Preparation and characterization of spinel nickel ferrite obtained by the soft mechanochemically assisted synthesis
Samo za registrovane korisnike
2013
Autori
Lazarević, Zorica Ž.Jovalekic, C.
Recnik, A.
Ivanovski, Valentin N.
Milutinovic, A.
Romčević, Maja J.
Pavlović, Miodrag B.
Cekić, Božidar Đ.
Romčević, Nebojša Ž.
Članak u časopisu (Objavljena verzija)
Metapodaci
Prikaz svih podataka o dokumentuApstrakt
Nickel ferrite, NiFe2O4 has been prepared by a soft mechanochemical route from mixture of (1) Ni(OH)(2) and alpha-Fe2O3 and (2) Ni(OH)(2) and Fe(OH)(3) powders in a planetary ball mill for varying duration. Soft mechanochemical reaction leading to formation of the NiFe2O4 spinel phase was followed by X-ray diffraction, Raman and infrared spectroscopy, TGA, scanning and transmission microscopy. The spinel phase formation was first observed after 4 h of milling and its formation was completed after 25 h in the both cases. The synthesized NiFe2O4 ferrite has a nanocrystalline structure with a crystallite size of about 20 and 10 nm respectively for the cases (1) and (2). The final grain size in the system (1) is about twice as large as that in the system (2), what is a consequence of different reaction paths in these two processing routes. There are five Raman and four IR active modes. Mossbauer spectroscopy studies implied on the possible cation distribution between the tetrahedral and oc...tahedral sites in formed NiFe2O4 spinel structure. We were able to estimate the degree of inversion at most 0.82 in the case (1) and 0.66 in the case (2). (c) 2012 Elsevier Ltd. All rights reserved.
Ključne reči:
Magnetic materials / Mossbauer spectroscopy / Raman spectroscopy / X-ray diffractionIzvor:
Materials Research Bulletin, 2013, 48, 2, 404-415Finansiranje / projekti:
- Optoelektronski nanodimenzioni sistemi - put ka primeni (RS-MESTD-Integrated and Interdisciplinary Research (IIR or III)-45003)
- Magnetni i radionuklidima obeleženi nanostrukturni materijali za primene u medicini (RS-MESTD-Integrated and Interdisciplinary Research (IIR or III)-45015)
- Istraživanje intermetalika i poluprovodnika i moguća primena u obnovljivim izvorima energije (RS-MESTD-Basic Research (BR or ON)-171001)
DOI: 10.1016/j.materresbull.2012.10.061
ISSN: 0025-5408
WoS: 000315751300041
Scopus: 2-s2.0-84871719230
Kolekcije
Institucija/grupa
VinčaTY - JOUR AU - Lazarević, Zorica Ž. AU - Jovalekic, C. AU - Recnik, A. AU - Ivanovski, Valentin N. AU - Milutinovic, A. AU - Romčević, Maja J. AU - Pavlović, Miodrag B. AU - Cekić, Božidar Đ. AU - Romčević, Nebojša Ž. PY - 2013 UR - https://vinar.vin.bg.ac.rs/handle/123456789/5357 AB - Nickel ferrite, NiFe2O4 has been prepared by a soft mechanochemical route from mixture of (1) Ni(OH)(2) and alpha-Fe2O3 and (2) Ni(OH)(2) and Fe(OH)(3) powders in a planetary ball mill for varying duration. Soft mechanochemical reaction leading to formation of the NiFe2O4 spinel phase was followed by X-ray diffraction, Raman and infrared spectroscopy, TGA, scanning and transmission microscopy. The spinel phase formation was first observed after 4 h of milling and its formation was completed after 25 h in the both cases. The synthesized NiFe2O4 ferrite has a nanocrystalline structure with a crystallite size of about 20 and 10 nm respectively for the cases (1) and (2). The final grain size in the system (1) is about twice as large as that in the system (2), what is a consequence of different reaction paths in these two processing routes. There are five Raman and four IR active modes. Mossbauer spectroscopy studies implied on the possible cation distribution between the tetrahedral and octahedral sites in formed NiFe2O4 spinel structure. We were able to estimate the degree of inversion at most 0.82 in the case (1) and 0.66 in the case (2). (c) 2012 Elsevier Ltd. All rights reserved. T2 - Materials Research Bulletin T1 - Preparation and characterization of spinel nickel ferrite obtained by the soft mechanochemically assisted synthesis VL - 48 IS - 2 SP - 404 EP - 415 DO - 10.1016/j.materresbull.2012.10.061 ER -
@article{ author = "Lazarević, Zorica Ž. and Jovalekic, C. and Recnik, A. and Ivanovski, Valentin N. and Milutinovic, A. and Romčević, Maja J. and Pavlović, Miodrag B. and Cekić, Božidar Đ. and Romčević, Nebojša Ž.", year = "2013", abstract = "Nickel ferrite, NiFe2O4 has been prepared by a soft mechanochemical route from mixture of (1) Ni(OH)(2) and alpha-Fe2O3 and (2) Ni(OH)(2) and Fe(OH)(3) powders in a planetary ball mill for varying duration. Soft mechanochemical reaction leading to formation of the NiFe2O4 spinel phase was followed by X-ray diffraction, Raman and infrared spectroscopy, TGA, scanning and transmission microscopy. The spinel phase formation was first observed after 4 h of milling and its formation was completed after 25 h in the both cases. The synthesized NiFe2O4 ferrite has a nanocrystalline structure with a crystallite size of about 20 and 10 nm respectively for the cases (1) and (2). The final grain size in the system (1) is about twice as large as that in the system (2), what is a consequence of different reaction paths in these two processing routes. There are five Raman and four IR active modes. Mossbauer spectroscopy studies implied on the possible cation distribution between the tetrahedral and octahedral sites in formed NiFe2O4 spinel structure. We were able to estimate the degree of inversion at most 0.82 in the case (1) and 0.66 in the case (2). (c) 2012 Elsevier Ltd. All rights reserved.", journal = "Materials Research Bulletin", title = "Preparation and characterization of spinel nickel ferrite obtained by the soft mechanochemically assisted synthesis", volume = "48", number = "2", pages = "404-415", doi = "10.1016/j.materresbull.2012.10.061" }
Lazarević, Z. Ž., Jovalekic, C., Recnik, A., Ivanovski, V. N., Milutinovic, A., Romčević, M. J., Pavlović, M. B., Cekić, B. Đ.,& Romčević, N. Ž.. (2013). Preparation and characterization of spinel nickel ferrite obtained by the soft mechanochemically assisted synthesis. in Materials Research Bulletin, 48(2), 404-415. https://doi.org/10.1016/j.materresbull.2012.10.061
Lazarević ZŽ, Jovalekic C, Recnik A, Ivanovski VN, Milutinovic A, Romčević MJ, Pavlović MB, Cekić BĐ, Romčević NŽ. Preparation and characterization of spinel nickel ferrite obtained by the soft mechanochemically assisted synthesis. in Materials Research Bulletin. 2013;48(2):404-415. doi:10.1016/j.materresbull.2012.10.061 .
Lazarević, Zorica Ž., Jovalekic, C., Recnik, A., Ivanovski, Valentin N., Milutinovic, A., Romčević, Maja J., Pavlović, Miodrag B., Cekić, Božidar Đ., Romčević, Nebojša Ž., "Preparation and characterization of spinel nickel ferrite obtained by the soft mechanochemically assisted synthesis" in Materials Research Bulletin, 48, no. 2 (2013):404-415, https://doi.org/10.1016/j.materresbull.2012.10.061 . .