Structural and magnetic properties of nanocomposites based on nanostructured polyaniline and titania nanotubes
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Radoičić, Marija B.Ćirić-Marjanović, Gordana N.
Šaponjić, Zoran
Mitrić, Miodrag
Konstantinović, Zorica
Stoiljković, Milovan
Nedeljković, Jovan
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Nanocomposites consisting of self-assembled polyaniline (PANI) nanostructures and titania nanotubes (TiO2-NT) were synthesized by the oxidative polymerization of aniline with ammonium peroxydisulfate in an aqueous dispersion of TiO2-NT (outer diameter similar to 10 nm), without added acid. The influence of initial mole ratio of aniline to TiO2 (80, 20, and 5) on the morphology, electrical conductivity, molecular structure, crystallinity, and magnetic properties of synthesized PANI/TiO2 nanocomposites was studied. Transmission electron microscopy, Raman spectroscopy, and X-ray powder diffraction proved that the shape and structure of TiO2-NT in the final nanocomposites were preserved. The shape of PANI nanostructures formed in the nanocomposites was influenced by the initial aniline/TiO2-NT mole ratio. Nanotubes and nanorods are predominant PANI nanostructures in the nanocomposite prepared with the highest aniline/TiO2 mol ratio of 80. The decrease of aniline/TiO2 molar ratio induced mo...re pronounced formation of nanorod network. The electrical conductivity of PANI/TiO2 nanocomposites was in the range (1.3-2.4) x 10(-3) S cm(-1). The nanocomposites exhibit weak ferromagnetic behavior. Approximately order of magnitude lower values of coercive field and remanent magnetization were obtained for nanocomposite samples in comparison to pure PANI.
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Journal of Materials Science, 2013, 48, 17, 5776-5787Funding / projects:
- Materials of Reduced Dimensions for Efficient Light Harvesting and Energy conversion (RS-MESTD-Integrated and Interdisciplinary Research (IIR or III)-45020)
- Size-, shape- and structure- dependent properties of nanoparticles and nanocomposites (RS-MESTD-Basic Research (BR or ON)-172056)
- Electroconducting and redox-active polymers and oligomers: synthesis, structure, properties and applications (RS-MESTD-Basic Research (BR or ON)-172043)
- Spanish MEC through the RyC Program
DOI: 10.1007/s10853-013-7370-1
ISSN: 0022-2461
WoS: 000321271100009
Scopus: 2-s2.0-84879933135
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VinčaTY - JOUR AU - Radoičić, Marija B. AU - Ćirić-Marjanović, Gordana N. AU - Šaponjić, Zoran AU - Mitrić, Miodrag AU - Konstantinović, Zorica AU - Stoiljković, Milovan AU - Nedeljković, Jovan PY - 2013 UR - https://vinar.vin.bg.ac.rs/handle/123456789/5573 AB - Nanocomposites consisting of self-assembled polyaniline (PANI) nanostructures and titania nanotubes (TiO2-NT) were synthesized by the oxidative polymerization of aniline with ammonium peroxydisulfate in an aqueous dispersion of TiO2-NT (outer diameter similar to 10 nm), without added acid. The influence of initial mole ratio of aniline to TiO2 (80, 20, and 5) on the morphology, electrical conductivity, molecular structure, crystallinity, and magnetic properties of synthesized PANI/TiO2 nanocomposites was studied. Transmission electron microscopy, Raman spectroscopy, and X-ray powder diffraction proved that the shape and structure of TiO2-NT in the final nanocomposites were preserved. The shape of PANI nanostructures formed in the nanocomposites was influenced by the initial aniline/TiO2-NT mole ratio. Nanotubes and nanorods are predominant PANI nanostructures in the nanocomposite prepared with the highest aniline/TiO2 mol ratio of 80. The decrease of aniline/TiO2 molar ratio induced more pronounced formation of nanorod network. The electrical conductivity of PANI/TiO2 nanocomposites was in the range (1.3-2.4) x 10(-3) S cm(-1). The nanocomposites exhibit weak ferromagnetic behavior. Approximately order of magnitude lower values of coercive field and remanent magnetization were obtained for nanocomposite samples in comparison to pure PANI. T2 - Journal of Materials Science T1 - Structural and magnetic properties of nanocomposites based on nanostructured polyaniline and titania nanotubes VL - 48 IS - 17 SP - 5776 EP - 5787 DO - 10.1007/s10853-013-7370-1 ER -
@article{ author = "Radoičić, Marija B. and Ćirić-Marjanović, Gordana N. and Šaponjić, Zoran and Mitrić, Miodrag and Konstantinović, Zorica and Stoiljković, Milovan and Nedeljković, Jovan", year = "2013", abstract = "Nanocomposites consisting of self-assembled polyaniline (PANI) nanostructures and titania nanotubes (TiO2-NT) were synthesized by the oxidative polymerization of aniline with ammonium peroxydisulfate in an aqueous dispersion of TiO2-NT (outer diameter similar to 10 nm), without added acid. The influence of initial mole ratio of aniline to TiO2 (80, 20, and 5) on the morphology, electrical conductivity, molecular structure, crystallinity, and magnetic properties of synthesized PANI/TiO2 nanocomposites was studied. Transmission electron microscopy, Raman spectroscopy, and X-ray powder diffraction proved that the shape and structure of TiO2-NT in the final nanocomposites were preserved. The shape of PANI nanostructures formed in the nanocomposites was influenced by the initial aniline/TiO2-NT mole ratio. Nanotubes and nanorods are predominant PANI nanostructures in the nanocomposite prepared with the highest aniline/TiO2 mol ratio of 80. The decrease of aniline/TiO2 molar ratio induced more pronounced formation of nanorod network. The electrical conductivity of PANI/TiO2 nanocomposites was in the range (1.3-2.4) x 10(-3) S cm(-1). The nanocomposites exhibit weak ferromagnetic behavior. Approximately order of magnitude lower values of coercive field and remanent magnetization were obtained for nanocomposite samples in comparison to pure PANI.", journal = "Journal of Materials Science", title = "Structural and magnetic properties of nanocomposites based on nanostructured polyaniline and titania nanotubes", volume = "48", number = "17", pages = "5776-5787", doi = "10.1007/s10853-013-7370-1" }
Radoičić, M. B., Ćirić-Marjanović, G. N., Šaponjić, Z., Mitrić, M., Konstantinović, Z., Stoiljković, M.,& Nedeljković, J.. (2013). Structural and magnetic properties of nanocomposites based on nanostructured polyaniline and titania nanotubes. in Journal of Materials Science, 48(17), 5776-5787. https://doi.org/10.1007/s10853-013-7370-1
Radoičić MB, Ćirić-Marjanović GN, Šaponjić Z, Mitrić M, Konstantinović Z, Stoiljković M, Nedeljković J. Structural and magnetic properties of nanocomposites based on nanostructured polyaniline and titania nanotubes. in Journal of Materials Science. 2013;48(17):5776-5787. doi:10.1007/s10853-013-7370-1 .
Radoičić, Marija B., Ćirić-Marjanović, Gordana N., Šaponjić, Zoran, Mitrić, Miodrag, Konstantinović, Zorica, Stoiljković, Milovan, Nedeljković, Jovan, "Structural and magnetic properties of nanocomposites based on nanostructured polyaniline and titania nanotubes" in Journal of Materials Science, 48, no. 17 (2013):5776-5787, https://doi.org/10.1007/s10853-013-7370-1 . .