Synthesis, characterization and antimicrobial activity of Pd(II) and Fe(III) complexes with ethyl (2E)-2-[2-(diphenylphosphino)benzylidene]hydrazinecarboxylate
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2014
Authors
Milenković, MilicaCantoni, Giulia
Bacchi, Alessia
Spasojević, Vojislav
Milenković, Marina
Sladić, Dušan M.
Krstić, Natalija
Anđelković, Katarina
Article (Published version)
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Complexes of Pd(II) and Fe(III) with the condensation derivative of 2-(diphenylphosphino)benzaldehyde and ethyl carbazate were synthesized, characterized, and their antimicrobial activity was evaluated. The structures of the Pd(II) and Fe(III) complexes in solid state were determined by IR, elemental analysis and X-ray analysis. The structure of Pd(II) complex in solution was determined by NMR spectroscopy. Results of magnetic measurements for Fe(III) complex were reported. In both complexes the ligand is coordinated as tridentate via the phosphorus, the imine nitrogen and the carbonyl oxygen atoms. Results of antimicrobial activity investigation indicate that the activity of the ligand is enhanced upon complexation, and that the MIC values of the iron complex to some bacterial strains are not much higher than those of cefotaxime. (C) 2014 Elsevier Ltd. All rights reserved.
Keywords:
Pd(II) complex / Fe(III) complex / 2-(Diphenylphosphino)benzaldehyde / Hydrazone / X-ray structureSource:
Polyhedron, 2014, 80, SI, 47-52Funding / projects:
DOI: 10.1016/j.poly.2014.01.022
ISSN: 0277-5387
WoS: 000341348300007
Scopus: 2-s2.0-84905501224
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VinčaTY - JOUR AU - Milenković, Milica AU - Cantoni, Giulia AU - Bacchi, Alessia AU - Spasojević, Vojislav AU - Milenković, Marina AU - Sladić, Dušan M. AU - Krstić, Natalija AU - Anđelković, Katarina PY - 2014 UR - https://vinar.vin.bg.ac.rs/handle/123456789/99 AB - Complexes of Pd(II) and Fe(III) with the condensation derivative of 2-(diphenylphosphino)benzaldehyde and ethyl carbazate were synthesized, characterized, and their antimicrobial activity was evaluated. The structures of the Pd(II) and Fe(III) complexes in solid state were determined by IR, elemental analysis and X-ray analysis. The structure of Pd(II) complex in solution was determined by NMR spectroscopy. Results of magnetic measurements for Fe(III) complex were reported. In both complexes the ligand is coordinated as tridentate via the phosphorus, the imine nitrogen and the carbonyl oxygen atoms. Results of antimicrobial activity investigation indicate that the activity of the ligand is enhanced upon complexation, and that the MIC values of the iron complex to some bacterial strains are not much higher than those of cefotaxime. (C) 2014 Elsevier Ltd. All rights reserved. T2 - Polyhedron T1 - Synthesis, characterization and antimicrobial activity of Pd(II) and Fe(III) complexes with ethyl (2E)-2-[2-(diphenylphosphino)benzylidene]hydrazinecarboxylate VL - 80 IS - SI SP - 47 EP - 52 DO - 10.1016/j.poly.2014.01.022 ER -
@article{ author = "Milenković, Milica and Cantoni, Giulia and Bacchi, Alessia and Spasojević, Vojislav and Milenković, Marina and Sladić, Dušan M. and Krstić, Natalija and Anđelković, Katarina", year = "2014", abstract = "Complexes of Pd(II) and Fe(III) with the condensation derivative of 2-(diphenylphosphino)benzaldehyde and ethyl carbazate were synthesized, characterized, and their antimicrobial activity was evaluated. The structures of the Pd(II) and Fe(III) complexes in solid state were determined by IR, elemental analysis and X-ray analysis. The structure of Pd(II) complex in solution was determined by NMR spectroscopy. Results of magnetic measurements for Fe(III) complex were reported. In both complexes the ligand is coordinated as tridentate via the phosphorus, the imine nitrogen and the carbonyl oxygen atoms. Results of antimicrobial activity investigation indicate that the activity of the ligand is enhanced upon complexation, and that the MIC values of the iron complex to some bacterial strains are not much higher than those of cefotaxime. (C) 2014 Elsevier Ltd. All rights reserved.", journal = "Polyhedron", title = "Synthesis, characterization and antimicrobial activity of Pd(II) and Fe(III) complexes with ethyl (2E)-2-[2-(diphenylphosphino)benzylidene]hydrazinecarboxylate", volume = "80", number = "SI", pages = "47-52", doi = "10.1016/j.poly.2014.01.022" }
Milenković, M., Cantoni, G., Bacchi, A., Spasojević, V., Milenković, M., Sladić, D. M., Krstić, N.,& Anđelković, K.. (2014). Synthesis, characterization and antimicrobial activity of Pd(II) and Fe(III) complexes with ethyl (2E)-2-[2-(diphenylphosphino)benzylidene]hydrazinecarboxylate. in Polyhedron, 80(SI), 47-52. https://doi.org/10.1016/j.poly.2014.01.022
Milenković M, Cantoni G, Bacchi A, Spasojević V, Milenković M, Sladić DM, Krstić N, Anđelković K. Synthesis, characterization and antimicrobial activity of Pd(II) and Fe(III) complexes with ethyl (2E)-2-[2-(diphenylphosphino)benzylidene]hydrazinecarboxylate. in Polyhedron. 2014;80(SI):47-52. doi:10.1016/j.poly.2014.01.022 .
Milenković, Milica, Cantoni, Giulia, Bacchi, Alessia, Spasojević, Vojislav, Milenković, Marina, Sladić, Dušan M., Krstić, Natalija, Anđelković, Katarina, "Synthesis, characterization and antimicrobial activity of Pd(II) and Fe(III) complexes with ethyl (2E)-2-[2-(diphenylphosphino)benzylidene]hydrazinecarboxylate" in Polyhedron, 80, no. SI (2014):47-52, https://doi.org/10.1016/j.poly.2014.01.022 . .