Electrochemical investigation of ionic liquid-derived porous carbon materials for supercapacitors: pseudocapacitance versus electrical double layer
Samo za registrovane korisnike
2019
Autori
Zdolšek, NikolaRocha, Raquel P.
Krstić, Jugoslav B.
Trtić-Petrović, Tatjana M.
Šljukić, Biljana
Figueiredo, Jose L.
Vujković, Milica
Članak u časopisu (Objavljena verzija)
,
© 2018 Elsevier Ltd
Metapodaci
Prikaz svih podataka o dokumentuApstrakt
This work shows the potential application of carbon materials prepared by three different ionic liquid-based methods, using 1-butyl-3-methylimidazolium methanesulfonate [bmim][MeSO3], for electrochemical supercapacitors. The effects of [bmim][MeSO3] on morphology, texture and surface chemistry of prepared materials has been explored by SEM/TEM, N2/CO2 adsorption measurements and XPS. The results indicate the possibility of synthesis of carbon materials with tunable physicochemical properties using ionic liquid based methods. The charge storage behavior of all materials was studied in three different pH aqueous electrolytes. The pseudocapacitive and double layer contributions were estimated and discussed from the aspect of the textural changes and the changes of the chemical composition of surface functional groups containing heteroatoms. C[dbnd]O type functional groups, with the contribution of COOH groups, were found to be responsible for a different amount of charge, which could be s...tored in alkaline and acidic electrolytic solution. The material prepared by direct carbonization of [bmim][MeSO3], showed the best electrochemical performance in alkaline electrolyte with a capacitance of 187 F g−1 at 5 mV s−1 (or 148 F g−1 at 1 A g−1), due to the contribution of both electric-double layer capacitance and pseudocapacitance which arises from oxygen, nitrogen and sulfur functional groups. © 2018 Elsevier Ltd
Ključne reči:
Supercapacitors / Charge storage / Pseudocapacitance / Ionic liquids / Carbon materialsIzvor:
Electrochimica Acta, 2019, 298, 541-551Finansiranje / projekti:
- Fizika i hemija sa jonskim snopovima (RS-MESTD-Integrated and Interdisciplinary Research (IIR or III)-45006)
- Litijum-jon baterije i gorivne ćelije-istraživanje i razvoj (RS-MESTD-Integrated and Interdisciplinary Research (IIR or III)-45014)
- Nanostrukturni funkcionalni i kompozitni materijali u katalitičkim i sorpcionim procesima (RS-MESTD-Integrated and Interdisciplinary Research (IIR or III)-45001)
- Project "AIProc-Mat@N2020-Advanced Industrial Processes and Materials for a Sustainable Northern Region of Portugal 2020" - Norte Portugal Regional Operational Programme (NORTE 2020), under the Portugal 2020 Partnership Agreement, through the European Regional Development Fund (ERDF) (NORTE-01-0145-FEDER-000006)
- Project POCI-01-0145-FEDER-006984 - Associate Laboratory LSRE-LCM funded by ERDF through COMPETE2020-Programa Operacional Competitividade e Internacionalizacao (POCI)
Napomena:
- Corrigendum at http://vinar.vin.bg.ac.rs/handle/123456789/8159
DOI: 10.1016/j.electacta.2018.12.129
ISSN: 0013-4686; 1873-3859
WoS: 000456432200057
Scopus: 2-s2.0-85059556534
URI
https://linkinghub.elsevier.com/retrieve/pii/S0013468618328482https://vinar.vin.bg.ac.rs/handle/123456789/8023
Kolekcije
Institucija/grupa
VinčaTY - JOUR AU - Zdolšek, Nikola AU - Rocha, Raquel P. AU - Krstić, Jugoslav B. AU - Trtić-Petrović, Tatjana M. AU - Šljukić, Biljana AU - Figueiredo, Jose L. AU - Vujković, Milica PY - 2019 UR - https://linkinghub.elsevier.com/retrieve/pii/S0013468618328482 UR - https://vinar.vin.bg.ac.rs/handle/123456789/8023 AB - This work shows the potential application of carbon materials prepared by three different ionic liquid-based methods, using 1-butyl-3-methylimidazolium methanesulfonate [bmim][MeSO3], for electrochemical supercapacitors. The effects of [bmim][MeSO3] on morphology, texture and surface chemistry of prepared materials has been explored by SEM/TEM, N2/CO2 adsorption measurements and XPS. The results indicate the possibility of synthesis of carbon materials with tunable physicochemical properties using ionic liquid based methods. The charge storage behavior of all materials was studied in three different pH aqueous electrolytes. The pseudocapacitive and double layer contributions were estimated and discussed from the aspect of the textural changes and the changes of the chemical composition of surface functional groups containing heteroatoms. C[dbnd]O type functional groups, with the contribution of COOH groups, were found to be responsible for a different amount of charge, which could be stored in alkaline and acidic electrolytic solution. The material prepared by direct carbonization of [bmim][MeSO3], showed the best electrochemical performance in alkaline electrolyte with a capacitance of 187 F g−1 at 5 mV s−1 (or 148 F g−1 at 1 A g−1), due to the contribution of both electric-double layer capacitance and pseudocapacitance which arises from oxygen, nitrogen and sulfur functional groups. © 2018 Elsevier Ltd T2 - Electrochimica Acta T1 - Electrochemical investigation of ionic liquid-derived porous carbon materials for supercapacitors: pseudocapacitance versus electrical double layer VL - 298 SP - 541 EP - 551 DO - 10.1016/j.electacta.2018.12.129 ER -
@article{ author = "Zdolšek, Nikola and Rocha, Raquel P. and Krstić, Jugoslav B. and Trtić-Petrović, Tatjana M. and Šljukić, Biljana and Figueiredo, Jose L. and Vujković, Milica", year = "2019", abstract = "This work shows the potential application of carbon materials prepared by three different ionic liquid-based methods, using 1-butyl-3-methylimidazolium methanesulfonate [bmim][MeSO3], for electrochemical supercapacitors. The effects of [bmim][MeSO3] on morphology, texture and surface chemistry of prepared materials has been explored by SEM/TEM, N2/CO2 adsorption measurements and XPS. The results indicate the possibility of synthesis of carbon materials with tunable physicochemical properties using ionic liquid based methods. The charge storage behavior of all materials was studied in three different pH aqueous electrolytes. The pseudocapacitive and double layer contributions were estimated and discussed from the aspect of the textural changes and the changes of the chemical composition of surface functional groups containing heteroatoms. C[dbnd]O type functional groups, with the contribution of COOH groups, were found to be responsible for a different amount of charge, which could be stored in alkaline and acidic electrolytic solution. The material prepared by direct carbonization of [bmim][MeSO3], showed the best electrochemical performance in alkaline electrolyte with a capacitance of 187 F g−1 at 5 mV s−1 (or 148 F g−1 at 1 A g−1), due to the contribution of both electric-double layer capacitance and pseudocapacitance which arises from oxygen, nitrogen and sulfur functional groups. © 2018 Elsevier Ltd", journal = "Electrochimica Acta", title = "Electrochemical investigation of ionic liquid-derived porous carbon materials for supercapacitors: pseudocapacitance versus electrical double layer", volume = "298", pages = "541-551", doi = "10.1016/j.electacta.2018.12.129" }
Zdolšek, N., Rocha, R. P., Krstić, J. B., Trtić-Petrović, T. M., Šljukić, B., Figueiredo, J. L.,& Vujković, M.. (2019). Electrochemical investigation of ionic liquid-derived porous carbon materials for supercapacitors: pseudocapacitance versus electrical double layer. in Electrochimica Acta, 298, 541-551. https://doi.org/10.1016/j.electacta.2018.12.129
Zdolšek N, Rocha RP, Krstić JB, Trtić-Petrović TM, Šljukić B, Figueiredo JL, Vujković M. Electrochemical investigation of ionic liquid-derived porous carbon materials for supercapacitors: pseudocapacitance versus electrical double layer. in Electrochimica Acta. 2019;298:541-551. doi:10.1016/j.electacta.2018.12.129 .
Zdolšek, Nikola, Rocha, Raquel P., Krstić, Jugoslav B., Trtić-Petrović, Tatjana M., Šljukić, Biljana, Figueiredo, Jose L., Vujković, Milica, "Electrochemical investigation of ionic liquid-derived porous carbon materials for supercapacitors: pseudocapacitance versus electrical double layer" in Electrochimica Acta, 298 (2019):541-551, https://doi.org/10.1016/j.electacta.2018.12.129 . .