Experimental study of low-rank coals using simultaneous thermal analysis (TG–DTA) techniques under air conditions and radiation level characterization
Само за регистроване кориснике
2020
Аутори
Janković, Marija M.Janković, Bojan Ž.
Marinović-Cincović, Milena
Porobić, Slavica
Krneta-Nikolić, Jelena D.
Sarap, Nataša
Чланак у часопису (Објављена верзија)
,
© 2020, Akadémiai Kiadó, Budapest, Hungary
Метаподаци
Приказ свих података о документуАпстракт
Simultaneous thermal analysis (TG–DTA) of low-rank coals from different annual periods (2015 and 2018) which originate from Kolubara and Nikola Tesla A (TENT A) coal-fired power plants was studied to identify their combustion characteristics and self-ignition risks. In order to investigate kinetics of thermo-oxidative degradation, model-free models including the Friedman and Kissinger–Akahira–Sunose methods were applied. In accordance with obtained kinetic results, numerical optimization of combustion process was implemented. Homogeneous and heterogeneous types of ignition were identified for the tested coals, and factors that affect their occurrence are the used heating rate and volatile matter content. From thermal susceptibility graph, it was found that the tested coals expand in a wide range of self-ignition risk, depending on their coal rank. The youngest coal (TENT A (2018)) has the largest propensity to self-ignite among high-ranking coals. It was found that less tendency of 201...8 coals to show true isokinetic temperature in comparison with 2015 coals is a consequence of intraparticle diffusion limitations, and change of char properties, at higher conversion values. Gamma spectrometry analysis of coals showed that higher concentration of 40K radionuclide (which is in mineral composition) may contribute through its deposition on available sites, decreasing surface area for reaction with oxidizing species. © 2020, Akadémiai Kiadó, Budapest, Hungary.
Кључне речи:
Low-rank coals / Combustion properties / Self-ignition / Fluidity / Kinetic compensation effect / Diffusion limitationsИзвор:
Journal of Thermal Analysis and Calorimetry, 2020, 142, 2, 547-564Финансирање / пројекти:
- Динамика нелинеарних физичкохемијских и биохемијских система са моделирањем и предвиђањем њихових понашања под неравнотежним условима (RS-MESTD-Basic Research (BR or ON)-172015)
- Утицај величине, облика и структуре наночестица на њихова својства и својства нанокомпозита (RS-MESTD-Basic Research (BR or ON)-172056)
- Нове технологије за мониторинг и заштиту животног окружења од штетних хемијских супстанци и радијационог оптерећења (RS-MESTD-Integrated and Interdisciplinary Research (IIR or III)-43009)
DOI: 10.1007/s10973-020-09288-5
ISSN: 1388-6150
WoS: 000581102300002
Scopus: 2-s2.0-85078254345
Колекције
Институција/група
VinčaTY - JOUR AU - Janković, Marija M. AU - Janković, Bojan Ž. AU - Marinović-Cincović, Milena AU - Porobić, Slavica AU - Krneta-Nikolić, Jelena D. AU - Sarap, Nataša PY - 2020 UR - https://vinar.vin.bg.ac.rs/handle/123456789/8905 AB - Simultaneous thermal analysis (TG–DTA) of low-rank coals from different annual periods (2015 and 2018) which originate from Kolubara and Nikola Tesla A (TENT A) coal-fired power plants was studied to identify their combustion characteristics and self-ignition risks. In order to investigate kinetics of thermo-oxidative degradation, model-free models including the Friedman and Kissinger–Akahira–Sunose methods were applied. In accordance with obtained kinetic results, numerical optimization of combustion process was implemented. Homogeneous and heterogeneous types of ignition were identified for the tested coals, and factors that affect their occurrence are the used heating rate and volatile matter content. From thermal susceptibility graph, it was found that the tested coals expand in a wide range of self-ignition risk, depending on their coal rank. The youngest coal (TENT A (2018)) has the largest propensity to self-ignite among high-ranking coals. It was found that less tendency of 2018 coals to show true isokinetic temperature in comparison with 2015 coals is a consequence of intraparticle diffusion limitations, and change of char properties, at higher conversion values. Gamma spectrometry analysis of coals showed that higher concentration of 40K radionuclide (which is in mineral composition) may contribute through its deposition on available sites, decreasing surface area for reaction with oxidizing species. © 2020, Akadémiai Kiadó, Budapest, Hungary. T2 - Journal of Thermal Analysis and Calorimetry T1 - Experimental study of low-rank coals using simultaneous thermal analysis (TG–DTA) techniques under air conditions and radiation level characterization VL - 142 IS - 2 SP - 547 EP - 564 DO - 10.1007/s10973-020-09288-5 ER -
@article{ author = "Janković, Marija M. and Janković, Bojan Ž. and Marinović-Cincović, Milena and Porobić, Slavica and Krneta-Nikolić, Jelena D. and Sarap, Nataša", year = "2020", abstract = "Simultaneous thermal analysis (TG–DTA) of low-rank coals from different annual periods (2015 and 2018) which originate from Kolubara and Nikola Tesla A (TENT A) coal-fired power plants was studied to identify their combustion characteristics and self-ignition risks. In order to investigate kinetics of thermo-oxidative degradation, model-free models including the Friedman and Kissinger–Akahira–Sunose methods were applied. In accordance with obtained kinetic results, numerical optimization of combustion process was implemented. Homogeneous and heterogeneous types of ignition were identified for the tested coals, and factors that affect their occurrence are the used heating rate and volatile matter content. From thermal susceptibility graph, it was found that the tested coals expand in a wide range of self-ignition risk, depending on their coal rank. The youngest coal (TENT A (2018)) has the largest propensity to self-ignite among high-ranking coals. It was found that less tendency of 2018 coals to show true isokinetic temperature in comparison with 2015 coals is a consequence of intraparticle diffusion limitations, and change of char properties, at higher conversion values. Gamma spectrometry analysis of coals showed that higher concentration of 40K radionuclide (which is in mineral composition) may contribute through its deposition on available sites, decreasing surface area for reaction with oxidizing species. © 2020, Akadémiai Kiadó, Budapest, Hungary.", journal = "Journal of Thermal Analysis and Calorimetry", title = "Experimental study of low-rank coals using simultaneous thermal analysis (TG–DTA) techniques under air conditions and radiation level characterization", volume = "142", number = "2", pages = "547-564", doi = "10.1007/s10973-020-09288-5" }
Janković, M. M., Janković, B. Ž., Marinović-Cincović, M., Porobić, S., Krneta-Nikolić, J. D.,& Sarap, N.. (2020). Experimental study of low-rank coals using simultaneous thermal analysis (TG–DTA) techniques under air conditions and radiation level characterization. in Journal of Thermal Analysis and Calorimetry, 142(2), 547-564. https://doi.org/10.1007/s10973-020-09288-5
Janković MM, Janković BŽ, Marinović-Cincović M, Porobić S, Krneta-Nikolić JD, Sarap N. Experimental study of low-rank coals using simultaneous thermal analysis (TG–DTA) techniques under air conditions and radiation level characterization. in Journal of Thermal Analysis and Calorimetry. 2020;142(2):547-564. doi:10.1007/s10973-020-09288-5 .
Janković, Marija M., Janković, Bojan Ž., Marinović-Cincović, Milena, Porobić, Slavica, Krneta-Nikolić, Jelena D., Sarap, Nataša, "Experimental study of low-rank coals using simultaneous thermal analysis (TG–DTA) techniques under air conditions and radiation level characterization" in Journal of Thermal Analysis and Calorimetry, 142, no. 2 (2020):547-564, https://doi.org/10.1007/s10973-020-09288-5 . .