TY  - JOUR
AU  - Stojisavljević, Predrag N.
AU  - Ivanković, Negovan D.
AU  - Mijin, Dušan Ž.
AU  - Tomašević, Anđelka V.
AU  - Grgur, Branimir N.
AU  - Samolov, Aleksandra D.
AU  - Stupar, Stevan Lj.
PY  - 2022
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/11789
AB  - The study's primary goal is to determine carbamate pesticide methomyl's kinetic parameters and degradation efficiency from water solution by direct electrochemical oxidation using IrOX anode. Also, define the dependence of the efficiency of methomyl decomposition by direct electrochemical oxidation on the initial concentration of pesticide and electrolyte, applied current, and pH value. The results of methomyl degradation by direct electrochemical oxidation obey the pseudo-first kinetic order. Ultraviolet-visible (UV-Vis) spectroscopy followed the methomyl concentration during the study. The degradation products were studied using the Fourier transform infrared (FT-IR) spectroscopy. Also, this study determines the energy consumption and optimal initial conditions. The phytotoxicity of pesticide and degradation products was studied using mung beans.
T2  - International Journal of Electrochemical Science
T1  - Direct Electrochemical Degradation of Carbamate Pesticide Methomyl Using IrOX Anode
VL  - 17
SP  - 220757
DO  - 10.20964/2022.07.56
ER  - 

@article{
author = "Stojisavljević, Predrag N. and Ivanković, Negovan D. and Mijin, Dušan Ž. and Tomašević, Anđelka V. and Grgur, Branimir N. and Samolov, Aleksandra D. and Stupar, Stevan Lj.",
year = "2022",
abstract = "The study's primary goal is to determine carbamate pesticide methomyl's kinetic parameters and degradation efficiency from water solution by direct electrochemical oxidation using IrOX anode. Also, define the dependence of the efficiency of methomyl decomposition by direct electrochemical oxidation on the initial concentration of pesticide and electrolyte, applied current, and pH value. The results of methomyl degradation by direct electrochemical oxidation obey the pseudo-first kinetic order. Ultraviolet-visible (UV-Vis) spectroscopy followed the methomyl concentration during the study. The degradation products were studied using the Fourier transform infrared (FT-IR) spectroscopy. Also, this study determines the energy consumption and optimal initial conditions. The phytotoxicity of pesticide and degradation products was studied using mung beans.",
journal = "International Journal of Electrochemical Science",
title = "Direct Electrochemical Degradation of Carbamate Pesticide Methomyl Using IrOX Anode",
volume = "17",
pages = "220757",
doi = "10.20964/2022.07.56"
}

Stojisavljević, P. N., Ivanković, N. D., Mijin, D. Ž., Tomašević, A. V., Grgur, B. N., Samolov, A. D.,& Stupar, S. Lj.. (2022). Direct Electrochemical Degradation of Carbamate Pesticide Methomyl Using IrOX Anode. in International Journal of Electrochemical Science, 17, 220757.
https://doi.org/10.20964/2022.07.56

Stojisavljević PN, Ivanković ND, Mijin DŽ, Tomašević AV, Grgur BN, Samolov AD, Stupar SL. Direct Electrochemical Degradation of Carbamate Pesticide Methomyl Using IrOX Anode. in International Journal of Electrochemical Science. 2022;17:220757.
doi:10.20964/2022.07.56 .

Stojisavljević, Predrag N., Ivanković, Negovan D., Mijin, Dušan Ž., Tomašević, Anđelka V., Grgur, Branimir N., Samolov, Aleksandra D., Stupar, Stevan Lj., "Direct Electrochemical Degradation of Carbamate Pesticide Methomyl Using IrOX Anode" in International Journal of Electrochemical Science, 17 (2022):220757,
https://doi.org/10.20964/2022.07.56 . .

TY  - JOUR
AU  - Stupar, Stevan Lj.
AU  - Grgur, Branimir N.
AU  - Onjia, Antonije E.
AU  - Mijin, Dušan Ž.
PY  - 2017
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/1774
AB  - The anthraquinone dye, C.I. Acid Blue 111, was subjected to electrochemical oxidation using an IrOx electrode and sodium sulphate or sodium chloride as electrolytes. The effects of different operating parameters on the rate of dye decolorization, such as applied current, electrolyte concentration, and initial pH were studied. The dye concentration during the study was followed via ultraviolet-visible spectroscopy. The changes in the dye molecule during electrochemical oxidation were analyzed by Fourier Transformation-infrared spectroscopy. The level of mineralization after electrochemical oxidation was established by total organic carbon analysis.
T2  - International Journal of Electrochemical Science
T1  - Direct and Indirect Electrochemical Degradation of Acid Blue 111 Using IrOx Anode
VL  - 12
IS  - 9
SP  - 8564
EP  - 8577
DO  - 10.20964/2017.09.44
ER  - 

@article{
author = "Stupar, Stevan Lj. and Grgur, Branimir N. and Onjia, Antonije E. and Mijin, Dušan Ž.",
year = "2017",
abstract = "The anthraquinone dye, C.I. Acid Blue 111, was subjected to electrochemical oxidation using an IrOx electrode and sodium sulphate or sodium chloride as electrolytes. The effects of different operating parameters on the rate of dye decolorization, such as applied current, electrolyte concentration, and initial pH were studied. The dye concentration during the study was followed via ultraviolet-visible spectroscopy. The changes in the dye molecule during electrochemical oxidation were analyzed by Fourier Transformation-infrared spectroscopy. The level of mineralization after electrochemical oxidation was established by total organic carbon analysis.",
journal = "International Journal of Electrochemical Science",
title = "Direct and Indirect Electrochemical Degradation of Acid Blue 111 Using IrOx Anode",
volume = "12",
number = "9",
pages = "8564-8577",
doi = "10.20964/2017.09.44"
}

Stupar, S. Lj., Grgur, B. N., Onjia, A. E.,& Mijin, D. Ž.. (2017). Direct and Indirect Electrochemical Degradation of Acid Blue 111 Using IrOx Anode. in International Journal of Electrochemical Science, 12(9), 8564-8577.
https://doi.org/10.20964/2017.09.44

Stupar SL, Grgur BN, Onjia AE, Mijin DŽ. Direct and Indirect Electrochemical Degradation of Acid Blue 111 Using IrOx Anode. in International Journal of Electrochemical Science. 2017;12(9):8564-8577.
doi:10.20964/2017.09.44 .

Stupar, Stevan Lj., Grgur, Branimir N., Onjia, Antonije E., Mijin, Dušan Ž., "Direct and Indirect Electrochemical Degradation of Acid Blue 111 Using IrOx Anode" in International Journal of Electrochemical Science, 12, no. 9 (2017):8564-8577,
https://doi.org/10.20964/2017.09.44 . .

TY  - JOUR
AU  - Sredojević, Dušan
AU  - Kovač, Tijana S.
AU  - Džunuzović, Enis S.
AU  - Đorđević, Vesna R.
AU  - Grgur, Branimir N.
AU  - Nedeljković, Jovan
PY  - 2017
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/1724
AB  - The charge transfer complex formation between TiO2 powder and variety of phenol derivatives (phenol, 4-nitrophenol, 4-bromophenol, 4-tert-butylphenol, hydroquinone) was achieved. The red-shift of optical absorption was observed upon surface modification of TiO2 powders with phenol derivatives. The influence of substituent functional groups in para position on the optical band gap and conduction band edge of inorganic/organic hybrids was studied using reflection spectroscopy and cyclic voltammetry. The experimental findings were supported by density functional theory calculations. The measured reflection spectra of surface-modified TiO2 powders with phenol derivatives were compared with calculated electronic excitation spectra of corresponding model systems. (C) 2017 Elsevier B.V. All rights reserved.
T2  - Chemical Physics Letters
T1  - Surface-modified TiO2 powders with phenol derivatives: A comparative DFT and experimental study
VL  - 686
SP  - 167
EP  - 172
DO  - 10.1016/j.cplett.2017.08.023
ER  - 

@article{
author = "Sredojević, Dušan and Kovač, Tijana S. and Džunuzović, Enis S. and Đorđević, Vesna R. and Grgur, Branimir N. and Nedeljković, Jovan",
year = "2017",
abstract = "The charge transfer complex formation between TiO2 powder and variety of phenol derivatives (phenol, 4-nitrophenol, 4-bromophenol, 4-tert-butylphenol, hydroquinone) was achieved. The red-shift of optical absorption was observed upon surface modification of TiO2 powders with phenol derivatives. The influence of substituent functional groups in para position on the optical band gap and conduction band edge of inorganic/organic hybrids was studied using reflection spectroscopy and cyclic voltammetry. The experimental findings were supported by density functional theory calculations. The measured reflection spectra of surface-modified TiO2 powders with phenol derivatives were compared with calculated electronic excitation spectra of corresponding model systems. (C) 2017 Elsevier B.V. All rights reserved.",
journal = "Chemical Physics Letters",
title = "Surface-modified TiO2 powders with phenol derivatives: A comparative DFT and experimental study",
volume = "686",
pages = "167-172",
doi = "10.1016/j.cplett.2017.08.023"
}

Sredojević, D., Kovač, T. S., Džunuzović, E. S., Đorđević, V. R., Grgur, B. N.,& Nedeljković, J.. (2017). Surface-modified TiO2 powders with phenol derivatives: A comparative DFT and experimental study. in Chemical Physics Letters, 686, 167-172.
https://doi.org/10.1016/j.cplett.2017.08.023

Sredojević D, Kovač TS, Džunuzović ES, Đorđević VR, Grgur BN, Nedeljković J. Surface-modified TiO2 powders with phenol derivatives: A comparative DFT and experimental study. in Chemical Physics Letters. 2017;686:167-172.
doi:10.1016/j.cplett.2017.08.023 .

Sredojević, Dušan, Kovač, Tijana S., Džunuzović, Enis S., Đorđević, Vesna R., Grgur, Branimir N., Nedeljković, Jovan, "Surface-modified TiO2 powders with phenol derivatives: A comparative DFT and experimental study" in Chemical Physics Letters, 686 (2017):167-172,
https://doi.org/10.1016/j.cplett.2017.08.023 . .

TY  - JOUR
AU  - Tomković, Tanja
AU  - Radovanović, Filip
AU  - Grgur, Branimir
AU  - Nastasović, Aleksandra B.
AU  - Vasiljević-Radović, Dana
AU  - Onjia, Antonije E.
PY  - 2016
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/1080
AB  - A novel method combining a traditional immersion precipitation process for making membranes with photopolymerization and crosslinking of functional monomers included in the casting solution was used to prepare asymmetric polyethersulfone membranes with submicron particles incorporating glycidyl methacrylate copolymer. In order to introduce sulfonic groups, the epoxide rings of glycidyl methacrylate were opened using two methods. The first method was functionalization with sodium sulfite, and the second was functionalization with sulfuric acid and then grafting with 2-acrylamido-2-methylpropanesulfonic acid. The obtained membranes were characterized using infrared spectroscopy, conductometric titration and water permeability measurements. Scanning electron microscopy and atomic force microscopy were used to investigate the surface morphology and topology of the membranes. Dynamic adsorption of rhodamine B as a model dye was used to demonstrate the suitability of these novel membranes for membrane adsorption since the adsorption capacity for dye cations was much better for the membranes functionalized with sodium sulfite and the membranes grafted with 2-acrylamido-2-methylpropanesulfonic acid compared to the non-functionalized membranes.
T2  - Journal of the Serbian Chemical Society
T1  - Novel negatively charged membrane adsorbers made using a combination of photopolymerization and immersion precipitation
VL  - 81
IS  - 4
SP  - 419
EP  - 431
DO  - 10.2298/JSC150805083T
ER  - 

@article{
author = "Tomković, Tanja and Radovanović, Filip and Grgur, Branimir and Nastasović, Aleksandra B. and Vasiljević-Radović, Dana and Onjia, Antonije E.",
year = "2016",
abstract = "A novel method combining a traditional immersion precipitation process for making membranes with photopolymerization and crosslinking of functional monomers included in the casting solution was used to prepare asymmetric polyethersulfone membranes with submicron particles incorporating glycidyl methacrylate copolymer. In order to introduce sulfonic groups, the epoxide rings of glycidyl methacrylate were opened using two methods. The first method was functionalization with sodium sulfite, and the second was functionalization with sulfuric acid and then grafting with 2-acrylamido-2-methylpropanesulfonic acid. The obtained membranes were characterized using infrared spectroscopy, conductometric titration and water permeability measurements. Scanning electron microscopy and atomic force microscopy were used to investigate the surface morphology and topology of the membranes. Dynamic adsorption of rhodamine B as a model dye was used to demonstrate the suitability of these novel membranes for membrane adsorption since the adsorption capacity for dye cations was much better for the membranes functionalized with sodium sulfite and the membranes grafted with 2-acrylamido-2-methylpropanesulfonic acid compared to the non-functionalized membranes.",
journal = "Journal of the Serbian Chemical Society",
title = "Novel negatively charged membrane adsorbers made using a combination of photopolymerization and immersion precipitation",
volume = "81",
number = "4",
pages = "419-431",
doi = "10.2298/JSC150805083T"
}

Tomković, T., Radovanović, F., Grgur, B., Nastasović, A. B., Vasiljević-Radović, D.,& Onjia, A. E.. (2016). Novel negatively charged membrane adsorbers made using a combination of photopolymerization and immersion precipitation. in Journal of the Serbian Chemical Society, 81(4), 419-431.
https://doi.org/10.2298/JSC150805083T

Tomković T, Radovanović F, Grgur B, Nastasović AB, Vasiljević-Radović D, Onjia AE. Novel negatively charged membrane adsorbers made using a combination of photopolymerization and immersion precipitation. in Journal of the Serbian Chemical Society. 2016;81(4):419-431.
doi:10.2298/JSC150805083T .

Tomković, Tanja, Radovanović, Filip, Grgur, Branimir, Nastasović, Aleksandra B., Vasiljević-Radović, Dana, Onjia, Antonije E., "Novel negatively charged membrane adsorbers made using a combination of photopolymerization and immersion precipitation" in Journal of the Serbian Chemical Society, 81, no. 4 (2016):419-431,
https://doi.org/10.2298/JSC150805083T . .

TY  - JOUR
AU  - Radoman, Tijana S.
AU  - Džunuzović, Jasna V.
AU  - Grgur, Branimir N.
AU  - Gvozdenovic, Milica M.
AU  - Jugović, Branimir Z.
AU  - Miličević, Dejan S.
AU  - Džunuzović, Enis S.
PY  - 2016
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/1223
AB  - Novel TiO2-PANI core-shell nanocomposite, prepared by in situ oxidative polymerization of aniline in the presence of TiO2 nanoparticles surface modified with vitamin B6, was used to reinforce epoxy resin. The size of prepared TiO2 nanoparticles and TiO2-PANI nanocomposite were determined by a transmission electron microscopy (TEM). The surface modification of TiO2 nanoparticles was confirmed by FTIR and UV-vis spectroscopy, while the morphology of PANI and TiO2-PANI nanocomposite was investigated by scanning electron microscopy (SEM). The influence of TiO2-PANI nanocomposite on glass transition temperature, dielectric and dynamic mechanical properties, thermooxidative stability, mechanical and anticorrosion properties of epoxy based nanocomposites was investigated and compared to the properties of epoxy/PANI nanocomposites. It has been observed that the glass transition temperature of epoxy resin increases after introduction of PANI and TiO2-PANI nanocomposite, as well as with increasing their content. Prepared nanocomposites exhibited higher value of dielectric constant than pure epoxy resin. Epoxy based coating containing TiO2-PANI nanocomposite showed lower dielectric loss, higher hardness and better anticorrosion properties than pure epoxy resin and epoxy/PANI nanocomposite. (C) 2016 Elsevier B.V. All rights reserved.
T2  - Progress in Organic Coatings
T1  - Improvement of the epoxy coating properties by incorporation of polyaniline surface treated TiO2 nanoparticles previously modified with vitamin B6
VL  - 99
SP  - 346
EP  - 355
DO  - 10.1016/j.porgcoat.2016.06.014
ER  - 

@article{
author = "Radoman, Tijana S. and Džunuzović, Jasna V. and Grgur, Branimir N. and Gvozdenovic, Milica M. and Jugović, Branimir Z. and Miličević, Dejan S. and Džunuzović, Enis S.",
year = "2016",
abstract = "Novel TiO2-PANI core-shell nanocomposite, prepared by in situ oxidative polymerization of aniline in the presence of TiO2 nanoparticles surface modified with vitamin B6, was used to reinforce epoxy resin. The size of prepared TiO2 nanoparticles and TiO2-PANI nanocomposite were determined by a transmission electron microscopy (TEM). The surface modification of TiO2 nanoparticles was confirmed by FTIR and UV-vis spectroscopy, while the morphology of PANI and TiO2-PANI nanocomposite was investigated by scanning electron microscopy (SEM). The influence of TiO2-PANI nanocomposite on glass transition temperature, dielectric and dynamic mechanical properties, thermooxidative stability, mechanical and anticorrosion properties of epoxy based nanocomposites was investigated and compared to the properties of epoxy/PANI nanocomposites. It has been observed that the glass transition temperature of epoxy resin increases after introduction of PANI and TiO2-PANI nanocomposite, as well as with increasing their content. Prepared nanocomposites exhibited higher value of dielectric constant than pure epoxy resin. Epoxy based coating containing TiO2-PANI nanocomposite showed lower dielectric loss, higher hardness and better anticorrosion properties than pure epoxy resin and epoxy/PANI nanocomposite. (C) 2016 Elsevier B.V. All rights reserved.",
journal = "Progress in Organic Coatings",
title = "Improvement of the epoxy coating properties by incorporation of polyaniline surface treated TiO2 nanoparticles previously modified with vitamin B6",
volume = "99",
pages = "346-355",
doi = "10.1016/j.porgcoat.2016.06.014"
}

Radoman, T. S., Džunuzović, J. V., Grgur, B. N., Gvozdenovic, M. M., Jugović, B. Z., Miličević, D. S.,& Džunuzović, E. S.. (2016). Improvement of the epoxy coating properties by incorporation of polyaniline surface treated TiO2 nanoparticles previously modified with vitamin B6. in Progress in Organic Coatings, 99, 346-355.
https://doi.org/10.1016/j.porgcoat.2016.06.014

Radoman TS, Džunuzović JV, Grgur BN, Gvozdenovic MM, Jugović BZ, Miličević DS, Džunuzović ES. Improvement of the epoxy coating properties by incorporation of polyaniline surface treated TiO2 nanoparticles previously modified with vitamin B6. in Progress in Organic Coatings. 2016;99:346-355.
doi:10.1016/j.porgcoat.2016.06.014 .

Radoman, Tijana S., Džunuzović, Jasna V., Grgur, Branimir N., Gvozdenovic, Milica M., Jugović, Branimir Z., Miličević, Dejan S., Džunuzović, Enis S., "Improvement of the epoxy coating properties by incorporation of polyaniline surface treated TiO2 nanoparticles previously modified with vitamin B6" in Progress in Organic Coatings, 99 (2016):346-355,
https://doi.org/10.1016/j.porgcoat.2016.06.014 . .

TY  - JOUR
AU  - Tomković, Tanja
AU  - Radovanović, Filip
AU  - Nastasović, Aleksandra B.
AU  - Vasiljević-Radović, Dana
AU  - Marković, Jelena P.
AU  - Grgur, Branimir
AU  - Onjia, Antonije E.
PY  - 2015
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/383
AB  - Asymmetric polyethersulfone membranes with submicron particles comprising crosslinked poly(glycidyl methacrylate-co-2-acrylamido-2-methylpropane sulfonic acid) were prepared by a combination of a traditional liquid phase inversion process for making membranes with photopolymerization and crosslinking of functional monomers included in the casting solution. Scanning electron microscope images of the membrane cross-section revealed a hybrid structure with an interconnected network of submicron particles embedded within the porous polyethersulfone support. Permeation of toluidine blue solutions through non-functionalized membranes showed a dramatic effect of 2-acrylamido-2-methylpropane sulfonic acid concentration in the casting solution on the dynamic adsorption performance. The epoxide groups present in glycidyl methacrylate copolymer were transformed into amine functionalities by ring opening under alkaline conditions. Permeation of dilute Cu2+ solutions through functionalized membranes demonstrated that the plate height for some of these membranes was an order of magnitude smaller than for commercial particle-filled membranes used in solid phase extraction. (C) 2014 Elsevier Ltd. All rights reserved.
T2  - European Polymer Journal
T1  - Solid phase extraction membranes with submicron multifunctional adsorbent particles
VL  - 63
SP  - 90
EP  - 100
DO  - 10.1016/j.eurpolymj.2014.12.015
ER  - 

@article{
author = "Tomković, Tanja and Radovanović, Filip and Nastasović, Aleksandra B. and Vasiljević-Radović, Dana and Marković, Jelena P. and Grgur, Branimir and Onjia, Antonije E.",
year = "2015",
abstract = "Asymmetric polyethersulfone membranes with submicron particles comprising crosslinked poly(glycidyl methacrylate-co-2-acrylamido-2-methylpropane sulfonic acid) were prepared by a combination of a traditional liquid phase inversion process for making membranes with photopolymerization and crosslinking of functional monomers included in the casting solution. Scanning electron microscope images of the membrane cross-section revealed a hybrid structure with an interconnected network of submicron particles embedded within the porous polyethersulfone support. Permeation of toluidine blue solutions through non-functionalized membranes showed a dramatic effect of 2-acrylamido-2-methylpropane sulfonic acid concentration in the casting solution on the dynamic adsorption performance. The epoxide groups present in glycidyl methacrylate copolymer were transformed into amine functionalities by ring opening under alkaline conditions. Permeation of dilute Cu2+ solutions through functionalized membranes demonstrated that the plate height for some of these membranes was an order of magnitude smaller than for commercial particle-filled membranes used in solid phase extraction. (C) 2014 Elsevier Ltd. All rights reserved.",
journal = "European Polymer Journal",
title = "Solid phase extraction membranes with submicron multifunctional adsorbent particles",
volume = "63",
pages = "90-100",
doi = "10.1016/j.eurpolymj.2014.12.015"
}

Tomković, T., Radovanović, F., Nastasović, A. B., Vasiljević-Radović, D., Marković, J. P., Grgur, B.,& Onjia, A. E.. (2015). Solid phase extraction membranes with submicron multifunctional adsorbent particles. in European Polymer Journal, 63, 90-100.
https://doi.org/10.1016/j.eurpolymj.2014.12.015

Tomković T, Radovanović F, Nastasović AB, Vasiljević-Radović D, Marković JP, Grgur B, Onjia AE. Solid phase extraction membranes with submicron multifunctional adsorbent particles. in European Polymer Journal. 2015;63:90-100.
doi:10.1016/j.eurpolymj.2014.12.015 .

Tomković, Tanja, Radovanović, Filip, Nastasović, Aleksandra B., Vasiljević-Radović, Dana, Marković, Jelena P., Grgur, Branimir, Onjia, Antonije E., "Solid phase extraction membranes with submicron multifunctional adsorbent particles" in European Polymer Journal, 63 (2015):90-100,
https://doi.org/10.1016/j.eurpolymj.2014.12.015 . .

TY  - JOUR
AU  - Radoman, Tijana S.
AU  - Džunuzović, Jasna V.
AU  - Jeremić, Katarina B.
AU  - Grgur, Branimir N.
AU  - Miličević, Dejan S.
AU  - Popović, Ivanka G.
AU  - Džunuzović, Enis S.
PY  - 2014
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/6098
AB  - Epoxy resin/titanium dioxide (epoxy/TiO2) nanocomposites were obtained by incorporation of TiO2 nanoparticles surface modified with gallic acid esters in epoxy resin. TiO2 nanoparticles were obtained by acid catalyzed hydrolysis of titanium isopropoxide and their structural characterization was performed by X-ray diffraction and transmission electron microscopy. Three gallic acid esters, having different hydrophobic part, were used for surface modification of the synthesized TiO2 nanoparticles: propyl, hexyl and lauryl gallate. The gallate chemisorption onto surface of TiO2 nanoparticles was confirmed by Fourier transform infrared and ultraviolet-visible spectroscopy, while the amount of surface-bonded gallates was determined using thermogravimetric analysis. The influence of the surface modified TiO2 nanoparticles, as well as the length of hydrophobic part of the gallate used for surface modification of TiO2 nanoparticles, on glass transition temperature, barrier, dielectric and anticorrosive properties of epoxy resin was investigated by differential scanning calorimetry, water vapor transmission test, dielectric spectroscopy, electrochemical impedance spectroscopy and polarization measurements. Incorporation of surface modified TiO2 nanoparticles in epoxy resin caused increase of glass transition temperature and decrease of the water vapor permeability of epoxy resin. The water vapor transmission rate of epoxy/TiO2 nanocomposites was reduced with increasing hydrophobic part chain length of gallate ligand. Dielectric constant of examined nanocomposites was influenced by gallate used for the modification of TiO2 nanoparticles. The nanocomposites have better anticorrosive properties than pure epoxy resin, because the surface modified TiO2 nanoparticles react as oxygen scavengers, which inhibit steel corrosion by cathodic mechanism. (C) 2014 Elsevier Ltd. All rights reserved.
T2  - Materials and Design
T1  - Improvement of epoxy resin properties by incorporation of TiO2 nanoparticles surface modified with gallic acid esters
VL  - 62
SP  - 158
EP  - 167
DO  - 10.1016/j.matdes.2014.05.015
ER  - 

@article{
author = "Radoman, Tijana S. and Džunuzović, Jasna V. and Jeremić, Katarina B. and Grgur, Branimir N. and Miličević, Dejan S. and Popović, Ivanka G. and Džunuzović, Enis S.",
year = "2014",
abstract = "Epoxy resin/titanium dioxide (epoxy/TiO2) nanocomposites were obtained by incorporation of TiO2 nanoparticles surface modified with gallic acid esters in epoxy resin. TiO2 nanoparticles were obtained by acid catalyzed hydrolysis of titanium isopropoxide and their structural characterization was performed by X-ray diffraction and transmission electron microscopy. Three gallic acid esters, having different hydrophobic part, were used for surface modification of the synthesized TiO2 nanoparticles: propyl, hexyl and lauryl gallate. The gallate chemisorption onto surface of TiO2 nanoparticles was confirmed by Fourier transform infrared and ultraviolet-visible spectroscopy, while the amount of surface-bonded gallates was determined using thermogravimetric analysis. The influence of the surface modified TiO2 nanoparticles, as well as the length of hydrophobic part of the gallate used for surface modification of TiO2 nanoparticles, on glass transition temperature, barrier, dielectric and anticorrosive properties of epoxy resin was investigated by differential scanning calorimetry, water vapor transmission test, dielectric spectroscopy, electrochemical impedance spectroscopy and polarization measurements. Incorporation of surface modified TiO2 nanoparticles in epoxy resin caused increase of glass transition temperature and decrease of the water vapor permeability of epoxy resin. The water vapor transmission rate of epoxy/TiO2 nanocomposites was reduced with increasing hydrophobic part chain length of gallate ligand. Dielectric constant of examined nanocomposites was influenced by gallate used for the modification of TiO2 nanoparticles. The nanocomposites have better anticorrosive properties than pure epoxy resin, because the surface modified TiO2 nanoparticles react as oxygen scavengers, which inhibit steel corrosion by cathodic mechanism. (C) 2014 Elsevier Ltd. All rights reserved.",
journal = "Materials and Design",
title = "Improvement of epoxy resin properties by incorporation of TiO2 nanoparticles surface modified with gallic acid esters",
volume = "62",
pages = "158-167",
doi = "10.1016/j.matdes.2014.05.015"
}

Radoman, T. S., Džunuzović, J. V., Jeremić, K. B., Grgur, B. N., Miličević, D. S., Popović, I. G.,& Džunuzović, E. S.. (2014). Improvement of epoxy resin properties by incorporation of TiO2 nanoparticles surface modified with gallic acid esters. in Materials and Design, 62, 158-167.
https://doi.org/10.1016/j.matdes.2014.05.015

Radoman TS, Džunuzović JV, Jeremić KB, Grgur BN, Miličević DS, Popović IG, Džunuzović ES. Improvement of epoxy resin properties by incorporation of TiO2 nanoparticles surface modified with gallic acid esters. in Materials and Design. 2014;62:158-167.
doi:10.1016/j.matdes.2014.05.015 .

Radoman, Tijana S., Džunuzović, Jasna V., Jeremić, Katarina B., Grgur, Branimir N., Miličević, Dejan S., Popović, Ivanka G., Džunuzović, Enis S., "Improvement of epoxy resin properties by incorporation of TiO2 nanoparticles surface modified with gallic acid esters" in Materials and Design, 62 (2014):158-167,
https://doi.org/10.1016/j.matdes.2014.05.015 . .

TY  - JOUR
AU  - Smiljanić, Milutin Lj.
AU  - Srejić, Irina
AU  - Grgur, Branimir
AU  - Rakočević, Zlatko Lj.
AU  - Štrbac, Svetlana
PY  - 2013
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/5316
AB  - Hydrogen evolution reaction (HER) was studied on Pd/Au(1 1 1) bimetallic surfaces in alkaline solution. Au(1 1 1) was modified by palladium nanoislands spontaneously deposited using PdSO4 center dot 2H(2)O and PdCl2 salts. As revealed from both surface topography Atomic Force Microscopy (AFM) and phase AFM images, for the same deposition conditions, the obtained Pd/Au(1 1 1) nanostructures differ depending on the counter anion in the depositing palladium salt. These differences are reflected on their catalytic activity toward HER, which occurs between the potentials for pure consisting metals. HER proceeded with the same mechanism, but it is shifted to more positive potentials for Pd/Au(1 1 1) nanostructures obtained using PdCl2 salt with respect to ones obtained using PdSO4 salt. Better catalytic activity of Pd/Au(1 1 1) nanostructures obtained using PdCl2 salt can be explained by their surface structure consisting of smaller and thinner Pd nanoislands, preferentially deposited at steps, which provides more Pd and Pd/Au sites suitable for hydrogen evolution reaction. (C) 2012 Elsevier Ltd. All rights reserved.
T2  - Electrochimica Acta
T1  - Catalysis of hydrogen evolution on different Pd/Au(111) nanostructures in alkaline solution
VL  - 88
SP  - 589
EP  - 596
DO  - 10.1016/j.electacta.2012.10.128
ER  - 

@article{
author = "Smiljanić, Milutin Lj. and Srejić, Irina and Grgur, Branimir and Rakočević, Zlatko Lj. and Štrbac, Svetlana",
year = "2013",
abstract = "Hydrogen evolution reaction (HER) was studied on Pd/Au(1 1 1) bimetallic surfaces in alkaline solution. Au(1 1 1) was modified by palladium nanoislands spontaneously deposited using PdSO4 center dot 2H(2)O and PdCl2 salts. As revealed from both surface topography Atomic Force Microscopy (AFM) and phase AFM images, for the same deposition conditions, the obtained Pd/Au(1 1 1) nanostructures differ depending on the counter anion in the depositing palladium salt. These differences are reflected on their catalytic activity toward HER, which occurs between the potentials for pure consisting metals. HER proceeded with the same mechanism, but it is shifted to more positive potentials for Pd/Au(1 1 1) nanostructures obtained using PdCl2 salt with respect to ones obtained using PdSO4 salt. Better catalytic activity of Pd/Au(1 1 1) nanostructures obtained using PdCl2 salt can be explained by their surface structure consisting of smaller and thinner Pd nanoislands, preferentially deposited at steps, which provides more Pd and Pd/Au sites suitable for hydrogen evolution reaction. (C) 2012 Elsevier Ltd. All rights reserved.",
journal = "Electrochimica Acta",
title = "Catalysis of hydrogen evolution on different Pd/Au(111) nanostructures in alkaline solution",
volume = "88",
pages = "589-596",
doi = "10.1016/j.electacta.2012.10.128"
}

Smiljanić, M. Lj., Srejić, I., Grgur, B., Rakočević, Z. Lj.,& Štrbac, S.. (2013). Catalysis of hydrogen evolution on different Pd/Au(111) nanostructures in alkaline solution. in Electrochimica Acta, 88, 589-596.
https://doi.org/10.1016/j.electacta.2012.10.128

Smiljanić ML, Srejić I, Grgur B, Rakočević ZL, Štrbac S. Catalysis of hydrogen evolution on different Pd/Au(111) nanostructures in alkaline solution. in Electrochimica Acta. 2013;88:589-596.
doi:10.1016/j.electacta.2012.10.128 .

Smiljanić, Milutin Lj., Srejić, Irina, Grgur, Branimir, Rakočević, Zlatko Lj., Štrbac, Svetlana, "Catalysis of hydrogen evolution on different Pd/Au(111) nanostructures in alkaline solution" in Electrochimica Acta, 88 (2013):589-596,
https://doi.org/10.1016/j.electacta.2012.10.128 . .

TY  - JOUR
AU  - Smiljanić, Milutin Lj.
AU  - Srejić, Irina
AU  - Grgur, B.
AU  - Rakočević, Zlatko Lj.
AU  - Štrbac, Svetlana
PY  - 2013
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/5344
AB  - Pronounced catalysis of hydrogen evolution reaction (HER) by rhodium nanoislands spontaneously deposited on Au(111) has been observed. Different Rh/Au(111) nanostructures were characterized ex situ by both height and phase imaging AFM. The most pronounced catalytic activity for HER in 0.5 M H2SO4 was obtained for 50% Rh coverage. This is ascribed to the suitable size of Rh nanoislands and to the electronic modification of Rh deposit by Au(111) substrate. (C) 2012 Elsevier B.V. All rights reserved.
T2  - Electrochemistry Communications
T1  - Hydrogen evolution on Au(111) catalyzed by rhodium nanoislands
VL  - 28
SP  - 37
EP  - 39
DO  - 10.1016/j.elecom.2012.12.009
ER  - 

@article{
author = "Smiljanić, Milutin Lj. and Srejić, Irina and Grgur, B. and Rakočević, Zlatko Lj. and Štrbac, Svetlana",
year = "2013",
abstract = "Pronounced catalysis of hydrogen evolution reaction (HER) by rhodium nanoislands spontaneously deposited on Au(111) has been observed. Different Rh/Au(111) nanostructures were characterized ex situ by both height and phase imaging AFM. The most pronounced catalytic activity for HER in 0.5 M H2SO4 was obtained for 50% Rh coverage. This is ascribed to the suitable size of Rh nanoislands and to the electronic modification of Rh deposit by Au(111) substrate. (C) 2012 Elsevier B.V. All rights reserved.",
journal = "Electrochemistry Communications",
title = "Hydrogen evolution on Au(111) catalyzed by rhodium nanoislands",
volume = "28",
pages = "37-39",
doi = "10.1016/j.elecom.2012.12.009"
}

Smiljanić, M. Lj., Srejić, I., Grgur, B., Rakočević, Z. Lj.,& Štrbac, S.. (2013). Hydrogen evolution on Au(111) catalyzed by rhodium nanoislands. in Electrochemistry Communications, 28, 37-39.
https://doi.org/10.1016/j.elecom.2012.12.009

Smiljanić ML, Srejić I, Grgur B, Rakočević ZL, Štrbac S. Hydrogen evolution on Au(111) catalyzed by rhodium nanoislands. in Electrochemistry Communications. 2013;28:37-39.
doi:10.1016/j.elecom.2012.12.009 .

Smiljanić, Milutin Lj., Srejić, Irina, Grgur, B., Rakočević, Zlatko Lj., Štrbac, Svetlana, "Hydrogen evolution on Au(111) catalyzed by rhodium nanoislands" in Electrochemistry Communications, 28 (2013):37-39,
https://doi.org/10.1016/j.elecom.2012.12.009 . .

TY  - JOUR
AU  - Mijin, Dušan Ž.
AU  - Ivic, Milka L. Avramov
AU  - Onjia, Antonije E.
AU  - Grgur, Branimir N.
PY  - 2012
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/5165
AB  - Reaction of the indirect electrochemical decolorization of cationic textile dye CI Basic Yellow 28 with electrochemically generated active chlorine has been studied, using UV-Vis spectrophotometry, ion chromatography, organic carbon analysis, and cyclic voltammetry. Decolorization has been investigated on Ti/PtOx anode for different currents in the range of 50-200 mA, sodium chloride concentration in the range from 5 to 25 g dm(-3), and dye concentration from 10 to 70 mg dm(-3). The optimum electrolysis conditions and possible active species have been suggested. (C) 2012 Elsevier B.V. All rights reserved.
T2  - Chemical Engineering Journal
T1  - Decolorization of textile dye CI Basic Yellow 28 with electrochemically generated active chlorine
VL  - 204
SP  - 151
EP  - 157
DO  - 10.1016/j.cej.2012.07.091
ER  - 

@article{
author = "Mijin, Dušan Ž. and Ivic, Milka L. Avramov and Onjia, Antonije E. and Grgur, Branimir N.",
year = "2012",
abstract = "Reaction of the indirect electrochemical decolorization of cationic textile dye CI Basic Yellow 28 with electrochemically generated active chlorine has been studied, using UV-Vis spectrophotometry, ion chromatography, organic carbon analysis, and cyclic voltammetry. Decolorization has been investigated on Ti/PtOx anode for different currents in the range of 50-200 mA, sodium chloride concentration in the range from 5 to 25 g dm(-3), and dye concentration from 10 to 70 mg dm(-3). The optimum electrolysis conditions and possible active species have been suggested. (C) 2012 Elsevier B.V. All rights reserved.",
journal = "Chemical Engineering Journal",
title = "Decolorization of textile dye CI Basic Yellow 28 with electrochemically generated active chlorine",
volume = "204",
pages = "151-157",
doi = "10.1016/j.cej.2012.07.091"
}

Mijin, D. Ž., Ivic, M. L. A., Onjia, A. E.,& Grgur, B. N.. (2012). Decolorization of textile dye CI Basic Yellow 28 with electrochemically generated active chlorine. in Chemical Engineering Journal, 204, 151-157.
https://doi.org/10.1016/j.cej.2012.07.091

Mijin DŽ, Ivic MLA, Onjia AE, Grgur BN. Decolorization of textile dye CI Basic Yellow 28 with electrochemically generated active chlorine. in Chemical Engineering Journal. 2012;204:151-157.
doi:10.1016/j.cej.2012.07.091 .

Mijin, Dušan Ž., Ivic, Milka L. Avramov, Onjia, Antonije E., Grgur, Branimir N., "Decolorization of textile dye CI Basic Yellow 28 with electrochemically generated active chlorine" in Chemical Engineering Journal, 204 (2012):151-157,
https://doi.org/10.1016/j.cej.2012.07.091 . .

TY  - JOUR
AU  - Srejić, Irina
AU  - Smiljanić, Milutin Lj.
AU  - Grgur, Branimir
AU  - Rakočević, Zlatko Lj.
AU  - Štrbac, Svetlana
PY  - 2012
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/4750
AB  - Oxygen reduction reaction (ORR) was studied on polycrystalline gold, Au(poly), modified by nanosized palladium islands in 0.1 M HClO4 solution using rotating disc electrode technique. Paladium was spontaneously deposited from 1 mM PdSO4 center dot 2H(2)O + 0.5 M H2SO4 solution for various deposition times at a submonolayer coverage. Topography of obtained Pd/Au(poly) surfaces was observed by tapping mode atomic force microscopy (AFM), while chemical surface composition changes were detected by simultaneously performed phase AFM. Deposited Pd islands were nonuniform in size and randomly distributed over the gold substrate. Size and number of Pd islands increase with the increase of the deposition time, and consequently surface coverage increases too. Deposited Pd was also identified by the changes in cyclic voltammetry (CV) profiles from which an active surface area was estimated. Obtained Pd/Au(poly) surfaces have shown a significant catalytic activity towards oxygen reduction reaction which increases with the increase of Pd islands coverage. The initial potential of ORR was shifted positively, while reaction pathway changes from 2e-reduction on pure gold to 4e-reduction on Pd modified gold. Additionally, obtained Pd/Au(poly) surfaces have shown a significant activity towards hydrogen peroxide reduction (HPRR), which appear as an intermediate during ORR. This supports the assumption that ORR on Pd/Au(poly) occurs partly through 4e-series reduction pathway, the fraction of which increases with the increase of Pd coverage. (C) 2012 Elsevier Ltd. All rights reserved.
T2  - Electrochimica Acta
T1  - Catalysis of oxygen reduction on Au modified by Pd nanoislands in perchloric acid solution
VL  - 64
SP  - 140
EP  - 146
DO  - 10.1016/j.electacta.2011.12.130
ER  - 

@article{
author = "Srejić, Irina and Smiljanić, Milutin Lj. and Grgur, Branimir and Rakočević, Zlatko Lj. and Štrbac, Svetlana",
year = "2012",
abstract = "Oxygen reduction reaction (ORR) was studied on polycrystalline gold, Au(poly), modified by nanosized palladium islands in 0.1 M HClO4 solution using rotating disc electrode technique. Paladium was spontaneously deposited from 1 mM PdSO4 center dot 2H(2)O + 0.5 M H2SO4 solution for various deposition times at a submonolayer coverage. Topography of obtained Pd/Au(poly) surfaces was observed by tapping mode atomic force microscopy (AFM), while chemical surface composition changes were detected by simultaneously performed phase AFM. Deposited Pd islands were nonuniform in size and randomly distributed over the gold substrate. Size and number of Pd islands increase with the increase of the deposition time, and consequently surface coverage increases too. Deposited Pd was also identified by the changes in cyclic voltammetry (CV) profiles from which an active surface area was estimated. Obtained Pd/Au(poly) surfaces have shown a significant catalytic activity towards oxygen reduction reaction which increases with the increase of Pd islands coverage. The initial potential of ORR was shifted positively, while reaction pathway changes from 2e-reduction on pure gold to 4e-reduction on Pd modified gold. Additionally, obtained Pd/Au(poly) surfaces have shown a significant activity towards hydrogen peroxide reduction (HPRR), which appear as an intermediate during ORR. This supports the assumption that ORR on Pd/Au(poly) occurs partly through 4e-series reduction pathway, the fraction of which increases with the increase of Pd coverage. (C) 2012 Elsevier Ltd. All rights reserved.",
journal = "Electrochimica Acta",
title = "Catalysis of oxygen reduction on Au modified by Pd nanoislands in perchloric acid solution",
volume = "64",
pages = "140-146",
doi = "10.1016/j.electacta.2011.12.130"
}

Srejić, I., Smiljanić, M. Lj., Grgur, B., Rakočević, Z. Lj.,& Štrbac, S.. (2012). Catalysis of oxygen reduction on Au modified by Pd nanoislands in perchloric acid solution. in Electrochimica Acta, 64, 140-146.
https://doi.org/10.1016/j.electacta.2011.12.130

Srejić I, Smiljanić ML, Grgur B, Rakočević ZL, Štrbac S. Catalysis of oxygen reduction on Au modified by Pd nanoislands in perchloric acid solution. in Electrochimica Acta. 2012;64:140-146.
doi:10.1016/j.electacta.2011.12.130 .

Srejić, Irina, Smiljanić, Milutin Lj., Grgur, Branimir, Rakočević, Zlatko Lj., Štrbac, Svetlana, "Catalysis of oxygen reduction on Au modified by Pd nanoislands in perchloric acid solution" in Electrochimica Acta, 64 (2012):140-146,
https://doi.org/10.1016/j.electacta.2011.12.130 . .

TY  - JOUR
AU  - Smiljanić, Milutin Lj.
AU  - Srejić, Irina
AU  - Grgur, Branimir
AU  - Rakočević, Zlatko Lj.
AU  - Štrbac, Svetlana
PY  - 2012
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/5217
AB  - Hydrogen evolution reaction was studied on Au(111) modified by palladium spontaneously deposited on the Au(111) surface from (1 mM PdSO4 center dot 2 H2O + 0.5 M H2SO4) solution at a submonolayer coverage. Number and size of Pd islands increased with the increase of the deposition time as observed by ex situ surface topography atomic force microscopy (AFM). The overall coverage of the underlying Au(111) surface by the deposited Pd islands was estimated from simultaneously acquired phase AFM images, which provided a clear contrast between different materials. The obtained Pd/Au(111) surfaces have shown a significant catalytic activity toward hydrogen evolution reaction in 0.5 M H2SO4 solution. This is discussed with respect to Pd islands size and coverage and to the influence of an electronic effect induced in Pd islands by the underlying Au(111) substrate.
T2  - Electrocatalysis
T1  - Catalysis of Hydrogen Evolution on Au(111) Modified by Spontaneously Deposited Pd Nanoislands
VL  - 3
IS  - 3-4
SP  - 369
EP  - 375
DO  - 10.1007/s12678-012-0093-2
ER  - 

@article{
author = "Smiljanić, Milutin Lj. and Srejić, Irina and Grgur, Branimir and Rakočević, Zlatko Lj. and Štrbac, Svetlana",
year = "2012",
abstract = "Hydrogen evolution reaction was studied on Au(111) modified by palladium spontaneously deposited on the Au(111) surface from (1 mM PdSO4 center dot 2 H2O + 0.5 M H2SO4) solution at a submonolayer coverage. Number and size of Pd islands increased with the increase of the deposition time as observed by ex situ surface topography atomic force microscopy (AFM). The overall coverage of the underlying Au(111) surface by the deposited Pd islands was estimated from simultaneously acquired phase AFM images, which provided a clear contrast between different materials. The obtained Pd/Au(111) surfaces have shown a significant catalytic activity toward hydrogen evolution reaction in 0.5 M H2SO4 solution. This is discussed with respect to Pd islands size and coverage and to the influence of an electronic effect induced in Pd islands by the underlying Au(111) substrate.",
journal = "Electrocatalysis",
title = "Catalysis of Hydrogen Evolution on Au(111) Modified by Spontaneously Deposited Pd Nanoislands",
volume = "3",
number = "3-4",
pages = "369-375",
doi = "10.1007/s12678-012-0093-2"
}

Smiljanić, M. Lj., Srejić, I., Grgur, B., Rakočević, Z. Lj.,& Štrbac, S.. (2012). Catalysis of Hydrogen Evolution on Au(111) Modified by Spontaneously Deposited Pd Nanoislands. in Electrocatalysis, 3(3-4), 369-375.
https://doi.org/10.1007/s12678-012-0093-2

Smiljanić ML, Srejić I, Grgur B, Rakočević ZL, Štrbac S. Catalysis of Hydrogen Evolution on Au(111) Modified by Spontaneously Deposited Pd Nanoislands. in Electrocatalysis. 2012;3(3-4):369-375.
doi:10.1007/s12678-012-0093-2 .

Smiljanić, Milutin Lj., Srejić, Irina, Grgur, Branimir, Rakočević, Zlatko Lj., Štrbac, Svetlana, "Catalysis of Hydrogen Evolution on Au(111) Modified by Spontaneously Deposited Pd Nanoislands" in Electrocatalysis, 3, no. 3-4 (2012):369-375,
https://doi.org/10.1007/s12678-012-0093-2 . .

TY  - JOUR
AU  - Grgur, Branimir N.
AU  - Gvozdenović, M.
AU  - Mišković-Stanković, Vesna B.
AU  - Kačarević-Popović, Zorica M.
PY  - 2006
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/3052
AB  - The corrosion behavior, sorption characteristics and thermal stability of epoxy coatings electrodeposited on mild steel (MS) and mild steel with electrochemically deposited polyaniline (PANI) film were investigated in 3% NaCl solution using electrochemical impedance spectroscopy (EIS) and thermogravimetric analysis (TGA). Electrochemical deposition of PANI film on mild steel was performed from aqueous solution of 0.5 M sodium benzoate and 0.1 M aniline at constant current density of 1.5 mA cm(-2). Epoxy coatings on mild steel and mild steel with PANI film were deposited at constant voltage. It was shown that during initial time of exposure to 3% NaCl, PANI/epoxy coating system on mild steel has lower values of pore resistance (obtained from EIS), greater amount of absorbed water and lower thermal stability (obtained from TGA) which indicate more porous structure comparing to epoxy coating on mild steel. During prolonged exposure to 3% NaCl, PANI/epoxy coating system exhibited increased corrosion protection of mild steel comparing to epoxy coating due to the barrier effect of PANI film and the influence of the dissolved molecular oxygen on cathodic and anodic reaction. Differences between corrosion behavior of epoxy coated and PANI/epoxy coated mild steel in acid and neutral solutions has been discussed. (C) 2006 Elsevier B.V. All rights reserved.
T2  - Progress in Organic Coatings
T1  - Corrosion behavior and thermal stability of electrodeposited PANI/epoxy coating system on mild steel in sodium chloride solution
VL  - 56
IS  - 2-3
SP  - 214
EP  - 219
DO  - 10.1016/j.porgcoat.2006.05.003
ER  - 

@article{
author = "Grgur, Branimir N. and Gvozdenović, M. and Mišković-Stanković, Vesna B. and Kačarević-Popović, Zorica M.",
year = "2006",
abstract = "The corrosion behavior, sorption characteristics and thermal stability of epoxy coatings electrodeposited on mild steel (MS) and mild steel with electrochemically deposited polyaniline (PANI) film were investigated in 3% NaCl solution using electrochemical impedance spectroscopy (EIS) and thermogravimetric analysis (TGA). Electrochemical deposition of PANI film on mild steel was performed from aqueous solution of 0.5 M sodium benzoate and 0.1 M aniline at constant current density of 1.5 mA cm(-2). Epoxy coatings on mild steel and mild steel with PANI film were deposited at constant voltage. It was shown that during initial time of exposure to 3% NaCl, PANI/epoxy coating system on mild steel has lower values of pore resistance (obtained from EIS), greater amount of absorbed water and lower thermal stability (obtained from TGA) which indicate more porous structure comparing to epoxy coating on mild steel. During prolonged exposure to 3% NaCl, PANI/epoxy coating system exhibited increased corrosion protection of mild steel comparing to epoxy coating due to the barrier effect of PANI film and the influence of the dissolved molecular oxygen on cathodic and anodic reaction. Differences between corrosion behavior of epoxy coated and PANI/epoxy coated mild steel in acid and neutral solutions has been discussed. (C) 2006 Elsevier B.V. All rights reserved.",
journal = "Progress in Organic Coatings",
title = "Corrosion behavior and thermal stability of electrodeposited PANI/epoxy coating system on mild steel in sodium chloride solution",
volume = "56",
number = "2-3",
pages = "214-219",
doi = "10.1016/j.porgcoat.2006.05.003"
}

Grgur, B. N., Gvozdenović, M., Mišković-Stanković, V. B.,& Kačarević-Popović, Z. M.. (2006). Corrosion behavior and thermal stability of electrodeposited PANI/epoxy coating system on mild steel in sodium chloride solution. in Progress in Organic Coatings, 56(2-3), 214-219.
https://doi.org/10.1016/j.porgcoat.2006.05.003

Grgur BN, Gvozdenović M, Mišković-Stanković VB, Kačarević-Popović ZM. Corrosion behavior and thermal stability of electrodeposited PANI/epoxy coating system on mild steel in sodium chloride solution. in Progress in Organic Coatings. 2006;56(2-3):214-219.
doi:10.1016/j.porgcoat.2006.05.003 .

Grgur, Branimir N., Gvozdenović, M., Mišković-Stanković, Vesna B., Kačarević-Popović, Zorica M., "Corrosion behavior and thermal stability of electrodeposited PANI/epoxy coating system on mild steel in sodium chloride solution" in Progress in Organic Coatings, 56, no. 2-3 (2006):214-219,
https://doi.org/10.1016/j.porgcoat.2006.05.003 . .