Synthesis and surface characterization of ordered mesoporous silica SBA-15
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2010
Authors
Kokunešoski, MajaGulicovski, Jelena J.
Matović, Branko
Logar, Mihovil
Milonjić, Slobodan K.
Babić, Biljana M.
Article (Published version)
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Ordered mesoporous silica SBA-15 materials were synthesized using Plutonic P123 (non-ionic triblock copolymer EO(20)PO(70)O(20)) as a template under acidic conditions and different heating temperatures and time of the reaction solution These materials were characterized by nitrogen adsorption-desorption measurements Fourier-transformed infrared spectroscopy (FT-IR) and determination of points of zero charge and izoelectric points as well as particle diameters Synthesis at lower temperature (80 C) and longer time of reaction (48 h) gives samples with higher specific surface area (S(BET) = 710 m(2) g(-1)) mesoporose surface (S(meso) = 481 m(2) g(-1)) and narrower pore size distribution Material synthesized at higher temperature (100 degrees C) and shorter time of reaction (24 h) has lower specific surface and mesoporosity (S(BET) = 641 m(2) g(-1) and S(meso) = 367 m(2) g(-1)) At both samples the presence of micropores was confirmed The point of zero charge pH(PZC) = 5 2 +/- 0 2 and the i...soelectric point pH(IEB) = 2 3 +/- 0 1 were not affected by synthesis conditions Washing of silica samples in a dilute solution of nitric acid shifts the isoelectric point to a higher value (pH(IEP) = 3 0 +/- 0 2) while the point of zero charge remains constant (C) 2010 Elsevier B V All rights reserved
Keywords:
Amorphous materials / Nanostructures / Surface propertiesSource:
Materials Chemistry and Physics, 2010, 124, 2-3, 1248-1252Funding / projects:
- Synthesis, processing and characterization of nanostructured materials for application in the field of energy, mechanical engineering, environmental protection and biomedicine (RS-MESTD-Integrated and Interdisciplinary Research (IIR or III)-45012)
DOI: 10.1016/j.matchemphys.2010.08.066
ISSN: 0254-0584
WoS: 000284434100062
Scopus: 2-s2.0-77957838762
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VinčaTY - JOUR AU - Kokunešoski, Maja AU - Gulicovski, Jelena J. AU - Matović, Branko AU - Logar, Mihovil AU - Milonjić, Slobodan K. AU - Babić, Biljana M. PY - 2010 UR - https://vinar.vin.bg.ac.rs/handle/123456789/4152 AB - Ordered mesoporous silica SBA-15 materials were synthesized using Plutonic P123 (non-ionic triblock copolymer EO(20)PO(70)O(20)) as a template under acidic conditions and different heating temperatures and time of the reaction solution These materials were characterized by nitrogen adsorption-desorption measurements Fourier-transformed infrared spectroscopy (FT-IR) and determination of points of zero charge and izoelectric points as well as particle diameters Synthesis at lower temperature (80 C) and longer time of reaction (48 h) gives samples with higher specific surface area (S(BET) = 710 m(2) g(-1)) mesoporose surface (S(meso) = 481 m(2) g(-1)) and narrower pore size distribution Material synthesized at higher temperature (100 degrees C) and shorter time of reaction (24 h) has lower specific surface and mesoporosity (S(BET) = 641 m(2) g(-1) and S(meso) = 367 m(2) g(-1)) At both samples the presence of micropores was confirmed The point of zero charge pH(PZC) = 5 2 +/- 0 2 and the isoelectric point pH(IEB) = 2 3 +/- 0 1 were not affected by synthesis conditions Washing of silica samples in a dilute solution of nitric acid shifts the isoelectric point to a higher value (pH(IEP) = 3 0 +/- 0 2) while the point of zero charge remains constant (C) 2010 Elsevier B V All rights reserved T2 - Materials Chemistry and Physics T1 - Synthesis and surface characterization of ordered mesoporous silica SBA-15 VL - 124 IS - 2-3 SP - 1248 EP - 1252 DO - 10.1016/j.matchemphys.2010.08.066 ER -
@article{ author = "Kokunešoski, Maja and Gulicovski, Jelena J. and Matović, Branko and Logar, Mihovil and Milonjić, Slobodan K. and Babić, Biljana M.", year = "2010", abstract = "Ordered mesoporous silica SBA-15 materials were synthesized using Plutonic P123 (non-ionic triblock copolymer EO(20)PO(70)O(20)) as a template under acidic conditions and different heating temperatures and time of the reaction solution These materials were characterized by nitrogen adsorption-desorption measurements Fourier-transformed infrared spectroscopy (FT-IR) and determination of points of zero charge and izoelectric points as well as particle diameters Synthesis at lower temperature (80 C) and longer time of reaction (48 h) gives samples with higher specific surface area (S(BET) = 710 m(2) g(-1)) mesoporose surface (S(meso) = 481 m(2) g(-1)) and narrower pore size distribution Material synthesized at higher temperature (100 degrees C) and shorter time of reaction (24 h) has lower specific surface and mesoporosity (S(BET) = 641 m(2) g(-1) and S(meso) = 367 m(2) g(-1)) At both samples the presence of micropores was confirmed The point of zero charge pH(PZC) = 5 2 +/- 0 2 and the isoelectric point pH(IEB) = 2 3 +/- 0 1 were not affected by synthesis conditions Washing of silica samples in a dilute solution of nitric acid shifts the isoelectric point to a higher value (pH(IEP) = 3 0 +/- 0 2) while the point of zero charge remains constant (C) 2010 Elsevier B V All rights reserved", journal = "Materials Chemistry and Physics", title = "Synthesis and surface characterization of ordered mesoporous silica SBA-15", volume = "124", number = "2-3", pages = "1248-1252", doi = "10.1016/j.matchemphys.2010.08.066" }
Kokunešoski, M., Gulicovski, J. J., Matović, B., Logar, M., Milonjić, S. K.,& Babić, B. M.. (2010). Synthesis and surface characterization of ordered mesoporous silica SBA-15. in Materials Chemistry and Physics, 124(2-3), 1248-1252. https://doi.org/10.1016/j.matchemphys.2010.08.066
Kokunešoski M, Gulicovski JJ, Matović B, Logar M, Milonjić SK, Babić BM. Synthesis and surface characterization of ordered mesoporous silica SBA-15. in Materials Chemistry and Physics. 2010;124(2-3):1248-1252. doi:10.1016/j.matchemphys.2010.08.066 .
Kokunešoski, Maja, Gulicovski, Jelena J., Matović, Branko, Logar, Mihovil, Milonjić, Slobodan K., Babić, Biljana M., "Synthesis and surface characterization of ordered mesoporous silica SBA-15" in Materials Chemistry and Physics, 124, no. 2-3 (2010):1248-1252, https://doi.org/10.1016/j.matchemphys.2010.08.066 . .