The thermal stability of porous alumina/stainless steel catalyst support obtained by spray pyrolysis
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Novaković, TatjanaRadić, Nenad
Grbic, Bosko
Dondur, Vera
Mitrić, Miodrag
Randjelovic, Danijela
Stoychev, Dimitar
Stefanov, Plamen
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Active porous alumina coatings were obtained by deposition of boehmite sol on stainless steel (SS) substrate by spray pyrolysis method. The temperature and the doping of polyethylene glycol (PEG) and La(3+) in the boehmite sol effects on the textural and structural properties and surface morphology of alumina coatings on stainless steel samples are presented. It was found that the addition of polyethylene glycol combined with La3+ to the boehmite sol before spraying improves the thermal stability of porous alumina coatings. X-ray diffraction patterns of a doped sample, even after 5 h at 1000 degrees C, point out to the presence only of delta-Al(2)O(3), with a S(BET) of 74 m(2)/g. XPS data and SEM photographs of coated samples show that alumina were well deposited on the metallic supports. The absence of any lanthanum compounds indicates very well homogeneous dispersion of La(3+)-ions on the surface of alumina crystallites. AFM images show sphere like alumina grains and agglomerates wit...h surface roughness from 60 to 180 nm, depending on temperature and doping. Surface roughness of doped alumina samples was higher than that of non-doped. It was pointed out that spray pyrolysis method enables preparation of alumina layers with relatively high specific surface area, suitable for applications as catalysts supports. (C) 2008 Elsevier B.V. All rights reserved.
Keywords:
Alumina / Coating / Spray pyrolysis / Stainless steal / Thermal stabilitySource:
Applied Surface Science, 2008, 255, 5, 3049-3055Funding / projects:
- Ministry of Science and Environmental Protection, Republic of Serbia [142019B]
DOI: 10.1016/j.apsusc.2008.08.074
ISSN: 0169-4332
WoS: 000261299200086
Scopus: 2-s2.0-57049171347
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VinčaTY - JOUR AU - Novaković, Tatjana AU - Radić, Nenad AU - Grbic, Bosko AU - Dondur, Vera AU - Mitrić, Miodrag AU - Randjelovic, Danijela AU - Stoychev, Dimitar AU - Stefanov, Plamen PY - 2008 UR - https://vinar.vin.bg.ac.rs/handle/123456789/3582 AB - Active porous alumina coatings were obtained by deposition of boehmite sol on stainless steel (SS) substrate by spray pyrolysis method. The temperature and the doping of polyethylene glycol (PEG) and La(3+) in the boehmite sol effects on the textural and structural properties and surface morphology of alumina coatings on stainless steel samples are presented. It was found that the addition of polyethylene glycol combined with La3+ to the boehmite sol before spraying improves the thermal stability of porous alumina coatings. X-ray diffraction patterns of a doped sample, even after 5 h at 1000 degrees C, point out to the presence only of delta-Al(2)O(3), with a S(BET) of 74 m(2)/g. XPS data and SEM photographs of coated samples show that alumina were well deposited on the metallic supports. The absence of any lanthanum compounds indicates very well homogeneous dispersion of La(3+)-ions on the surface of alumina crystallites. AFM images show sphere like alumina grains and agglomerates with surface roughness from 60 to 180 nm, depending on temperature and doping. Surface roughness of doped alumina samples was higher than that of non-doped. It was pointed out that spray pyrolysis method enables preparation of alumina layers with relatively high specific surface area, suitable for applications as catalysts supports. (C) 2008 Elsevier B.V. All rights reserved. T2 - Applied Surface Science T1 - The thermal stability of porous alumina/stainless steel catalyst support obtained by spray pyrolysis VL - 255 IS - 5 SP - 3049 EP - 3055 DO - 10.1016/j.apsusc.2008.08.074 ER -
@article{ author = "Novaković, Tatjana and Radić, Nenad and Grbic, Bosko and Dondur, Vera and Mitrić, Miodrag and Randjelovic, Danijela and Stoychev, Dimitar and Stefanov, Plamen", year = "2008", abstract = "Active porous alumina coatings were obtained by deposition of boehmite sol on stainless steel (SS) substrate by spray pyrolysis method. The temperature and the doping of polyethylene glycol (PEG) and La(3+) in the boehmite sol effects on the textural and structural properties and surface morphology of alumina coatings on stainless steel samples are presented. It was found that the addition of polyethylene glycol combined with La3+ to the boehmite sol before spraying improves the thermal stability of porous alumina coatings. X-ray diffraction patterns of a doped sample, even after 5 h at 1000 degrees C, point out to the presence only of delta-Al(2)O(3), with a S(BET) of 74 m(2)/g. XPS data and SEM photographs of coated samples show that alumina were well deposited on the metallic supports. The absence of any lanthanum compounds indicates very well homogeneous dispersion of La(3+)-ions on the surface of alumina crystallites. AFM images show sphere like alumina grains and agglomerates with surface roughness from 60 to 180 nm, depending on temperature and doping. Surface roughness of doped alumina samples was higher than that of non-doped. It was pointed out that spray pyrolysis method enables preparation of alumina layers with relatively high specific surface area, suitable for applications as catalysts supports. (C) 2008 Elsevier B.V. All rights reserved.", journal = "Applied Surface Science", title = "The thermal stability of porous alumina/stainless steel catalyst support obtained by spray pyrolysis", volume = "255", number = "5", pages = "3049-3055", doi = "10.1016/j.apsusc.2008.08.074" }
Novaković, T., Radić, N., Grbic, B., Dondur, V., Mitrić, M., Randjelovic, D., Stoychev, D.,& Stefanov, P.. (2008). The thermal stability of porous alumina/stainless steel catalyst support obtained by spray pyrolysis. in Applied Surface Science, 255(5), 3049-3055. https://doi.org/10.1016/j.apsusc.2008.08.074
Novaković T, Radić N, Grbic B, Dondur V, Mitrić M, Randjelovic D, Stoychev D, Stefanov P. The thermal stability of porous alumina/stainless steel catalyst support obtained by spray pyrolysis. in Applied Surface Science. 2008;255(5):3049-3055. doi:10.1016/j.apsusc.2008.08.074 .
Novaković, Tatjana, Radić, Nenad, Grbic, Bosko, Dondur, Vera, Mitrić, Miodrag, Randjelovic, Danijela, Stoychev, Dimitar, Stefanov, Plamen, "The thermal stability of porous alumina/stainless steel catalyst support obtained by spray pyrolysis" in Applied Surface Science, 255, no. 5 (2008):3049-3055, https://doi.org/10.1016/j.apsusc.2008.08.074 . .