Analysis of lead-based archaeological pottery glazes by laser induced breakdown spectroscopy
Samo za registrovane korisnike
2021
Autori
Kuzmanović, Miroslav M.Stancalie, Andrei
Milovanović, Dubravka S.
Staicu, Angela
Damjanović-Vasilić, Ljiljana S.
Ranković, Dragan
Savović, Jelena
Članak u časopisu (Objavljena verzija)
Metapodaci
Prikaz svih podataka o dokumentuApstrakt
The aim of this study was to demonstrate the potential of Laser-Induced Breakdown Spectroscopy (LIBS) in the analysis of pottery shards, which are commonly the most abundant artefacts recovered at archaeological sites. The analytical capability of LIBS in identification of elements characteristic to inorganic pigments used for decoration was assessed. Based on the specific elements detected in the LIBS spectra of glazes, correlations between the elemental composition of the glaze and the colours of the glazed surface were established. The results were in accordance with the previously reported Energy Dispersive X-ray Fluorescence (EDXRF) and Raman analyses of some of the samples, and with the presently performed XRF analysis. Two important parameters for plasma characterization, temperature and electron number density, were estimated from the spectral data. A potential use of LIBS for depth profiling was also investigated by analysing the silicon to aluminium intensity ratio as a funct...ion of the number of laser shots applied. Profilometry analysis of the damages created on the glazed surfaces by laser shots was used to estimate the average ablation depth and ablated mass.
Ključne reči:
Archaeological pottery / Elemental analysis / Lead-glazes / LIBS / XRFIzvor:
Optics & Laser Technology, 2021, 134, 106599-Finansiranje / projekti:
- Ministarstvo nauke, tehnološkog razvoja i inovacija Republike Srbije, institucionalno finansiranje - 200146 (Univerzitet u Beogradu, Fakultet za fizičku hemiju) (RS-MESTD-inst-2020-200146)
- Ministarstvo nauke, tehnološkog razvoja i inovacija Republike Srbije, institucionalno finansiranje - 200017 (Univerzitet u Beogradu, Institut za nuklearne nauke Vinča, Beograd-Vinča) (RS-MESTD-inst-2020-200017)
- Ministarstvo nauke, tehnološkog razvoja i inovacija Republike Srbije, institucionalno finansiranje - 200051 (Institut za opštu i fizičku hemiju, Beograd) (RS-MESTD-inst-2020-200051)
- Romanian Ministry of Education LAPLAS VI [16N/2019]
DOI: 10.1016/j.optlastec.2020.106599
ISSN: 0030-3992
WoS: 000591864800005
Scopus: 2-s2.0-85091080806
Kolekcije
Institucija/grupa
VinčaTY - JOUR AU - Kuzmanović, Miroslav M. AU - Stancalie, Andrei AU - Milovanović, Dubravka S. AU - Staicu, Angela AU - Damjanović-Vasilić, Ljiljana S. AU - Ranković, Dragan AU - Savović, Jelena PY - 2021 UR - https://vinar.vin.bg.ac.rs/handle/123456789/9644 AB - The aim of this study was to demonstrate the potential of Laser-Induced Breakdown Spectroscopy (LIBS) in the analysis of pottery shards, which are commonly the most abundant artefacts recovered at archaeological sites. The analytical capability of LIBS in identification of elements characteristic to inorganic pigments used for decoration was assessed. Based on the specific elements detected in the LIBS spectra of glazes, correlations between the elemental composition of the glaze and the colours of the glazed surface were established. The results were in accordance with the previously reported Energy Dispersive X-ray Fluorescence (EDXRF) and Raman analyses of some of the samples, and with the presently performed XRF analysis. Two important parameters for plasma characterization, temperature and electron number density, were estimated from the spectral data. A potential use of LIBS for depth profiling was also investigated by analysing the silicon to aluminium intensity ratio as a function of the number of laser shots applied. Profilometry analysis of the damages created on the glazed surfaces by laser shots was used to estimate the average ablation depth and ablated mass. T2 - Optics & Laser Technology T1 - Analysis of lead-based archaeological pottery glazes by laser induced breakdown spectroscopy VL - 134 SP - 106599 DO - 10.1016/j.optlastec.2020.106599 ER -
@article{ author = "Kuzmanović, Miroslav M. and Stancalie, Andrei and Milovanović, Dubravka S. and Staicu, Angela and Damjanović-Vasilić, Ljiljana S. and Ranković, Dragan and Savović, Jelena", year = "2021", abstract = "The aim of this study was to demonstrate the potential of Laser-Induced Breakdown Spectroscopy (LIBS) in the analysis of pottery shards, which are commonly the most abundant artefacts recovered at archaeological sites. The analytical capability of LIBS in identification of elements characteristic to inorganic pigments used for decoration was assessed. Based on the specific elements detected in the LIBS spectra of glazes, correlations between the elemental composition of the glaze and the colours of the glazed surface were established. The results were in accordance with the previously reported Energy Dispersive X-ray Fluorescence (EDXRF) and Raman analyses of some of the samples, and with the presently performed XRF analysis. Two important parameters for plasma characterization, temperature and electron number density, were estimated from the spectral data. A potential use of LIBS for depth profiling was also investigated by analysing the silicon to aluminium intensity ratio as a function of the number of laser shots applied. Profilometry analysis of the damages created on the glazed surfaces by laser shots was used to estimate the average ablation depth and ablated mass.", journal = "Optics & Laser Technology", title = "Analysis of lead-based archaeological pottery glazes by laser induced breakdown spectroscopy", volume = "134", pages = "106599", doi = "10.1016/j.optlastec.2020.106599" }
Kuzmanović, M. M., Stancalie, A., Milovanović, D. S., Staicu, A., Damjanović-Vasilić, L. S., Ranković, D.,& Savović, J.. (2021). Analysis of lead-based archaeological pottery glazes by laser induced breakdown spectroscopy. in Optics & Laser Technology, 134, 106599. https://doi.org/10.1016/j.optlastec.2020.106599
Kuzmanović MM, Stancalie A, Milovanović DS, Staicu A, Damjanović-Vasilić LS, Ranković D, Savović J. Analysis of lead-based archaeological pottery glazes by laser induced breakdown spectroscopy. in Optics & Laser Technology. 2021;134:106599. doi:10.1016/j.optlastec.2020.106599 .
Kuzmanović, Miroslav M., Stancalie, Andrei, Milovanović, Dubravka S., Staicu, Angela, Damjanović-Vasilić, Ljiljana S., Ranković, Dragan, Savović, Jelena, "Analysis of lead-based archaeological pottery glazes by laser induced breakdown spectroscopy" in Optics & Laser Technology, 134 (2021):106599, https://doi.org/10.1016/j.optlastec.2020.106599 . .