Electrocatalytic Activity of Ionic-Liquid-Derived Porous Carbon Materials for the Oxygen Reduction Reaction
2018
Preuzimanje 🢃
Autori
Zdolšek, NikolaDimitrijević, Aleksandra
Bendova, Magdalena
Krstić, Jugoslav B.
Rocha, Raquel P.
Figueiredo, Jose L.
Bajuk-Bogdanović, Danica V.
Trtić-Petrović, Tatjana M.
Šljukić, Biljana
Članak u časopisu (Recenzirana verzija)
Metapodaci
Prikaz svih podataka o dokumentuApstrakt
Carbon materials, prepared by using different methods with ionic liquids, are compared as electrocatalysts for the oxygen reduction reaction (ORR). Materials were synthesized through the hydrothermal carbonization of glucose and by using the same method in the presence of 1-butyl-3-methylimidazolium methanesulfonate [bmim][MeSO3] as an additive. Another two carbon-based materials were prepared by using ionic-liquid-based methods: ionothermal carbonization of glucose using [bmim][MeSO3] as a recyclable medium for the carbonization reaction and by direct carbonization of the ionic liquid in a one-step method using [bmim][MeSO3] as the precursor for N- and S-doped porous carbon (Carb-IL). Characterization results showed the possibility of morphology and porosity control by using [bmim][MeSO3]. All materials were subsequently tested for the ORR in alkaline media. Carb-IL showed enhanced and stable electrocatalytic ORR activity, even in the presence of methanol, ethanol, and borohydride, op...ening the possibility for its application in fuel cells.
Ključne reči:
ionic liquids / porous carbon materials / ionothermal carbonization / oxygen reduction reaction / fuel cellsIzvor:
ChemElectroChem, 2018, 5, 7, 1037-1046Finansiranje / projekti:
- Fizika i hemija sa jonskim snopovima (RS-MESTD-Integrated and Interdisciplinary Research (IIR or III)-45006)
- Litijum-jon baterije i gorivne ćelije-istraživanje i razvoj (RS-MESTD-Integrated and Interdisciplinary Research (IIR or III)-45014)
- Nanostrukturni funkcionalni i kompozitni materijali u katalitičkim i sorpcionim procesima (RS-MESTD-Integrated and Interdisciplinary Research (IIR or III)-45001)
- ERDF through COMPETE - Programa Operacional Competitividade e Internacionalizacao (POCI) - POCI-01-0145-FEDER-006984
- FCT - Fundacao para a Ciencia e a Tecnologia
- FCT - SFRH/BD/95411/2013
- Ministry of Education, Sports, and Youth of the Czech Republic - COST LD14090
- COST Action [CM1206]
Napomena:
- This the peer-reviewed version of the article: https://doi.org/10.1002/celc.201701369
Povezane informacije:
- Povezani sadržaj
https://vinar.vin.bg.ac.rs/handle/123456789/7672 - Povezani sadržaj
https://doi.org/10.1002/celc.201701369
DOI: 10.1002/celc.201701369
ISSN: 2196-0216
WoS: 000429413700007
Scopus: 2-s2.0-85041637185
Kolekcije
Institucija/grupa
VinčaTY - JOUR AU - Zdolšek, Nikola AU - Dimitrijević, Aleksandra AU - Bendova, Magdalena AU - Krstić, Jugoslav B. AU - Rocha, Raquel P. AU - Figueiredo, Jose L. AU - Bajuk-Bogdanović, Danica V. AU - Trtić-Petrović, Tatjana M. AU - Šljukić, Biljana PY - 2018 UR - https://vinar.vin.bg.ac.rs/handle/123456789/9881 AB - Carbon materials, prepared by using different methods with ionic liquids, are compared as electrocatalysts for the oxygen reduction reaction (ORR). Materials were synthesized through the hydrothermal carbonization of glucose and by using the same method in the presence of 1-butyl-3-methylimidazolium methanesulfonate [bmim][MeSO3] as an additive. Another two carbon-based materials were prepared by using ionic-liquid-based methods: ionothermal carbonization of glucose using [bmim][MeSO3] as a recyclable medium for the carbonization reaction and by direct carbonization of the ionic liquid in a one-step method using [bmim][MeSO3] as the precursor for N- and S-doped porous carbon (Carb-IL). Characterization results showed the possibility of morphology and porosity control by using [bmim][MeSO3]. All materials were subsequently tested for the ORR in alkaline media. Carb-IL showed enhanced and stable electrocatalytic ORR activity, even in the presence of methanol, ethanol, and borohydride, opening the possibility for its application in fuel cells. T2 - ChemElectroChem T1 - Electrocatalytic Activity of Ionic-Liquid-Derived Porous Carbon Materials for the Oxygen Reduction Reaction VL - 5 IS - 7 SP - 1037 EP - 1046 DO - 10.1002/celc.201701369 ER -
@article{ author = "Zdolšek, Nikola and Dimitrijević, Aleksandra and Bendova, Magdalena and Krstić, Jugoslav B. and Rocha, Raquel P. and Figueiredo, Jose L. and Bajuk-Bogdanović, Danica V. and Trtić-Petrović, Tatjana M. and Šljukić, Biljana", year = "2018", abstract = "Carbon materials, prepared by using different methods with ionic liquids, are compared as electrocatalysts for the oxygen reduction reaction (ORR). Materials were synthesized through the hydrothermal carbonization of glucose and by using the same method in the presence of 1-butyl-3-methylimidazolium methanesulfonate [bmim][MeSO3] as an additive. Another two carbon-based materials were prepared by using ionic-liquid-based methods: ionothermal carbonization of glucose using [bmim][MeSO3] as a recyclable medium for the carbonization reaction and by direct carbonization of the ionic liquid in a one-step method using [bmim][MeSO3] as the precursor for N- and S-doped porous carbon (Carb-IL). Characterization results showed the possibility of morphology and porosity control by using [bmim][MeSO3]. All materials were subsequently tested for the ORR in alkaline media. Carb-IL showed enhanced and stable electrocatalytic ORR activity, even in the presence of methanol, ethanol, and borohydride, opening the possibility for its application in fuel cells.", journal = "ChemElectroChem", title = "Electrocatalytic Activity of Ionic-Liquid-Derived Porous Carbon Materials for the Oxygen Reduction Reaction", volume = "5", number = "7", pages = "1037-1046", doi = "10.1002/celc.201701369" }
Zdolšek, N., Dimitrijević, A., Bendova, M., Krstić, J. B., Rocha, R. P., Figueiredo, J. L., Bajuk-Bogdanović, D. V., Trtić-Petrović, T. M.,& Šljukić, B.. (2018). Electrocatalytic Activity of Ionic-Liquid-Derived Porous Carbon Materials for the Oxygen Reduction Reaction. in ChemElectroChem, 5(7), 1037-1046. https://doi.org/10.1002/celc.201701369
Zdolšek N, Dimitrijević A, Bendova M, Krstić JB, Rocha RP, Figueiredo JL, Bajuk-Bogdanović DV, Trtić-Petrović TM, Šljukić B. Electrocatalytic Activity of Ionic-Liquid-Derived Porous Carbon Materials for the Oxygen Reduction Reaction. in ChemElectroChem. 2018;5(7):1037-1046. doi:10.1002/celc.201701369 .
Zdolšek, Nikola, Dimitrijević, Aleksandra, Bendova, Magdalena, Krstić, Jugoslav B., Rocha, Raquel P., Figueiredo, Jose L., Bajuk-Bogdanović, Danica V., Trtić-Petrović, Tatjana M., Šljukić, Biljana, "Electrocatalytic Activity of Ionic-Liquid-Derived Porous Carbon Materials for the Oxygen Reduction Reaction" in ChemElectroChem, 5, no. 7 (2018):1037-1046, https://doi.org/10.1002/celc.201701369 . .