Žunić, Milan

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orcid::0000-0002-0416-805X
  • Žunić, Milan (9)
  • Zunic, M. (4)
Projects

Author's Bibliography

Application of a new system of solid ionic conductors based on multi-doped ceria as electrolytes for it-sofc technology- test in a single cell

Nišić, Neda; Kragović, Milan; Žunić, Milan; Gulicovski, Jelena; Vasić, Andrijana; Kandić, Irina; Stojmenović, Marija

(Belgrade : University of Belgrade : Faculty of Mining and Geology, 2023)

TY  - CONF
AU  - Nišić, Neda
AU  - Kragović, Milan
AU  - Žunić, Milan
AU  - Gulicovski, Jelena
AU  - Vasić, Andrijana
AU  - Kandić, Irina
AU  - Stojmenović, Marija
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/11996
AB  - Nanopowders of CeO2 as a major component and different rare earth oxides added as dopants were synthesized using the modified glycine-nitrate procedure (MGNP) for the purpose of fabrication of electrolytes for IT-SOFC. Synthesized nanopowder was characterized by XRPD and Raman spectroscopy. According to results, single phase solid solution of fluorite structure were evidenced. Produced powder was then subjected to sintering at 1550 ºC for 2 h in air. By SEM analysis, highly ordered microstructure of sintered sample was verified, while EDS method revealed that the sintered sample have chemical composition very similar to a nominal one. Afterwards, the ionic conductivity of the sintered sample was measured by EIS method. The highest value was obtained at 700 ºC, amounting to 1.92×10-1 Ω-1 cm-1 .
PB  - Belgrade : University of Belgrade : Faculty of Mining and Geology
C3  - MEP-23 : 9th International Conference Mining and Environmental Protection : Proceedings book
T1  - Application of a new system of solid ionic conductors based on multi-doped ceria as electrolytes for it-sofc technology- test in a single cell
SP  - 316
EP  - 320
UR  - https://hdl.handle.net/21.15107/rcub_vinar_11996
ER  - 
@conference{
author = "Nišić, Neda and Kragović, Milan and Žunić, Milan and Gulicovski, Jelena and Vasić, Andrijana and Kandić, Irina and Stojmenović, Marija",
year = "2023",
abstract = "Nanopowders of CeO2 as a major component and different rare earth oxides added as dopants were synthesized using the modified glycine-nitrate procedure (MGNP) for the purpose of fabrication of electrolytes for IT-SOFC. Synthesized nanopowder was characterized by XRPD and Raman spectroscopy. According to results, single phase solid solution of fluorite structure were evidenced. Produced powder was then subjected to sintering at 1550 ºC for 2 h in air. By SEM analysis, highly ordered microstructure of sintered sample was verified, while EDS method revealed that the sintered sample have chemical composition very similar to a nominal one. Afterwards, the ionic conductivity of the sintered sample was measured by EIS method. The highest value was obtained at 700 ºC, amounting to 1.92×10-1 Ω-1 cm-1 .",
publisher = "Belgrade : University of Belgrade : Faculty of Mining and Geology",
journal = "MEP-23 : 9th International Conference Mining and Environmental Protection : Proceedings book",
title = "Application of a new system of solid ionic conductors based on multi-doped ceria as electrolytes for it-sofc technology- test in a single cell",
pages = "316-320",
url = "https://hdl.handle.net/21.15107/rcub_vinar_11996"
}
Nišić, N., Kragović, M., Žunić, M., Gulicovski, J., Vasić, A., Kandić, I.,& Stojmenović, M.. (2023). Application of a new system of solid ionic conductors based on multi-doped ceria as electrolytes for it-sofc technology- test in a single cell. in MEP-23 : 9th International Conference Mining and Environmental Protection : Proceedings book
Belgrade : University of Belgrade : Faculty of Mining and Geology., 316-320.
https://hdl.handle.net/21.15107/rcub_vinar_11996
Nišić N, Kragović M, Žunić M, Gulicovski J, Vasić A, Kandić I, Stojmenović M. Application of a new system of solid ionic conductors based on multi-doped ceria as electrolytes for it-sofc technology- test in a single cell. in MEP-23 : 9th International Conference Mining and Environmental Protection : Proceedings book. 2023;:316-320.
https://hdl.handle.net/21.15107/rcub_vinar_11996 .
Nišić, Neda, Kragović, Milan, Žunić, Milan, Gulicovski, Jelena, Vasić, Andrijana, Kandić, Irina, Stojmenović, Marija, "Application of a new system of solid ionic conductors based on multi-doped ceria as electrolytes for it-sofc technology- test in a single cell" in MEP-23 : 9th International Conference Mining and Environmental Protection : Proceedings book (2023):316-320,
https://hdl.handle.net/21.15107/rcub_vinar_11996 .

Characterization of innovative high-temperature resistant adhesives with addition of aluminosilicate waste

Nišić, Neda; Kragović, Milan; Gulicovski, Jelena; Nikolić, Katarina; Vasić, Andrijana; Žunić, Milan; Stojmenović, Marija

(Belgrade : University of Belgrade : Faculty of Mining and Geology, 2023)

TY  - CONF
AU  - Nišić, Neda
AU  - Kragović, Milan
AU  - Gulicovski, Jelena
AU  - Nikolić, Katarina
AU  - Vasić, Andrijana
AU  - Žunić, Milan
AU  - Stojmenović, Marija
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/11997
AB  - In the present paper, possible application of novel ceramic adhesives with implementation of waste sludge for bonding of heating devices constructions was studied. For a comparison, five different samples with increasing waste addition percentage were prepared and their performance as heat-resistant adhesives were evaluated in terms of chemical and thermostability as well as ecological safety. Based on ICP-OES analysis it was observed that only sample GC20 is not ecologically-safe due to high level of Cu+ concentration. By withstanding thermal treatment in the range of 200-800˚C for over 100h, all adhesive samples showed satisfactory thermostability. This research confirms the great potential of the studied materials for application as uncostly and eco-friendly adhesives for industrial purpose.
PB  - Belgrade : University of Belgrade : Faculty of Mining and Geology
C3  - MEP-23 : 9th International Conference Mining and Environmental Protection : Proceedings book
T1  - Characterization of innovative high-temperature resistant adhesives with addition of aluminosilicate waste
SP  - 312
EP  - 315
UR  - https://hdl.handle.net/21.15107/rcub_vinar_11997
ER  - 
@conference{
author = "Nišić, Neda and Kragović, Milan and Gulicovski, Jelena and Nikolić, Katarina and Vasić, Andrijana and Žunić, Milan and Stojmenović, Marija",
year = "2023",
abstract = "In the present paper, possible application of novel ceramic adhesives with implementation of waste sludge for bonding of heating devices constructions was studied. For a comparison, five different samples with increasing waste addition percentage were prepared and their performance as heat-resistant adhesives were evaluated in terms of chemical and thermostability as well as ecological safety. Based on ICP-OES analysis it was observed that only sample GC20 is not ecologically-safe due to high level of Cu+ concentration. By withstanding thermal treatment in the range of 200-800˚C for over 100h, all adhesive samples showed satisfactory thermostability. This research confirms the great potential of the studied materials for application as uncostly and eco-friendly adhesives for industrial purpose.",
publisher = "Belgrade : University of Belgrade : Faculty of Mining and Geology",
journal = "MEP-23 : 9th International Conference Mining and Environmental Protection : Proceedings book",
title = "Characterization of innovative high-temperature resistant adhesives with addition of aluminosilicate waste",
pages = "312-315",
url = "https://hdl.handle.net/21.15107/rcub_vinar_11997"
}
Nišić, N., Kragović, M., Gulicovski, J., Nikolić, K., Vasić, A., Žunić, M.,& Stojmenović, M.. (2023). Characterization of innovative high-temperature resistant adhesives with addition of aluminosilicate waste. in MEP-23 : 9th International Conference Mining and Environmental Protection : Proceedings book
Belgrade : University of Belgrade : Faculty of Mining and Geology., 312-315.
https://hdl.handle.net/21.15107/rcub_vinar_11997
Nišić N, Kragović M, Gulicovski J, Nikolić K, Vasić A, Žunić M, Stojmenović M. Characterization of innovative high-temperature resistant adhesives with addition of aluminosilicate waste. in MEP-23 : 9th International Conference Mining and Environmental Protection : Proceedings book. 2023;:312-315.
https://hdl.handle.net/21.15107/rcub_vinar_11997 .
Nišić, Neda, Kragović, Milan, Gulicovski, Jelena, Nikolić, Katarina, Vasić, Andrijana, Žunić, Milan, Stojmenović, Marija, "Characterization of innovative high-temperature resistant adhesives with addition of aluminosilicate waste" in MEP-23 : 9th International Conference Mining and Environmental Protection : Proceedings book (2023):312-315,
https://hdl.handle.net/21.15107/rcub_vinar_11997 .

The Incorporation of Waste Sludge into the Production of High-Temperature-Resistant Adhesive Ceramic Materials

Nišić, Neda; Kragović, Milan; Gulicovski, Jelena; Žunić, Milan; Basoli, Francesco; Gordić, Milan; Stojmenović, Marija

(2023)

TY  - JOUR
AU  - Nišić, Neda
AU  - Kragović, Milan
AU  - Gulicovski, Jelena
AU  - Žunić, Milan
AU  - Basoli, Francesco
AU  - Gordić, Milan
AU  - Stojmenović, Marija
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/11455
AB  - In recent years, the interest of the scientific community has become focused on the integration of circular economy principles by eliminating end-of-life concepts and forming zero-waste strategies. The present paper suggests the possible application of innovative, eco-friendly, cost-effective, and highly efficient ceramic materials with the partial implementation of aluminosilicate-based waste in the form of wastewater sludge in advanced technology solutions. The specific objective was to demonstrate the effective utilization of the investigated waste in the production of refractory adhesives and/or sealants for Intermediate-Temperature Solid-Oxide Fuel Cells (IT-SOFCs). Different physical–mechanical and chemical properties were determined along with the performance of leaching tests, the thermal cycling procedure, and leakage tests in a single cell. Based on the maintenance of mechanical integrity after thermal cycling and satisfying crystal and microstructural stability after high-temperature treatment, it was concluded that the investigated materials may be considered promising candidates for application as heat-resistant adhesives for connecting components in heating systems. However, they were not found to be applicable as sealants for IT-SOFCs in raw form according to the failure of testing in a single cell. Still, requirements for this purpose could be met after certain modifications of the composition and synthesis methodology, which presents the major initiative for our further research in this field. © 2023 by the authors.
T2  - Applied Sciences (Switzerland)
T1  - The Incorporation of Waste Sludge into the Production of High-Temperature-Resistant Adhesive Ceramic Materials
VL  - 13
IS  - 16
SP  - 9044
DO  - 10.3390/app13169044
ER  - 
@article{
author = "Nišić, Neda and Kragović, Milan and Gulicovski, Jelena and Žunić, Milan and Basoli, Francesco and Gordić, Milan and Stojmenović, Marija",
year = "2023",
abstract = "In recent years, the interest of the scientific community has become focused on the integration of circular economy principles by eliminating end-of-life concepts and forming zero-waste strategies. The present paper suggests the possible application of innovative, eco-friendly, cost-effective, and highly efficient ceramic materials with the partial implementation of aluminosilicate-based waste in the form of wastewater sludge in advanced technology solutions. The specific objective was to demonstrate the effective utilization of the investigated waste in the production of refractory adhesives and/or sealants for Intermediate-Temperature Solid-Oxide Fuel Cells (IT-SOFCs). Different physical–mechanical and chemical properties were determined along with the performance of leaching tests, the thermal cycling procedure, and leakage tests in a single cell. Based on the maintenance of mechanical integrity after thermal cycling and satisfying crystal and microstructural stability after high-temperature treatment, it was concluded that the investigated materials may be considered promising candidates for application as heat-resistant adhesives for connecting components in heating systems. However, they were not found to be applicable as sealants for IT-SOFCs in raw form according to the failure of testing in a single cell. Still, requirements for this purpose could be met after certain modifications of the composition and synthesis methodology, which presents the major initiative for our further research in this field. © 2023 by the authors.",
journal = "Applied Sciences (Switzerland)",
title = "The Incorporation of Waste Sludge into the Production of High-Temperature-Resistant Adhesive Ceramic Materials",
volume = "13",
number = "16",
pages = "9044",
doi = "10.3390/app13169044"
}
Nišić, N., Kragović, M., Gulicovski, J., Žunić, M., Basoli, F., Gordić, M.,& Stojmenović, M.. (2023). The Incorporation of Waste Sludge into the Production of High-Temperature-Resistant Adhesive Ceramic Materials. in Applied Sciences (Switzerland), 13(16), 9044.
https://doi.org/10.3390/app13169044
Nišić N, Kragović M, Gulicovski J, Žunić M, Basoli F, Gordić M, Stojmenović M. The Incorporation of Waste Sludge into the Production of High-Temperature-Resistant Adhesive Ceramic Materials. in Applied Sciences (Switzerland). 2023;13(16):9044.
doi:10.3390/app13169044 .
Nišić, Neda, Kragović, Milan, Gulicovski, Jelena, Žunić, Milan, Basoli, Francesco, Gordić, Milan, Stojmenović, Marija, "The Incorporation of Waste Sludge into the Production of High-Temperature-Resistant Adhesive Ceramic Materials" in Applied Sciences (Switzerland), 13, no. 16 (2023):9044,
https://doi.org/10.3390/app13169044 . .
1

Development of a new system of solid ionic conductors based on multi-doped ceria for application in IT-SOFCs

Stojmenović, Marija; Nišić, Neda; Žunić, Milan; Basoli, Francesco; Gulicovki, Jelena; Ristović, Ivica; Kragović, Milan M.

(2022)

TY  - JOUR
AU  - Stojmenović, Marija
AU  - Nišić, Neda
AU  - Žunić, Milan
AU  - Basoli, Francesco
AU  - Gulicovki, Jelena
AU  - Ristović, Ivica
AU  - Kragović, Milan M.
PY  - 2022
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10622
AB  - Nanosized multi-doped ceria with composition Ce0.8Nd0.0025Sm0.0025Gd0.005Dy0.095Y0.095O2-δ (CNSGDY) as perspective solid ionic conductor was obtained by modified glycine-nitrate procedure (MGNP) and room temperature self-propagating reaction (SPRT). The pressed pellets of both powders were sintered at 1550°C for 2 h in an air atmosphere. The obtained sintered samples were characterized by XRPD, Raman spectroscopy, FESEM, EDS and EIS methods. Despite a high temperature of sintering, XRPD and FESEM analyses of the samples confirmed appropriate dimensions of grains with fluorite structure. Overall concentration of introduced dopants (x = 0.2) in the structure of CeO2 after the sintering process was confirmed by EDS analysis. After sintering, Raman spectroscopy confirmed retention of the oxygen vacancies in the ceria lattice, which is in accordance with the improvement of ionic conductivity of solid ionic conductors. The highest value of total conductivity was obtained for the sintered MGNP sample at 700°C (4.22 × 10−2 S cm−1), with the corresponding activation energy of 0.26 eV.
T2  - Processing and Application of Ceramics
T1  - Development of a new system of solid ionic conductors based on multi-doped ceria for application in IT-SOFCs
VL  - 16
IS  - 4
SP  - 391
EP  - 401
DO  - 10.2298/PAC2204391S
ER  - 
@article{
author = "Stojmenović, Marija and Nišić, Neda and Žunić, Milan and Basoli, Francesco and Gulicovki, Jelena and Ristović, Ivica and Kragović, Milan M.",
year = "2022",
abstract = "Nanosized multi-doped ceria with composition Ce0.8Nd0.0025Sm0.0025Gd0.005Dy0.095Y0.095O2-δ (CNSGDY) as perspective solid ionic conductor was obtained by modified glycine-nitrate procedure (MGNP) and room temperature self-propagating reaction (SPRT). The pressed pellets of both powders were sintered at 1550°C for 2 h in an air atmosphere. The obtained sintered samples were characterized by XRPD, Raman spectroscopy, FESEM, EDS and EIS methods. Despite a high temperature of sintering, XRPD and FESEM analyses of the samples confirmed appropriate dimensions of grains with fluorite structure. Overall concentration of introduced dopants (x = 0.2) in the structure of CeO2 after the sintering process was confirmed by EDS analysis. After sintering, Raman spectroscopy confirmed retention of the oxygen vacancies in the ceria lattice, which is in accordance with the improvement of ionic conductivity of solid ionic conductors. The highest value of total conductivity was obtained for the sintered MGNP sample at 700°C (4.22 × 10−2 S cm−1), with the corresponding activation energy of 0.26 eV.",
journal = "Processing and Application of Ceramics",
title = "Development of a new system of solid ionic conductors based on multi-doped ceria for application in IT-SOFCs",
volume = "16",
number = "4",
pages = "391-401",
doi = "10.2298/PAC2204391S"
}
Stojmenović, M., Nišić, N., Žunić, M., Basoli, F., Gulicovki, J., Ristović, I.,& Kragović, M. M.. (2022). Development of a new system of solid ionic conductors based on multi-doped ceria for application in IT-SOFCs. in Processing and Application of Ceramics, 16(4), 391-401.
https://doi.org/10.2298/PAC2204391S
Stojmenović M, Nišić N, Žunić M, Basoli F, Gulicovki J, Ristović I, Kragović MM. Development of a new system of solid ionic conductors based on multi-doped ceria for application in IT-SOFCs. in Processing and Application of Ceramics. 2022;16(4):391-401.
doi:10.2298/PAC2204391S .
Stojmenović, Marija, Nišić, Neda, Žunić, Milan, Basoli, Francesco, Gulicovki, Jelena, Ristović, Ivica, Kragović, Milan M., "Development of a new system of solid ionic conductors based on multi-doped ceria for application in IT-SOFCs" in Processing and Application of Ceramics, 16, no. 4 (2022):391-401,
https://doi.org/10.2298/PAC2204391S . .
1
1

Novel Glass-Ceramic Sealant With Addition of Alumosilicate-Based Waste Material for Application in IT-SOFC

Nišić, Neda; Gulicovski, Jelena J.; Kragović, Milan; Nedeljković, Andrijana; Žunić, Milan; Rosić, Milena; Stojmenović, Marija

(Belgrade : Serbian Ceramic Society, 2021)

TY  - CONF
AU  - Nišić, Neda
AU  - Gulicovski, Jelena J.
AU  - Kragović, Milan
AU  - Nedeljković, Andrijana
AU  - Žunić, Milan
AU  - Rosić, Milena
AU  - Stojmenović, Marija
PY  - 2021
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10798
AB  - In the present paper, possible application of novel concept synthesis method of glass-ceramic sealant with implementation of alumosilicate-based waste material in intermediate temperature solid oxide fuel cells (IT-SOFC) was investigated. Besides basic components for glass-ceramic sealant (sample GC0), for this purpose four additional sealant compositions with certain waste content, designated as GC1, GC2, GC3, GC4, were prepared for a comparative study. Waste was added in the basic sealant composition in such a way that certain percent of alumosilicate clay was substituted with alumosilicate-based waste material, with proper amount of water as a solvent. Waste share in compositions was 5, 10, 15 and 20% of total amout of alumosilicate clay as a replacement, respectively.A total of five different joint specimens were assembled by placing a sealant paste of 10mm thickness between two bricks to form brick/glass–ceramic/brick sandwich specimens appropriate for further heat treatments. Such formed ‘green’ joints were initially air-dried for 24h at room temperature, which was required for solvent to evaporate and cause initial bonding. Heating cycle in the period of four weeks was carried out in a chamber furnace. First day samples were heated to 200 ̊C for 2 h. Each day heating temperature was raised for 100 °C while dwelling time was prolonged for one hour, so by the end of the first week samples were heated to 600 °C for 6 hours. Next three weeks annealing of the samples was performed at 600 °C for 6 hours, 700 °C for 7 hours and 800 °C for 8 h, respectively, after what the thermal cycle was completed. The heating rate of the furnace at each heating step in the given joining process was 5 °C/min,while cooling was at natural speed. Mentioned firing temperatures were selected in accordance to common operating temperature range of IT-SOFC so as to simulate real working conditions. After the completion of the cycle, it was observed that all variants of the sealant withstood high temperatures without significant cracks or damage. Moreover, after detailed chemical, physical, mechanical and optical properties examination it was determined that compositions remained unaltered, which clearly indicates to their stability and reliability that is required for their application as sealants for IT-SOFC components. In addition, this research shows the possibility of forming a cost-effective, environmentally-friendly and high- efficient sealant for application in IT-SOFC by incorporating waste materials in its composition, without significant negative effects on its performance and main properties.
PB  - Belgrade : Serbian Ceramic Society
C3  - Advanced Ceramics and Application : 9th Serbian Ceramic Society Conference : program and the book of abstracts; September 20-21, 2021; Belgrade
T1  - Novel Glass-Ceramic Sealant With Addition of Alumosilicate-Based Waste Material for Application in IT-SOFC
SP  - 65
EP  - 66
UR  - https://hdl.handle.net/21.15107/rcub_vinar_10798
ER  - 
@conference{
author = "Nišić, Neda and Gulicovski, Jelena J. and Kragović, Milan and Nedeljković, Andrijana and Žunić, Milan and Rosić, Milena and Stojmenović, Marija",
year = "2021",
abstract = "In the present paper, possible application of novel concept synthesis method of glass-ceramic sealant with implementation of alumosilicate-based waste material in intermediate temperature solid oxide fuel cells (IT-SOFC) was investigated. Besides basic components for glass-ceramic sealant (sample GC0), for this purpose four additional sealant compositions with certain waste content, designated as GC1, GC2, GC3, GC4, were prepared for a comparative study. Waste was added in the basic sealant composition in such a way that certain percent of alumosilicate clay was substituted with alumosilicate-based waste material, with proper amount of water as a solvent. Waste share in compositions was 5, 10, 15 and 20% of total amout of alumosilicate clay as a replacement, respectively.A total of five different joint specimens were assembled by placing a sealant paste of 10mm thickness between two bricks to form brick/glass–ceramic/brick sandwich specimens appropriate for further heat treatments. Such formed ‘green’ joints were initially air-dried for 24h at room temperature, which was required for solvent to evaporate and cause initial bonding. Heating cycle in the period of four weeks was carried out in a chamber furnace. First day samples were heated to 200 ̊C for 2 h. Each day heating temperature was raised for 100 °C while dwelling time was prolonged for one hour, so by the end of the first week samples were heated to 600 °C for 6 hours. Next three weeks annealing of the samples was performed at 600 °C for 6 hours, 700 °C for 7 hours and 800 °C for 8 h, respectively, after what the thermal cycle was completed. The heating rate of the furnace at each heating step in the given joining process was 5 °C/min,while cooling was at natural speed. Mentioned firing temperatures were selected in accordance to common operating temperature range of IT-SOFC so as to simulate real working conditions. After the completion of the cycle, it was observed that all variants of the sealant withstood high temperatures without significant cracks or damage. Moreover, after detailed chemical, physical, mechanical and optical properties examination it was determined that compositions remained unaltered, which clearly indicates to their stability and reliability that is required for their application as sealants for IT-SOFC components. In addition, this research shows the possibility of forming a cost-effective, environmentally-friendly and high- efficient sealant for application in IT-SOFC by incorporating waste materials in its composition, without significant negative effects on its performance and main properties.",
publisher = "Belgrade : Serbian Ceramic Society",
journal = "Advanced Ceramics and Application : 9th Serbian Ceramic Society Conference : program and the book of abstracts; September 20-21, 2021; Belgrade",
title = "Novel Glass-Ceramic Sealant With Addition of Alumosilicate-Based Waste Material for Application in IT-SOFC",
pages = "65-66",
url = "https://hdl.handle.net/21.15107/rcub_vinar_10798"
}
Nišić, N., Gulicovski, J. J., Kragović, M., Nedeljković, A., Žunić, M., Rosić, M.,& Stojmenović, M.. (2021). Novel Glass-Ceramic Sealant With Addition of Alumosilicate-Based Waste Material for Application in IT-SOFC. in Advanced Ceramics and Application : 9th Serbian Ceramic Society Conference : program and the book of abstracts; September 20-21, 2021; Belgrade
Belgrade : Serbian Ceramic Society., 65-66.
https://hdl.handle.net/21.15107/rcub_vinar_10798
Nišić N, Gulicovski JJ, Kragović M, Nedeljković A, Žunić M, Rosić M, Stojmenović M. Novel Glass-Ceramic Sealant With Addition of Alumosilicate-Based Waste Material for Application in IT-SOFC. in Advanced Ceramics and Application : 9th Serbian Ceramic Society Conference : program and the book of abstracts; September 20-21, 2021; Belgrade. 2021;:65-66.
https://hdl.handle.net/21.15107/rcub_vinar_10798 .
Nišić, Neda, Gulicovski, Jelena J., Kragović, Milan, Nedeljković, Andrijana, Žunić, Milan, Rosić, Milena, Stojmenović, Marija, "Novel Glass-Ceramic Sealant With Addition of Alumosilicate-Based Waste Material for Application in IT-SOFC" in Advanced Ceramics and Application : 9th Serbian Ceramic Society Conference : program and the book of abstracts; September 20-21, 2021; Belgrade (2021):65-66,
https://hdl.handle.net/21.15107/rcub_vinar_10798 .

Studies on Structural and Morphological Properties of Multidoped Ceria Ce0.8Nd0.0025Sm0.0025Gd0.005Dy0.095Y0.095O2-delta (x=0.2) as Solid Solutions

Stojmenović, Marija; Pagnacco, Maja C.; Dodevski, Vladimir; Gulicovski, Jelena J.; Žunić, Milan; Bošković, Snežana B.

(2016)

TY  - JOUR
AU  - Stojmenović, Marija
AU  - Pagnacco, Maja C.
AU  - Dodevski, Vladimir
AU  - Gulicovski, Jelena J.
AU  - Žunić, Milan
AU  - Bošković, Snežana B.
PY  - 2016
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/1083
AB  - The nanopowdery solid solutions of multidoped ceria Ce0.8Nd0.0025Sm0.0025Gd0.005Dy0.095Y0.095O2 (delta) (x = 0.2) with the fluorite type crystal structure of CeO2 were synthesized for the first time. Two synthesis procedures were applied: the modified glycine-nitrate procedure (MGNP method) and room temperature self-propagating reaction (SPRT method). All nanopowders were characterized by XRPD analysis, Raman spectroscopy, low temperature nitrogen physisorption, TEM, and SEM methods. According to the XRPD and Raman spectroscopy results, single phase solid solutions of fluorite structure were evidenced regardless of the number of dopants and synthesis procedure. Both XRPD and TEM were analyses evidenced nanometer particle dimensions. The SPRT method results in obtaining sample with higher specific surface area, smaller crystallite and particles sizes, and the same values of the lattice parameter in comparison to pure CeO2. Raman spectroscopy was confirmed to the oxygen vacancies introduced into the ceria lattice when Ce4+ ions were replaced with cations (dopants) of lower valence state (3+), which may indicate the potential improvement of ionic conductivity. Additionally, the presence of oxygen vacancies in the lattice ceria, as well as very developed grain boundaries, gives a new possibility for potential application of obtained nanopowders in the area of room temperature ferromagnetism as spintronics.
T2  - Journal of Spectroscopy
T1  - Studies on Structural and Morphological Properties of Multidoped Ceria Ce0.8Nd0.0025Sm0.0025Gd0.005Dy0.095Y0.095O2-delta (x=0.2) as Solid Solutions
SP  - 1
EP  - 9
DO  - 10.1155/2016/5184542
ER  - 
@article{
author = "Stojmenović, Marija and Pagnacco, Maja C. and Dodevski, Vladimir and Gulicovski, Jelena J. and Žunić, Milan and Bošković, Snežana B.",
year = "2016",
abstract = "The nanopowdery solid solutions of multidoped ceria Ce0.8Nd0.0025Sm0.0025Gd0.005Dy0.095Y0.095O2 (delta) (x = 0.2) with the fluorite type crystal structure of CeO2 were synthesized for the first time. Two synthesis procedures were applied: the modified glycine-nitrate procedure (MGNP method) and room temperature self-propagating reaction (SPRT method). All nanopowders were characterized by XRPD analysis, Raman spectroscopy, low temperature nitrogen physisorption, TEM, and SEM methods. According to the XRPD and Raman spectroscopy results, single phase solid solutions of fluorite structure were evidenced regardless of the number of dopants and synthesis procedure. Both XRPD and TEM were analyses evidenced nanometer particle dimensions. The SPRT method results in obtaining sample with higher specific surface area, smaller crystallite and particles sizes, and the same values of the lattice parameter in comparison to pure CeO2. Raman spectroscopy was confirmed to the oxygen vacancies introduced into the ceria lattice when Ce4+ ions were replaced with cations (dopants) of lower valence state (3+), which may indicate the potential improvement of ionic conductivity. Additionally, the presence of oxygen vacancies in the lattice ceria, as well as very developed grain boundaries, gives a new possibility for potential application of obtained nanopowders in the area of room temperature ferromagnetism as spintronics.",
journal = "Journal of Spectroscopy",
title = "Studies on Structural and Morphological Properties of Multidoped Ceria Ce0.8Nd0.0025Sm0.0025Gd0.005Dy0.095Y0.095O2-delta (x=0.2) as Solid Solutions",
pages = "1-9",
doi = "10.1155/2016/5184542"
}
Stojmenović, M., Pagnacco, M. C., Dodevski, V., Gulicovski, J. J., Žunić, M.,& Bošković, S. B.. (2016). Studies on Structural and Morphological Properties of Multidoped Ceria Ce0.8Nd0.0025Sm0.0025Gd0.005Dy0.095Y0.095O2-delta (x=0.2) as Solid Solutions. in Journal of Spectroscopy, 1-9.
https://doi.org/10.1155/2016/5184542
Stojmenović M, Pagnacco MC, Dodevski V, Gulicovski JJ, Žunić M, Bošković SB. Studies on Structural and Morphological Properties of Multidoped Ceria Ce0.8Nd0.0025Sm0.0025Gd0.005Dy0.095Y0.095O2-delta (x=0.2) as Solid Solutions. in Journal of Spectroscopy. 2016;:1-9.
doi:10.1155/2016/5184542 .
Stojmenović, Marija, Pagnacco, Maja C., Dodevski, Vladimir, Gulicovski, Jelena J., Žunić, Milan, Bošković, Snežana B., "Studies on Structural and Morphological Properties of Multidoped Ceria Ce0.8Nd0.0025Sm0.0025Gd0.005Dy0.095Y0.095O2-delta (x=0.2) as Solid Solutions" in Journal of Spectroscopy (2016):1-9,
https://doi.org/10.1155/2016/5184542 . .
5
5
6

Structural, morphological and electrical properties of Ce1-xRuxO2-delta (x=0.005-0.02) solid solutions

Stojmenović, Marija; Žunić, Milan; Gulicovski, Jelena J.; Dodevski, Vladimir; Prekajski, Marija D.; Raduovic, Aleksandar; Mentus, Slavko V.

(2016)

TY  - JOUR
AU  - Stojmenović, Marija
AU  - Žunić, Milan
AU  - Gulicovski, Jelena J.
AU  - Dodevski, Vladimir
AU  - Prekajski, Marija D.
AU  - Raduovic, Aleksandar
AU  - Mentus, Slavko V.
PY  - 2016
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/1185
AB  - Nanoparticles of ceria ruthenium oxide solid solutions with composition Ce1-xRuxO2-delta (X=0.005-0.02) were successfully produced by self propagating room temperature synthesis using reaction between metal nitrates and sodium hydroxide. These compositions were characterized by X-ray powder diffraction (XRD), Raman spectroscopy, specific surface area, transmission electron microscopy (TEM), scanning electron microscopy (SEM) and energy dispersive X-ray spectroscopy (EDX). The experimental measurements were complemented by calculations based on the ion packing model. XRD analysis revealed the presence of single phase solid solutions with CeO2 fluorite structure (regardless of dopants concentration) and Raman spectroscopy confirmed the presence of the RuO2 phase. Electrochemical impedance spectroscopy (EIS) measurements of sintered samples at different temperatures showed that the small ionic radius dopant reduces oxygen vacancies mobility that is responsible for the conductivity of these ceramics. (C) 2016 Elsevier Ltd and Techna Group S.r.l. All rights reserved.
T2  - Ceramics International
T1  - Structural, morphological and electrical properties of Ce1-xRuxO2-delta (x=0.005-0.02) solid solutions
VL  - 42
IS  - 12
SP  - 14011
EP  - 14020
DO  - 10.1016/j.ceramint.2016.06.007
ER  - 
@article{
author = "Stojmenović, Marija and Žunić, Milan and Gulicovski, Jelena J. and Dodevski, Vladimir and Prekajski, Marija D. and Raduovic, Aleksandar and Mentus, Slavko V.",
year = "2016",
abstract = "Nanoparticles of ceria ruthenium oxide solid solutions with composition Ce1-xRuxO2-delta (X=0.005-0.02) were successfully produced by self propagating room temperature synthesis using reaction between metal nitrates and sodium hydroxide. These compositions were characterized by X-ray powder diffraction (XRD), Raman spectroscopy, specific surface area, transmission electron microscopy (TEM), scanning electron microscopy (SEM) and energy dispersive X-ray spectroscopy (EDX). The experimental measurements were complemented by calculations based on the ion packing model. XRD analysis revealed the presence of single phase solid solutions with CeO2 fluorite structure (regardless of dopants concentration) and Raman spectroscopy confirmed the presence of the RuO2 phase. Electrochemical impedance spectroscopy (EIS) measurements of sintered samples at different temperatures showed that the small ionic radius dopant reduces oxygen vacancies mobility that is responsible for the conductivity of these ceramics. (C) 2016 Elsevier Ltd and Techna Group S.r.l. All rights reserved.",
journal = "Ceramics International",
title = "Structural, morphological and electrical properties of Ce1-xRuxO2-delta (x=0.005-0.02) solid solutions",
volume = "42",
number = "12",
pages = "14011-14020",
doi = "10.1016/j.ceramint.2016.06.007"
}
Stojmenović, M., Žunić, M., Gulicovski, J. J., Dodevski, V., Prekajski, M. D., Raduovic, A.,& Mentus, S. V.. (2016). Structural, morphological and electrical properties of Ce1-xRuxO2-delta (x=0.005-0.02) solid solutions. in Ceramics International, 42(12), 14011-14020.
https://doi.org/10.1016/j.ceramint.2016.06.007
Stojmenović M, Žunić M, Gulicovski JJ, Dodevski V, Prekajski MD, Raduovic A, Mentus SV. Structural, morphological and electrical properties of Ce1-xRuxO2-delta (x=0.005-0.02) solid solutions. in Ceramics International. 2016;42(12):14011-14020.
doi:10.1016/j.ceramint.2016.06.007 .
Stojmenović, Marija, Žunić, Milan, Gulicovski, Jelena J., Dodevski, Vladimir, Prekajski, Marija D., Raduovic, Aleksandar, Mentus, Slavko V., "Structural, morphological and electrical properties of Ce1-xRuxO2-delta (x=0.005-0.02) solid solutions" in Ceramics International, 42, no. 12 (2016):14011-14020,
https://doi.org/10.1016/j.ceramint.2016.06.007 . .
8
7
11

Influence of temperature and dopant concentration on structural, morphological and optical properties of nanometric Ce1-xErxO2-delta (x=0.05-0.20) as a pigment

Stojmenović, Marija; Milenković, Maja C.; Banković, Predrag T.; Žunić, Milan; Gulicovski, Jelena J.; Pantić, Jelena R.; Bošković, Snežana B.

(Elsevier, 2015)

TY  - JOUR
AU  - Stojmenović, Marija
AU  - Milenković, Maja C.
AU  - Banković, Predrag T.
AU  - Žunić, Milan
AU  - Gulicovski, Jelena J.
AU  - Pantić, Jelena R.
AU  - Bošković, Snežana B.
PY  - 2015
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/880
AB  - Ceramic pigments based on cerium oxide were synthesized by self-propagating room temperature method and their color properties were assessed from the viewpoint of potential environmentally nontoxic pink pigments. Thermal stabilities of the pigments were examined at 600, 900 and 1200 degrees C. According to X-ray powder diffraction and Raman spectroscopy results, all obtained pigments were singlephase solid solutions of cerium oxide, independent of the concentration of dopants. The X-ray analysis showed that the crystallites were of nanometric dimensions, as recorded and by transmission electron microscopy analysis. Color characteristics of solid solutions, which depended on concentration erbium ions and calcination temperature, and their position in the chromaticity diagram were studied by ultraviolet visible spectrophotometry, which confirmed potential application of environmentally friendly pigments of desired color. The color efficiency of pigments was also evaluated by calorimetric analysis. (C) 2015 Elsevier Ltd. All rights reserved.
PB  - Elsevier
T2  - Dyes and Pigments
T1  - Influence of temperature and dopant concentration on structural, morphological and optical properties of nanometric Ce1-xErxO2-delta (x=0.05-0.20) as a pigment
VL  - 123
SP  - 116
EP  - 124
DO  - 10.1016/j.dyepig.2015.07.030
ER  - 
@article{
author = "Stojmenović, Marija and Milenković, Maja C. and Banković, Predrag T. and Žunić, Milan and Gulicovski, Jelena J. and Pantić, Jelena R. and Bošković, Snežana B.",
year = "2015",
abstract = "Ceramic pigments based on cerium oxide were synthesized by self-propagating room temperature method and their color properties were assessed from the viewpoint of potential environmentally nontoxic pink pigments. Thermal stabilities of the pigments were examined at 600, 900 and 1200 degrees C. According to X-ray powder diffraction and Raman spectroscopy results, all obtained pigments were singlephase solid solutions of cerium oxide, independent of the concentration of dopants. The X-ray analysis showed that the crystallites were of nanometric dimensions, as recorded and by transmission electron microscopy analysis. Color characteristics of solid solutions, which depended on concentration erbium ions and calcination temperature, and their position in the chromaticity diagram were studied by ultraviolet visible spectrophotometry, which confirmed potential application of environmentally friendly pigments of desired color. The color efficiency of pigments was also evaluated by calorimetric analysis. (C) 2015 Elsevier Ltd. All rights reserved.",
publisher = "Elsevier",
journal = "Dyes and Pigments",
title = "Influence of temperature and dopant concentration on structural, morphological and optical properties of nanometric Ce1-xErxO2-delta (x=0.05-0.20) as a pigment",
volume = "123",
pages = "116-124",
doi = "10.1016/j.dyepig.2015.07.030"
}
Stojmenović, M., Milenković, M. C., Banković, P. T., Žunić, M., Gulicovski, J. J., Pantić, J. R.,& Bošković, S. B.. (2015). Influence of temperature and dopant concentration on structural, morphological and optical properties of nanometric Ce1-xErxO2-delta (x=0.05-0.20) as a pigment. in Dyes and Pigments
Elsevier., 123, 116-124.
https://doi.org/10.1016/j.dyepig.2015.07.030
Stojmenović M, Milenković MC, Banković PT, Žunić M, Gulicovski JJ, Pantić JR, Bošković SB. Influence of temperature and dopant concentration on structural, morphological and optical properties of nanometric Ce1-xErxO2-delta (x=0.05-0.20) as a pigment. in Dyes and Pigments. 2015;123:116-124.
doi:10.1016/j.dyepig.2015.07.030 .
Stojmenović, Marija, Milenković, Maja C., Banković, Predrag T., Žunić, Milan, Gulicovski, Jelena J., Pantić, Jelena R., Bošković, Snežana B., "Influence of temperature and dopant concentration on structural, morphological and optical properties of nanometric Ce1-xErxO2-delta (x=0.05-0.20) as a pigment" in Dyes and Pigments, 123 (2015):116-124,
https://doi.org/10.1016/j.dyepig.2015.07.030 . .
11
10
13

Structural, morphological, and electrical properties of doped ceria as a solid electrolyte for intermediate-temperature solid oxide fuel cells

Stojmenović, Marija; Zunic, M.; Gulicovski, Jelena J.; Bajuk-Bogdanović, Danica V.; Holclajtner-Antunović, Ivanka D.; Dodevski, Vladimir; Mentus, Slavko V.

(2015)

TY  - JOUR
AU  - Stojmenović, Marija
AU  - Zunic, M.
AU  - Gulicovski, Jelena J.
AU  - Bajuk-Bogdanović, Danica V.
AU  - Holclajtner-Antunović, Ivanka D.
AU  - Dodevski, Vladimir
AU  - Mentus, Slavko V.
PY  - 2015
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/450
AB  - The solid solutions of CeO2 with one or more rare-earth oxides among Yb2O3, Sm2O3, and Gd2O3 are synthesized by either modified glycine nitrate procedure (MGNP) or self-propagating reaction at room temperature (SPRT). The overall mole fraction of rare-earth oxide dopants was x = 0.2. The characterization was committed by XRPD, TEM, BET, and Raman Spectroscopy methods. According to XRPD and Raman spectroscopy, the obtained products presented the single-phase solid solutions with basic fluorite-type CeO2 structure, regardless on the number and the concentration of dopants. Both XRPD and TEM analysis evidenced the nanometer particle dimensions. The defect model was applied to calculate lattice parameters of single-, co-, and multi-doped solids. The sintering of the sample nanopowders was performed at 1550 A degrees C, in air atmosphere. The sintered samples were characterized by XRPD, SEM, and complex impedance methods. The sintering did not affect the concentration ratios of the constituents. The highest conductivity at 700 A degrees C amounting to 2.14 x 10(-2) and 1.92 x 10(-2) Omega(-1) cm(-1) was measured for the sample Ce0.8Sm0.08Gd0.12O2-delta, synthesized by SPRT and MGNP methods, respectively. The corresponding activation energies of conductivity, measured in the temperature range 500-700 A degrees C, amounted to 0.24 and 0.23 eV.
T2  - Journal of Materials Science
T1  - Structural, morphological, and electrical properties of doped ceria as a solid electrolyte for intermediate-temperature solid oxide fuel cells
VL  - 50
IS  - 10
SP  - 3781
EP  - 3794
DO  - 10.1007/s10853-015-8943-y
ER  - 
@article{
author = "Stojmenović, Marija and Zunic, M. and Gulicovski, Jelena J. and Bajuk-Bogdanović, Danica V. and Holclajtner-Antunović, Ivanka D. and Dodevski, Vladimir and Mentus, Slavko V.",
year = "2015",
abstract = "The solid solutions of CeO2 with one or more rare-earth oxides among Yb2O3, Sm2O3, and Gd2O3 are synthesized by either modified glycine nitrate procedure (MGNP) or self-propagating reaction at room temperature (SPRT). The overall mole fraction of rare-earth oxide dopants was x = 0.2. The characterization was committed by XRPD, TEM, BET, and Raman Spectroscopy methods. According to XRPD and Raman spectroscopy, the obtained products presented the single-phase solid solutions with basic fluorite-type CeO2 structure, regardless on the number and the concentration of dopants. Both XRPD and TEM analysis evidenced the nanometer particle dimensions. The defect model was applied to calculate lattice parameters of single-, co-, and multi-doped solids. The sintering of the sample nanopowders was performed at 1550 A degrees C, in air atmosphere. The sintered samples were characterized by XRPD, SEM, and complex impedance methods. The sintering did not affect the concentration ratios of the constituents. The highest conductivity at 700 A degrees C amounting to 2.14 x 10(-2) and 1.92 x 10(-2) Omega(-1) cm(-1) was measured for the sample Ce0.8Sm0.08Gd0.12O2-delta, synthesized by SPRT and MGNP methods, respectively. The corresponding activation energies of conductivity, measured in the temperature range 500-700 A degrees C, amounted to 0.24 and 0.23 eV.",
journal = "Journal of Materials Science",
title = "Structural, morphological, and electrical properties of doped ceria as a solid electrolyte for intermediate-temperature solid oxide fuel cells",
volume = "50",
number = "10",
pages = "3781-3794",
doi = "10.1007/s10853-015-8943-y"
}
Stojmenović, M., Zunic, M., Gulicovski, J. J., Bajuk-Bogdanović, D. V., Holclajtner-Antunović, I. D., Dodevski, V.,& Mentus, S. V.. (2015). Structural, morphological, and electrical properties of doped ceria as a solid electrolyte for intermediate-temperature solid oxide fuel cells. in Journal of Materials Science, 50(10), 3781-3794.
https://doi.org/10.1007/s10853-015-8943-y
Stojmenović M, Zunic M, Gulicovski JJ, Bajuk-Bogdanović DV, Holclajtner-Antunović ID, Dodevski V, Mentus SV. Structural, morphological, and electrical properties of doped ceria as a solid electrolyte for intermediate-temperature solid oxide fuel cells. in Journal of Materials Science. 2015;50(10):3781-3794.
doi:10.1007/s10853-015-8943-y .
Stojmenović, Marija, Zunic, M., Gulicovski, Jelena J., Bajuk-Bogdanović, Danica V., Holclajtner-Antunović, Ivanka D., Dodevski, Vladimir, Mentus, Slavko V., "Structural, morphological, and electrical properties of doped ceria as a solid electrolyte for intermediate-temperature solid oxide fuel cells" in Journal of Materials Science, 50, no. 10 (2015):3781-3794,
https://doi.org/10.1007/s10853-015-8943-y . .
22
21
28

Studies on structural, morphological and electrical properties of Ce1-xErxO2-delta (x=0.05-0.20) as solid electrolyte for IT - SOFC

Stojmenović, Marija; Bošković, Snežana B.; Zunic, M.; Babić, Biljana M.; Matović, Branko; Bajuk-Bogdanović, Danica V.; Mentus, Slavko V.

(2015)

TY  - JOUR
AU  - Stojmenović, Marija
AU  - Bošković, Snežana B.
AU  - Zunic, M.
AU  - Babić, Biljana M.
AU  - Matović, Branko
AU  - Bajuk-Bogdanović, Danica V.
AU  - Mentus, Slavko V.
PY  - 2015
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/400
AB  - A series of four different powders ceria doped Ce1-xErxO2-delta (0.05 LT = x LT = 0.20) were synthesized by applying self-propagating reaction at room temperature (SPRT method). SPRT procedure is based on the self-propagating room temperature reaction between metal nitrates and sodium hydroxide, wherein the reaction is spontaneous and terminates extremely fast. The method is known to assure very precise stoichiometry of the final product in comparison with a tailored composition. XRPD, Raman spectroscopy, TEM and BET measurements were used to characterize the nanopowders at room temperature. It was shown that all obtained powders were single phase solid solutions with a fluorite-type crystal structure and all powder particles have nanometric size (about 3-4 nm). Densification was performed at 1550 degrees C, in an air atmosphere for 2 h. XRPD, SEM and complex impedance method measurements were carried out on sintered samples. Single phase form was evidenced for each sintered materials. The best value of conductivity at 700 degrees C amounted to 1.10 x 10(-2) Omega(-1) cm(-1) for Ce0.85Er0.O-3(2-delta) sample. Corresponding activation energies of conductivity amounted to 0.28 eV in the temperature range 500-700 degrees C. (C) 2015 Elsevier B.V. All rights reserved.
T2  - Materials Chemistry and Physics
T1  - Studies on structural, morphological and electrical properties of Ce1-xErxO2-delta (x=0.05-0.20) as solid electrolyte for IT - SOFC
VL  - 153
SP  - 422
EP  - 431
DO  - 10.1016/j.matchemphys.2015.01.036
ER  - 
@article{
author = "Stojmenović, Marija and Bošković, Snežana B. and Zunic, M. and Babić, Biljana M. and Matović, Branko and Bajuk-Bogdanović, Danica V. and Mentus, Slavko V.",
year = "2015",
abstract = "A series of four different powders ceria doped Ce1-xErxO2-delta (0.05 LT = x LT = 0.20) were synthesized by applying self-propagating reaction at room temperature (SPRT method). SPRT procedure is based on the self-propagating room temperature reaction between metal nitrates and sodium hydroxide, wherein the reaction is spontaneous and terminates extremely fast. The method is known to assure very precise stoichiometry of the final product in comparison with a tailored composition. XRPD, Raman spectroscopy, TEM and BET measurements were used to characterize the nanopowders at room temperature. It was shown that all obtained powders were single phase solid solutions with a fluorite-type crystal structure and all powder particles have nanometric size (about 3-4 nm). Densification was performed at 1550 degrees C, in an air atmosphere for 2 h. XRPD, SEM and complex impedance method measurements were carried out on sintered samples. Single phase form was evidenced for each sintered materials. The best value of conductivity at 700 degrees C amounted to 1.10 x 10(-2) Omega(-1) cm(-1) for Ce0.85Er0.O-3(2-delta) sample. Corresponding activation energies of conductivity amounted to 0.28 eV in the temperature range 500-700 degrees C. (C) 2015 Elsevier B.V. All rights reserved.",
journal = "Materials Chemistry and Physics",
title = "Studies on structural, morphological and electrical properties of Ce1-xErxO2-delta (x=0.05-0.20) as solid electrolyte for IT - SOFC",
volume = "153",
pages = "422-431",
doi = "10.1016/j.matchemphys.2015.01.036"
}
Stojmenović, M., Bošković, S. B., Zunic, M., Babić, B. M., Matović, B., Bajuk-Bogdanović, D. V.,& Mentus, S. V.. (2015). Studies on structural, morphological and electrical properties of Ce1-xErxO2-delta (x=0.05-0.20) as solid electrolyte for IT - SOFC. in Materials Chemistry and Physics, 153, 422-431.
https://doi.org/10.1016/j.matchemphys.2015.01.036
Stojmenović M, Bošković SB, Zunic M, Babić BM, Matović B, Bajuk-Bogdanović DV, Mentus SV. Studies on structural, morphological and electrical properties of Ce1-xErxO2-delta (x=0.05-0.20) as solid electrolyte for IT - SOFC. in Materials Chemistry and Physics. 2015;153:422-431.
doi:10.1016/j.matchemphys.2015.01.036 .
Stojmenović, Marija, Bošković, Snežana B., Zunic, M., Babić, Biljana M., Matović, Branko, Bajuk-Bogdanović, Danica V., Mentus, Slavko V., "Studies on structural, morphological and electrical properties of Ce1-xErxO2-delta (x=0.05-0.20) as solid electrolyte for IT - SOFC" in Materials Chemistry and Physics, 153 (2015):422-431,
https://doi.org/10.1016/j.matchemphys.2015.01.036 . .
18
19
23

Electrical and microstructural properties of Yb-doped CeO2

Matović, Branko; Stojmenović, Marija; Pantić, Jelena R.; Varela, A.; Žunić, Milan; Jiraborvornpongsa, Noppasint; Yano, Toyohiko

(2014)

TY  - JOUR
AU  - Matović, Branko
AU  - Stojmenović, Marija
AU  - Pantić, Jelena R.
AU  - Varela, A.
AU  - Žunić, Milan
AU  - Jiraborvornpongsa, Noppasint
AU  - Yano, Toyohiko
PY  - 2014
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/9202
AB  - Nanopowdered Ce1−xYbxO2−δ solid solutions (0 ≤ x ≤ 0.2) were synthesized by a self-propagating room temperature synthesis. XRD and SEM were used to study the properties of these materials as well as the Yb solubility in CeO2 lattice. Results showed that all the obtained powders were solid solutions with a fluorite-type crystal structure and with nanometric particle size. The average size of Ce1−xYbxO2−δ particles was approximately 3 nm. Electrochemical impedance spectroscopy for the sintered pellets depicted that it was possible to separate Rbulk and Rgb in the temperature interval of 550–800 °C. The activation energy for the bulk conduction was 1.03 eV and for grain boundary conduction was 1.14 eV. Grain boundary resistivity dominates over the other resistivities. These measurements confirmed that Yb3+-doped CeO2 material had a potential as electrolyte for intermediate-temperature solid oxide fuel cell applications.
T2  - Journal of Asian Ceramic Societies
T1  - Electrical and microstructural properties of Yb-doped CeO2
VL  - 2
IS  - 2
SP  - 117
EP  - 122
DO  - 10.1016/j.jascer.2014.01.008
ER  - 
@article{
author = "Matović, Branko and Stojmenović, Marija and Pantić, Jelena R. and Varela, A. and Žunić, Milan and Jiraborvornpongsa, Noppasint and Yano, Toyohiko",
year = "2014",
abstract = "Nanopowdered Ce1−xYbxO2−δ solid solutions (0 ≤ x ≤ 0.2) were synthesized by a self-propagating room temperature synthesis. XRD and SEM were used to study the properties of these materials as well as the Yb solubility in CeO2 lattice. Results showed that all the obtained powders were solid solutions with a fluorite-type crystal structure and with nanometric particle size. The average size of Ce1−xYbxO2−δ particles was approximately 3 nm. Electrochemical impedance spectroscopy for the sintered pellets depicted that it was possible to separate Rbulk and Rgb in the temperature interval of 550–800 °C. The activation energy for the bulk conduction was 1.03 eV and for grain boundary conduction was 1.14 eV. Grain boundary resistivity dominates over the other resistivities. These measurements confirmed that Yb3+-doped CeO2 material had a potential as electrolyte for intermediate-temperature solid oxide fuel cell applications.",
journal = "Journal of Asian Ceramic Societies",
title = "Electrical and microstructural properties of Yb-doped CeO2",
volume = "2",
number = "2",
pages = "117-122",
doi = "10.1016/j.jascer.2014.01.008"
}
Matović, B., Stojmenović, M., Pantić, J. R., Varela, A., Žunić, M., Jiraborvornpongsa, N.,& Yano, T.. (2014). Electrical and microstructural properties of Yb-doped CeO2. in Journal of Asian Ceramic Societies, 2(2), 117-122.
https://doi.org/10.1016/j.jascer.2014.01.008
Matović B, Stojmenović M, Pantić JR, Varela A, Žunić M, Jiraborvornpongsa N, Yano T. Electrical and microstructural properties of Yb-doped CeO2. in Journal of Asian Ceramic Societies. 2014;2(2):117-122.
doi:10.1016/j.jascer.2014.01.008 .
Matović, Branko, Stojmenović, Marija, Pantić, Jelena R., Varela, A., Žunić, Milan, Jiraborvornpongsa, Noppasint, Yano, Toyohiko, "Electrical and microstructural properties of Yb-doped CeO2" in Journal of Asian Ceramic Societies, 2, no. 2 (2014):117-122,
https://doi.org/10.1016/j.jascer.2014.01.008 . .
27
29

Electrical properties of multidoped ceria

Stojmenović, Marija; Bošković, Snežana B.; Zunic, M.; Varela, J. A.; Prekajski, Marija D.; Matović, Branko; Mentus, Slavko V.

(2014)

TY  - JOUR
AU  - Stojmenović, Marija
AU  - Bošković, Snežana B.
AU  - Zunic, M.
AU  - Varela, J. A.
AU  - Prekajski, Marija D.
AU  - Matović, Branko
AU  - Mentus, Slavko V.
PY  - 2014
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/6029
AB  - Multidoped nanosized ceria powders were prepared by either modified glycine nitrate procedure (MGNP) or self-propagating reaction at room temperature (SPRT). As the dopants to CeO2, trivalent rare earth oxides such as Nd2O3, Sm2O3, Gd2O3, Dy2O3 and Y2O3 were used, with the total molar fraction of 20%. The pressed powder pellets were subjected to the densification by sintering at 1500 degrees C, in an air atmosphere. A single-phase crystalline form was evidenced by X-ray diffractometry for both sintered materials. By means of complex impedance measurements, the conductivity of the sintered samples was determined as a function of temperature. At 700 degrees C, the conductivity amounted to 2.19 x 10(-2) and 1.40 x 10(-2) ohm(-1) cm(-1) for the SPRT and for the MGNP sample, respectively. The corresponding values of activation energies of conductivity amounted to 0.72 (MGNP) and 0.59 (SPRT) eV in the temperature range 550-700 degrees C. (C) 2014 Elsevier Ltd and Techna Group S.r.l. All rights reserved.
T2  - Ceramics International
T1  - Electrical properties of multidoped ceria
VL  - 40
IS  - 7
SP  - 9285
EP  - 9292
DO  - 10.1016/j.ceramint.2014.01.151
ER  - 
@article{
author = "Stojmenović, Marija and Bošković, Snežana B. and Zunic, M. and Varela, J. A. and Prekajski, Marija D. and Matović, Branko and Mentus, Slavko V.",
year = "2014",
abstract = "Multidoped nanosized ceria powders were prepared by either modified glycine nitrate procedure (MGNP) or self-propagating reaction at room temperature (SPRT). As the dopants to CeO2, trivalent rare earth oxides such as Nd2O3, Sm2O3, Gd2O3, Dy2O3 and Y2O3 were used, with the total molar fraction of 20%. The pressed powder pellets were subjected to the densification by sintering at 1500 degrees C, in an air atmosphere. A single-phase crystalline form was evidenced by X-ray diffractometry for both sintered materials. By means of complex impedance measurements, the conductivity of the sintered samples was determined as a function of temperature. At 700 degrees C, the conductivity amounted to 2.19 x 10(-2) and 1.40 x 10(-2) ohm(-1) cm(-1) for the SPRT and for the MGNP sample, respectively. The corresponding values of activation energies of conductivity amounted to 0.72 (MGNP) and 0.59 (SPRT) eV in the temperature range 550-700 degrees C. (C) 2014 Elsevier Ltd and Techna Group S.r.l. All rights reserved.",
journal = "Ceramics International",
title = "Electrical properties of multidoped ceria",
volume = "40",
number = "7",
pages = "9285-9292",
doi = "10.1016/j.ceramint.2014.01.151"
}
Stojmenović, M., Bošković, S. B., Zunic, M., Varela, J. A., Prekajski, M. D., Matović, B.,& Mentus, S. V.. (2014). Electrical properties of multidoped ceria. in Ceramics International, 40(7), 9285-9292.
https://doi.org/10.1016/j.ceramint.2014.01.151
Stojmenović M, Bošković SB, Zunic M, Varela JA, Prekajski MD, Matović B, Mentus SV. Electrical properties of multidoped ceria. in Ceramics International. 2014;40(7):9285-9292.
doi:10.1016/j.ceramint.2014.01.151 .
Stojmenović, Marija, Bošković, Snežana B., Zunic, M., Varela, J. A., Prekajski, Marija D., Matović, Branko, Mentus, Slavko V., "Electrical properties of multidoped ceria" in Ceramics International, 40, no. 7 (2014):9285-9292,
https://doi.org/10.1016/j.ceramint.2014.01.151 . .
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Porous glycidyl methacrylate-bentonite composite

Marinovic, S.; Milutinovic-Nikolic, A.; Zunic, M.; Vuković, Zorica M.; Maksin, Danijela D.; Nastasović, Aleksandra B.; Jovanović, Dragana J.

(2011)

TY  - JOUR
AU  - Marinovic, S.
AU  - Milutinovic-Nikolic, A.
AU  - Zunic, M.
AU  - Vuković, Zorica M.
AU  - Maksin, Danijela D.
AU  - Nastasović, Aleksandra B.
AU  - Jovanović, Dragana J.
PY  - 2011
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/4600
AB  - Crosslinked macroporous copolymer of glycidyl methacrylate and ethylene glycol dimethacrylate (CP) and copolymer composite with acid modified clay (CP-S-A) were prepared by radical suspension copolymerization and functionalized by ring-opening reaction of the pendant epoxy groups with diethylene triamine (CP-deta and CP-S-A-deta). Both S(A)mples were characterized by mercury porosimetry. The influence of pH, sorption time and initial 4-nitrophenol (4-NP) concentration on sorption efficiency of CP-deta and CP-S-A-deta was studied in order to evaluate this material as wastewater sorbent. The isotherm data were best fitted with Langmuir model, while the sorption dynamics obeyed the pseudo-second-order kinetic model.
T2  - Russian Journal of Physical Chemistry A
T1  - Porous glycidyl methacrylate-bentonite composite
VL  - 85
IS  - 13
SP  - 2386
EP  - 2391
DO  - 10.1134/S0036024411130103
ER  - 
@article{
author = "Marinovic, S. and Milutinovic-Nikolic, A. and Zunic, M. and Vuković, Zorica M. and Maksin, Danijela D. and Nastasović, Aleksandra B. and Jovanović, Dragana J.",
year = "2011",
abstract = "Crosslinked macroporous copolymer of glycidyl methacrylate and ethylene glycol dimethacrylate (CP) and copolymer composite with acid modified clay (CP-S-A) were prepared by radical suspension copolymerization and functionalized by ring-opening reaction of the pendant epoxy groups with diethylene triamine (CP-deta and CP-S-A-deta). Both S(A)mples were characterized by mercury porosimetry. The influence of pH, sorption time and initial 4-nitrophenol (4-NP) concentration on sorption efficiency of CP-deta and CP-S-A-deta was studied in order to evaluate this material as wastewater sorbent. The isotherm data were best fitted with Langmuir model, while the sorption dynamics obeyed the pseudo-second-order kinetic model.",
journal = "Russian Journal of Physical Chemistry A",
title = "Porous glycidyl methacrylate-bentonite composite",
volume = "85",
number = "13",
pages = "2386-2391",
doi = "10.1134/S0036024411130103"
}
Marinovic, S., Milutinovic-Nikolic, A., Zunic, M., Vuković, Z. M., Maksin, D. D., Nastasović, A. B.,& Jovanović, D. J.. (2011). Porous glycidyl methacrylate-bentonite composite. in Russian Journal of Physical Chemistry A, 85(13), 2386-2391.
https://doi.org/10.1134/S0036024411130103
Marinovic S, Milutinovic-Nikolic A, Zunic M, Vuković ZM, Maksin DD, Nastasović AB, Jovanović DJ. Porous glycidyl methacrylate-bentonite composite. in Russian Journal of Physical Chemistry A. 2011;85(13):2386-2391.
doi:10.1134/S0036024411130103 .
Marinovic, S., Milutinovic-Nikolic, A., Zunic, M., Vuković, Zorica M., Maksin, Danijela D., Nastasović, Aleksandra B., Jovanović, Dragana J., "Porous glycidyl methacrylate-bentonite composite" in Russian Journal of Physical Chemistry A, 85, no. 13 (2011):2386-2391,
https://doi.org/10.1134/S0036024411130103 . .
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