ZnO micro and nanocrystals with enhanced visible light absorption
Нема приказа
Аутори
Stanković, AnaStojanović, Zoran S.
Veselinović, Ljiljana M.
Škapin, Srečo Davor
Bračko, Ines
Marković, Smilja
Uskoković, Dragan
Чланак у часопису
Метаподаци
Приказ свих података о документуАпстракт
In this paper, we investigate the effect of the particle size and morphology on the optical properties of ZnO. A series of ZnO micro and nanocrystals were synthesized by the hydrothermal processing of zinc acetate dihydrate and sodium hydroxide as the starting materials, and polyvinylpyrrolidone (PVP) as the polymer surfactant. The particle size and morphology were tailored by adjusting the reactant molar ratios [Zn2+]/[OH−], while the reaction temperature and the time remained unchanged. X-ray diffraction (XRD), transmission electron microscopy (TEM), selected area electron diffraction (SAED) and high-resolution TEM (HRTEM) have shown that the micro and nanocrystals have a high crystalline pure wurtzite-type hexagonal structure with nanosized crystallites. The size and morphology of the ZnO micro and nanocrystals were investigated by field emission scanning electron microscopy (FE-SEM), which showed a modification from micro-rods via hexagonal-faceted prismatic morphology to nanospher...es, caused by simple adjustment of the reactant molar ratio [Zn2+]/[OH−] from 1:1 to 1:5. The optical properties of the ZnO micro and nanocrystals, as well as their dependence on the particle size and morphology were investigated by Raman and ultraviolet–visible (UV–vis) diffuse reflectance spectroscopy (DRS). The UV–vis spectra showed that the modification of the particle size and morphology from nanospheres to micro-rods resulted in increased absorption, and a slight red-shift of the absorption edge (0.06 eV). Besides, the band gap energy of the synthesized ZnO micro and nanocrystals showed the red shift (∼0.20 eV) compared to bulk ZnO. According to the results of a Raman spectroscopy, the enhanced visible light absorption of the ZnO micro and nanocrystals is related to two phenomena: (1) the existence of lattice defects (oxygen vacancies and zinc interstitials), and (2) the particle surface sensitization by PVP.
Кључне речи:
zinc oxide / hydrothermal synthesis / morphology / optical propertiesИзвор:
Materials Science and Engineering: B, 2012, 1038-1045Издавач:
- Elsevier
Финансирање / пројекти:
DOI: 10.1016/j.mseb.2012.05.013
ISSN: 0921-5107
WoS: 000309313000005
Scopus: 2-s2.0-84863989861
Колекције
Институција/група
VinčaTY - JOUR AU - Stanković, Ana AU - Stojanović, Zoran S. AU - Veselinović, Ljiljana M. AU - Škapin, Srečo Davor AU - Bračko, Ines AU - Marković, Smilja AU - Uskoković, Dragan PY - 2012 UR - http://dais.sanu.ac.rs/123456789/486 UR - https://vinar.vin.bg.ac.rs/handle/123456789/7450 AB - In this paper, we investigate the effect of the particle size and morphology on the optical properties of ZnO. A series of ZnO micro and nanocrystals were synthesized by the hydrothermal processing of zinc acetate dihydrate and sodium hydroxide as the starting materials, and polyvinylpyrrolidone (PVP) as the polymer surfactant. The particle size and morphology were tailored by adjusting the reactant molar ratios [Zn2+]/[OH−], while the reaction temperature and the time remained unchanged. X-ray diffraction (XRD), transmission electron microscopy (TEM), selected area electron diffraction (SAED) and high-resolution TEM (HRTEM) have shown that the micro and nanocrystals have a high crystalline pure wurtzite-type hexagonal structure with nanosized crystallites. The size and morphology of the ZnO micro and nanocrystals were investigated by field emission scanning electron microscopy (FE-SEM), which showed a modification from micro-rods via hexagonal-faceted prismatic morphology to nanospheres, caused by simple adjustment of the reactant molar ratio [Zn2+]/[OH−] from 1:1 to 1:5. The optical properties of the ZnO micro and nanocrystals, as well as their dependence on the particle size and morphology were investigated by Raman and ultraviolet–visible (UV–vis) diffuse reflectance spectroscopy (DRS). The UV–vis spectra showed that the modification of the particle size and morphology from nanospheres to micro-rods resulted in increased absorption, and a slight red-shift of the absorption edge (0.06 eV). Besides, the band gap energy of the synthesized ZnO micro and nanocrystals showed the red shift (∼0.20 eV) compared to bulk ZnO. According to the results of a Raman spectroscopy, the enhanced visible light absorption of the ZnO micro and nanocrystals is related to two phenomena: (1) the existence of lattice defects (oxygen vacancies and zinc interstitials), and (2) the particle surface sensitization by PVP. PB - Elsevier T2 - Materials Science and Engineering: B T1 - ZnO micro and nanocrystals with enhanced visible light absorption SP - 1038 EP - 1045 DO - 10.1016/j.mseb.2012.05.013 ER -
@article{ author = "Stanković, Ana and Stojanović, Zoran S. and Veselinović, Ljiljana M. and Škapin, Srečo Davor and Bračko, Ines and Marković, Smilja and Uskoković, Dragan", year = "2012", abstract = "In this paper, we investigate the effect of the particle size and morphology on the optical properties of ZnO. A series of ZnO micro and nanocrystals were synthesized by the hydrothermal processing of zinc acetate dihydrate and sodium hydroxide as the starting materials, and polyvinylpyrrolidone (PVP) as the polymer surfactant. The particle size and morphology were tailored by adjusting the reactant molar ratios [Zn2+]/[OH−], while the reaction temperature and the time remained unchanged. X-ray diffraction (XRD), transmission electron microscopy (TEM), selected area electron diffraction (SAED) and high-resolution TEM (HRTEM) have shown that the micro and nanocrystals have a high crystalline pure wurtzite-type hexagonal structure with nanosized crystallites. The size and morphology of the ZnO micro and nanocrystals were investigated by field emission scanning electron microscopy (FE-SEM), which showed a modification from micro-rods via hexagonal-faceted prismatic morphology to nanospheres, caused by simple adjustment of the reactant molar ratio [Zn2+]/[OH−] from 1:1 to 1:5. The optical properties of the ZnO micro and nanocrystals, as well as their dependence on the particle size and morphology were investigated by Raman and ultraviolet–visible (UV–vis) diffuse reflectance spectroscopy (DRS). The UV–vis spectra showed that the modification of the particle size and morphology from nanospheres to micro-rods resulted in increased absorption, and a slight red-shift of the absorption edge (0.06 eV). Besides, the band gap energy of the synthesized ZnO micro and nanocrystals showed the red shift (∼0.20 eV) compared to bulk ZnO. According to the results of a Raman spectroscopy, the enhanced visible light absorption of the ZnO micro and nanocrystals is related to two phenomena: (1) the existence of lattice defects (oxygen vacancies and zinc interstitials), and (2) the particle surface sensitization by PVP.", publisher = "Elsevier", journal = "Materials Science and Engineering: B", title = "ZnO micro and nanocrystals with enhanced visible light absorption", pages = "1038-1045", doi = "10.1016/j.mseb.2012.05.013" }
Stanković, A., Stojanović, Z. S., Veselinović, L. M., Škapin, S. D., Bračko, I., Marković, S.,& Uskoković, D.. (2012). ZnO micro and nanocrystals with enhanced visible light absorption. in Materials Science and Engineering: B Elsevier., 1038-1045. https://doi.org/10.1016/j.mseb.2012.05.013
Stanković A, Stojanović ZS, Veselinović LM, Škapin SD, Bračko I, Marković S, Uskoković D. ZnO micro and nanocrystals with enhanced visible light absorption. in Materials Science and Engineering: B. 2012;:1038-1045. doi:10.1016/j.mseb.2012.05.013 .
Stanković, Ana, Stojanović, Zoran S., Veselinović, Ljiljana M., Škapin, Srečo Davor, Bračko, Ines, Marković, Smilja, Uskoković, Dragan, "ZnO micro and nanocrystals with enhanced visible light absorption" in Materials Science and Engineering: B (2012):1038-1045, https://doi.org/10.1016/j.mseb.2012.05.013 . .