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dc.creatorMarinović-Cincović, Milena
dc.creatorKačarević-Popović, Zorica M.
dc.creatorBabić, Dragan
dc.date.accessioned2018-03-03T13:57:56Z
dc.date.available2018-03-03T13:57:56Z
dc.date.issued2003
dc.identifier.issn0969-806X
dc.identifier.urihttps://vinar.vin.bg.ac.rs/handle/123456789/6368
dc.description.abstractThe heat properties of gamma-ray crosslinked polyethylene are determined by differential scanning calorimetry (DSC). The changes in the supermolecular structure are evaluated and correlated to the heterogeneous distribution of crosslinks in polymer structure caused by the specific early excitation process. The nonlinear change in enthalpy of fusion, peak melting temperature, activation energy of ordering transition, number of defects, and maximal specific heat capacity with absorbed dose is explained in terms of separated crosslinking processes, fast on the lamellae surfaces and slow in the crystal core at double bond site that is evident for absorbed dose greater than 1000 kGy. (C) 2003 Elsevier Science Ltd. All rights reserved.en
dc.rightsrestrictedAccessen
dc.sourceRadiation Physics and Chemistryen
dc.subjectpolyethyleneen
dc.subjectgamma-irradiationen
dc.subjectcrosslinkingen
dc.subjectsupermolecular structureen
dc.titleStructural changes in highly crosslinked polyethylene irradiated in absence of oxygenen
dc.typearticleen
dcterms.abstractМариновић-Цинцовић Милена; Бабиц, Д; Качаревић-Поповић Зорица М;
dc.citation.volume67
dc.citation.issue3-4
dc.citation.spage425
dc.citation.epage429
dc.identifier.wos000183749200044
dc.identifier.doi10.1016/S0969-806X(03)00079-3
dc.citation.rankM22
dc.description.other10th Tihany Symposium on Radiation Chemistry, Aug 31-Sep 05, 2002, Sopron, Hungaryen
dc.identifier.scopus2-s2.0-0038696003


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