TY  - CONF
AU  - Carević, Milica
AU  - Vulić, Tatjana
AU  - Šaponjić, Zoran
AU  - Mojović, Zorica
AU  - Abazović, Nadica
AU  - Čomor, Mirjana
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/11652
AB  - Urea-based graphitic carbon nitride (g-C3N4) is thermally exfoliated at 500 °C in the air
atmosphere, and nano-carbon nitride (n-C3N4) is obtained. While optical properties are assessed
using UV/Vis DR spectroscopy, structural and morphological parameters of two materials are
obtained using XRD, TEM, and FTIR. Flat-band potentials were determined from Mott-Schottky
plots, and combined with corresponding band-gap energies, to estimate conduction and valence
band potentials of both materials. Photocatalytic efficacy of both semiconductors in photocatalytic
degradation of three textile dyes under simulated solar light irradiation is compared, with the
conclusion that n-C3N4 expressed higher photocatalytic ability in the studied systems. Finally, in
order to provide reusability of the semiconductors in multiple consecutive photocatalytic cycles,
both photocatalysts were drop-coated on the jute-based post industrial waste. Reusability of juten-C3N4 material is probed in three consecutive photocatalytic cycles, and the obtained results
showed that this material can have a future in solving real-life environmental problems.
PB  - Belgrade : Materials Research Society of Serbia
C3  - YUCOMAT 2023 : 24th Annual Conference YUCOMAT 2023 : programme and the book of abstracts; September 4-8, 2023; Herceg Novi, Montenegro
T1  - Jute post-industrial waste as carbon nitride support in photocatalytic degradation of
textile dyes under simulated solar light illumination
SP  - 63
EP  - 63
UR  - https://hdl.handle.net/21.15107/rcub_vinar_11652
ER  - 

@conference{
author = "Carević, Milica and Vulić, Tatjana and Šaponjić, Zoran and Mojović, Zorica and Abazović, Nadica and Čomor, Mirjana",
year = "2023",
abstract = "Urea-based graphitic carbon nitride (g-C3N4) is thermally exfoliated at 500 °C in the air
atmosphere, and nano-carbon nitride (n-C3N4) is obtained. While optical properties are assessed
using UV/Vis DR spectroscopy, structural and morphological parameters of two materials are
obtained using XRD, TEM, and FTIR. Flat-band potentials were determined from Mott-Schottky
plots, and combined with corresponding band-gap energies, to estimate conduction and valence
band potentials of both materials. Photocatalytic efficacy of both semiconductors in photocatalytic
degradation of three textile dyes under simulated solar light irradiation is compared, with the
conclusion that n-C3N4 expressed higher photocatalytic ability in the studied systems. Finally, in
order to provide reusability of the semiconductors in multiple consecutive photocatalytic cycles,
both photocatalysts were drop-coated on the jute-based post industrial waste. Reusability of juten-C3N4 material is probed in three consecutive photocatalytic cycles, and the obtained results
showed that this material can have a future in solving real-life environmental problems.",
publisher = "Belgrade : Materials Research Society of Serbia",
journal = "YUCOMAT 2023 : 24th Annual Conference YUCOMAT 2023 : programme and the book of abstracts; September 4-8, 2023; Herceg Novi, Montenegro",
title = "Jute post-industrial waste as carbon nitride support in photocatalytic degradation of
textile dyes under simulated solar light illumination",
pages = "63-63",
url = "https://hdl.handle.net/21.15107/rcub_vinar_11652"
}

Carević, M., Vulić, T., Šaponjić, Z., Mojović, Z., Abazović, N.,& Čomor, M.. (2023). Jute post-industrial waste as carbon nitride support in photocatalytic degradation of
textile dyes under simulated solar light illumination. in YUCOMAT 2023 : 24th Annual Conference YUCOMAT 2023 : programme and the book of abstracts; September 4-8, 2023; Herceg Novi, Montenegro
Belgrade : Materials Research Society of Serbia., 63-63.
https://hdl.handle.net/21.15107/rcub_vinar_11652

Carević M, Vulić T, Šaponjić Z, Mojović Z, Abazović N, Čomor M. Jute post-industrial waste as carbon nitride support in photocatalytic degradation of
textile dyes under simulated solar light illumination. in YUCOMAT 2023 : 24th Annual Conference YUCOMAT 2023 : programme and the book of abstracts; September 4-8, 2023; Herceg Novi, Montenegro. 2023;:63-63.
https://hdl.handle.net/21.15107/rcub_vinar_11652 .

Carević, Milica, Vulić, Tatjana, Šaponjić, Zoran, Mojović, Zorica, Abazović, Nadica, Čomor, Mirjana, "Jute post-industrial waste as carbon nitride support in photocatalytic degradation of
textile dyes under simulated solar light illumination" in YUCOMAT 2023 : 24th Annual Conference YUCOMAT 2023 : programme and the book of abstracts; September 4-8, 2023; Herceg Novi, Montenegro (2023):63-63,
https://hdl.handle.net/21.15107/rcub_vinar_11652 .

TY  - JOUR
AU  - Milošević, Milica V.
AU  - Radoičić, Marija B.
AU  - Ohara, Satoshi
AU  - Abe, Hiroya
AU  - Spasojević, Jelena
AU  - Mančić, Lidija
AU  - Šaponjić, Zoran
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10853
AB  - Novel cotton-based TiO2/Ag/TiO2 nanocomposites for wastewater treatment were developed by fine chemical synthesis path with the goal of coping with wastewater issues and environmental remediation. The photocatalytic performances of nanocomposites were tested during photodegradation processes of RB, AO7 and MR under simulated solar light. Double- and single-loaded nanocomposites were synthesized by a simple bottom-up approach implying in situ photoreduction of Ag+ ions on the surface of TiO2 NPs previously deposited on cotton fibers from colloids. The spherical-like colloidal TiO2 NPs (4.5 nm) and TiO2/Ag NPs (8 nm) and the formation of uniform TiO2/Ag and TiO2/Ag/TiO2 nano-coatings on cotton fibers were examined by TEM and FESEM. The reduction of Ag+ ions on TiO2 surface was undoubtedly proven by the appearance of SPR band of Ag NPs in UV/Vis spectra. Raman spectroscopy clearly confirmed the presence of anatase TiO2 in nanocomposites. Quantitative determination of TiO2 and Ag in nanocomposites was accomplished using EDX and ICP–OES. The cotton-based TiO2/Ag/TiO2 nanocomposite showed the highest photocatalytic efficiency (> 90%) and maintained its removal efficiency after three reuse cycles, indicated its exceptional photochemical ability. The initial idea of improved photocatalytic performances of a TiO2 NPs double-layer with immobilized Ag NPs was justified as the TiO2/Ag/TiO2 processed sample contributed additional binding sites for dye molecules. Considering that the photocatalytic activity of the cotton-based TiO2 and TiO2/Ag samples was practically imperceptible, it can be assumed that the synthesized Ag NPs act predominantly as electron traps in the double-loaded synthesized system.
T2  - Cellulose
T1  - Advanced photocatalysis mediated by TiO2/Ag/TiO2 nanoparticles modified cotton fabric
VL  - 30
SP  - 4749
EP  - 4771
DO  - 10.1007/s10570-023-05165-0
ER  - 

@article{
author = "Milošević, Milica V. and Radoičić, Marija B. and Ohara, Satoshi and Abe, Hiroya and Spasojević, Jelena and Mančić, Lidija and Šaponjić, Zoran",
year = "2023",
abstract = "Novel cotton-based TiO2/Ag/TiO2 nanocomposites for wastewater treatment were developed by fine chemical synthesis path with the goal of coping with wastewater issues and environmental remediation. The photocatalytic performances of nanocomposites were tested during photodegradation processes of RB, AO7 and MR under simulated solar light. Double- and single-loaded nanocomposites were synthesized by a simple bottom-up approach implying in situ photoreduction of Ag+ ions on the surface of TiO2 NPs previously deposited on cotton fibers from colloids. The spherical-like colloidal TiO2 NPs (4.5 nm) and TiO2/Ag NPs (8 nm) and the formation of uniform TiO2/Ag and TiO2/Ag/TiO2 nano-coatings on cotton fibers were examined by TEM and FESEM. The reduction of Ag+ ions on TiO2 surface was undoubtedly proven by the appearance of SPR band of Ag NPs in UV/Vis spectra. Raman spectroscopy clearly confirmed the presence of anatase TiO2 in nanocomposites. Quantitative determination of TiO2 and Ag in nanocomposites was accomplished using EDX and ICP–OES. The cotton-based TiO2/Ag/TiO2 nanocomposite showed the highest photocatalytic efficiency (> 90%) and maintained its removal efficiency after three reuse cycles, indicated its exceptional photochemical ability. The initial idea of improved photocatalytic performances of a TiO2 NPs double-layer with immobilized Ag NPs was justified as the TiO2/Ag/TiO2 processed sample contributed additional binding sites for dye molecules. Considering that the photocatalytic activity of the cotton-based TiO2 and TiO2/Ag samples was practically imperceptible, it can be assumed that the synthesized Ag NPs act predominantly as electron traps in the double-loaded synthesized system.",
journal = "Cellulose",
title = "Advanced photocatalysis mediated by TiO2/Ag/TiO2 nanoparticles modified cotton fabric",
volume = "30",
pages = "4749-4771",
doi = "10.1007/s10570-023-05165-0"
}

Milošević, M. V., Radoičić, M. B., Ohara, S., Abe, H., Spasojević, J., Mančić, L.,& Šaponjić, Z.. (2023). Advanced photocatalysis mediated by TiO2/Ag/TiO2 nanoparticles modified cotton fabric. in Cellulose, 30, 4749-4771.
https://doi.org/10.1007/s10570-023-05165-0

Milošević MV, Radoičić MB, Ohara S, Abe H, Spasojević J, Mančić L, Šaponjić Z. Advanced photocatalysis mediated by TiO2/Ag/TiO2 nanoparticles modified cotton fabric. in Cellulose. 2023;30:4749-4771.
doi:10.1007/s10570-023-05165-0 .

Milošević, Milica V., Radoičić, Marija B., Ohara, Satoshi, Abe, Hiroya, Spasojević, Jelena, Mančić, Lidija, Šaponjić, Zoran, "Advanced photocatalysis mediated by TiO2/Ag/TiO2 nanoparticles modified cotton fabric" in Cellulose, 30 (2023):4749-4771,
https://doi.org/10.1007/s10570-023-05165-0 . .

TY  - JOUR
AU  - Kovačević, Aleksandar
AU  - Marković, Dragan D.
AU  - Radoičić, Marija B.
AU  - Šaponjić, Zoran
AU  - Radetić, Maja M.
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10588
AB  - Intensified oil exploitation accompanied with frequent oil spills having a detrimental impact on ecosystems are seeking efficient, environmentally and economically feasible solutions. In an attempt to develop an efficient, reusable, biodegradable and cheap sorbent for oil clean-up non-woven sorbents based on recycled jute post-industrial textile waste were fabricated. The influence of area density of non-woven sorbents and hydrophobicity of fibers on overall oil sorption performance was the focus of this research. All sorbents showed a good reusability after five sorption cycles and buoyancy in water even after 24 h independently of sorbent structure. The area density of sorbents and viscosity of studied oils (crude oil, diesel oil and two types of motor oils) highly affected the oil sorption capacity and oil retention. The sorbent with the lowest area density exhibited the best oil sorption performance. The esterification of jute with stearic fatty acid contributed to decrease in water uptake of sorbents but also to negligible change of oil sorption behavior indicating that the structure of the sorbent in this case plays a crucial role.
T2  - Journal of Cleaner Production
T1  - Sustainable non-woven sorbents based on jute post-industrial waste for cleaning of oil spills
VL  - 386
SP  - 135811
DO  - 10.1016/j.jclepro.2022.135811
ER  - 

@article{
author = "Kovačević, Aleksandar and Marković, Dragan D. and Radoičić, Marija B. and Šaponjić, Zoran and Radetić, Maja M.",
year = "2023",
abstract = "Intensified oil exploitation accompanied with frequent oil spills having a detrimental impact on ecosystems are seeking efficient, environmentally and economically feasible solutions. In an attempt to develop an efficient, reusable, biodegradable and cheap sorbent for oil clean-up non-woven sorbents based on recycled jute post-industrial textile waste were fabricated. The influence of area density of non-woven sorbents and hydrophobicity of fibers on overall oil sorption performance was the focus of this research. All sorbents showed a good reusability after five sorption cycles and buoyancy in water even after 24 h independently of sorbent structure. The area density of sorbents and viscosity of studied oils (crude oil, diesel oil and two types of motor oils) highly affected the oil sorption capacity and oil retention. The sorbent with the lowest area density exhibited the best oil sorption performance. The esterification of jute with stearic fatty acid contributed to decrease in water uptake of sorbents but also to negligible change of oil sorption behavior indicating that the structure of the sorbent in this case plays a crucial role.",
journal = "Journal of Cleaner Production",
title = "Sustainable non-woven sorbents based on jute post-industrial waste for cleaning of oil spills",
volume = "386",
pages = "135811",
doi = "10.1016/j.jclepro.2022.135811"
}

Kovačević, A., Marković, D. D., Radoičić, M. B., Šaponjić, Z.,& Radetić, M. M.. (2023). Sustainable non-woven sorbents based on jute post-industrial waste for cleaning of oil spills. in Journal of Cleaner Production, 386, 135811.
https://doi.org/10.1016/j.jclepro.2022.135811

Kovačević A, Marković DD, Radoičić MB, Šaponjić Z, Radetić MM. Sustainable non-woven sorbents based on jute post-industrial waste for cleaning of oil spills. in Journal of Cleaner Production. 2023;386:135811.
doi:10.1016/j.jclepro.2022.135811 .

Kovačević, Aleksandar, Marković, Dragan D., Radoičić, Marija B., Šaponjić, Zoran, Radetić, Maja M., "Sustainable non-woven sorbents based on jute post-industrial waste for cleaning of oil spills" in Journal of Cleaner Production, 386 (2023):135811,
https://doi.org/10.1016/j.jclepro.2022.135811 . .

TY  - CONF
AU  - Milošević, Milica
AU  - Radoičić, Marija
AU  - Ćirić-Marjanović, Gordana
AU  - Spasojević, Jelena
AU  - Vukoje, Ivana
AU  - Radosavljević, Aleksandra
AU  - Šaponjić, Zoran
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/11596
AB  - A  calling  need  for  environmental  protection  is  not  abating  and  high  demands  have  been  set for  the  current  topic  that  deals  with  applied  technologies  for  removal  of  organic  pollutants.  The AOPs  appear  to  be  one  of  the  most  effective  processes,  where  heterogeneous  photocatalysis  using efficient  UV  light-harvesting  TiO2nanocrystals  has  unquestionably  become  one  of  the  most  com-monly used process for dyes degradation treatment. Limited photocatalytic efficiency of TiO2under sunlight  illumination  was  overcame  bycoupling  with  polyaniline  (PANI)  as  notably  investigated conductive polymer. Reducing the level of e-/h+recombination in TiO2and photosensitized proper-ties of PANI was the basis for creation of new functional PANI/TiO2nanocomposites. Such hybrid functional  nanomaterials  consisting  of  conductive  polymers  and  dissimilar  nanocrystals  manifest the  unique  properties,  usually  not  characteristic  of  independent  componentsbut  their  synergistic effect. Series of developed functional nanocomposites based on PANI and colloidal TiO2nanoparti-cles  (NPs)  (TP),  carbonized  PANI  and  colloidal  TiO2NPs  (TPC)  and  carbonized  PANI  and  TiO2nanotubes (NTs) (TTPC) by the efficient and harmless synthesis pathways are presented. Differently shaped  TiO2nanocrystals  are  carefully  prepared  via  sol-gel  and  hydrothermal  synthesis  and  the influence  of  their  size  and  shape  on  the  photocatalytic  efficiency  of  hybrid  nanocomposites  was evaluated. The non-carbonized PANI/TiO2nanocomposites were synthesized by the chemical oxida-tive  polymerization  of  aniline  with  ammonium  peroxydisulfate,  in  the  presence  of  selected  TiO2nanocrystals,  while  the  carbonized  class  was  obtained  in the subsequent  carbonization  process, following  the  polymerization,  in  an  inert  atmosphere  at  650  °C.  The  morphology  and  structureof these nano-based photocatalysts was determined by TEM analysis and Raman spectroscopy. Func-tionality  of  nanocomposites  was  evaluated  following  the  photocatalytic  degradation  processes  of model compoundsMethylene blue and Rhodamine B and enhanced degradation efficiencies in the used dyes were observed
AB  - Aktuelna potreba za zaštitom životne sredine ne jenjava i s tim u vezi postavljeni su visoki zahtevi vezani za tematiku primenjenih tehnologija za uklanjanje organskih zagađujućih supstanci. Ispostavlja se da napredni procesi oksidacije (engl. Advanced oxidation processes, AOPs) predstavljaju jedan od najefikasnijih procesa, među kojima heterogena fotokataliza, bazirana na upotrebi nanokristala TiO2 aktiviranih UV zračenjem, nesumnjivo predstavlja jedan od najčešće korišćenih tretmana za degradaciju organskih boja. Problem ograničene fotokatalitičke efikasnosti TiO2 pod dejstvom sunčevog zračenja može se prevazići formiranjem kompozita sa polianilinom (PANI), čija se uloga bazira na smanjenju rekombinativnih procesa e-/h+, kao i sposobnosti PANI-a da optički aktivira nanokristale TiO2, što je bila osnova za formiranje novih funkcionalnih PANI/TiO2 nanokompozita. Takvi hibridni nanomaterijali bazirani na provodnom polimeru i nanokristalima različitih oblika pokazuju jedinstvena svojstva koja najčešće nisu karakteristika pojedinačnih komponenti, već njihovog sinergističkog dejstva. Efikasnim i ekološki prihvatljivim sintezama razvijena je serija funkcionalnih nanokompozita na bazi PANI-a i koloidnih TiO2 nanočestica (NPs) (TP), karbonizovanog PANI-a i koloidnih TiO2 NPs (TPC) i karbonizovanog PANI-a i TiO2 nanotuba (NTs) (TTPC). Nanokristali TiO2 različitog oblika pažljivo su sintetisani sol-gel i hidrotermalnom metodom i procenjen je uticaj njihove veličine i oblika na fotokatalitičku efikasnost hibridnih nanokompozita. Nekarbonizovani PANI/TiO2 nanokompoziti sintetisani su hemijskom oksidativnom polimerizacijom anilina sa amonijum peroksidisulfatom, u prisustvu odabranih nanokristala TiO2, dok je karbonizovana serija uzoraka dobijena naknadnim procesom karbonizacije, prateći polimerizaciju, u inertnoj atmosferi na 650 °C. Morfologija i struktura sintetisanih fotokatalitički aktivnih sistema ispitana je TEM analizom i Ramanskom spektroskopijom. Funkcionalnost nanokompozita je procenjena prateći procese fotokatalitičke degradacije model-jedinjenja Methylene blue i Rhodamine B i primećena je povećana efikasnost degradacije testiranih organskih boja
PB  - Beograd : Savez mašinskih i elektrotehničkih inženjera i tehničara Srbije (SMEITS) : Društvo za procesnu tehniku
C3  - 36. Međunarodni kongres o procesnoj industriji - PROCESING ′23 : zbornik radova
T1  - Hybrid functional Pani/TiO2 nanocomposites for dyes degradation treatment
T1  - Hibridni funkcionalni Pani/TiO2 nanokompoziti za tretman degradacije organskih boja
SP  - 83
EP  - 89
DO  - 10.24094/ptk.023.083
ER  - 

@conference{
author = "Milošević, Milica and Radoičić, Marija and Ćirić-Marjanović, Gordana and Spasojević, Jelena and Vukoje, Ivana and Radosavljević, Aleksandra and Šaponjić, Zoran",
year = "2023",
abstract = "A  calling  need  for  environmental  protection  is  not  abating  and  high  demands  have  been  set for  the  current  topic  that  deals  with  applied  technologies  for  removal  of  organic  pollutants.  The AOPs  appear  to  be  one  of  the  most  effective  processes,  where  heterogeneous  photocatalysis  using efficient  UV  light-harvesting  TiO2nanocrystals  has  unquestionably  become  one  of  the  most  com-monly used process for dyes degradation treatment. Limited photocatalytic efficiency of TiO2under sunlight  illumination  was  overcame  bycoupling  with  polyaniline  (PANI)  as  notably  investigated conductive polymer. Reducing the level of e-/h+recombination in TiO2and photosensitized proper-ties of PANI was the basis for creation of new functional PANI/TiO2nanocomposites. Such hybrid functional  nanomaterials  consisting  of  conductive  polymers  and  dissimilar  nanocrystals  manifest the  unique  properties,  usually  not  characteristic  of  independent  componentsbut  their  synergistic effect. Series of developed functional nanocomposites based on PANI and colloidal TiO2nanoparti-cles  (NPs)  (TP),  carbonized  PANI  and  colloidal  TiO2NPs  (TPC)  and  carbonized  PANI  and  TiO2nanotubes (NTs) (TTPC) by the efficient and harmless synthesis pathways are presented. Differently shaped  TiO2nanocrystals  are  carefully  prepared  via  sol-gel  and  hydrothermal  synthesis  and  the influence  of  their  size  and  shape  on  the  photocatalytic  efficiency  of  hybrid  nanocomposites  was evaluated. The non-carbonized PANI/TiO2nanocomposites were synthesized by the chemical oxida-tive  polymerization  of  aniline  with  ammonium  peroxydisulfate,  in  the  presence  of  selected  TiO2nanocrystals,  while  the  carbonized  class  was  obtained  in the subsequent  carbonization  process, following  the  polymerization,  in  an  inert  atmosphere  at  650  °C.  The  morphology  and  structureof these nano-based photocatalysts was determined by TEM analysis and Raman spectroscopy. Func-tionality  of  nanocomposites  was  evaluated  following  the  photocatalytic  degradation  processes  of model compoundsMethylene blue and Rhodamine B and enhanced degradation efficiencies in the used dyes were observed, Aktuelna potreba za zaštitom životne sredine ne jenjava i s tim u vezi postavljeni su visoki zahtevi vezani za tematiku primenjenih tehnologija za uklanjanje organskih zagađujućih supstanci. Ispostavlja se da napredni procesi oksidacije (engl. Advanced oxidation processes, AOPs) predstavljaju jedan od najefikasnijih procesa, među kojima heterogena fotokataliza, bazirana na upotrebi nanokristala TiO2 aktiviranih UV zračenjem, nesumnjivo predstavlja jedan od najčešće korišćenih tretmana za degradaciju organskih boja. Problem ograničene fotokatalitičke efikasnosti TiO2 pod dejstvom sunčevog zračenja može se prevazići formiranjem kompozita sa polianilinom (PANI), čija se uloga bazira na smanjenju rekombinativnih procesa e-/h+, kao i sposobnosti PANI-a da optički aktivira nanokristale TiO2, što je bila osnova za formiranje novih funkcionalnih PANI/TiO2 nanokompozita. Takvi hibridni nanomaterijali bazirani na provodnom polimeru i nanokristalima različitih oblika pokazuju jedinstvena svojstva koja najčešće nisu karakteristika pojedinačnih komponenti, već njihovog sinergističkog dejstva. Efikasnim i ekološki prihvatljivim sintezama razvijena je serija funkcionalnih nanokompozita na bazi PANI-a i koloidnih TiO2 nanočestica (NPs) (TP), karbonizovanog PANI-a i koloidnih TiO2 NPs (TPC) i karbonizovanog PANI-a i TiO2 nanotuba (NTs) (TTPC). Nanokristali TiO2 različitog oblika pažljivo su sintetisani sol-gel i hidrotermalnom metodom i procenjen je uticaj njihove veličine i oblika na fotokatalitičku efikasnost hibridnih nanokompozita. Nekarbonizovani PANI/TiO2 nanokompoziti sintetisani su hemijskom oksidativnom polimerizacijom anilina sa amonijum peroksidisulfatom, u prisustvu odabranih nanokristala TiO2, dok je karbonizovana serija uzoraka dobijena naknadnim procesom karbonizacije, prateći polimerizaciju, u inertnoj atmosferi na 650 °C. Morfologija i struktura sintetisanih fotokatalitički aktivnih sistema ispitana je TEM analizom i Ramanskom spektroskopijom. Funkcionalnost nanokompozita je procenjena prateći procese fotokatalitičke degradacije model-jedinjenja Methylene blue i Rhodamine B i primećena je povećana efikasnost degradacije testiranih organskih boja",
publisher = "Beograd : Savez mašinskih i elektrotehničkih inženjera i tehničara Srbije (SMEITS) : Društvo za procesnu tehniku",
journal = "36. Međunarodni kongres o procesnoj industriji - PROCESING ′23 : zbornik radova",
title = "Hybrid functional Pani/TiO2 nanocomposites for dyes degradation treatment, Hibridni funkcionalni Pani/TiO2 nanokompoziti za tretman degradacije organskih boja",
pages = "83-89",
doi = "10.24094/ptk.023.083"
}

Milošević, M., Radoičić, M., Ćirić-Marjanović, G., Spasojević, J., Vukoje, I., Radosavljević, A.,& Šaponjić, Z.. (2023). Hybrid functional Pani/TiO2 nanocomposites for dyes degradation treatment. in 36. Međunarodni kongres o procesnoj industriji - PROCESING ′23 : zbornik radova
Beograd : Savez mašinskih i elektrotehničkih inženjera i tehničara Srbije (SMEITS) : Društvo za procesnu tehniku., 83-89.
https://doi.org/10.24094/ptk.023.083

Milošević M, Radoičić M, Ćirić-Marjanović G, Spasojević J, Vukoje I, Radosavljević A, Šaponjić Z. Hybrid functional Pani/TiO2 nanocomposites for dyes degradation treatment. in 36. Međunarodni kongres o procesnoj industriji - PROCESING ′23 : zbornik radova. 2023;:83-89.
doi:10.24094/ptk.023.083 .

Milošević, Milica, Radoičić, Marija, Ćirić-Marjanović, Gordana, Spasojević, Jelena, Vukoje, Ivana, Radosavljević, Aleksandra, Šaponjić, Zoran, "Hybrid functional Pani/TiO2 nanocomposites for dyes degradation treatment" in 36. Međunarodni kongres o procesnoj industriji - PROCESING ′23 : zbornik radova (2023):83-89,
https://doi.org/10.24094/ptk.023.083 . .

TY  - CONF
AU  - Milošević, Milica
AU  - Radoičić, Marija
AU  - Šaponjić, Zoran
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/12195
C3  - ModTech 2023 : 11th International Conference on Modern Manufacturing Technologies in Industrial Engineering 2023 (hybrid edition) : Book of Abstracts
T1  - Bottom-up creation of multifunctional textile nano-entities using TiO2/Ag nanocrystals
SP  - 41
EP  - 41
UR  - https://hdl.handle.net/21.15107/rcub_vinar_12195
ER  - 

@conference{
author = "Milošević, Milica and Radoičić, Marija and Šaponjić, Zoran",
year = "2023",
journal = "ModTech 2023 : 11th International Conference on Modern Manufacturing Technologies in Industrial Engineering 2023 (hybrid edition) : Book of Abstracts",
title = "Bottom-up creation of multifunctional textile nano-entities using TiO2/Ag nanocrystals",
pages = "41-41",
url = "https://hdl.handle.net/21.15107/rcub_vinar_12195"
}

Milošević, M., Radoičić, M.,& Šaponjić, Z.. (2023). Bottom-up creation of multifunctional textile nano-entities using TiO2/Ag nanocrystals. in ModTech 2023 : 11th International Conference on Modern Manufacturing Technologies in Industrial Engineering 2023 (hybrid edition) : Book of Abstracts, 41-41.
https://hdl.handle.net/21.15107/rcub_vinar_12195

Milošević M, Radoičić M, Šaponjić Z. Bottom-up creation of multifunctional textile nano-entities using TiO2/Ag nanocrystals. in ModTech 2023 : 11th International Conference on Modern Manufacturing Technologies in Industrial Engineering 2023 (hybrid edition) : Book of Abstracts. 2023;:41-41.
https://hdl.handle.net/21.15107/rcub_vinar_12195 .

Milošević, Milica, Radoičić, Marija, Šaponjić, Zoran, "Bottom-up creation of multifunctional textile nano-entities using TiO2/Ag nanocrystals" in ModTech 2023 : 11th International Conference on Modern Manufacturing Technologies in Industrial Engineering 2023 (hybrid edition) : Book of Abstracts (2023):41-41,
https://hdl.handle.net/21.15107/rcub_vinar_12195 .

TY  - CONF
AU  - Milošević, Milica
AU  - Radoičić, Marija
AU  - Ćirić-Marjanović, Gordana
AU  - Spasojević, Jelena
AU  - Vukoje, Ivana
AU  - Radosavljević, Aleksandra
AU  - Šaponjić, Zoran
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/12197
AB  - Differently-shaped TiO2 photo-nanocatalysts play a principal role in the remediation of environmental and pollution challenges considering their proven potential for treating organic contaminants in wastewaters [1]. However, increasing the photoactivity of TiO2 i.e. its optical response from UV into visible region is a constant challenge of many ongoing researchers [2]. An proceed towards this demand may be the creation of hybrid functional nanocomposites by coating the TiO2 nanocrystals (NCs) with electronically coupled conductive polymers (e.g., polyaniline (PANI), polypyrrole, etc.) [3]. By the carbonization process of mentioned conductive polymers at high temperatures, obtained final material possess carbon-like structure which impart additional properties [4]. Thus, the evolution of carbonized PANI (CPANI)- coated TiO2 NCs opens up the possibility for tailoring the photocatalyst with distinctive properties. This study implies development of new nanocomposites based on CPANI and colloidal TiO2 nanoparticles (NPs) (TPC) and CPANI and TiO2 nanotubes (NTs) (TTPC). Sol- gel and hydrothermal synthesis paths were used to obtain TiO2 NCs. The influence of their size and shape on the photocatalytic activity of formed carbonized nanocomposites was estimated. TPC and TTPC nanocomposites were synthesized according to the steps: 1) the non-carbonized PANI/TiO2 class was firstly prepared by the chemical oxidative polymerization of aniline with ammonium peroxydisulfate in the presence of TiO2 NPs or NTs and 2) the subsequent carbonization process was applied (650 °C). Developed hybrid nanocomposites were morphologically and structurally characterized by TEM measurements and Raman spectroscopy, while their functionality was estimated through the photocatalytic degradation processes of Methylene blue and Rhodamine B. All TPC and TTPC nanocomposites showed excellent photocatalytic properties, however, shape-depending of used TiO2 NCs.
PB  - Szeged : University of Szeged
C3  - 29th International Symposium on Analytical and Environmental Problems : Proceedings
T1  - Shape-dependent carbonized PANI-coated TiO2 nanocrystals and its use in the decomposition of organic pollutants
SP  - 225
EP  - 225
UR  - https://hdl.handle.net/21.15107/rcub_vinar_12197
ER  - 

@conference{
author = "Milošević, Milica and Radoičić, Marija and Ćirić-Marjanović, Gordana and Spasojević, Jelena and Vukoje, Ivana and Radosavljević, Aleksandra and Šaponjić, Zoran",
year = "2023",
abstract = "Differently-shaped TiO2 photo-nanocatalysts play a principal role in the remediation of environmental and pollution challenges considering their proven potential for treating organic contaminants in wastewaters [1]. However, increasing the photoactivity of TiO2 i.e. its optical response from UV into visible region is a constant challenge of many ongoing researchers [2]. An proceed towards this demand may be the creation of hybrid functional nanocomposites by coating the TiO2 nanocrystals (NCs) with electronically coupled conductive polymers (e.g., polyaniline (PANI), polypyrrole, etc.) [3]. By the carbonization process of mentioned conductive polymers at high temperatures, obtained final material possess carbon-like structure which impart additional properties [4]. Thus, the evolution of carbonized PANI (CPANI)- coated TiO2 NCs opens up the possibility for tailoring the photocatalyst with distinctive properties. This study implies development of new nanocomposites based on CPANI and colloidal TiO2 nanoparticles (NPs) (TPC) and CPANI and TiO2 nanotubes (NTs) (TTPC). Sol- gel and hydrothermal synthesis paths were used to obtain TiO2 NCs. The influence of their size and shape on the photocatalytic activity of formed carbonized nanocomposites was estimated. TPC and TTPC nanocomposites were synthesized according to the steps: 1) the non-carbonized PANI/TiO2 class was firstly prepared by the chemical oxidative polymerization of aniline with ammonium peroxydisulfate in the presence of TiO2 NPs or NTs and 2) the subsequent carbonization process was applied (650 °C). Developed hybrid nanocomposites were morphologically and structurally characterized by TEM measurements and Raman spectroscopy, while their functionality was estimated through the photocatalytic degradation processes of Methylene blue and Rhodamine B. All TPC and TTPC nanocomposites showed excellent photocatalytic properties, however, shape-depending of used TiO2 NCs.",
publisher = "Szeged : University of Szeged",
journal = "29th International Symposium on Analytical and Environmental Problems : Proceedings",
title = "Shape-dependent carbonized PANI-coated TiO2 nanocrystals and its use in the decomposition of organic pollutants",
pages = "225-225",
url = "https://hdl.handle.net/21.15107/rcub_vinar_12197"
}

Milošević, M., Radoičić, M., Ćirić-Marjanović, G., Spasojević, J., Vukoje, I., Radosavljević, A.,& Šaponjić, Z.. (2023). Shape-dependent carbonized PANI-coated TiO2 nanocrystals and its use in the decomposition of organic pollutants. in 29th International Symposium on Analytical and Environmental Problems : Proceedings
Szeged : University of Szeged., 225-225.
https://hdl.handle.net/21.15107/rcub_vinar_12197

Milošević M, Radoičić M, Ćirić-Marjanović G, Spasojević J, Vukoje I, Radosavljević A, Šaponjić Z. Shape-dependent carbonized PANI-coated TiO2 nanocrystals and its use in the decomposition of organic pollutants. in 29th International Symposium on Analytical and Environmental Problems : Proceedings. 2023;:225-225.
https://hdl.handle.net/21.15107/rcub_vinar_12197 .

Milošević, Milica, Radoičić, Marija, Ćirić-Marjanović, Gordana, Spasojević, Jelena, Vukoje, Ivana, Radosavljević, Aleksandra, Šaponjić, Zoran, "Shape-dependent carbonized PANI-coated TiO2 nanocrystals and its use in the decomposition of organic pollutants" in 29th International Symposium on Analytical and Environmental Problems : Proceedings (2023):225-225,
https://hdl.handle.net/21.15107/rcub_vinar_12197 .

TY  - CONF
AU  - Gajić, Brankica
AU  - Ćirić-Marjanović, Gordana
AU  - Šaponjić, Zoran
AU  - Radoičić, Marija
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/12291
AB  - Polyaniline (PANI) is a promising conducting polymer for surface modification and sensitizing of TiO2 to achieve extended photoresponse to visible light and increased photocatalytic efficiency [1]. Reducing the level of e-/h+ recombination in TiO2 and photosensitized properties of PANI was the basis for creation of new functional PANI/TiO2 nanocomposites. Carbonization process additionally contribute improving photoactivity of TiO2 due to formation of new structures. Namely, after carbonization process of PANI component, graphene-like structures are formed [2]. On the other hand, temperature treatment during carbonization caused appearance of rutile beside anatase crystal structure of TiO2, so combination of mentioned crystal phases induced better photocatalytic activity. In this study, we report the synthesis of a carbonized PANI/TiO2composite with different initial weight ratios of PANI, which was subsequently employed for photocatalytic degradation of methylene blue (MB), Rhodamine B (RB) and Acid Orange 7 (AO7) under white-light irradiation. Molecular and crystal structure, morphology, and photocatalytic response of the synthesized nanocomposite were characterized by Raman spectroscopy, XRD measurements, field-emission scanning electron microscopy, and UV visible spectroscopy, respectively. Obtained results showed significant enhance of photocatalytic properties of synthesized nanocomposites in comparison to neat titania nanotubes.
PB  - Belgrade : Serbian Chemical Society and Serbian Young Chemists' Club
C3  - 9th Conference of Young Chemists of Serbia : Book of abstracts
T1  - Photocatalytic properties of carbonized nanocomposites based on polyniline and titania nanotubes
SP  - 81
EP  - 81
UR  - https://hdl.handle.net/21.15107/rcub_vinar_12291
ER  - 

@conference{
author = "Gajić, Brankica and Ćirić-Marjanović, Gordana and Šaponjić, Zoran and Radoičić, Marija",
year = "2023",
abstract = "Polyaniline (PANI) is a promising conducting polymer for surface modification and sensitizing of TiO2 to achieve extended photoresponse to visible light and increased photocatalytic efficiency [1]. Reducing the level of e-/h+ recombination in TiO2 and photosensitized properties of PANI was the basis for creation of new functional PANI/TiO2 nanocomposites. Carbonization process additionally contribute improving photoactivity of TiO2 due to formation of new structures. Namely, after carbonization process of PANI component, graphene-like structures are formed [2]. On the other hand, temperature treatment during carbonization caused appearance of rutile beside anatase crystal structure of TiO2, so combination of mentioned crystal phases induced better photocatalytic activity. In this study, we report the synthesis of a carbonized PANI/TiO2composite with different initial weight ratios of PANI, which was subsequently employed for photocatalytic degradation of methylene blue (MB), Rhodamine B (RB) and Acid Orange 7 (AO7) under white-light irradiation. Molecular and crystal structure, morphology, and photocatalytic response of the synthesized nanocomposite were characterized by Raman spectroscopy, XRD measurements, field-emission scanning electron microscopy, and UV visible spectroscopy, respectively. Obtained results showed significant enhance of photocatalytic properties of synthesized nanocomposites in comparison to neat titania nanotubes.",
publisher = "Belgrade : Serbian Chemical Society and Serbian Young Chemists' Club",
journal = "9th Conference of Young Chemists of Serbia : Book of abstracts",
title = "Photocatalytic properties of carbonized nanocomposites based on polyniline and titania nanotubes",
pages = "81-81",
url = "https://hdl.handle.net/21.15107/rcub_vinar_12291"
}

Gajić, B., Ćirić-Marjanović, G., Šaponjić, Z.,& Radoičić, M.. (2023). Photocatalytic properties of carbonized nanocomposites based on polyniline and titania nanotubes. in 9th Conference of Young Chemists of Serbia : Book of abstracts
Belgrade : Serbian Chemical Society and Serbian Young Chemists' Club., 81-81.
https://hdl.handle.net/21.15107/rcub_vinar_12291

Gajić B, Ćirić-Marjanović G, Šaponjić Z, Radoičić M. Photocatalytic properties of carbonized nanocomposites based on polyniline and titania nanotubes. in 9th Conference of Young Chemists of Serbia : Book of abstracts. 2023;:81-81.
https://hdl.handle.net/21.15107/rcub_vinar_12291 .

Gajić, Brankica, Ćirić-Marjanović, Gordana, Šaponjić, Zoran, Radoičić, Marija, "Photocatalytic properties of carbonized nanocomposites based on polyniline and titania nanotubes" in 9th Conference of Young Chemists of Serbia : Book of abstracts (2023):81-81,
https://hdl.handle.net/21.15107/rcub_vinar_12291 .

TY  - JOUR
AU  - Stojanović, Srna R.
AU  - Vranješ, Mila
AU  - Šaponjić, Zoran
AU  - Rac, Vladislav
AU  - Rakić, Vesna M.
AU  - Ignjatović, Ljubiša M.
AU  - Damjanović-Vasilić, Ljiljana S.
PY  - 2022
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10343
AB  - Removal of the β-blocker atenolol from an aqueous solution was studied using TiO2/zeolites, prepared by a simple and cost-effective solid-state dispersion method. Synthetic zeolites 13X and ZSM-5 (Si/Al = 40) and natural zeolite clinoptilolite were used as one component of the hybrid materials, whereas TiO2 nanocrystals obtained from TiO2 nanotubes and P25 TiO2 nanoparticles were used as the other. The synthesized materials were characterized by X-ray powder diffraction, transmission electron microscopy, Fourier transformed infrared spectroscopy, ultraviolet–visible diffuse reflectance spectroscopy and scanning electron microscopy with energy-dispersive spectroscopy. The photocatalytic activity for the degradation of atenolol was investigated under simulated solar light. Additionally, the effect of initial pH on atenolol removal and the reusability of prepared catalysts were tested. The best loading of TiO2 was 20 wt% over all investigated zeolites. The degradation of atenolol followed the pseudo-first-order kinetics. The photocatalytic degradation of atenolol after 70 min of irradiation was ~ 50% for TiO2/13X materials, ~ 45% for clinoptilolite combined with P25 TiO2 and ~ 57% for clinoptilolite combined with TiO2 nanocrystals obtained from TiO2 nanotubes. The results showed the highest removal efficiency after 70 min of irradiation for ZSM-5 combined with P25 TiO2 (~ 94%), followed by ZSM-5 combined with TiO2 nanocrystals obtained from TiO2 nanotubes (~ 88%) at near-neutral pH (~ 6.5). The total removal of atenolol from an aqueous solution for TiO2/ZSM-5 materials resulted from two processes: adsorption and photocatalytic degradation. The TiO2/ZSM-5 photocatalysts can be easily recovered and reused as their activity was preserved after four cycles.
T2  - International Journal of Environmental Science and Technology
T1  - Photocatalytic performance of TiO2/zeolites under simulated solar light for removal of atenolol from aqueous solution
DO  - 10.1007/s13762-022-04305-6
ER  - 

@article{
author = "Stojanović, Srna R. and Vranješ, Mila and Šaponjić, Zoran and Rac, Vladislav and Rakić, Vesna M. and Ignjatović, Ljubiša M. and Damjanović-Vasilić, Ljiljana S.",
year = "2022",
abstract = "Removal of the β-blocker atenolol from an aqueous solution was studied using TiO2/zeolites, prepared by a simple and cost-effective solid-state dispersion method. Synthetic zeolites 13X and ZSM-5 (Si/Al = 40) and natural zeolite clinoptilolite were used as one component of the hybrid materials, whereas TiO2 nanocrystals obtained from TiO2 nanotubes and P25 TiO2 nanoparticles were used as the other. The synthesized materials were characterized by X-ray powder diffraction, transmission electron microscopy, Fourier transformed infrared spectroscopy, ultraviolet–visible diffuse reflectance spectroscopy and scanning electron microscopy with energy-dispersive spectroscopy. The photocatalytic activity for the degradation of atenolol was investigated under simulated solar light. Additionally, the effect of initial pH on atenolol removal and the reusability of prepared catalysts were tested. The best loading of TiO2 was 20 wt% over all investigated zeolites. The degradation of atenolol followed the pseudo-first-order kinetics. The photocatalytic degradation of atenolol after 70 min of irradiation was ~ 50% for TiO2/13X materials, ~ 45% for clinoptilolite combined with P25 TiO2 and ~ 57% for clinoptilolite combined with TiO2 nanocrystals obtained from TiO2 nanotubes. The results showed the highest removal efficiency after 70 min of irradiation for ZSM-5 combined with P25 TiO2 (~ 94%), followed by ZSM-5 combined with TiO2 nanocrystals obtained from TiO2 nanotubes (~ 88%) at near-neutral pH (~ 6.5). The total removal of atenolol from an aqueous solution for TiO2/ZSM-5 materials resulted from two processes: adsorption and photocatalytic degradation. The TiO2/ZSM-5 photocatalysts can be easily recovered and reused as their activity was preserved after four cycles.",
journal = "International Journal of Environmental Science and Technology",
title = "Photocatalytic performance of TiO2/zeolites under simulated solar light for removal of atenolol from aqueous solution",
doi = "10.1007/s13762-022-04305-6"
}

Stojanović, S. R., Vranješ, M., Šaponjić, Z., Rac, V., Rakić, V. M., Ignjatović, L. M.,& Damjanović-Vasilić, L. S.. (2022). Photocatalytic performance of TiO2/zeolites under simulated solar light for removal of atenolol from aqueous solution. in International Journal of Environmental Science and Technology.
https://doi.org/10.1007/s13762-022-04305-6

Stojanović SR, Vranješ M, Šaponjić Z, Rac V, Rakić VM, Ignjatović LM, Damjanović-Vasilić LS. Photocatalytic performance of TiO2/zeolites under simulated solar light for removal of atenolol from aqueous solution. in International Journal of Environmental Science and Technology. 2022;.
doi:10.1007/s13762-022-04305-6 .

Stojanović, Srna R., Vranješ, Mila, Šaponjić, Zoran, Rac, Vladislav, Rakić, Vesna M., Ignjatović, Ljubiša M., Damjanović-Vasilić, Ljiljana S., "Photocatalytic performance of TiO2/zeolites under simulated solar light for removal of atenolol from aqueous solution" in International Journal of Environmental Science and Technology (2022),
https://doi.org/10.1007/s13762-022-04305-6 . .

TY  - CONF
AU  - Milošević, Milica
AU  - Radoičić, Marija
AU  - Spasojević, Jelena
AU  - Šaponjić, Zoran
PY  - 2022
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/12194
C3  - ICCCI 2022 : 7th International Conference on the Characterization and Control of Interfaces for High Quality Advanced Materials and the 57th Summer Symposium on Powder Technology 2022 : Program and Abstracts
T1  - Novel TiO2/Ag/TiO2 cotton-based nanocomposites for wastewater treatment
SP  - 106
EP  - 106
UR  - https://hdl.handle.net/21.15107/rcub_vinar_12194
ER  - 

@conference{
author = "Milošević, Milica and Radoičić, Marija and Spasojević, Jelena and Šaponjić, Zoran",
year = "2022",
journal = "ICCCI 2022 : 7th International Conference on the Characterization and Control of Interfaces for High Quality Advanced Materials and the 57th Summer Symposium on Powder Technology 2022 : Program and Abstracts",
title = "Novel TiO2/Ag/TiO2 cotton-based nanocomposites for wastewater treatment",
pages = "106-106",
url = "https://hdl.handle.net/21.15107/rcub_vinar_12194"
}

Milošević, M., Radoičić, M., Spasojević, J.,& Šaponjić, Z.. (2022). Novel TiO2/Ag/TiO2 cotton-based nanocomposites for wastewater treatment. in ICCCI 2022 : 7th International Conference on the Characterization and Control of Interfaces for High Quality Advanced Materials and the 57th Summer Symposium on Powder Technology 2022 : Program and Abstracts, 106-106.
https://hdl.handle.net/21.15107/rcub_vinar_12194

Milošević M, Radoičić M, Spasojević J, Šaponjić Z. Novel TiO2/Ag/TiO2 cotton-based nanocomposites for wastewater treatment. in ICCCI 2022 : 7th International Conference on the Characterization and Control of Interfaces for High Quality Advanced Materials and the 57th Summer Symposium on Powder Technology 2022 : Program and Abstracts. 2022;:106-106.
https://hdl.handle.net/21.15107/rcub_vinar_12194 .

Milošević, Milica, Radoičić, Marija, Spasojević, Jelena, Šaponjić, Zoran, "Novel TiO2/Ag/TiO2 cotton-based nanocomposites for wastewater treatment" in ICCCI 2022 : 7th International Conference on the Characterization and Control of Interfaces for High Quality Advanced Materials and the 57th Summer Symposium on Powder Technology 2022 : Program and Abstracts (2022):106-106,
https://hdl.handle.net/21.15107/rcub_vinar_12194 .

TY  - JOUR
AU  - Radoičić, Marija
AU  - Ćirić-Marjanović, Gordana
AU  - Miličević, Dejan
AU  - Suljovrujić, Edin
AU  - Milošević, Milica
AU  - Kuljanin Jakovljević, Jadranka
AU  - Šaponjić, Zoran
PY  - 2021
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/11893
AB  - Structural, conductive and dielectric properties of hybrid Polypyrrole (PPy)-TiO2 nanocomposite-coated polyamide fabric (PA-PPy/TiO2) synthesized by in-situ oxidative polymerization of pyrrole on the surface of polyamide in the presence of colloidal TiO2 NPs (d ~ 4.5 nm) have been studied. Raman spectra confirmed salt form of PPy in both neat PPy and PPy/TiO2-coated PA fabric and indicated its complete coverage. SEM/EDX analysis confirmed presence of TiO2 NPs and changes in granular structure of PPy deposited on the surface of PA fiber depending on the amount of TiO2 NPs. The PA-PPy/TiO2 nanocomposite sample with lowest content of TiO2 NPs (6.79 At.% Ti) showed highest conductivity (~10−6 S/cm) and dissipation factor (tan δ) in the entire frequency range. The lowest amount of TiO2 NPs in the PA-PPy/TiO2 nanocomposite induced two to four orders of magnitude higher tan δ value, compared to neat PPy covered PA fabric, depending on the frequency range. Frequency dependence of real (ϵ′) and imaginary part (ϵ″) of the complex permittivity for neat PA and PPy/TiO2-coated PA fabrics follow the trend of changes in dissipation factor for the same TiO2 NPs concentrations. The presence of TiO2 NPs could be exploited for tuning the conductive and dielectric properties of a conductive layer.
T2  - Composite Interfaces
T1  - Fine-tuning of conductive and dielectric properties of polypyrrole/TiO                    2                    nanocomposite-coated polyamide fabric
VL  - 28
IS  - 8
SP  - 795
EP  - 808
DO  - 10.1080/09276440.2020.1805219
ER  - 

@article{
author = "Radoičić, Marija and Ćirić-Marjanović, Gordana and Miličević, Dejan and Suljovrujić, Edin and Milošević, Milica and Kuljanin Jakovljević, Jadranka and Šaponjić, Zoran",
year = "2021",
abstract = "Structural, conductive and dielectric properties of hybrid Polypyrrole (PPy)-TiO2 nanocomposite-coated polyamide fabric (PA-PPy/TiO2) synthesized by in-situ oxidative polymerization of pyrrole on the surface of polyamide in the presence of colloidal TiO2 NPs (d ~ 4.5 nm) have been studied. Raman spectra confirmed salt form of PPy in both neat PPy and PPy/TiO2-coated PA fabric and indicated its complete coverage. SEM/EDX analysis confirmed presence of TiO2 NPs and changes in granular structure of PPy deposited on the surface of PA fiber depending on the amount of TiO2 NPs. The PA-PPy/TiO2 nanocomposite sample with lowest content of TiO2 NPs (6.79 At.% Ti) showed highest conductivity (~10−6 S/cm) and dissipation factor (tan δ) in the entire frequency range. The lowest amount of TiO2 NPs in the PA-PPy/TiO2 nanocomposite induced two to four orders of magnitude higher tan δ value, compared to neat PPy covered PA fabric, depending on the frequency range. Frequency dependence of real (ϵ′) and imaginary part (ϵ″) of the complex permittivity for neat PA and PPy/TiO2-coated PA fabrics follow the trend of changes in dissipation factor for the same TiO2 NPs concentrations. The presence of TiO2 NPs could be exploited for tuning the conductive and dielectric properties of a conductive layer.",
journal = "Composite Interfaces",
title = "Fine-tuning of conductive and dielectric properties of polypyrrole/TiO                    2                    nanocomposite-coated polyamide fabric",
volume = "28",
number = "8",
pages = "795-808",
doi = "10.1080/09276440.2020.1805219"
}

Radoičić, M., Ćirić-Marjanović, G., Miličević, D., Suljovrujić, E., Milošević, M., Kuljanin Jakovljević, J.,& Šaponjić, Z.. (2021). Fine-tuning of conductive and dielectric properties of polypyrrole/TiO                    2                    nanocomposite-coated polyamide fabric. in Composite Interfaces, 28(8), 795-808.
https://doi.org/10.1080/09276440.2020.1805219

Radoičić M, Ćirić-Marjanović G, Miličević D, Suljovrujić E, Milošević M, Kuljanin Jakovljević J, Šaponjić Z. Fine-tuning of conductive and dielectric properties of polypyrrole/TiO                    2                    nanocomposite-coated polyamide fabric. in Composite Interfaces. 2021;28(8):795-808.
doi:10.1080/09276440.2020.1805219 .

Radoičić, Marija, Ćirić-Marjanović, Gordana, Miličević, Dejan, Suljovrujić, Edin, Milošević, Milica, Kuljanin Jakovljević, Jadranka, Šaponjić, Zoran, "Fine-tuning of conductive and dielectric properties of polypyrrole/TiO                    2                    nanocomposite-coated polyamide fabric" in Composite Interfaces, 28, no. 8 (2021):795-808,
https://doi.org/10.1080/09276440.2020.1805219 . .

TY  - JOUR
AU  - Matijević, Milica
AU  - Nakarada, Đura
AU  - Liang, Xinyue
AU  - Korićanac, Lela
AU  - Rajsiglova, Lenka
AU  - Vannucci, Luca
AU  - Nešić, Maja D.
AU  - Vranješ, Mila
AU  - Mojović, Miloš D.
AU  - Mi, Lan
AU  - Estrela-Lopis, Irina
AU  - Böttner, Julia
AU  - Šaponjić, Zoran
AU  - Petković, Marijana
AU  - Stepić, Milutin
PY  - 2020
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/9058
AB  - TiO2 prolatenanospheroids (PNSs) may be photosensitizers (PSs), which act by catalyzation of hydroxyl radical (∙OH) formation upon light illumination. ∙OH might, in turn, contribute to killing of cancer cells. On the other hand, there is great concern about toxicity in the dark of TiO2 nanoparticles in general. In this work, we have investigated the biocompatibility of TiO2 PNSs of the anatase crystal form (length between 100 and 300 nm and width 50 nm) in the dark with immune cells and light-induced cytotoxicity on several cancer cell lines. The effects of the treatment of different cell lines with several concentrations of TiO2 PNSs suspensions showed the specifics of cells’ viability and the intracellular localization. The results of in vitro studies obtained by cytotoxicity assays adjusted to individual cell lines’ metabolism point towards the biocompatibility of TiO2 PNSs at low and moderate concentrations in the dark, which neither kill the cells, nor induce activation of the immune system cells. Laser scanning confocal microscopy revealed that PNSs are taken up by cells, and insight into the intracellular distribution was obtained in this study.
T2  - Journal of Nanoparticle Research
T1  - Biocompatibility of TiO2 prolate nanospheroids as a potential photosenzitizer in therapy of cancer
VL  - 22
IS  - 7
SP  - 175
DO  - 10.1007/s11051-020-04899-3
ER  - 

@article{
author = "Matijević, Milica and Nakarada, Đura and Liang, Xinyue and Korićanac, Lela and Rajsiglova, Lenka and Vannucci, Luca and Nešić, Maja D. and Vranješ, Mila and Mojović, Miloš D. and Mi, Lan and Estrela-Lopis, Irina and Böttner, Julia and Šaponjić, Zoran and Petković, Marijana and Stepić, Milutin",
year = "2020",
abstract = "TiO2 prolatenanospheroids (PNSs) may be photosensitizers (PSs), which act by catalyzation of hydroxyl radical (∙OH) formation upon light illumination. ∙OH might, in turn, contribute to killing of cancer cells. On the other hand, there is great concern about toxicity in the dark of TiO2 nanoparticles in general. In this work, we have investigated the biocompatibility of TiO2 PNSs of the anatase crystal form (length between 100 and 300 nm and width 50 nm) in the dark with immune cells and light-induced cytotoxicity on several cancer cell lines. The effects of the treatment of different cell lines with several concentrations of TiO2 PNSs suspensions showed the specifics of cells’ viability and the intracellular localization. The results of in vitro studies obtained by cytotoxicity assays adjusted to individual cell lines’ metabolism point towards the biocompatibility of TiO2 PNSs at low and moderate concentrations in the dark, which neither kill the cells, nor induce activation of the immune system cells. Laser scanning confocal microscopy revealed that PNSs are taken up by cells, and insight into the intracellular distribution was obtained in this study.",
journal = "Journal of Nanoparticle Research",
title = "Biocompatibility of TiO2 prolate nanospheroids as a potential photosenzitizer in therapy of cancer",
volume = "22",
number = "7",
pages = "175",
doi = "10.1007/s11051-020-04899-3"
}

Matijević, M., Nakarada, Đ., Liang, X., Korićanac, L., Rajsiglova, L., Vannucci, L., Nešić, M. D., Vranješ, M., Mojović, M. D., Mi, L., Estrela-Lopis, I., Böttner, J., Šaponjić, Z., Petković, M.,& Stepić, M.. (2020). Biocompatibility of TiO2 prolate nanospheroids as a potential photosenzitizer in therapy of cancer. in Journal of Nanoparticle Research, 22(7), 175.
https://doi.org/10.1007/s11051-020-04899-3

Matijević M, Nakarada Đ, Liang X, Korićanac L, Rajsiglova L, Vannucci L, Nešić MD, Vranješ M, Mojović MD, Mi L, Estrela-Lopis I, Böttner J, Šaponjić Z, Petković M, Stepić M. Biocompatibility of TiO2 prolate nanospheroids as a potential photosenzitizer in therapy of cancer. in Journal of Nanoparticle Research. 2020;22(7):175.
doi:10.1007/s11051-020-04899-3 .

Matijević, Milica, Nakarada, Đura, Liang, Xinyue, Korićanac, Lela, Rajsiglova, Lenka, Vannucci, Luca, Nešić, Maja D., Vranješ, Mila, Mojović, Miloš D., Mi, Lan, Estrela-Lopis, Irina, Böttner, Julia, Šaponjić, Zoran, Petković, Marijana, Stepić, Milutin, "Biocompatibility of TiO2 prolate nanospheroids as a potential photosenzitizer in therapy of cancer" in Journal of Nanoparticle Research, 22, no. 7 (2020):175,
https://doi.org/10.1007/s11051-020-04899-3 . .

TY  - JOUR
AU  - Stojanović, Goran M.
AU  - Radetić, Maja M.
AU  - Šaponjić, Zoran
AU  - Radoičić, Marija B.
AU  - Radovanović, Milan R.
AU  - Popović, Željko V.
AU  - Vukmirović, Saša N.
PY  - 2020
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/9067
AB  - This work presents a new multilayered microfluidic platform, manufactured using a rapid and cost-effective xurography technique, for the detection of drug concentrations in sweat. Textile fabrics made of cotton and polyester were used as a component of the platform, and they were positioned in the middle of the microfluidic device. In order to obtain a highly conductive textile, the fabrics were in situ coated with different amounts of polyaniline and titanium dioxide nanocomposite. This portable microfluidic platform comprises at least three layers of optically transparent and flexible PVC foils which were stacked one on top of the other. Electrical contacts were provided from the edge of the textile material when a microfluidic variable resistor was actually created. The platform was tested in plain artificial sweat and in artificial sweat with a dissolved cytostatic test drug, cyclophosphamide, of different concentrations. The proposed microfluidic device decreased in resistance when the sweat was applied. In addition, it could successfully detect different concentrations of cytostatic medication in the sweat, which could make it a very useful tool for simple, reliable, and fast diagnostics.
T2  - Applied Sciences
T1  - A Textile-Based Microfluidic Platform for the Detection of Cytostatic Drug Concentration in Sweat Samples
VL  - 10
IS  - 12
SP  - 4392
DO  - 10.3390/app10124392
ER  - 

@article{
author = "Stojanović, Goran M. and Radetić, Maja M. and Šaponjić, Zoran and Radoičić, Marija B. and Radovanović, Milan R. and Popović, Željko V. and Vukmirović, Saša N.",
year = "2020",
abstract = "This work presents a new multilayered microfluidic platform, manufactured using a rapid and cost-effective xurography technique, for the detection of drug concentrations in sweat. Textile fabrics made of cotton and polyester were used as a component of the platform, and they were positioned in the middle of the microfluidic device. In order to obtain a highly conductive textile, the fabrics were in situ coated with different amounts of polyaniline and titanium dioxide nanocomposite. This portable microfluidic platform comprises at least three layers of optically transparent and flexible PVC foils which were stacked one on top of the other. Electrical contacts were provided from the edge of the textile material when a microfluidic variable resistor was actually created. The platform was tested in plain artificial sweat and in artificial sweat with a dissolved cytostatic test drug, cyclophosphamide, of different concentrations. The proposed microfluidic device decreased in resistance when the sweat was applied. In addition, it could successfully detect different concentrations of cytostatic medication in the sweat, which could make it a very useful tool for simple, reliable, and fast diagnostics.",
journal = "Applied Sciences",
title = "A Textile-Based Microfluidic Platform for the Detection of Cytostatic Drug Concentration in Sweat Samples",
volume = "10",
number = "12",
pages = "4392",
doi = "10.3390/app10124392"
}

Stojanović, G. M., Radetić, M. M., Šaponjić, Z., Radoičić, M. B., Radovanović, M. R., Popović, Ž. V.,& Vukmirović, S. N.. (2020). A Textile-Based Microfluidic Platform for the Detection of Cytostatic Drug Concentration in Sweat Samples. in Applied Sciences, 10(12), 4392.
https://doi.org/10.3390/app10124392

Stojanović GM, Radetić MM, Šaponjić Z, Radoičić MB, Radovanović MR, Popović ŽV, Vukmirović SN. A Textile-Based Microfluidic Platform for the Detection of Cytostatic Drug Concentration in Sweat Samples. in Applied Sciences. 2020;10(12):4392.
doi:10.3390/app10124392 .

Stojanović, Goran M., Radetić, Maja M., Šaponjić, Zoran, Radoičić, Marija B., Radovanović, Milan R., Popović, Željko V., Vukmirović, Saša N., "A Textile-Based Microfluidic Platform for the Detection of Cytostatic Drug Concentration in Sweat Samples" in Applied Sciences, 10, no. 12 (2020):4392,
https://doi.org/10.3390/app10124392 . .

TY  - CHAP
AU  - Radoičić, Marija
AU  - Vranješ, Mila
AU  - Kuljanin-Jakovljević, Jadranka
AU  - Ćirić-Marjanović, Gordana
AU  - Šaponjić, Zoran
PY  - 2020
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/12272
AB  - This research paper focuses on doped TiO2  nanocrystals of different shape, size and structures, in addition to nanocomposites consisting of TiO2  nanocrystals and conductive polymers (Polyaniline (PANI)). The primary objective of this research paper is to ensure understanding of the influence of size, shape, structure and doping level on optical and magnetic properties of TiO2  nanoparticles, as well as the interaction between nanoparticles and PANI due to the creation of desired photocatalytic properties of nanocomposites. The doping of TiO2  nanocrystals with rare earth ions opens up the possibility of controlling their optical properties. The Sm3+ doped TiO2  faceted nanocrystals exhibited red photoluminescence, associated with 4 G5/2-6 HJ  (J=5/2, 7/2 and 9/2) f–f transitions of Sm3+ in the 4f5  configuration, after band-to-band excitation, confirming the accomplishment of energy transfers. The Ni2+ doped TiO2  nanocrystals enabled the synthesis of optically transparent nanostructured films that showed room-temperature ferromagnetism with almost closed loop (HC ~ 150-200 Oe) and saturation magnetization in the range of 10-3-5x10-2 μB/Ni depending on dopant concentration. Ni2+ ions that substitute core Ti atoms were found to participate in the light excitation processes, too. The improvement of photocatalytic efficiency of TiO2  nanocrystals by surface modification with carbonized form of PANI was tested in degradation processes of Rhodamine B and Methylene blue. The carbonized PANI/TiO2  nanocomposites showed significantly higher photocatalytic efficacy compared to the bare TiO2 and the non-carbonized PANI/TiO2  nanocomposites. Their photocatalytic activity is influenced by their surface and crystalline structures, absorption coefficient in the visible part of the spectrum, high mobility of charge carriers and finally by the molecular structures of the organic dyes used.
AB  - Испитиване су допиране и недопиране наночестице титан (IV) оксида (ТiО2 ), великог енергијског процепа, различитих облика (сферични, тубуларни, штапићасти (елипсоидни)), величина кристалних структура, као и хибридни материјали-нанокомпозити на бази проводног полимера (полианилин, ПАНИ) и наночестица TiO2 . Испитивања утицаја величине, облика, структуре и нивоа допираности наночестица ТiО2  на њихове оптичке, магнетне и фотокаталитичке особине, као и разумевање интеракције наночестица и полимерне матрице (ПАНИ) у циљу креирања нанокомпозита одговарајућих фотокаталитичких својстава представљају главне правце овог истраживања. Обзиром на структуру енергетског процепа наночестица TiO2 , допирање јонима ретких земаља отвара могућност за контролу њихових оптичких карактеристика. Нанокристали TiO2  допирани јонима Sm3+ показују наранџасто-црвену емисију, која је последица f-f прелаза јона Sm3+ (4 G5/2→6 HJ  (J=5/2, 7/2 i 9/2)) и која потврђује постојање енергијског трансфера. Допирање наночестица TiO2  јонима Ni2+ отвара могућност за синтезу транспарентних наноструктурних филмова који показују феромагнeтно уређење на собној температури (HC ~ 150-200 Oe) и сатурациону магнетизацију у опсегу 10-3- 5x10-2 μB/Ni, у зависности од концентрације допанта. Следећи циљ ових истраживања био је повећање фотокаталитичке ефикасности/активности наночестица TiO2  површинском модификацијом проводним ПАНИ полимером у карбонизованој форми, уз дефинисање механизма процеса фотокаталитичке деградације модел молекула метиленско плавог (Methylene blue) и родамина Б (Rhodamine B). У поређењу са немодификованим наночестицама TiO2 , ПАНИ/TiO2  нанокомпозити, ексцитовани белом светлошћу, показали су значајно већу фотокаталитичку ефикасност. Процес карбонизације полианилина у ПАНИ/TiO2  нанокомпозитима је довео до даљег повећања њихове фотокаталитичке ефикасности. Фотокаталитичка активност нанокомпозита је условљена њиховом површинском структуром, високом мобилношћу носилаца наелектрисања и апсорпционим коефицијентом полианилина у видљивом делу спектра, као и молекулском структуром испитиваних боја.
T2  - Fascinating world of nanoscience and nanotechnology
T1  - Probing the optical, magnetic and photocatalytic properties of doped TiO2 nanocrystals and polymer-based nanocomposites for various applications
T1  - Испитивање оптичких, магнетних и фотокаталитичких особина допираних ТIО2 нанокристала и нанокомпозита на бази полимера за различите примене
VL  - 6
SP  - 155
EP  - 182
UR  - https://hdl.handle.net/21.15107/rcub_vinar_12272
ER  - 

@inbook{
author = "Radoičić, Marija and Vranješ, Mila and Kuljanin-Jakovljević, Jadranka and Ćirić-Marjanović, Gordana and Šaponjić, Zoran",
year = "2020",
abstract = "This research paper focuses on doped TiO2  nanocrystals of different shape, size and structures, in addition to nanocomposites consisting of TiO2  nanocrystals and conductive polymers (Polyaniline (PANI)). The primary objective of this research paper is to ensure understanding of the influence of size, shape, structure and doping level on optical and magnetic properties of TiO2  nanoparticles, as well as the interaction between nanoparticles and PANI due to the creation of desired photocatalytic properties of nanocomposites. The doping of TiO2  nanocrystals with rare earth ions opens up the possibility of controlling their optical properties. The Sm3+ doped TiO2  faceted nanocrystals exhibited red photoluminescence, associated with 4 G5/2-6 HJ  (J=5/2, 7/2 and 9/2) f–f transitions of Sm3+ in the 4f5  configuration, after band-to-band excitation, confirming the accomplishment of energy transfers. The Ni2+ doped TiO2  nanocrystals enabled the synthesis of optically transparent nanostructured films that showed room-temperature ferromagnetism with almost closed loop (HC ~ 150-200 Oe) and saturation magnetization in the range of 10-3-5x10-2 μB/Ni depending on dopant concentration. Ni2+ ions that substitute core Ti atoms were found to participate in the light excitation processes, too. The improvement of photocatalytic efficiency of TiO2  nanocrystals by surface modification with carbonized form of PANI was tested in degradation processes of Rhodamine B and Methylene blue. The carbonized PANI/TiO2  nanocomposites showed significantly higher photocatalytic efficacy compared to the bare TiO2 and the non-carbonized PANI/TiO2  nanocomposites. Their photocatalytic activity is influenced by their surface and crystalline structures, absorption coefficient in the visible part of the spectrum, high mobility of charge carriers and finally by the molecular structures of the organic dyes used., Испитиване су допиране и недопиране наночестице титан (IV) оксида (ТiО2 ), великог енергијског процепа, различитих облика (сферични, тубуларни, штапићасти (елипсоидни)), величина кристалних структура, као и хибридни материјали-нанокомпозити на бази проводног полимера (полианилин, ПАНИ) и наночестица TiO2 . Испитивања утицаја величине, облика, структуре и нивоа допираности наночестица ТiО2  на њихове оптичке, магнетне и фотокаталитичке особине, као и разумевање интеракције наночестица и полимерне матрице (ПАНИ) у циљу креирања нанокомпозита одговарајућих фотокаталитичких својстава представљају главне правце овог истраживања. Обзиром на структуру енергетског процепа наночестица TiO2 , допирање јонима ретких земаља отвара могућност за контролу њихових оптичких карактеристика. Нанокристали TiO2  допирани јонима Sm3+ показују наранџасто-црвену емисију, која је последица f-f прелаза јона Sm3+ (4 G5/2→6 HJ  (J=5/2, 7/2 i 9/2)) и која потврђује постојање енергијског трансфера. Допирање наночестица TiO2  јонима Ni2+ отвара могућност за синтезу транспарентних наноструктурних филмова који показују феромагнeтно уређење на собној температури (HC ~ 150-200 Oe) и сатурациону магнетизацију у опсегу 10-3- 5x10-2 μB/Ni, у зависности од концентрације допанта. Следећи циљ ових истраживања био је повећање фотокаталитичке ефикасности/активности наночестица TiO2  површинском модификацијом проводним ПАНИ полимером у карбонизованој форми, уз дефинисање механизма процеса фотокаталитичке деградације модел молекула метиленско плавог (Methylene blue) и родамина Б (Rhodamine B). У поређењу са немодификованим наночестицама TiO2 , ПАНИ/TiO2  нанокомпозити, ексцитовани белом светлошћу, показали су значајно већу фотокаталитичку ефикасност. Процес карбонизације полианилина у ПАНИ/TiO2  нанокомпозитима је довео до даљег повећања њихове фотокаталитичке ефикасности. Фотокаталитичка активност нанокомпозита је условљена њиховом површинском структуром, високом мобилношћу носилаца наелектрисања и апсорпционим коефицијентом полианилина у видљивом делу спектра, као и молекулском структуром испитиваних боја.",
journal = "Fascinating world of nanoscience and nanotechnology",
booktitle = "Probing the optical, magnetic and photocatalytic properties of doped TiO2 nanocrystals and polymer-based nanocomposites for various applications, Испитивање оптичких, магнетних и фотокаталитичких особина допираних ТIО2 нанокристала и нанокомпозита на бази полимера за различите примене",
volume = "6",
pages = "155-182",
url = "https://hdl.handle.net/21.15107/rcub_vinar_12272"
}

Radoičić, M., Vranješ, M., Kuljanin-Jakovljević, J., Ćirić-Marjanović, G.,& Šaponjić, Z.. (2020). Probing the optical, magnetic and photocatalytic properties of doped TiO2 nanocrystals and polymer-based nanocomposites for various applications. in Fascinating world of nanoscience and nanotechnology, 6, 155-182.
https://hdl.handle.net/21.15107/rcub_vinar_12272

Radoičić M, Vranješ M, Kuljanin-Jakovljević J, Ćirić-Marjanović G, Šaponjić Z. Probing the optical, magnetic and photocatalytic properties of doped TiO2 nanocrystals and polymer-based nanocomposites for various applications. in Fascinating world of nanoscience and nanotechnology. 2020;6:155-182.
https://hdl.handle.net/21.15107/rcub_vinar_12272 .

Radoičić, Marija, Vranješ, Mila, Kuljanin-Jakovljević, Jadranka, Ćirić-Marjanović, Gordana, Šaponjić, Zoran, "Probing the optical, magnetic and photocatalytic properties of doped TiO2 nanocrystals and polymer-based nanocomposites for various applications" in Fascinating world of nanoscience and nanotechnology, 6 (2020):155-182,
https://hdl.handle.net/21.15107/rcub_vinar_12272 .

TY  - JOUR
AU  - Vranješ, Mila
AU  - Kuljanin-Jakovljević, Jadranka Ž.
AU  - Milošević, Milica V.
AU  - Ćirić-Marjanović, Gordana N.
AU  - Stoiljković, Milovan
AU  - Konstantinović, Zorica
AU  - Pavlović, Vladimir B.
AU  - Milivojević, Dušan
AU  - Šaponjić, Zoran
PY  - 2019
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/8358
AB  - Hydrothermal synthesis of Mn2+ doped titanate nanotubes (TNTs), which exhibited room temperature ferromagnetism (RTFM), is reported. Dispersions of 1 and 5 at.% Mn2+ doped anatase TiO2 nanocrystals were used as precursors. Size and shape of Mn2+ doped TNTs and precursor nanocrystals were studied by transmission electron microscopy (TEM). The relatively uniform size distribution of transverse dimension of nanotubes of about 10 nm was observed while their lengths varied up to few hundred nanometers. The X-Ray Diffraction (XRD) analysis and Raman spectroscopy of resultant powder confirmed the hydrogen dititanate (H2Ti2O5 x H2O) crystal phase of Mn2+ doped TNTs with the presence of small amount of sodium titanates. Electron paramagnetic resonance (EPR) experiments were performed to probe the local atomic and electronic structure of Mn in the nanotubes. Room temperature ferromagnetic ordering with saturation magnetic moment (Ms) in the range of 0.6–1.5 μB per Mn atom was observed. © 2019 Elsevier Masson SAS
T2  - Solid State Sciences
T1  - Hydrothermal synthesis of Mn2+ doped titanate nanotubes: Investigation of their structure and room temperature ferromagnetic behavior
VL  - 94
SP  - 155
EP  - 161
DO  - 10.1016/j.solidstatesciences.2019.06.008
ER  - 

@article{
author = "Vranješ, Mila and Kuljanin-Jakovljević, Jadranka Ž. and Milošević, Milica V. and Ćirić-Marjanović, Gordana N. and Stoiljković, Milovan and Konstantinović, Zorica and Pavlović, Vladimir B. and Milivojević, Dušan and Šaponjić, Zoran",
year = "2019",
abstract = "Hydrothermal synthesis of Mn2+ doped titanate nanotubes (TNTs), which exhibited room temperature ferromagnetism (RTFM), is reported. Dispersions of 1 and 5 at.% Mn2+ doped anatase TiO2 nanocrystals were used as precursors. Size and shape of Mn2+ doped TNTs and precursor nanocrystals were studied by transmission electron microscopy (TEM). The relatively uniform size distribution of transverse dimension of nanotubes of about 10 nm was observed while their lengths varied up to few hundred nanometers. The X-Ray Diffraction (XRD) analysis and Raman spectroscopy of resultant powder confirmed the hydrogen dititanate (H2Ti2O5 x H2O) crystal phase of Mn2+ doped TNTs with the presence of small amount of sodium titanates. Electron paramagnetic resonance (EPR) experiments were performed to probe the local atomic and electronic structure of Mn in the nanotubes. Room temperature ferromagnetic ordering with saturation magnetic moment (Ms) in the range of 0.6–1.5 μB per Mn atom was observed. © 2019 Elsevier Masson SAS",
journal = "Solid State Sciences",
title = "Hydrothermal synthesis of Mn2+ doped titanate nanotubes: Investigation of their structure and room temperature ferromagnetic behavior",
volume = "94",
pages = "155-161",
doi = "10.1016/j.solidstatesciences.2019.06.008"
}

Vranješ, M., Kuljanin-Jakovljević, J. Ž., Milošević, M. V., Ćirić-Marjanović, G. N., Stoiljković, M., Konstantinović, Z., Pavlović, V. B., Milivojević, D.,& Šaponjić, Z.. (2019). Hydrothermal synthesis of Mn2+ doped titanate nanotubes: Investigation of their structure and room temperature ferromagnetic behavior. in Solid State Sciences, 94, 155-161.
https://doi.org/10.1016/j.solidstatesciences.2019.06.008

Vranješ M, Kuljanin-Jakovljević JŽ, Milošević MV, Ćirić-Marjanović GN, Stoiljković M, Konstantinović Z, Pavlović VB, Milivojević D, Šaponjić Z. Hydrothermal synthesis of Mn2+ doped titanate nanotubes: Investigation of their structure and room temperature ferromagnetic behavior. in Solid State Sciences. 2019;94:155-161.
doi:10.1016/j.solidstatesciences.2019.06.008 .

Vranješ, Mila, Kuljanin-Jakovljević, Jadranka Ž., Milošević, Milica V., Ćirić-Marjanović, Gordana N., Stoiljković, Milovan, Konstantinović, Zorica, Pavlović, Vladimir B., Milivojević, Dušan, Šaponjić, Zoran, "Hydrothermal synthesis of Mn2+ doped titanate nanotubes: Investigation of their structure and room temperature ferromagnetic behavior" in Solid State Sciences, 94 (2019):155-161,
https://doi.org/10.1016/j.solidstatesciences.2019.06.008 . .

TY  - CONF
AU  - Nešić, Maja D.
AU  - Stepić, Milutin
AU  - Korićanac, Lela
AU  - Radoičić, Marija
AU  - Šaponjić, Zoran
AU  - Popović, Iva
AU  - Petković, Marijana
PY  - 2019
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/11891
AB  - There has been a growing demand for development and improvement of cancer treatment in order to overcome disadvantages and limitations of traditional chemotherapy such as resistance, toxicity, and activity against a small number of tumor types. Photodynamic therapy is a rapidly developing cancer treatment that utilizes the combination of photoactive drug and/or carrier and light as an external stimulus to destroy tumors, achieve a maximum concentration of the drug on tumor site, reduce side effects of drug onto the healthy tissue, enable dosage control, and more effective treatment which could improve outcome of therapy [1]. We investigated possibility to use ТiО2 nanoparticles as a carrier for potential antitumor drug [Ru(II)(dcbpy)2Cl2], cis-dichlorobis (2, 2'-bipyridyl-4, 4'-dicarboxylicacid) ruthenium(II). Nanocomposite system has been formed by binding of ruthenium complex to the ТiО2 nanoparticles. Components of the system are selected according to their preferences, such as biocompatibility, photo activity, and easy surface modification for ТiО2, and less toxicity, significant activity against cancer metastases, and activity on tumors that were resistant to a variety of standard chemotherapeutic agents for Ru-complexes. Both components of the system are also photoactive, therefore potential for system manipulation and use in photodinamic therapy has been investigated by irradiation with UV and visible light. Additionally, the feasibility of using this system as a light-triggered drug delivery system was shown on amelanotic melanoma cancer line. The experimental results revealed a potential of nanocomposite system for long-term constant release of complex which is suitable for clinical practice. The further investigation of nanocomposite system indicated that it exhibited UV and red light susceptible drug release behavior [2]. More precisely, the system demonstrated slower complex release upon visible and increased release rate upon UV light illumination which was also in good correlation with the light–dependent cytotoxicity of the system demonstrated on amelanotic melanoma cancer line. The melanoma cancer cell death is enhanced by UV and reduced by red light in the presence of investigated nanocomposite system [3]. All obtained results suggested that nanocomposite system may have a potential use as a light sensitive drug delivery system in photodynamic therapy which could significantly contribute to development of more efficient and less invasive therapy of melanoma which is highly aggressive and deadliest form of skin cancer.
PB  - Belgrade : Vinča Institute of Nuclear Sciences, University of Belgrade
C3  - PHOTONICA2019 : 7th International School and Conference on Photonics & Machine Learning with Photonics Symposium : Book of abstracts
T1  - Development of photo-sensitive nanocomposite system for controlled metallo-drug delivery in skin cancer therapy
SP  - 39
EP  - 39
UR  - https://hdl.handle.net/21.15107/rcub_vinar_11891
ER  - 

@conference{
author = "Nešić, Maja D. and Stepić, Milutin and Korićanac, Lela and Radoičić, Marija and Šaponjić, Zoran and Popović, Iva and Petković, Marijana",
year = "2019",
abstract = "There has been a growing demand for development and improvement of cancer treatment in order to overcome disadvantages and limitations of traditional chemotherapy such as resistance, toxicity, and activity against a small number of tumor types. Photodynamic therapy is a rapidly developing cancer treatment that utilizes the combination of photoactive drug and/or carrier and light as an external stimulus to destroy tumors, achieve a maximum concentration of the drug on tumor site, reduce side effects of drug onto the healthy tissue, enable dosage control, and more effective treatment which could improve outcome of therapy [1]. We investigated possibility to use ТiО2 nanoparticles as a carrier for potential antitumor drug [Ru(II)(dcbpy)2Cl2], cis-dichlorobis (2, 2'-bipyridyl-4, 4'-dicarboxylicacid) ruthenium(II). Nanocomposite system has been formed by binding of ruthenium complex to the ТiО2 nanoparticles. Components of the system are selected according to their preferences, such as biocompatibility, photo activity, and easy surface modification for ТiО2, and less toxicity, significant activity against cancer metastases, and activity on tumors that were resistant to a variety of standard chemotherapeutic agents for Ru-complexes. Both components of the system are also photoactive, therefore potential for system manipulation and use in photodinamic therapy has been investigated by irradiation with UV and visible light. Additionally, the feasibility of using this system as a light-triggered drug delivery system was shown on amelanotic melanoma cancer line. The experimental results revealed a potential of nanocomposite system for long-term constant release of complex which is suitable for clinical practice. The further investigation of nanocomposite system indicated that it exhibited UV and red light susceptible drug release behavior [2]. More precisely, the system demonstrated slower complex release upon visible and increased release rate upon UV light illumination which was also in good correlation with the light–dependent cytotoxicity of the system demonstrated on amelanotic melanoma cancer line. The melanoma cancer cell death is enhanced by UV and reduced by red light in the presence of investigated nanocomposite system [3]. All obtained results suggested that nanocomposite system may have a potential use as a light sensitive drug delivery system in photodynamic therapy which could significantly contribute to development of more efficient and less invasive therapy of melanoma which is highly aggressive and deadliest form of skin cancer.",
publisher = "Belgrade : Vinča Institute of Nuclear Sciences, University of Belgrade",
journal = "PHOTONICA2019 : 7th International School and Conference on Photonics & Machine Learning with Photonics Symposium : Book of abstracts",
title = "Development of photo-sensitive nanocomposite system for controlled metallo-drug delivery in skin cancer therapy",
pages = "39-39",
url = "https://hdl.handle.net/21.15107/rcub_vinar_11891"
}

Nešić, M. D., Stepić, M., Korićanac, L., Radoičić, M., Šaponjić, Z., Popović, I.,& Petković, M.. (2019). Development of photo-sensitive nanocomposite system for controlled metallo-drug delivery in skin cancer therapy. in PHOTONICA2019 : 7th International School and Conference on Photonics & Machine Learning with Photonics Symposium : Book of abstracts
Belgrade : Vinča Institute of Nuclear Sciences, University of Belgrade., 39-39.
https://hdl.handle.net/21.15107/rcub_vinar_11891

Nešić MD, Stepić M, Korićanac L, Radoičić M, Šaponjić Z, Popović I, Petković M. Development of photo-sensitive nanocomposite system for controlled metallo-drug delivery in skin cancer therapy. in PHOTONICA2019 : 7th International School and Conference on Photonics & Machine Learning with Photonics Symposium : Book of abstracts. 2019;:39-39.
https://hdl.handle.net/21.15107/rcub_vinar_11891 .

Nešić, Maja D., Stepić, Milutin, Korićanac, Lela, Radoičić, Marija, Šaponjić, Zoran, Popović, Iva, Petković, Marijana, "Development of photo-sensitive nanocomposite system for controlled metallo-drug delivery in skin cancer therapy" in PHOTONICA2019 : 7th International School and Conference on Photonics & Machine Learning with Photonics Symposium : Book of abstracts (2019):39-39,
https://hdl.handle.net/21.15107/rcub_vinar_11891 .

TY  - PAT
AU  - Radetić, Maja
AU  - Marković, Darka
AU  - Milovanović, Stoja
AU  - Žižović, Irena
AU  - Šaponjić, Zoran
AU  - Radoičić, Marija
PY  - 2019
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/12273
T2  - Zavod za intelektualnu svojinu Republike Srbije
T1  - Plutajući fotokatalizator na bazi pene polikaprolaktona i nanočestica titan(IV)-oksida
T1  - Floating photocatalyst based on polycaprolactone foam and titanium dioxide nanoparticles
UR  - https://hdl.handle.net/21.15107/rcub_vinar_12273
ER  - 

@misc{
author = "Radetić, Maja and Marković, Darka and Milovanović, Stoja and Žižović, Irena and Šaponjić, Zoran and Radoičić, Marija",
year = "2019",
journal = "Zavod za intelektualnu svojinu Republike Srbije",
title = "Plutajući fotokatalizator na bazi pene polikaprolaktona i nanočestica titan(IV)-oksida, Floating photocatalyst based on polycaprolactone foam and titanium dioxide nanoparticles",
url = "https://hdl.handle.net/21.15107/rcub_vinar_12273"
}

Radetić, M., Marković, D., Milovanović, S., Žižović, I., Šaponjić, Z.,& Radoičić, M.. (2019). Plutajući fotokatalizator na bazi pene polikaprolaktona i nanočestica titan(IV)-oksida. in Zavod za intelektualnu svojinu Republike Srbije.
https://hdl.handle.net/21.15107/rcub_vinar_12273

Radetić M, Marković D, Milovanović S, Žižović I, Šaponjić Z, Radoičić M. Plutajući fotokatalizator na bazi pene polikaprolaktona i nanočestica titan(IV)-oksida. in Zavod za intelektualnu svojinu Republike Srbije. 2019;.
https://hdl.handle.net/21.15107/rcub_vinar_12273 .

Radetić, Maja, Marković, Darka, Milovanović, Stoja, Žižović, Irena, Šaponjić, Zoran, Radoičić, Marija, "Plutajući fotokatalizator na bazi pene polikaprolaktona i nanočestica titan(IV)-oksida" in Zavod za intelektualnu svojinu Republike Srbije (2019),
https://hdl.handle.net/21.15107/rcub_vinar_12273 .

TY  - JOUR
AU  - Šojić Merkulov, Daniela V.
AU  - Despotović, Vesna N.
AU  - Banić, Nemanja D.
AU  - Armaković, Sanja J.
AU  - Finčur, Nina L.
AU  - Lazarević, Marina J.
AU  - Četojević-Simin, Dragana D.
AU  - Orčić, Dejan Z.
AU  - Radoičić, Marija B.
AU  - Šaponjić, Zoran
AU  - Čomor, Mirjana
AU  - Abramović, Biljana F.
PY  - 2018
UR  - http://linkinghub.elsevier.com/retrieve/pii/S0269749117352053
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/7699
AB  - A comprehensive study of the removal of selected biologically active compounds (pharmaceuticals and pesticides) from different water types was conducted using bare TiO2nanoparticles and TiO2/polyaniline (TP-50, TP-100, and TP-150) nanocomposite powders. In order to investigate how molecular structure of the substrate influences the rate of its removal, we compared degradation efficiency of the initial substrates and degree of mineralization for the active components of pharmaceuticals (propranolol, and amitriptyline) and pesticides (sulcotrione, and clomazone) in double distilled (DDW) and environmental waters. The results indicate that the efficiency of photocatalytic degradation of propranolol and amitriptyline was higher in environmental waters: rivers (Danube, Tisa, and Begej) and lakes (Moharač, and Sot) in comparison with DDW. On the contrary, degradation efficacy of sulcotrione and clomazone was lower in environmental waters. Further, of the all catalysts applied, bare TiO2and TP-100 were found to be most effective in the mineralization of propranolol and amitriptyline, respectively, while TP-150 appeared to be the most efficient in terms of sulcotrione and clomazone mineralization. Also, there was no significant toxicity observed after the irradiation of pharmaceuticals or pesticides solutions using appropriate catalysts on rat hepatoma (H-4-II-E), mouse neuroblastoma (Neuro-2a), human colon adenocarcinoma (HT-29), and human fetal lung (MRC-5) cell lines. Subsequently, detection and identification of the formed intermediates in the case of sulcotrione photocatalytic degradation using bare TiO2and TP-150 showed slightly different pathways of degradation. Furthermore, tentative pathways of sulcotrione photocatalytic degradation were proposed and discussed. Kinetics, toxicity and intermediates assessment of biologically active compounds (pesticides and pharmaceuticals) in environmental waters.
T2  - Environmental Pollution
T1  - Photocatalytic decomposition of selected biologically active compounds in environmental waters using TiO 2 /polyaniline nanocomposites: Kinetics, toxicity and intermediates assessment
VL  - 239
SP  - 457
EP  - 465
DO  - 10.1016/j.envpol.2018.04.039
ER  - 

@article{
author = "Šojić Merkulov, Daniela V. and Despotović, Vesna N. and Banić, Nemanja D. and Armaković, Sanja J. and Finčur, Nina L. and Lazarević, Marina J. and Četojević-Simin, Dragana D. and Orčić, Dejan Z. and Radoičić, Marija B. and Šaponjić, Zoran and Čomor, Mirjana and Abramović, Biljana F.",
year = "2018",
abstract = "A comprehensive study of the removal of selected biologically active compounds (pharmaceuticals and pesticides) from different water types was conducted using bare TiO2nanoparticles and TiO2/polyaniline (TP-50, TP-100, and TP-150) nanocomposite powders. In order to investigate how molecular structure of the substrate influences the rate of its removal, we compared degradation efficiency of the initial substrates and degree of mineralization for the active components of pharmaceuticals (propranolol, and amitriptyline) and pesticides (sulcotrione, and clomazone) in double distilled (DDW) and environmental waters. The results indicate that the efficiency of photocatalytic degradation of propranolol and amitriptyline was higher in environmental waters: rivers (Danube, Tisa, and Begej) and lakes (Moharač, and Sot) in comparison with DDW. On the contrary, degradation efficacy of sulcotrione and clomazone was lower in environmental waters. Further, of the all catalysts applied, bare TiO2and TP-100 were found to be most effective in the mineralization of propranolol and amitriptyline, respectively, while TP-150 appeared to be the most efficient in terms of sulcotrione and clomazone mineralization. Also, there was no significant toxicity observed after the irradiation of pharmaceuticals or pesticides solutions using appropriate catalysts on rat hepatoma (H-4-II-E), mouse neuroblastoma (Neuro-2a), human colon adenocarcinoma (HT-29), and human fetal lung (MRC-5) cell lines. Subsequently, detection and identification of the formed intermediates in the case of sulcotrione photocatalytic degradation using bare TiO2and TP-150 showed slightly different pathways of degradation. Furthermore, tentative pathways of sulcotrione photocatalytic degradation were proposed and discussed. Kinetics, toxicity and intermediates assessment of biologically active compounds (pesticides and pharmaceuticals) in environmental waters.",
journal = "Environmental Pollution",
title = "Photocatalytic decomposition of selected biologically active compounds in environmental waters using TiO 2 /polyaniline nanocomposites: Kinetics, toxicity and intermediates assessment",
volume = "239",
pages = "457-465",
doi = "10.1016/j.envpol.2018.04.039"
}

Šojić Merkulov, D. V., Despotović, V. N., Banić, N. D., Armaković, S. J., Finčur, N. L., Lazarević, M. J., Četojević-Simin, D. D., Orčić, D. Z., Radoičić, M. B., Šaponjić, Z., Čomor, M.,& Abramović, B. F.. (2018). Photocatalytic decomposition of selected biologically active compounds in environmental waters using TiO 2 /polyaniline nanocomposites: Kinetics, toxicity and intermediates assessment. in Environmental Pollution, 239, 457-465.
https://doi.org/10.1016/j.envpol.2018.04.039

Šojić Merkulov DV, Despotović VN, Banić ND, Armaković SJ, Finčur NL, Lazarević MJ, Četojević-Simin DD, Orčić DZ, Radoičić MB, Šaponjić Z, Čomor M, Abramović BF. Photocatalytic decomposition of selected biologically active compounds in environmental waters using TiO 2 /polyaniline nanocomposites: Kinetics, toxicity and intermediates assessment. in Environmental Pollution. 2018;239:457-465.
doi:10.1016/j.envpol.2018.04.039 .

Šojić Merkulov, Daniela V., Despotović, Vesna N., Banić, Nemanja D., Armaković, Sanja J., Finčur, Nina L., Lazarević, Marina J., Četojević-Simin, Dragana D., Orčić, Dejan Z., Radoičić, Marija B., Šaponjić, Zoran, Čomor, Mirjana, Abramović, Biljana F., "Photocatalytic decomposition of selected biologically active compounds in environmental waters using TiO 2 /polyaniline nanocomposites: Kinetics, toxicity and intermediates assessment" in Environmental Pollution, 239 (2018):457-465,
https://doi.org/10.1016/j.envpol.2018.04.039 . .

TY  - JOUR
AU  - Matijević, Milica
AU  - Nešić, Maja
AU  - Stepić, Milutin
AU  - Radoičić, Marija B.
AU  - Šaponjić, Zoran
AU  - Petković, Marijana
PY  - 2018
UR  - http://link.springer.com/10.1007/s11082-018-1495-z
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/7697
AB  - Photodynamic therapy implies a combined use of a photosensitizing medicament and low-intensity light to cause selective damage to the target tissue—tumor. As potential medicament, we use Ru(II)(dcbpy)2Cl2complex, and in order to achieve better photosensitization properties, the Ru complex was attached to the nano carrier—TiO2nanoparticles. Additionally, this nanocomposite system was encapsulated in the phospholipid vesicles, which could be classified as small unilamellar vesicles, based on the technique of production. The complex-release tests were performed under light illumination, at pH 5, characteristic for tumor cells` interior and compared with the release pattern at pH 7, characteristic for the serum, i.e. physiological solution.
T2  - Optical and Quantum Electronics
T1  - Light controllable TiO2-Ru nanocomposite system encapsulated in phospholipid unilamellar vesicles for anti-cancer photodynamic therapy
VL  - 50
IS  - 6
SP  - 232
DO  - 10.1007/s11082-018-1495-z
ER  - 

@article{
author = "Matijević, Milica and Nešić, Maja and Stepić, Milutin and Radoičić, Marija B. and Šaponjić, Zoran and Petković, Marijana",
year = "2018",
abstract = "Photodynamic therapy implies a combined use of a photosensitizing medicament and low-intensity light to cause selective damage to the target tissue—tumor. As potential medicament, we use Ru(II)(dcbpy)2Cl2complex, and in order to achieve better photosensitization properties, the Ru complex was attached to the nano carrier—TiO2nanoparticles. Additionally, this nanocomposite system was encapsulated in the phospholipid vesicles, which could be classified as small unilamellar vesicles, based on the technique of production. The complex-release tests were performed under light illumination, at pH 5, characteristic for tumor cells` interior and compared with the release pattern at pH 7, characteristic for the serum, i.e. physiological solution.",
journal = "Optical and Quantum Electronics",
title = "Light controllable TiO2-Ru nanocomposite system encapsulated in phospholipid unilamellar vesicles for anti-cancer photodynamic therapy",
volume = "50",
number = "6",
pages = "232",
doi = "10.1007/s11082-018-1495-z"
}

Matijević, M., Nešić, M., Stepić, M., Radoičić, M. B., Šaponjić, Z.,& Petković, M.. (2018). Light controllable TiO2-Ru nanocomposite system encapsulated in phospholipid unilamellar vesicles for anti-cancer photodynamic therapy. in Optical and Quantum Electronics, 50(6), 232.
https://doi.org/10.1007/s11082-018-1495-z

Matijević M, Nešić M, Stepić M, Radoičić MB, Šaponjić Z, Petković M. Light controllable TiO2-Ru nanocomposite system encapsulated in phospholipid unilamellar vesicles for anti-cancer photodynamic therapy. in Optical and Quantum Electronics. 2018;50(6):232.
doi:10.1007/s11082-018-1495-z .

Matijević, Milica, Nešić, Maja, Stepić, Milutin, Radoičić, Marija B., Šaponjić, Zoran, Petković, Marijana, "Light controllable TiO2-Ru nanocomposite system encapsulated in phospholipid unilamellar vesicles for anti-cancer photodynamic therapy" in Optical and Quantum Electronics, 50, no. 6 (2018):232,
https://doi.org/10.1007/s11082-018-1495-z . .

TY  - JOUR
AU  - Matijević, Milica
AU  - Popović, Iva A.
AU  - Stepić, Milutin
AU  - Nešić, Maja D.
AU  - Radoičić, Marija B.
AU  - Stanković, Maja
AU  - Šaponjić, Zoran
AU  - Petković, Marijana
PY  - 2018
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/9062
AB  - Among various nano-scaled materials composed from a spectrum of chemical compounds, inorganic nanoparticles are very attractive due to their physico-chemical properties, as well as their availability, simplicity, possibility of modifications, stability and biocompatibility. They are, on the one hand, an useful tool in advanced analytical chemistry, in particular for studying of biologically-relevant processes, but also important as functional parts of the systems designed for controlled and targeted delivery of medicaments for treatment of a variety of diseases and for imaging. So far, thousands of compounds and systems have been developed for the above-mentioned purposes, but there are only a few reviews dealing with these topics. The aim of this review is, thus, to summarize recent applications of nano-structured inorganic materials in the field of drug delivery, bioimaging and bioanalytics, and to give a prospective from the standpoint of biology-related applications.
T2  - Biologica Nyssana
T1  - Inorganic Nanoparticles In Biology: Drug Carriers And Auxiliary Tools In Bioimaging And Bioanalytics
VL  - 9
IS  - 1
SP  - 1
EP  - 19
DO  - 10.5281/zenodo.1470841
ER  - 

@article{
author = "Matijević, Milica and Popović, Iva A. and Stepić, Milutin and Nešić, Maja D. and Radoičić, Marija B. and Stanković, Maja and Šaponjić, Zoran and Petković, Marijana",
year = "2018",
abstract = "Among various nano-scaled materials composed from a spectrum of chemical compounds, inorganic nanoparticles are very attractive due to their physico-chemical properties, as well as their availability, simplicity, possibility of modifications, stability and biocompatibility. They are, on the one hand, an useful tool in advanced analytical chemistry, in particular for studying of biologically-relevant processes, but also important as functional parts of the systems designed for controlled and targeted delivery of medicaments for treatment of a variety of diseases and for imaging. So far, thousands of compounds and systems have been developed for the above-mentioned purposes, but there are only a few reviews dealing with these topics. The aim of this review is, thus, to summarize recent applications of nano-structured inorganic materials in the field of drug delivery, bioimaging and bioanalytics, and to give a prospective from the standpoint of biology-related applications.",
journal = "Biologica Nyssana",
title = "Inorganic Nanoparticles In Biology: Drug Carriers And Auxiliary Tools In Bioimaging And Bioanalytics",
volume = "9",
number = "1",
pages = "1-19",
doi = "10.5281/zenodo.1470841"
}

Matijević, M., Popović, I. A., Stepić, M., Nešić, M. D., Radoičić, M. B., Stanković, M., Šaponjić, Z.,& Petković, M.. (2018). Inorganic Nanoparticles In Biology: Drug Carriers And Auxiliary Tools In Bioimaging And Bioanalytics. in Biologica Nyssana, 9(1), 1-19.
https://doi.org/10.5281/zenodo.1470841

Matijević M, Popović IA, Stepić M, Nešić MD, Radoičić MB, Stanković M, Šaponjić Z, Petković M. Inorganic Nanoparticles In Biology: Drug Carriers And Auxiliary Tools In Bioimaging And Bioanalytics. in Biologica Nyssana. 2018;9(1):1-19.
doi:10.5281/zenodo.1470841 .

Matijević, Milica, Popović, Iva A., Stepić, Milutin, Nešić, Maja D., Radoičić, Marija B., Stanković, Maja, Šaponjić, Zoran, Petković, Marijana, "Inorganic Nanoparticles In Biology: Drug Carriers And Auxiliary Tools In Bioimaging And Bioanalytics" in Biologica Nyssana, 9, no. 1 (2018):1-19,
https://doi.org/10.5281/zenodo.1470841 . .

TY  - JOUR
AU  - Marković, Darka
AU  - Milovanović, Stoja
AU  - Radovanović, Željko
AU  - Žižović, Irena T.
AU  - Šaponjić, Zoran
AU  - Radetić, Maja M.
PY  - 2018
UR  - http://link.springer.com/10.1007/s12221-018-8148-5
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/7782
AB  - This study discusses a novel approach for fabrication of floating photocatalyst which can be efficiently exploited for photodegradation of dyes in aqueous solutions. A fabrication of the floating photocatalyst consisted of two steps: transformation of the poly(ε-caprolactone) beads (PCLb) into poly(ε-caprolactone) foam (PCLf) with porous structure in supercritical carbon-dioxide and subsequent loading of PCLf with TiO2 nanoparticles (NPs). Morphological characterization of the PCLf before and after TiO2 NPs loading was carried out by FESEM. The presence of titanium on the surface and inside the PCLf was detected by EDX. Photocatalytical activity of the floating photocatalyst was investigated in aqueous solution of textile dyes C.I. Acid Orange 7 (AO7) and C.I. Basic Yellow 28 (BY28) which were exposed to lamp that simulates the sun light. In addition to sustainable floatability for a long period of time, developed floating photocatalyst exhibited high rate of photodegradation since the complete discoloration of AO7 and BY28 solutions and photocatalysts alone occurred after 300 and 180 min of illumination, respectively. Its photocatalytic activity was preserved after three repeated photodegradation cycles with unchanged chemical structure that was confirmed by FTIR analysis.
T2  - Fibers and Polymers
T1  - Floating Photocatalyst Based on Poly(ε-caprolactone) Foam and TiO2 Nanoparticles for Removal of Textile Dyes
VL  - 19
IS  - 6
SP  - 1219
EP  - 1227
DO  - 10.1007/s12221-018-8148-5
ER  - 

@article{
author = "Marković, Darka and Milovanović, Stoja and Radovanović, Željko and Žižović, Irena T. and Šaponjić, Zoran and Radetić, Maja M.",
year = "2018",
abstract = "This study discusses a novel approach for fabrication of floating photocatalyst which can be efficiently exploited for photodegradation of dyes in aqueous solutions. A fabrication of the floating photocatalyst consisted of two steps: transformation of the poly(ε-caprolactone) beads (PCLb) into poly(ε-caprolactone) foam (PCLf) with porous structure in supercritical carbon-dioxide and subsequent loading of PCLf with TiO2 nanoparticles (NPs). Morphological characterization of the PCLf before and after TiO2 NPs loading was carried out by FESEM. The presence of titanium on the surface and inside the PCLf was detected by EDX. Photocatalytical activity of the floating photocatalyst was investigated in aqueous solution of textile dyes C.I. Acid Orange 7 (AO7) and C.I. Basic Yellow 28 (BY28) which were exposed to lamp that simulates the sun light. In addition to sustainable floatability for a long period of time, developed floating photocatalyst exhibited high rate of photodegradation since the complete discoloration of AO7 and BY28 solutions and photocatalysts alone occurred after 300 and 180 min of illumination, respectively. Its photocatalytic activity was preserved after three repeated photodegradation cycles with unchanged chemical structure that was confirmed by FTIR analysis.",
journal = "Fibers and Polymers",
title = "Floating Photocatalyst Based on Poly(ε-caprolactone) Foam and TiO2 Nanoparticles for Removal of Textile Dyes",
volume = "19",
number = "6",
pages = "1219-1227",
doi = "10.1007/s12221-018-8148-5"
}

Marković, D., Milovanović, S., Radovanović, Ž., Žižović, I. T., Šaponjić, Z.,& Radetić, M. M.. (2018). Floating Photocatalyst Based on Poly(ε-caprolactone) Foam and TiO2 Nanoparticles for Removal of Textile Dyes. in Fibers and Polymers, 19(6), 1219-1227.
https://doi.org/10.1007/s12221-018-8148-5

Marković D, Milovanović S, Radovanović Ž, Žižović IT, Šaponjić Z, Radetić MM. Floating Photocatalyst Based on Poly(ε-caprolactone) Foam and TiO2 Nanoparticles for Removal of Textile Dyes. in Fibers and Polymers. 2018;19(6):1219-1227.
doi:10.1007/s12221-018-8148-5 .

Marković, Darka, Milovanović, Stoja, Radovanović, Željko, Žižović, Irena T., Šaponjić, Zoran, Radetić, Maja M., "Floating Photocatalyst Based on Poly(ε-caprolactone) Foam and TiO2 Nanoparticles for Removal of Textile Dyes" in Fibers and Polymers, 19, no. 6 (2018):1219-1227,
https://doi.org/10.1007/s12221-018-8148-5 . .

TY  - JOUR
AU  - Marković, Darka
AU  - Deeks, Christopher
AU  - Nunney, Tim
AU  - Radovanović, Željko
AU  - Radoičić, Marija B.
AU  - Šaponjić, Zoran
AU  - Radetić, Maja M.
PY  - 2018
UR  - https://linkinghub.elsevier.com/retrieve/pii/S0144861718308890
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/7826
AB  - The fabrication of antimicrobial textile nanocomposite by in situ synthesis of Cu-based nanoparticles on cotton fabrics modified with different polycarboxylic acids was discussed in this study. In order to evaluate the influence of carboxyl group content on Cu2+-ions adsorption, their subsequent reduction with sodium borohydride and formation of Cu-based nanoparticles, cotton fabrics were modified with succinic, citric and 1,2,3,4-butanetetracarboxylic acids. It was shown that the larger the number of carboxyl groups in applied acid, the larger the content of free carboxyl groups on the fibers and consequently, the larger the Cu2+-ions uptake and total amounts of Cu-based nanoparticles. On the basis of the XPS and XRD measurements, it was suggested that synthesized nanoparticles were mixture of Cu2O and CuO. Fabricated nanocomposites provided maximum reduction of Gram-negative bacterium E. coli and Gram-positive bacterium S. aureus and controlled release of Cu2+-ions in physiological saline solution which are necessary prerequisites for infection prevention.
T2  - Carbohydrate Polymers
T1  - Antibacterial activity of Cu-based nanoparticles synthesized on the cotton fabrics modified with polycarboxylic acids
VL  - 200
SP  - 173
EP  - 182
DO  - 10.1016/j.carbpol.2018.08.001
ER  - 

@article{
author = "Marković, Darka and Deeks, Christopher and Nunney, Tim and Radovanović, Željko and Radoičić, Marija B. and Šaponjić, Zoran and Radetić, Maja M.",
year = "2018",
abstract = "The fabrication of antimicrobial textile nanocomposite by in situ synthesis of Cu-based nanoparticles on cotton fabrics modified with different polycarboxylic acids was discussed in this study. In order to evaluate the influence of carboxyl group content on Cu2+-ions adsorption, their subsequent reduction with sodium borohydride and formation of Cu-based nanoparticles, cotton fabrics were modified with succinic, citric and 1,2,3,4-butanetetracarboxylic acids. It was shown that the larger the number of carboxyl groups in applied acid, the larger the content of free carboxyl groups on the fibers and consequently, the larger the Cu2+-ions uptake and total amounts of Cu-based nanoparticles. On the basis of the XPS and XRD measurements, it was suggested that synthesized nanoparticles were mixture of Cu2O and CuO. Fabricated nanocomposites provided maximum reduction of Gram-negative bacterium E. coli and Gram-positive bacterium S. aureus and controlled release of Cu2+-ions in physiological saline solution which are necessary prerequisites for infection prevention.",
journal = "Carbohydrate Polymers",
title = "Antibacterial activity of Cu-based nanoparticles synthesized on the cotton fabrics modified with polycarboxylic acids",
volume = "200",
pages = "173-182",
doi = "10.1016/j.carbpol.2018.08.001"
}

Marković, D., Deeks, C., Nunney, T., Radovanović, Ž., Radoičić, M. B., Šaponjić, Z.,& Radetić, M. M.. (2018). Antibacterial activity of Cu-based nanoparticles synthesized on the cotton fabrics modified with polycarboxylic acids. in Carbohydrate Polymers, 200, 173-182.
https://doi.org/10.1016/j.carbpol.2018.08.001

Marković D, Deeks C, Nunney T, Radovanović Ž, Radoičić MB, Šaponjić Z, Radetić MM. Antibacterial activity of Cu-based nanoparticles synthesized on the cotton fabrics modified with polycarboxylic acids. in Carbohydrate Polymers. 2018;200:173-182.
doi:10.1016/j.carbpol.2018.08.001 .

Marković, Darka, Deeks, Christopher, Nunney, Tim, Radovanović, Željko, Radoičić, Marija B., Šaponjić, Zoran, Radetić, Maja M., "Antibacterial activity of Cu-based nanoparticles synthesized on the cotton fabrics modified with polycarboxylic acids" in Carbohydrate Polymers, 200 (2018):173-182,
https://doi.org/10.1016/j.carbpol.2018.08.001 . .

TY  - JOUR
AU  - Marković, Darka
AU  - Milovanović, Stoja
AU  - Radoičić, Marija B.
AU  - Radovanović, Željko
AU  - Žižović, Irena T.
AU  - Šaponjić, Zoran
AU  - Radetić, Maja M.
PY  - 2018
UR  - http://www.doiserbia.nb.rs/Article.aspx?ID=0352-51391800089M
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/8018
AB  - This study discusses the possibility of immobilization of colloidal TiO2 nanoparticles (NPs) onto poly(ε-caprolactone) (PCL) beads and foams that could be utilized for the removal of textile dyes from water by photodegradation. PCL foams were fabricated by environmentally friendly treatment of PCL beads in supercritical carbon dioxide. PCL beads and foams loaded with colloidal TiO2 NPs were used as photocatalysts for the removal of the textile dyes C.I. Acid Orange 7 and C.I. Basic Yellow 28 from aqueous solutions (10 mg L-1) under illumination that simulated sunlight. Unlike the PCL beads, the PCL foams provided complete discoloration of the dye solution within 24 h of illumination. The PCL foams also exhibited excellent floatability that was maintained for more than four weeks. Additionally, their photocatalytic activity was preserved within three repeated photodegradation cycles, indicating that the floating photocatalyst provided superior photocatalytic activity compared to the non-floating PCL beads.
AB  - У овом раду је дискутована могућност имобилизације колоидних наночестица TiO2 на
перлама или пени од поли(ε-капролактона) (PCL) које би се искористиле за уклањање боја
за текстил из воде процесом фотодеградације. PCL пена је добијена еколошки прихватљивим третманом PCL перли у наткритичном CO2. PCL перле и пене су накнадно импрегниране колоидним наночестицама TiO2 и употребљене су као фотокатализатори за
уклањање боја за текстил C.I. Acid Orange 7 и C.I. Basic Yellow 28 из воденог раствора (10
mg L-1) при осветљењу које симулира сунчеву светлост. За разлику од PCL перли, PCL пене
су обезбедиле потпуно обезбојавање раствора боје током 24 h осветљавања. PCL пена је
такође показала одличну способност плутања која је очувана дуже од четири недеље.
Фотокаталитичка активност пена је задржана таком три поновљена циклуса испитивања
фотодеградације што указује да овај плутајући фотокатализатор показује супериорну
фотокаталитичку активност у поређењу са неплутајућим PCL перлама.
T2  - Journal of the Serbian Chemical Society
T1  - Removal of textile dyes from water by TiO2 nanoparticles immobilized on poly(ε-caprolactone) beads and foams
VL  - 83
IS  - 12
SP  - 1379
EP  - 1389
DO  - 10.2298/JSC180913089M
ER  - 

@article{
author = "Marković, Darka and Milovanović, Stoja and Radoičić, Marija B. and Radovanović, Željko and Žižović, Irena T. and Šaponjić, Zoran and Radetić, Maja M.",
year = "2018",
abstract = "This study discusses the possibility of immobilization of colloidal TiO2 nanoparticles (NPs) onto poly(ε-caprolactone) (PCL) beads and foams that could be utilized for the removal of textile dyes from water by photodegradation. PCL foams were fabricated by environmentally friendly treatment of PCL beads in supercritical carbon dioxide. PCL beads and foams loaded with colloidal TiO2 NPs were used as photocatalysts for the removal of the textile dyes C.I. Acid Orange 7 and C.I. Basic Yellow 28 from aqueous solutions (10 mg L-1) under illumination that simulated sunlight. Unlike the PCL beads, the PCL foams provided complete discoloration of the dye solution within 24 h of illumination. The PCL foams also exhibited excellent floatability that was maintained for more than four weeks. Additionally, their photocatalytic activity was preserved within three repeated photodegradation cycles, indicating that the floating photocatalyst provided superior photocatalytic activity compared to the non-floating PCL beads., У овом раду је дискутована могућност имобилизације колоидних наночестица TiO2 на
перлама или пени од поли(ε-капролактона) (PCL) које би се искористиле за уклањање боја
за текстил из воде процесом фотодеградације. PCL пена је добијена еколошки прихватљивим третманом PCL перли у наткритичном CO2. PCL перле и пене су накнадно импрегниране колоидним наночестицама TiO2 и употребљене су као фотокатализатори за
уклањање боја за текстил C.I. Acid Orange 7 и C.I. Basic Yellow 28 из воденог раствора (10
mg L-1) при осветљењу које симулира сунчеву светлост. За разлику од PCL перли, PCL пене
су обезбедиле потпуно обезбојавање раствора боје током 24 h осветљавања. PCL пена је
такође показала одличну способност плутања која је очувана дуже од четири недеље.
Фотокаталитичка активност пена је задржана таком три поновљена циклуса испитивања
фотодеградације што указује да овај плутајући фотокатализатор показује супериорну
фотокаталитичку активност у поређењу са неплутајућим PCL перлама.",
journal = "Journal of the Serbian Chemical Society",
title = "Removal of textile dyes from water by TiO2 nanoparticles immobilized on poly(ε-caprolactone) beads and foams",
volume = "83",
number = "12",
pages = "1379-1389",
doi = "10.2298/JSC180913089M"
}

Marković, D., Milovanović, S., Radoičić, M. B., Radovanović, Ž., Žižović, I. T., Šaponjić, Z.,& Radetić, M. M.. (2018). Removal of textile dyes from water by TiO2 nanoparticles immobilized on poly(ε-caprolactone) beads and foams. in Journal of the Serbian Chemical Society, 83(12), 1379-1389.
https://doi.org/10.2298/JSC180913089M

Marković D, Milovanović S, Radoičić MB, Radovanović Ž, Žižović IT, Šaponjić Z, Radetić MM. Removal of textile dyes from water by TiO2 nanoparticles immobilized on poly(ε-caprolactone) beads and foams. in Journal of the Serbian Chemical Society. 2018;83(12):1379-1389.
doi:10.2298/JSC180913089M .

Marković, Darka, Milovanović, Stoja, Radoičić, Marija B., Radovanović, Željko, Žižović, Irena T., Šaponjić, Zoran, Radetić, Maja M., "Removal of textile dyes from water by TiO2 nanoparticles immobilized on poly(ε-caprolactone) beads and foams" in Journal of the Serbian Chemical Society, 83, no. 12 (2018):1379-1389,
https://doi.org/10.2298/JSC180913089M . .

TY  - CONF
AU  - Milošević, Milica V.
AU  - Radoičić, Marija B.
AU  - Šaponjić, Zoran
PY  - 2018
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/12270
AB  - In a series researches so far, it has been shown that TiO2 nanoparticles have become the focus of intensive exploration in the field of photocatalysis, as a consequence of their unique properties and potential applications. In order to improve photocatalytic and functional properties of TiO2 nanoparticles, different methods should be used. One of the most effective approaches is capping of nobel metal (Pt, Ag, Au) clusters on nanoparticle surface. Namely, metal clusters act as electron traps and they promote interfacial charge- -transfer processes and reduce undesirable recombination processes on TiO2 nanoparticle surface.  As a consequence, photocatalytic efficiency of the system should be improved.  The cotton fabric modified by TiO2/Ag nanoparticles was synthesized by in situ photoreduction of Ag+-ions on alanine modified TiO2 colloidal nanoparticles previously deposited onto cotton fabric. Adsorption of Ag+-ions on TiO2 nanoparticle surface was improved by addition of alanine amino-acid. As a result, separation of photoinduced charges is preferred and recombination process is significantly reduced. In order to further improve the efficiency of the system, methyl alcohol was employed as hole-scavenger. Obtained results confirmed the presence of TiO2/Ag nanoparticles across the surface of cotton fabric (SEM), as well as successful fabrication of metallic Ag on investigated fabric (XRD). Interaction between alanine modified TiO2 and Ag nanoparticles was studied by FTIR, while structural properties of synthesized samples were investigated by Raman spectroscopy. The photocatalytic performance of TiO2/Ag nanoparticles modified cotton fabric was tested in the process of photodegradation of organic dyes under simulated solar light: Rhodamine B, Acid Orange 7 and Methyl Red.
PB  - Belgrade : Institute of Technical Sciences of SASA
C3  - 17th Young Researchers' Conference Materials Sciences and Engineering : program and the book of abstracts; December 5-7, Belgrade
T1  - TiO2/Ag nanoparticles modified cotton fabric and its application to photocatalysis
SP  - 67
EP  - 67
UR  - https://hdl.handle.net/21.15107/rcub_vinar_12270
ER  - 

@conference{
author = "Milošević, Milica V. and Radoičić, Marija B. and Šaponjić, Zoran",
year = "2018",
abstract = "In a series researches so far, it has been shown that TiO2 nanoparticles have become the focus of intensive exploration in the field of photocatalysis, as a consequence of their unique properties and potential applications. In order to improve photocatalytic and functional properties of TiO2 nanoparticles, different methods should be used. One of the most effective approaches is capping of nobel metal (Pt, Ag, Au) clusters on nanoparticle surface. Namely, metal clusters act as electron traps and they promote interfacial charge- -transfer processes and reduce undesirable recombination processes on TiO2 nanoparticle surface.  As a consequence, photocatalytic efficiency of the system should be improved.  The cotton fabric modified by TiO2/Ag nanoparticles was synthesized by in situ photoreduction of Ag+-ions on alanine modified TiO2 colloidal nanoparticles previously deposited onto cotton fabric. Adsorption of Ag+-ions on TiO2 nanoparticle surface was improved by addition of alanine amino-acid. As a result, separation of photoinduced charges is preferred and recombination process is significantly reduced. In order to further improve the efficiency of the system, methyl alcohol was employed as hole-scavenger. Obtained results confirmed the presence of TiO2/Ag nanoparticles across the surface of cotton fabric (SEM), as well as successful fabrication of metallic Ag on investigated fabric (XRD). Interaction between alanine modified TiO2 and Ag nanoparticles was studied by FTIR, while structural properties of synthesized samples were investigated by Raman spectroscopy. The photocatalytic performance of TiO2/Ag nanoparticles modified cotton fabric was tested in the process of photodegradation of organic dyes under simulated solar light: Rhodamine B, Acid Orange 7 and Methyl Red.",
publisher = "Belgrade : Institute of Technical Sciences of SASA",
journal = "17th Young Researchers' Conference Materials Sciences and Engineering : program and the book of abstracts; December 5-7, Belgrade",
title = "TiO2/Ag nanoparticles modified cotton fabric and its application to photocatalysis",
pages = "67-67",
url = "https://hdl.handle.net/21.15107/rcub_vinar_12270"
}

Milošević, M. V., Radoičić, M. B.,& Šaponjić, Z.. (2018). TiO2/Ag nanoparticles modified cotton fabric and its application to photocatalysis. in 17th Young Researchers' Conference Materials Sciences and Engineering : program and the book of abstracts; December 5-7, Belgrade
Belgrade : Institute of Technical Sciences of SASA., 67-67.
https://hdl.handle.net/21.15107/rcub_vinar_12270

Milošević MV, Radoičić MB, Šaponjić Z. TiO2/Ag nanoparticles modified cotton fabric and its application to photocatalysis. in 17th Young Researchers' Conference Materials Sciences and Engineering : program and the book of abstracts; December 5-7, Belgrade. 2018;:67-67.
https://hdl.handle.net/21.15107/rcub_vinar_12270 .

Milošević, Milica V., Radoičić, Marija B., Šaponjić, Zoran, "TiO2/Ag nanoparticles modified cotton fabric and its application to photocatalysis" in 17th Young Researchers' Conference Materials Sciences and Engineering : program and the book of abstracts; December 5-7, Belgrade (2018):67-67,
https://hdl.handle.net/21.15107/rcub_vinar_12270 .

TY  - JOUR
AU  - Boni, Mihai
AU  - Staicu, Angela
AU  - Andrei, Ionut Relu
AU  - Smarandache, Adriana
AU  - Nastasa, Viorel
AU  - Šaponjić, Zoran
AU  - Pascu, Mihail Lucian
PY  - 2018
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/8075
AB  - This work aims to investigate the effect of TiO 2 nanoparticles addition on the fluorescence emission of solutions of Rhodamine 6G excited in micro-volumetric droplets. In this paper are presented the similarities and the differences of the emission spectra by modifying parameters such as TiO 2 concentration, solutions pH and laser fluence. The pumping laser source used was the second harmonic beam emitted by a pulsed ns Nd:YAG laser at 532 nm. Lasing emission is observed and it is favorised by the solution acidity and laser beam intensity. © 2018, Editura Academiei Romane. All rights reserved.
T2  - Romanian Reports in Physics
T1  - TiO2 nanoparticles influence on rhodamine 6G droplet emission
VL  - 70
IS  - 4
SP  - Art. 513
UR  - https://hdl.handle.net/21.15107/rcub_vinar_8075
ER  - 

@article{
author = "Boni, Mihai and Staicu, Angela and Andrei, Ionut Relu and Smarandache, Adriana and Nastasa, Viorel and Šaponjić, Zoran and Pascu, Mihail Lucian",
year = "2018",
abstract = "This work aims to investigate the effect of TiO 2 nanoparticles addition on the fluorescence emission of solutions of Rhodamine 6G excited in micro-volumetric droplets. In this paper are presented the similarities and the differences of the emission spectra by modifying parameters such as TiO 2 concentration, solutions pH and laser fluence. The pumping laser source used was the second harmonic beam emitted by a pulsed ns Nd:YAG laser at 532 nm. Lasing emission is observed and it is favorised by the solution acidity and laser beam intensity. © 2018, Editura Academiei Romane. All rights reserved.",
journal = "Romanian Reports in Physics",
title = "TiO2 nanoparticles influence on rhodamine 6G droplet emission",
volume = "70",
number = "4",
pages = "Art. 513",
url = "https://hdl.handle.net/21.15107/rcub_vinar_8075"
}

Boni, M., Staicu, A., Andrei, I. R., Smarandache, A., Nastasa, V., Šaponjić, Z.,& Pascu, M. L.. (2018). TiO2 nanoparticles influence on rhodamine 6G droplet emission. in Romanian Reports in Physics, 70(4), Art. 513.
https://hdl.handle.net/21.15107/rcub_vinar_8075

Boni M, Staicu A, Andrei IR, Smarandache A, Nastasa V, Šaponjić Z, Pascu ML. TiO2 nanoparticles influence on rhodamine 6G droplet emission. in Romanian Reports in Physics. 2018;70(4):Art. 513.
https://hdl.handle.net/21.15107/rcub_vinar_8075 .

Boni, Mihai, Staicu, Angela, Andrei, Ionut Relu, Smarandache, Adriana, Nastasa, Viorel, Šaponjić, Zoran, Pascu, Mihail Lucian, "TiO2 nanoparticles influence on rhodamine 6G droplet emission" in Romanian Reports in Physics, 70, no. 4 (2018):Art. 513,
https://hdl.handle.net/21.15107/rcub_vinar_8075 .

TY  - JOUR
AU  - Marković, Darka
AU  - Korica, Matea
AU  - Kostić, Mirjana M.
AU  - Radovanović, Željko
AU  - Šaponjić, Zoran
AU  - Mitrić, Miodrag
AU  - Radetić, Maja M.
PY  - 2018
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/1911
AB  - In situ synthesis of Cu/Cu2O nanoparticles on the cotton fabric discussed in this study relies on adsorption of Cu2+-ions by carboxylate groups generated through the TEMPO-mediated oxidation of cellulose and their subsequent reduction by sodium borohydride. In order to establish the influence of aldehyde and carboxylate groups on the nanoparticles formation, the duration of TEMPO-mediated oxidation was varied. Chemical changes induced by TEMPO-mediated oxidation were evaluated by titrimetric determination of the amounts of aldehyde and carboxylic groups in cotton and FTIR spectroscopy. The presence of Cu/Cu2O nanoparticles on the cotton fabric was confirmed by FE-SEM, AAS and XRD analyses. Antimicrobial activity of synthesized nanoparticles was tested against Gram-negative bacteria E. coli, Gram-positive bacteria S. aureus and fungi C. albicans. The extension of TEMPO oxidation time led to an increase of carboxylate group content and consequently, formation of larger amounts of Cu/Cu2O nanoparticles. All fabricated textile nanocomposites provided excellent antibacterial and acceptable antifungal activity. They also ensured a controlled release of Cu2+-ions in physiological solution which is an imperative for infection prevention.
T2  - Cellulose
T1  - In situ synthesis of Cu/Cu2O nanoparticles on the TEMPO oxidized cotton fabrics
VL  - 25
IS  - 1
SP  - 829
EP  - 841
DO  - 10.1007/s10570-017-1566-5
ER  - 

@article{
author = "Marković, Darka and Korica, Matea and Kostić, Mirjana M. and Radovanović, Željko and Šaponjić, Zoran and Mitrić, Miodrag and Radetić, Maja M.",
year = "2018",
abstract = "In situ synthesis of Cu/Cu2O nanoparticles on the cotton fabric discussed in this study relies on adsorption of Cu2+-ions by carboxylate groups generated through the TEMPO-mediated oxidation of cellulose and their subsequent reduction by sodium borohydride. In order to establish the influence of aldehyde and carboxylate groups on the nanoparticles formation, the duration of TEMPO-mediated oxidation was varied. Chemical changes induced by TEMPO-mediated oxidation were evaluated by titrimetric determination of the amounts of aldehyde and carboxylic groups in cotton and FTIR spectroscopy. The presence of Cu/Cu2O nanoparticles on the cotton fabric was confirmed by FE-SEM, AAS and XRD analyses. Antimicrobial activity of synthesized nanoparticles was tested against Gram-negative bacteria E. coli, Gram-positive bacteria S. aureus and fungi C. albicans. The extension of TEMPO oxidation time led to an increase of carboxylate group content and consequently, formation of larger amounts of Cu/Cu2O nanoparticles. All fabricated textile nanocomposites provided excellent antibacterial and acceptable antifungal activity. They also ensured a controlled release of Cu2+-ions in physiological solution which is an imperative for infection prevention.",
journal = "Cellulose",
title = "In situ synthesis of Cu/Cu2O nanoparticles on the TEMPO oxidized cotton fabrics",
volume = "25",
number = "1",
pages = "829-841",
doi = "10.1007/s10570-017-1566-5"
}

Marković, D., Korica, M., Kostić, M. M., Radovanović, Ž., Šaponjić, Z., Mitrić, M.,& Radetić, M. M.. (2018). In situ synthesis of Cu/Cu2O nanoparticles on the TEMPO oxidized cotton fabrics. in Cellulose, 25(1), 829-841.
https://doi.org/10.1007/s10570-017-1566-5

Marković D, Korica M, Kostić MM, Radovanović Ž, Šaponjić Z, Mitrić M, Radetić MM. In situ synthesis of Cu/Cu2O nanoparticles on the TEMPO oxidized cotton fabrics. in Cellulose. 2018;25(1):829-841.
doi:10.1007/s10570-017-1566-5 .

Marković, Darka, Korica, Matea, Kostić, Mirjana M., Radovanović, Željko, Šaponjić, Zoran, Mitrić, Miodrag, Radetić, Maja M., "In situ synthesis of Cu/Cu2O nanoparticles on the TEMPO oxidized cotton fabrics" in Cellulose, 25, no. 1 (2018):829-841,
https://doi.org/10.1007/s10570-017-1566-5 . .