,
https://doi.org/10.2298/JSC130611151M . .
5
3
6

Structural, textural and adsorption characteristics of bentonite-based composite

Ranđelović, Marjan S.; Purenović, Milovan M.; Matović, Branko; Zarubica, Aleksandra R.; Momčilović, Milan Z.; Purenović, Jelena M.

(2014)

TY  - JOUR
AU  - Ranđelović, Marjan S.
AU  - Purenović, Milovan M.
AU  - Matović, Branko
AU  - Zarubica, Aleksandra R.
AU  - Momčilović, Milan Z.
AU  - Purenović, Jelena M.
PY  - 2014
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/6042
AB  - An application of coatings composed of mixed (hydr)oxides over bentonite particles in aqueous suspension, in narrow range of pH, has been proven as a useful method for obtaining bentonite based composite with a developed, specific surface area and pronounced adsorption features toward cationic pollutants. This paper deals with detailed characterization of structure as well as textural and adsorption properties of bentonite based composite. The structure of the composite was examined by using XRD technique providing results that confirm changes in orientation of layered quasi-crystalline particles of montmorillonite, which is the most common component of bentonite clay. Surface area and pore volumes were determined by N-2 adsorption at -196 degrees C using BET, t-plot, alpha(s)-plot, Dubinin Radushkevich and Dolli-more Heal method. The results have revealed that the specific surface area for composite is about two times higher than for starting bentonite. Moreover, modification of bentonite leads to significant changes in the meso- and microporosity. Adsorption properties of the composite were studied by analyzing the adsorption of dye methylene blue which was used in this study as a model of cationic pollutant in water. The most prominent role in the mechanism of dye molecules retention on the surface, interlayers and in the pores of the adsorbent is ascribed to establishing of electrostatic, van der Waals and hydrogen bonds. The shape of adsorption isotherm indicates that methylene blue can be adsorbed onto composite in more than one layer. (C) 2014 Elsevier Inc. All rights reserved.
T2  - Microporous and Mesoporous Materials
T1  - Structural, textural and adsorption characteristics of bentonite-based composite
VL  - 195
SP  - 67
EP  - 74
DO  - 10.1016/j.micromeso.2014.03.031
ER  - 
@article{
author = "Ranđelović, Marjan S. and Purenović, Milovan M. and Matović, Branko and Zarubica, Aleksandra R. and Momčilović, Milan Z. and Purenović, Jelena M.",
year = "2014",
abstract = "An application of coatings composed of mixed (hydr)oxides over bentonite particles in aqueous suspension, in narrow range of pH, has been proven as a useful method for obtaining bentonite based composite with a developed, specific surface area and pronounced adsorption features toward cationic pollutants. This paper deals with detailed characterization of structure as well as textural and adsorption properties of bentonite based composite. The structure of the composite was examined by using XRD technique providing results that confirm changes in orientation of layered quasi-crystalline particles of montmorillonite, which is the most common component of bentonite clay. Surface area and pore volumes were determined by N-2 adsorption at -196 degrees C using BET, t-plot, alpha(s)-plot, Dubinin Radushkevich and Dolli-more Heal method. The results have revealed that the specific surface area for composite is about two times higher than for starting bentonite. Moreover, modification of bentonite leads to significant changes in the meso- and microporosity. Adsorption properties of the composite were studied by analyzing the adsorption of dye methylene blue which was used in this study as a model of cationic pollutant in water. The most prominent role in the mechanism of dye molecules retention on the surface, interlayers and in the pores of the adsorbent is ascribed to establishing of electrostatic, van der Waals and hydrogen bonds. The shape of adsorption isotherm indicates that methylene blue can be adsorbed onto composite in more than one layer. (C) 2014 Elsevier Inc. All rights reserved.",
journal = "Microporous and Mesoporous Materials",
title = "Structural, textural and adsorption characteristics of bentonite-based composite",
volume = "195",
pages = "67-74",
doi = "10.1016/j.micromeso.2014.03.031"
}
Ranđelović, M. S., Purenović, M. M., Matović, B., Zarubica, A. R., Momčilović, M. Z.,& Purenović, J. M.. (2014). Structural, textural and adsorption characteristics of bentonite-based composite. in Microporous and Mesoporous Materials, 195, 67-74.
https://doi.org/10.1016/j.micromeso.2014.03.031
Ranđelović MS, Purenović MM, Matović B, Zarubica AR, Momčilović MZ, Purenović JM. Structural, textural and adsorption characteristics of bentonite-based composite. in Microporous and Mesoporous Materials. 2014;195:67-74.
doi:10.1016/j.micromeso.2014.03.031 .
Ranđelović, Marjan S., Purenović, Milovan M., Matović, Branko, Zarubica, Aleksandra R., Momčilović, Milan Z., Purenović, Jelena M., "Structural, textural and adsorption characteristics of bentonite-based composite" in Microporous and Mesoporous Materials, 195 (2014):67-74,
https://doi.org/10.1016/j.micromeso.2014.03.031 . .
35
27
38

Design and photocatalytic ability of ordered mesoporous TiO2 thin films

Zarubica, Aleksandra R.; Vučinić-Vasić, Milica; Antonijević, Milan D.; Ranđelović, Marjan S.; Momčilović, Milan Z.; Krstić, Jugoslav B.; Nedeljković, Jovan

(2014)

TY  - JOUR
AU  - Zarubica, Aleksandra R.
AU  - Vučinić-Vasić, Milica
AU  - Antonijević, Milan D.
AU  - Ranđelović, Marjan S.
AU  - Momčilović, Milan Z.
AU  - Krstić, Jugoslav B.
AU  - Nedeljković, Jovan
PY  - 2014
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/95
AB  - Homogeneous and crack-free TiO2 films with templated mesoporosity were prepared by the dip coating technique using an evaporation-induced, self-assembly method. The synthesized mesoporous TiO2 films were characterized using SEM/TEM, BET and XRD techniques. Degradation reactions of methylene blue and crystal violet dyes were used to test the photocatalytic capability of mesoporous TiO2 films. The degradation kinetics of methylene blue and crystal violet were investigated over a broad range of initial concentrations of the organic dyes. The kinetic data were correlated with the specific surface area and thickness of mesoporous TiO2 films, as well as number of reaction cycles. (C) 2014 Elsevier Ltd. All rights reserved.
T2  - Materials Research Bulletin
T1  - Design and photocatalytic ability of ordered mesoporous TiO2 thin films
VL  - 57
SP  - 146
EP  - 151
DO  - 10.1016/j.materresbull.2014.03.015
ER  - 
@article{
author = "Zarubica, Aleksandra R. and Vučinić-Vasić, Milica and Antonijević, Milan D. and Ranđelović, Marjan S. and Momčilović, Milan Z. and Krstić, Jugoslav B. and Nedeljković, Jovan",
year = "2014",
abstract = "Homogeneous and crack-free TiO2 films with templated mesoporosity were prepared by the dip coating technique using an evaporation-induced, self-assembly method. The synthesized mesoporous TiO2 films were characterized using SEM/TEM, BET and XRD techniques. Degradation reactions of methylene blue and crystal violet dyes were used to test the photocatalytic capability of mesoporous TiO2 films. The degradation kinetics of methylene blue and crystal violet were investigated over a broad range of initial concentrations of the organic dyes. The kinetic data were correlated with the specific surface area and thickness of mesoporous TiO2 films, as well as number of reaction cycles. (C) 2014 Elsevier Ltd. All rights reserved.",
journal = "Materials Research Bulletin",
title = "Design and photocatalytic ability of ordered mesoporous TiO2 thin films",
volume = "57",
pages = "146-151",
doi = "10.1016/j.materresbull.2014.03.015"
}
Zarubica, A. R., Vučinić-Vasić, M., Antonijević, M. D., Ranđelović, M. S., Momčilović, M. Z., Krstić, J. B.,& Nedeljković, J.. (2014). Design and photocatalytic ability of ordered mesoporous TiO2 thin films. in Materials Research Bulletin, 57, 146-151.
https://doi.org/10.1016/j.materresbull.2014.03.015
Zarubica AR, Vučinić-Vasić M, Antonijević MD, Ranđelović MS, Momčilović MZ, Krstić JB, Nedeljković J. Design and photocatalytic ability of ordered mesoporous TiO2 thin films. in Materials Research Bulletin. 2014;57:146-151.
doi:10.1016/j.materresbull.2014.03.015 .
Zarubica, Aleksandra R., Vučinić-Vasić, Milica, Antonijević, Milan D., Ranđelović, Marjan S., Momčilović, Milan Z., Krstić, Jugoslav B., Nedeljković, Jovan, "Design and photocatalytic ability of ordered mesoporous TiO2 thin films" in Materials Research Bulletin, 57 (2014):146-151,
https://doi.org/10.1016/j.materresbull.2014.03.015 . .
1
14
12
14

The balance between acidity and tetragonal phase fraction in the favorable catalytic act of modified zirconia towards isomerized n-hexane(s)

Zarubica, Aleksandra R.; Ranđelović, Marjan S.; Momčilović, Milan Z.; Stojković, Nikola; Vučinić-Vasić, Milica; Radulovic, N.

(2013)

TY  - JOUR
AU  - Zarubica, Aleksandra R.
AU  - Ranđelović, Marjan S.
AU  - Momčilović, Milan Z.
AU  - Stojković, Nikola
AU  - Vučinić-Vasić, Milica
AU  - Radulovic, N.
PY  - 2013
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/5369
AB  - Zirconia-based catalysts were promoted by acid functions (sulfate and phosphate anions) and tested in order to establish catalyst efficiency in test reaction of n-hexane isomerization. The impact of surface and structural properties on the final catalytic performance is also investigated. It is proven that well-established balance between total catalyst acidity, acidic surface density and crystal phase nano-structure determines the catalytic activity in the reaction towards isomerized products. Type of acidic promoter strongly affects the resulted catalytic act. This stands for pyrosylfate groups in sulfated zirconia catalysts and orthophosphate groups in phosphated zirconia catalysts both essential in the favorable reaction run.
T2  - Optoelectronics and Advanced Materials - Rapid Communications
T1  - The balance between acidity and tetragonal phase fraction in the favorable catalytic act of modified zirconia towards isomerized n-hexane(s)
VL  - 7
IS  - 1-2
SP  - 62
EP  - 69
UR  - https://hdl.handle.net/21.15107/rcub_vinar_5369
ER  - 
@article{
author = "Zarubica, Aleksandra R. and Ranđelović, Marjan S. and Momčilović, Milan Z. and Stojković, Nikola and Vučinić-Vasić, Milica and Radulovic, N.",
year = "2013",
abstract = "Zirconia-based catalysts were promoted by acid functions (sulfate and phosphate anions) and tested in order to establish catalyst efficiency in test reaction of n-hexane isomerization. The impact of surface and structural properties on the final catalytic performance is also investigated. It is proven that well-established balance between total catalyst acidity, acidic surface density and crystal phase nano-structure determines the catalytic activity in the reaction towards isomerized products. Type of acidic promoter strongly affects the resulted catalytic act. This stands for pyrosylfate groups in sulfated zirconia catalysts and orthophosphate groups in phosphated zirconia catalysts both essential in the favorable reaction run.",
journal = "Optoelectronics and Advanced Materials - Rapid Communications",
title = "The balance between acidity and tetragonal phase fraction in the favorable catalytic act of modified zirconia towards isomerized n-hexane(s)",
volume = "7",
number = "1-2",
pages = "62-69",
url = "https://hdl.handle.net/21.15107/rcub_vinar_5369"
}
Zarubica, A. R., Ranđelović, M. S., Momčilović, M. Z., Stojković, N., Vučinić-Vasić, M.,& Radulovic, N.. (2013). The balance between acidity and tetragonal phase fraction in the favorable catalytic act of modified zirconia towards isomerized n-hexane(s). in Optoelectronics and Advanced Materials - Rapid Communications, 7(1-2), 62-69.
https://hdl.handle.net/21.15107/rcub_vinar_5369
Zarubica AR, Ranđelović MS, Momčilović MZ, Stojković N, Vučinić-Vasić M, Radulovic N. The balance between acidity and tetragonal phase fraction in the favorable catalytic act of modified zirconia towards isomerized n-hexane(s). in Optoelectronics and Advanced Materials - Rapid Communications. 2013;7(1-2):62-69.
https://hdl.handle.net/21.15107/rcub_vinar_5369 .
Zarubica, Aleksandra R., Ranđelović, Marjan S., Momčilović, Milan Z., Stojković, Nikola, Vučinić-Vasić, Milica, Radulovic, N., "The balance between acidity and tetragonal phase fraction in the favorable catalytic act of modified zirconia towards isomerized n-hexane(s)" in Optoelectronics and Advanced Materials - Rapid Communications, 7, no. 1-2 (2013):62-69,
https://hdl.handle.net/21.15107/rcub_vinar_5369 .