Densification behaviour of nano-size CeO2
Апстракт
A nano-sized CeO2 powder was synthesized by a modified glycine nitrate process (MGNP). The synthesized powder was characterized by X-ray diffraction (XRD), the Brunauer Emmett Teller (BET) method, and transmission electron microscopy (TEM). The lattice parameter and crystallite size were determined by the Rietveld refinement of X-ray diffraction patterns. The shrinkage kinetics of the green body was continuously monitored in air and in oxygen atmospheres using a high temperature dilatometer up to 1500 degrees C. During the high temperature sintering in redox reaction occurred (Ce4+ was partially reduced to Ce3+ and oxygen gas was released). The redox reaction influenced the sintering behaviour of CeO2, resulting in a decrease in density. On the basis of shrinkage kinetics data in oxygen atmosphere a master sintering curve for CeO2 was constructed. Using the concept of the master sintering curve, the densification behaviour in oxygen atmosphere was successfully predicted from early to f...inal stages of sintering. During sintering of CeO2 at lower temperature in air atmosphere a significant contribution of the surface diffusion was observed.
Кључне речи:
ceria nanopowders / sintering / the master sintering curve.Извор:
Materials Science Forum, 2007, 555, 189-+Напомена:
- Research Trends in Contemporary Materials Science, 8th Conference of the Yugoslav-Materials-Research-Society (Yu-MRS), Sep 04-08, 2006, Herceg Novi, Montenegro
Колекције
Институција/група
VinčaTY - CONF AU - Đurović, Dejan R. AU - Zinkevich, M. AU - Bošković, Snežana B. AU - Srot, V. AU - Aldinger, Fritz PY - 2007 UR - https://vinar.vin.bg.ac.rs/handle/123456789/6683 AB - A nano-sized CeO2 powder was synthesized by a modified glycine nitrate process (MGNP). The synthesized powder was characterized by X-ray diffraction (XRD), the Brunauer Emmett Teller (BET) method, and transmission electron microscopy (TEM). The lattice parameter and crystallite size were determined by the Rietveld refinement of X-ray diffraction patterns. The shrinkage kinetics of the green body was continuously monitored in air and in oxygen atmospheres using a high temperature dilatometer up to 1500 degrees C. During the high temperature sintering in redox reaction occurred (Ce4+ was partially reduced to Ce3+ and oxygen gas was released). The redox reaction influenced the sintering behaviour of CeO2, resulting in a decrease in density. On the basis of shrinkage kinetics data in oxygen atmosphere a master sintering curve for CeO2 was constructed. Using the concept of the master sintering curve, the densification behaviour in oxygen atmosphere was successfully predicted from early to final stages of sintering. During sintering of CeO2 at lower temperature in air atmosphere a significant contribution of the surface diffusion was observed. C3 - Materials Science Forum T1 - Densification behaviour of nano-size CeO2 VL - 555 SP - 189 EP - + DO - 10.4028/www.scientific.net/MSF.555.189 ER -
@conference{ author = "Đurović, Dejan R. and Zinkevich, M. and Bošković, Snežana B. and Srot, V. and Aldinger, Fritz", year = "2007", abstract = "A nano-sized CeO2 powder was synthesized by a modified glycine nitrate process (MGNP). The synthesized powder was characterized by X-ray diffraction (XRD), the Brunauer Emmett Teller (BET) method, and transmission electron microscopy (TEM). The lattice parameter and crystallite size were determined by the Rietveld refinement of X-ray diffraction patterns. The shrinkage kinetics of the green body was continuously monitored in air and in oxygen atmospheres using a high temperature dilatometer up to 1500 degrees C. During the high temperature sintering in redox reaction occurred (Ce4+ was partially reduced to Ce3+ and oxygen gas was released). The redox reaction influenced the sintering behaviour of CeO2, resulting in a decrease in density. On the basis of shrinkage kinetics data in oxygen atmosphere a master sintering curve for CeO2 was constructed. Using the concept of the master sintering curve, the densification behaviour in oxygen atmosphere was successfully predicted from early to final stages of sintering. During sintering of CeO2 at lower temperature in air atmosphere a significant contribution of the surface diffusion was observed.", journal = "Materials Science Forum", title = "Densification behaviour of nano-size CeO2", volume = "555", pages = "189-+", doi = "10.4028/www.scientific.net/MSF.555.189" }
Đurović, D. R., Zinkevich, M., Bošković, S. B., Srot, V.,& Aldinger, F.. (2007). Densification behaviour of nano-size CeO2. in Materials Science Forum, 555, 189-+. https://doi.org/10.4028/www.scientific.net/MSF.555.189
Đurović DR, Zinkevich M, Bošković SB, Srot V, Aldinger F. Densification behaviour of nano-size CeO2. in Materials Science Forum. 2007;555:189-+. doi:10.4028/www.scientific.net/MSF.555.189 .
Đurović, Dejan R., Zinkevich, M., Bošković, Snežana B., Srot, V., Aldinger, Fritz, "Densification behaviour of nano-size CeO2" in Materials Science Forum, 555 (2007):189-+, https://doi.org/10.4028/www.scientific.net/MSF.555.189 . .