Simple route for the preparation of graphene/poly(styrene-b-butadiene-b-styrene) nanocomposite films with enhanced electrical conductivity and hydrophobicity
Нема приказа
Аутори
Kepić, Dejan P.Ristić, Ivan S.
Marinović-Cincović, Milena
Peruško, Davor
Špitalsky, Zdenko
Pavlović, Vladimir B.
Budimir, Milica
Šiffalovič, Peter
Dramićanin, Miroslav
Mičušik, Matej
Kleinova, Angela
Janigova, Ivica
Marković, Zoran M.
Todorović-Marković, Biljana
Чланак у часопису (Објављена верзија)
,
© 2018 Society of Chemical Industry
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Приказ свих података о документуАпстракт
This paper reports a simple route for the preparation of graphene/poly(styrene-b-butadiene-b-styrene) (SBS) nanocomposite films employing a vacuum filtration method. Graphene is exfoliated well by an electrochemical procedure and homogeneously dispersed in the polymer matrix. The prepared nanocomposite films were characterized by XRD, Fourier transform IR (FTIR) spectroscopy, X-ray photoelectron spectroscopy (XPS), Raman spectroscopy, AFM and SEM. Morphological studies showed that graphene formed a smooth coating over the surface of SBS. The increase in graphene concentration induces the wrinkling of graphene sheets at the composite surface which causes a further increase in surface roughness. The FTIR, Raman and XPS spectra of graphene/SBS nanocomposite films indicate the strong interactions between graphene and the polymer matrix. According to the XRD patterns, introducing SBS into graphene did not modify the graphene structure additionally, i.e. the crystal lattice parameters do not... depend on SBS content in graphene/SBS nanocomposite films. The graphene/SBS nanocomposite films also exhibited better hydrophobicity due to the increased surface roughness and lower sheet resistivity (reduced 10 times) compared to exfoliated graphene.
Кључне речи:
layered structures / electrical properties / microstructures / surface analysisИзвор:
Polymer International, 2018, 67, 8, 1118-1127Финансирање / пројекти:
- Танки слојеви једнослојних угљеничних нанотуба и графена за примену у електроници (RS-MESTD-Basic Research (BR or ON)-172003)
- Вишескално структурирање полимерних нанокомпозита и функционалних материјала применом различитих прекурсора (RS-MESTD-Integrated and Interdisciplinary Research (IIR or III)-45022)
- Утицај величине, облика и структуре наночестица на њихова својства и својства нанокомпозита (RS-MESTD-Basic Research (BR or ON)-172056)
- bilateral project Serbia-Slovakia (SK-SRB-2016-0038)
- VEGA [2/0093/16]
- SASPRO Programme project (1237/02/02-b)
- European Union under REA (609427)
- Slovak Academy of Sciences
DOI: 10.1002/pi.5620
ISSN: 0959-8103; 1097-0126
WoS: 000438218900018
Scopus: 2-s2.0-85049837334
Колекције
Институција/група
VinčaTY - JOUR AU - Kepić, Dejan P. AU - Ristić, Ivan S. AU - Marinović-Cincović, Milena AU - Peruško, Davor AU - Špitalsky, Zdenko AU - Pavlović, Vladimir B. AU - Budimir, Milica AU - Šiffalovič, Peter AU - Dramićanin, Miroslav AU - Mičušik, Matej AU - Kleinova, Angela AU - Janigova, Ivica AU - Marković, Zoran M. AU - Todorović-Marković, Biljana PY - 2018 UR - http://doi.wiley.com/10.1002/pi.5620 UR - https://vinar.vin.bg.ac.rs/handle/123456789/7796 AB - This paper reports a simple route for the preparation of graphene/poly(styrene-b-butadiene-b-styrene) (SBS) nanocomposite films employing a vacuum filtration method. Graphene is exfoliated well by an electrochemical procedure and homogeneously dispersed in the polymer matrix. The prepared nanocomposite films were characterized by XRD, Fourier transform IR (FTIR) spectroscopy, X-ray photoelectron spectroscopy (XPS), Raman spectroscopy, AFM and SEM. Morphological studies showed that graphene formed a smooth coating over the surface of SBS. The increase in graphene concentration induces the wrinkling of graphene sheets at the composite surface which causes a further increase in surface roughness. The FTIR, Raman and XPS spectra of graphene/SBS nanocomposite films indicate the strong interactions between graphene and the polymer matrix. According to the XRD patterns, introducing SBS into graphene did not modify the graphene structure additionally, i.e. the crystal lattice parameters do not depend on SBS content in graphene/SBS nanocomposite films. The graphene/SBS nanocomposite films also exhibited better hydrophobicity due to the increased surface roughness and lower sheet resistivity (reduced 10 times) compared to exfoliated graphene. T2 - Polymer International T1 - Simple route for the preparation of graphene/poly(styrene-b-butadiene-b-styrene) nanocomposite films with enhanced electrical conductivity and hydrophobicity VL - 67 IS - 8 SP - 1118 EP - 1127 DO - 10.1002/pi.5620 ER -
@article{ author = "Kepić, Dejan P. and Ristić, Ivan S. and Marinović-Cincović, Milena and Peruško, Davor and Špitalsky, Zdenko and Pavlović, Vladimir B. and Budimir, Milica and Šiffalovič, Peter and Dramićanin, Miroslav and Mičušik, Matej and Kleinova, Angela and Janigova, Ivica and Marković, Zoran M. and Todorović-Marković, Biljana", year = "2018", abstract = "This paper reports a simple route for the preparation of graphene/poly(styrene-b-butadiene-b-styrene) (SBS) nanocomposite films employing a vacuum filtration method. Graphene is exfoliated well by an electrochemical procedure and homogeneously dispersed in the polymer matrix. The prepared nanocomposite films were characterized by XRD, Fourier transform IR (FTIR) spectroscopy, X-ray photoelectron spectroscopy (XPS), Raman spectroscopy, AFM and SEM. Morphological studies showed that graphene formed a smooth coating over the surface of SBS. The increase in graphene concentration induces the wrinkling of graphene sheets at the composite surface which causes a further increase in surface roughness. The FTIR, Raman and XPS spectra of graphene/SBS nanocomposite films indicate the strong interactions between graphene and the polymer matrix. According to the XRD patterns, introducing SBS into graphene did not modify the graphene structure additionally, i.e. the crystal lattice parameters do not depend on SBS content in graphene/SBS nanocomposite films. The graphene/SBS nanocomposite films also exhibited better hydrophobicity due to the increased surface roughness and lower sheet resistivity (reduced 10 times) compared to exfoliated graphene.", journal = "Polymer International", title = "Simple route for the preparation of graphene/poly(styrene-b-butadiene-b-styrene) nanocomposite films with enhanced electrical conductivity and hydrophobicity", volume = "67", number = "8", pages = "1118-1127", doi = "10.1002/pi.5620" }
Kepić, D. P., Ristić, I. S., Marinović-Cincović, M., Peruško, D., Špitalsky, Z., Pavlović, V. B., Budimir, M., Šiffalovič, P., Dramićanin, M., Mičušik, M., Kleinova, A., Janigova, I., Marković, Z. M.,& Todorović-Marković, B.. (2018). Simple route for the preparation of graphene/poly(styrene-b-butadiene-b-styrene) nanocomposite films with enhanced electrical conductivity and hydrophobicity. in Polymer International, 67(8), 1118-1127. https://doi.org/10.1002/pi.5620
Kepić DP, Ristić IS, Marinović-Cincović M, Peruško D, Špitalsky Z, Pavlović VB, Budimir M, Šiffalovič P, Dramićanin M, Mičušik M, Kleinova A, Janigova I, Marković ZM, Todorović-Marković B. Simple route for the preparation of graphene/poly(styrene-b-butadiene-b-styrene) nanocomposite films with enhanced electrical conductivity and hydrophobicity. in Polymer International. 2018;67(8):1118-1127. doi:10.1002/pi.5620 .
Kepić, Dejan P., Ristić, Ivan S., Marinović-Cincović, Milena, Peruško, Davor, Špitalsky, Zdenko, Pavlović, Vladimir B., Budimir, Milica, Šiffalovič, Peter, Dramićanin, Miroslav, Mičušik, Matej, Kleinova, Angela, Janigova, Ivica, Marković, Zoran M., Todorović-Marković, Biljana, "Simple route for the preparation of graphene/poly(styrene-b-butadiene-b-styrene) nanocomposite films with enhanced electrical conductivity and hydrophobicity" in Polymer International, 67, no. 8 (2018):1118-1127, https://doi.org/10.1002/pi.5620 . .