Synthesis and characterization of the nanometric Pr-doped ceria
Nema prikaza
Autori
Matović, BrankoBošković, Snežana B.
Logar, Mihovil
Radović, Marko B.
Dohcevic-Mitrovic, Z.
Popović, Zoran V.
Aldinger, Fritz
Članak u časopisu
Metapodaci
Prikaz svih podataka o dokumentuApstrakt
In this paper nanometric powders of solid solution of the host compound ceria (CeO(2)) with Pr dopant in the lattice were synthesized by self-propagating room temperature (SPRT) synthesis with composition (Ce(0.9)Pr(0.1)O(2-delta)). Powder properties such as specific surface area crystallite and particle size and lattice parameters have been studied. BET, TEM, X-ray diffraction (XRD) analysis and Raman scattering measurements were used to characterize the samples at room temperature. Obtained solid solution exhibits a fluorite-type crystal structure. The average crystallite size is about 3-4 nm. Williamson-Hall plots were used to separate the effect of the size and strain in the nanocrystals. It is noticed the redshift and asymmetric broadening of the Raman F(2g) mode which is explained with nanocrystalline nature of powders. Color characters of solid solution depending on calcinations temperature and their position in the chromaticity diagram were studied by UV-vis spectrophotometry (...diffuse reflectance). (C) 2010 Elsevier B.V. All rights reserved.
Ključne reči:
Ceria solid solution / XRD measurements / Raman spectroscopy / Red pigmentsIzvor:
Journal of Alloys and Compounds, 2010, 505, 1, 235-238Finansiranje / projekti:
- Ministry of Science and Technological Development of Serbia, A. von Humboldt Foundation
DOI: 10.1016/j.jallcom.2010.06.036
ISSN: 0925-8388
WoS: 000281271200047
Scopus: 2-s2.0-77955561605
Kolekcije
Institucija/grupa
VinčaTY - JOUR AU - Matović, Branko AU - Bošković, Snežana B. AU - Logar, Mihovil AU - Radović, Marko B. AU - Dohcevic-Mitrovic, Z. AU - Popović, Zoran V. AU - Aldinger, Fritz PY - 2010 UR - https://vinar.vin.bg.ac.rs/handle/123456789/4089 AB - In this paper nanometric powders of solid solution of the host compound ceria (CeO(2)) with Pr dopant in the lattice were synthesized by self-propagating room temperature (SPRT) synthesis with composition (Ce(0.9)Pr(0.1)O(2-delta)). Powder properties such as specific surface area crystallite and particle size and lattice parameters have been studied. BET, TEM, X-ray diffraction (XRD) analysis and Raman scattering measurements were used to characterize the samples at room temperature. Obtained solid solution exhibits a fluorite-type crystal structure. The average crystallite size is about 3-4 nm. Williamson-Hall plots were used to separate the effect of the size and strain in the nanocrystals. It is noticed the redshift and asymmetric broadening of the Raman F(2g) mode which is explained with nanocrystalline nature of powders. Color characters of solid solution depending on calcinations temperature and their position in the chromaticity diagram were studied by UV-vis spectrophotometry (diffuse reflectance). (C) 2010 Elsevier B.V. All rights reserved. T2 - Journal of Alloys and Compounds T1 - Synthesis and characterization of the nanometric Pr-doped ceria VL - 505 IS - 1 SP - 235 EP - 238 DO - 10.1016/j.jallcom.2010.06.036 ER -
@article{ author = "Matović, Branko and Bošković, Snežana B. and Logar, Mihovil and Radović, Marko B. and Dohcevic-Mitrovic, Z. and Popović, Zoran V. and Aldinger, Fritz", year = "2010", abstract = "In this paper nanometric powders of solid solution of the host compound ceria (CeO(2)) with Pr dopant in the lattice were synthesized by self-propagating room temperature (SPRT) synthesis with composition (Ce(0.9)Pr(0.1)O(2-delta)). Powder properties such as specific surface area crystallite and particle size and lattice parameters have been studied. BET, TEM, X-ray diffraction (XRD) analysis and Raman scattering measurements were used to characterize the samples at room temperature. Obtained solid solution exhibits a fluorite-type crystal structure. The average crystallite size is about 3-4 nm. Williamson-Hall plots were used to separate the effect of the size and strain in the nanocrystals. It is noticed the redshift and asymmetric broadening of the Raman F(2g) mode which is explained with nanocrystalline nature of powders. Color characters of solid solution depending on calcinations temperature and their position in the chromaticity diagram were studied by UV-vis spectrophotometry (diffuse reflectance). (C) 2010 Elsevier B.V. All rights reserved.", journal = "Journal of Alloys and Compounds", title = "Synthesis and characterization of the nanometric Pr-doped ceria", volume = "505", number = "1", pages = "235-238", doi = "10.1016/j.jallcom.2010.06.036" }
Matović, B., Bošković, S. B., Logar, M., Radović, M. B., Dohcevic-Mitrovic, Z., Popović, Z. V.,& Aldinger, F.. (2010). Synthesis and characterization of the nanometric Pr-doped ceria. in Journal of Alloys and Compounds, 505(1), 235-238. https://doi.org/10.1016/j.jallcom.2010.06.036
Matović B, Bošković SB, Logar M, Radović MB, Dohcevic-Mitrovic Z, Popović ZV, Aldinger F. Synthesis and characterization of the nanometric Pr-doped ceria. in Journal of Alloys and Compounds. 2010;505(1):235-238. doi:10.1016/j.jallcom.2010.06.036 .
Matović, Branko, Bošković, Snežana B., Logar, Mihovil, Radović, Marko B., Dohcevic-Mitrovic, Z., Popović, Zoran V., Aldinger, Fritz, "Synthesis and characterization of the nanometric Pr-doped ceria" in Journal of Alloys and Compounds, 505, no. 1 (2010):235-238, https://doi.org/10.1016/j.jallcom.2010.06.036 . .