Rhenium(I) and technetium-99m(I) fac-tricarbonyl complexes with 4-(imidazolin-2-yl)-3-thiabutanoic acid derivatives as tridentate ligands: Synthesis and structural characterization
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Kyprianidou, P.Tsoukalas, C.
Patsis, G.
Papagiannopoulou, D.
Nikolić, Nadežda S.
Janković, Drina
Đokić, Divna Đ.
Raptopoulou, C. P.
Pelecanou, M.
Papadopoulos, M.
Pirmettis, Ioannis
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Two rhenium(l) tricarbonyl complexes, with the monoanionic tridentate NSO type ligand, 4-(imidazolin-2-yl)-3-thiabutanoic acid and 4-(N-ethylimidazolin-2-yl)-3-thiabutanoic acid were synthesized and isolated in pure form. Both complexes were characterized by spectroscopic methods and elemental analysis. The solid-state structure of 4-(imidazolin-2-yl)-3-thiabutanoic acid and of both complexes was established by X-ray crystallography. The geometry about the rhenium is octahedral. The analogous technetium-99m complexes were also prepared quantitatively by the reaction of both ligands with the fac-[(99m)Tc(CO)(3)(H(2)O)(3)](+) synthon and their identity was established by chromatographic comparison to their rhenium congeners. (C) 2009 Elsevier Ltd. All rights reserved.
Keywords:
Technetium-99m / Rhenium / CarbonylsSource:
Polyhedron, 2009, 28, 15, 3171-3176Funding / projects:
- GSRT, Hellenic Ministry of Development
DOI: 10.1016/j.poly.2009.04.005
ISSN: 0277-5387
WoS: 000271144200002
Scopus: 2-s2.0-70349601162
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VinčaTY - JOUR AU - Kyprianidou, P. AU - Tsoukalas, C. AU - Patsis, G. AU - Papagiannopoulou, D. AU - Nikolić, Nadežda S. AU - Janković, Drina AU - Đokić, Divna Đ. AU - Raptopoulou, C. P. AU - Pelecanou, M. AU - Papadopoulos, M. AU - Pirmettis, Ioannis PY - 2009 UR - https://vinar.vin.bg.ac.rs/handle/123456789/3811 AB - Two rhenium(l) tricarbonyl complexes, with the monoanionic tridentate NSO type ligand, 4-(imidazolin-2-yl)-3-thiabutanoic acid and 4-(N-ethylimidazolin-2-yl)-3-thiabutanoic acid were synthesized and isolated in pure form. Both complexes were characterized by spectroscopic methods and elemental analysis. The solid-state structure of 4-(imidazolin-2-yl)-3-thiabutanoic acid and of both complexes was established by X-ray crystallography. The geometry about the rhenium is octahedral. The analogous technetium-99m complexes were also prepared quantitatively by the reaction of both ligands with the fac-[(99m)Tc(CO)(3)(H(2)O)(3)](+) synthon and their identity was established by chromatographic comparison to their rhenium congeners. (C) 2009 Elsevier Ltd. All rights reserved. T2 - Polyhedron T1 - Rhenium(I) and technetium-99m(I) fac-tricarbonyl complexes with 4-(imidazolin-2-yl)-3-thiabutanoic acid derivatives as tridentate ligands: Synthesis and structural characterization VL - 28 IS - 15 SP - 3171 EP - 3176 DO - 10.1016/j.poly.2009.04.005 ER -
@article{ author = "Kyprianidou, P. and Tsoukalas, C. and Patsis, G. and Papagiannopoulou, D. and Nikolić, Nadežda S. and Janković, Drina and Đokić, Divna Đ. and Raptopoulou, C. P. and Pelecanou, M. and Papadopoulos, M. and Pirmettis, Ioannis", year = "2009", abstract = "Two rhenium(l) tricarbonyl complexes, with the monoanionic tridentate NSO type ligand, 4-(imidazolin-2-yl)-3-thiabutanoic acid and 4-(N-ethylimidazolin-2-yl)-3-thiabutanoic acid were synthesized and isolated in pure form. Both complexes were characterized by spectroscopic methods and elemental analysis. The solid-state structure of 4-(imidazolin-2-yl)-3-thiabutanoic acid and of both complexes was established by X-ray crystallography. The geometry about the rhenium is octahedral. The analogous technetium-99m complexes were also prepared quantitatively by the reaction of both ligands with the fac-[(99m)Tc(CO)(3)(H(2)O)(3)](+) synthon and their identity was established by chromatographic comparison to their rhenium congeners. (C) 2009 Elsevier Ltd. All rights reserved.", journal = "Polyhedron", title = "Rhenium(I) and technetium-99m(I) fac-tricarbonyl complexes with 4-(imidazolin-2-yl)-3-thiabutanoic acid derivatives as tridentate ligands: Synthesis and structural characterization", volume = "28", number = "15", pages = "3171-3176", doi = "10.1016/j.poly.2009.04.005" }
Kyprianidou, P., Tsoukalas, C., Patsis, G., Papagiannopoulou, D., Nikolić, N. S., Janković, D., Đokić, D. Đ., Raptopoulou, C. P., Pelecanou, M., Papadopoulos, M.,& Pirmettis, I.. (2009). Rhenium(I) and technetium-99m(I) fac-tricarbonyl complexes with 4-(imidazolin-2-yl)-3-thiabutanoic acid derivatives as tridentate ligands: Synthesis and structural characterization. in Polyhedron, 28(15), 3171-3176. https://doi.org/10.1016/j.poly.2009.04.005
Kyprianidou P, Tsoukalas C, Patsis G, Papagiannopoulou D, Nikolić NS, Janković D, Đokić DĐ, Raptopoulou CP, Pelecanou M, Papadopoulos M, Pirmettis I. Rhenium(I) and technetium-99m(I) fac-tricarbonyl complexes with 4-(imidazolin-2-yl)-3-thiabutanoic acid derivatives as tridentate ligands: Synthesis and structural characterization. in Polyhedron. 2009;28(15):3171-3176. doi:10.1016/j.poly.2009.04.005 .
Kyprianidou, P., Tsoukalas, C., Patsis, G., Papagiannopoulou, D., Nikolić, Nadežda S., Janković, Drina, Đokić, Divna Đ., Raptopoulou, C. P., Pelecanou, M., Papadopoulos, M., Pirmettis, Ioannis, "Rhenium(I) and technetium-99m(I) fac-tricarbonyl complexes with 4-(imidazolin-2-yl)-3-thiabutanoic acid derivatives as tridentate ligands: Synthesis and structural characterization" in Polyhedron, 28, no. 15 (2009):3171-3176, https://doi.org/10.1016/j.poly.2009.04.005 . .