Densities, Refractive Indices, Viscosities, and Spectroscopic Study of 1-Amino-2-propanol+1-Butanol and+2-Butanol Solutions at (288.15 to 333.15) K
Nema prikaza
Autori
Spasojević, Vuk D.Djordjevic, Bojan D.
Šerbanović, Slobodan P.
Radović, Ivona R.
Kijevčanin, Mirjana Lj.
Članak u časopisu
Metapodaci
Prikaz svih podataka o dokumentuApstrakt
Densities, refractive indices, and viscosities of 1-amino-2-propanol (monoisopropanolamine (MIPA)) + 1-butanol and 1-amino-2-propanol + 2-butanol solutions are reported over the entire range of mole fractions and the temperature range from (288.15 to 333.15) K. The Redlich-Kister relation was used for correlation of measured results of excess molar volumes, viscosities, and refractive indices as a function of temperature and composition. Partial molar volumes at infinite dilution were determined from apparent molar volumes. Negative values for excess molar volumes, refractive indices, and viscosity deviations are observed over the entire composition range. The viscosities of 1-amino-2-propanol with 1-butanol and 1-amino-2-propanol with 2-butanol are well represented by an Arrhenius equation. Activation energies for viscous flows are determined by linearization of the Arrhenius equation, providing a clear explanation of the influence on hydrogen bonding. In order to confirm molecular in...teractions between compounds obtained by analysis of infinite dilution of solute, a FT-IR spectroscopy study was performed at T = 298.15 K. Interactional and structural effects were investigated through calculations of excess Gibbs free energy of activation of viscous flow.
Izvor:
Journal of Chemical and Engineering Data, 2014, 59, 6, 1817-1829Finansiranje / projekti:
- Novi industrijski i ekološki aspekti primene hemijske termodinamike na unapređenje hemijskih procesa sa višefaznim i višekomponentnim sistemima (RS-MESTD-Basic Research (BR or ON)-172063)
- Ministry of Science and Environmental Protection, Serbia
DOI: 10.1021/je401036f
ISSN: 0021-9568
WoS: 000337336700012
Scopus: 2-s2.0-84902357305
Kolekcije
Institucija/grupa
VinčaTY - JOUR AU - Spasojević, Vuk D. AU - Djordjevic, Bojan D. AU - Šerbanović, Slobodan P. AU - Radović, Ivona R. AU - Kijevčanin, Mirjana Lj. PY - 2014 UR - https://vinar.vin.bg.ac.rs/handle/123456789/6039 AB - Densities, refractive indices, and viscosities of 1-amino-2-propanol (monoisopropanolamine (MIPA)) + 1-butanol and 1-amino-2-propanol + 2-butanol solutions are reported over the entire range of mole fractions and the temperature range from (288.15 to 333.15) K. The Redlich-Kister relation was used for correlation of measured results of excess molar volumes, viscosities, and refractive indices as a function of temperature and composition. Partial molar volumes at infinite dilution were determined from apparent molar volumes. Negative values for excess molar volumes, refractive indices, and viscosity deviations are observed over the entire composition range. The viscosities of 1-amino-2-propanol with 1-butanol and 1-amino-2-propanol with 2-butanol are well represented by an Arrhenius equation. Activation energies for viscous flows are determined by linearization of the Arrhenius equation, providing a clear explanation of the influence on hydrogen bonding. In order to confirm molecular interactions between compounds obtained by analysis of infinite dilution of solute, a FT-IR spectroscopy study was performed at T = 298.15 K. Interactional and structural effects were investigated through calculations of excess Gibbs free energy of activation of viscous flow. T2 - Journal of Chemical and Engineering Data T1 - Densities, Refractive Indices, Viscosities, and Spectroscopic Study of 1-Amino-2-propanol+1-Butanol and+2-Butanol Solutions at (288.15 to 333.15) K VL - 59 IS - 6 SP - 1817 EP - 1829 DO - 10.1021/je401036f ER -
@article{ author = "Spasojević, Vuk D. and Djordjevic, Bojan D. and Šerbanović, Slobodan P. and Radović, Ivona R. and Kijevčanin, Mirjana Lj.", year = "2014", abstract = "Densities, refractive indices, and viscosities of 1-amino-2-propanol (monoisopropanolamine (MIPA)) + 1-butanol and 1-amino-2-propanol + 2-butanol solutions are reported over the entire range of mole fractions and the temperature range from (288.15 to 333.15) K. The Redlich-Kister relation was used for correlation of measured results of excess molar volumes, viscosities, and refractive indices as a function of temperature and composition. Partial molar volumes at infinite dilution were determined from apparent molar volumes. Negative values for excess molar volumes, refractive indices, and viscosity deviations are observed over the entire composition range. The viscosities of 1-amino-2-propanol with 1-butanol and 1-amino-2-propanol with 2-butanol are well represented by an Arrhenius equation. Activation energies for viscous flows are determined by linearization of the Arrhenius equation, providing a clear explanation of the influence on hydrogen bonding. In order to confirm molecular interactions between compounds obtained by analysis of infinite dilution of solute, a FT-IR spectroscopy study was performed at T = 298.15 K. Interactional and structural effects were investigated through calculations of excess Gibbs free energy of activation of viscous flow.", journal = "Journal of Chemical and Engineering Data", title = "Densities, Refractive Indices, Viscosities, and Spectroscopic Study of 1-Amino-2-propanol+1-Butanol and+2-Butanol Solutions at (288.15 to 333.15) K", volume = "59", number = "6", pages = "1817-1829", doi = "10.1021/je401036f" }
Spasojević, V. D., Djordjevic, B. D., Šerbanović, S. P., Radović, I. R.,& Kijevčanin, M. Lj.. (2014). Densities, Refractive Indices, Viscosities, and Spectroscopic Study of 1-Amino-2-propanol+1-Butanol and+2-Butanol Solutions at (288.15 to 333.15) K. in Journal of Chemical and Engineering Data, 59(6), 1817-1829. https://doi.org/10.1021/je401036f
Spasojević VD, Djordjevic BD, Šerbanović SP, Radović IR, Kijevčanin ML. Densities, Refractive Indices, Viscosities, and Spectroscopic Study of 1-Amino-2-propanol+1-Butanol and+2-Butanol Solutions at (288.15 to 333.15) K. in Journal of Chemical and Engineering Data. 2014;59(6):1817-1829. doi:10.1021/je401036f .
Spasojević, Vuk D., Djordjevic, Bojan D., Šerbanović, Slobodan P., Radović, Ivona R., Kijevčanin, Mirjana Lj., "Densities, Refractive Indices, Viscosities, and Spectroscopic Study of 1-Amino-2-propanol+1-Butanol and+2-Butanol Solutions at (288.15 to 333.15) K" in Journal of Chemical and Engineering Data, 59, no. 6 (2014):1817-1829, https://doi.org/10.1021/je401036f . .