Bratić, Milan

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  • Bratić, Milan (1)
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Insertion of lithium ion in anatase TiO2 nanotube arrays of different morphology

Bratić, Milan; Jugović, Dragana; Mitrić, Miodrag; Cvjetićanin, Nikola

(2017)

TY  - JOUR
AU  - Bratić, Milan
AU  - Jugović, Dragana
AU  - Mitrić, Miodrag
AU  - Cvjetićanin, Nikola
PY  - 2017
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/1585
AB  - Anatase TiO2 nanotube arrays of different morphology were prepared by a two-step process: anodic oxidation at voltages 20-60 V and subsequent annealing at 400 degrees C. By amplifying anodization voltage the inner diameter of nanotubes increased. At 60 V nanotubes changed the shape from cylindrical tube to truncated cone with elliptical opening. Electrochemical insertion of Li-ion in nanotubes was studied by cyclic voltammetry and galvanostatic charge-discharge experiments. The cyclovoltammetric response was fast for all nanotube arrays. The galvanostatic areal charge/discharge capacity of nanotube arrays increased with increasing anodizaton voltage. Although the mass of nanotubes prepared at 45 V was larger, the gravimetrical capacity was much higher for nanotubes prepared at 60 V because of the larger surface area exposed to the electrolyte. Gravimetrical capacity values exceed theoretical bulk capacity of anatase due to the surface storage of Li-ion. Diffusion coefficient of Li-ion was calculated to be between 5.9.10(-16) and 5.9.10(-15) cm(2) s(-1). (C) 2017 Elsevier B.V. All rights reserved.
T2  - Journal of Alloys and Compounds
T1  - Insertion of lithium ion in anatase TiO2 nanotube arrays of different morphology
VL  - 712
SP  - 90
EP  - 96
DO  - 10.1016/j.jallcom.2017.04.065
ER  - 
@article{
author = "Bratić, Milan and Jugović, Dragana and Mitrić, Miodrag and Cvjetićanin, Nikola",
year = "2017",
abstract = "Anatase TiO2 nanotube arrays of different morphology were prepared by a two-step process: anodic oxidation at voltages 20-60 V and subsequent annealing at 400 degrees C. By amplifying anodization voltage the inner diameter of nanotubes increased. At 60 V nanotubes changed the shape from cylindrical tube to truncated cone with elliptical opening. Electrochemical insertion of Li-ion in nanotubes was studied by cyclic voltammetry and galvanostatic charge-discharge experiments. The cyclovoltammetric response was fast for all nanotube arrays. The galvanostatic areal charge/discharge capacity of nanotube arrays increased with increasing anodizaton voltage. Although the mass of nanotubes prepared at 45 V was larger, the gravimetrical capacity was much higher for nanotubes prepared at 60 V because of the larger surface area exposed to the electrolyte. Gravimetrical capacity values exceed theoretical bulk capacity of anatase due to the surface storage of Li-ion. Diffusion coefficient of Li-ion was calculated to be between 5.9.10(-16) and 5.9.10(-15) cm(2) s(-1). (C) 2017 Elsevier B.V. All rights reserved.",
journal = "Journal of Alloys and Compounds",
title = "Insertion of lithium ion in anatase TiO2 nanotube arrays of different morphology",
volume = "712",
pages = "90-96",
doi = "10.1016/j.jallcom.2017.04.065"
}
Bratić, M., Jugović, D., Mitrić, M.,& Cvjetićanin, N.. (2017). Insertion of lithium ion in anatase TiO2 nanotube arrays of different morphology. in Journal of Alloys and Compounds, 712, 90-96.
https://doi.org/10.1016/j.jallcom.2017.04.065
Bratić M, Jugović D, Mitrić M, Cvjetićanin N. Insertion of lithium ion in anatase TiO2 nanotube arrays of different morphology. in Journal of Alloys and Compounds. 2017;712:90-96.
doi:10.1016/j.jallcom.2017.04.065 .
Bratić, Milan, Jugović, Dragana, Mitrić, Miodrag, Cvjetićanin, Nikola, "Insertion of lithium ion in anatase TiO2 nanotube arrays of different morphology" in Journal of Alloys and Compounds, 712 (2017):90-96,
https://doi.org/10.1016/j.jallcom.2017.04.065 . .
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