Experimental and theoretical investigation of new hypervalent molecules LinF (n=2-4)
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Veličković, SuzanaKoteski, Vasil J.
Belošević-Čavor, Jelena
Đorđević, Vesna R.
Cvetićanin, Jelena M.
Đustebek, Jasmina B.
Veljković, Miomir V.
Nešković, Olivera M.
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Hypervalent molecules of Li3F and Li4F were detected experimentally for the first time. Ionization energies determined by the thermal ionization mass spectrometry were 3.8 +/- 0.2 eV for Li2F, 4.0 +/- 0.2 eV for Li3F and 3.9 +/- 0.2 eV for Li4F. The ionization energies obtained by ab initio calculations support the experimental findings. The lowest energy structures of the LinF (n = 2-4) molecules and their cations were also predicted. (C) 2007 Elsevier B.V. All rights reserved.
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Chemical Physics Letters, 2007, 448, 4-6, 151-155
DOI: 10.1016/j.cplett.2007.09.082
ISSN: 0009-2614
WoS: 000251408300001
Scopus: 2-s2.0-35649009980
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VinčaTY - JOUR AU - Veličković, Suzana AU - Koteski, Vasil J. AU - Belošević-Čavor, Jelena AU - Đorđević, Vesna R. AU - Cvetićanin, Jelena M. AU - Đustebek, Jasmina B. AU - Veljković, Miomir V. AU - Nešković, Olivera M. PY - 2007 UR - https://vinar.vin.bg.ac.rs/handle/123456789/3323 AB - Hypervalent molecules of Li3F and Li4F were detected experimentally for the first time. Ionization energies determined by the thermal ionization mass spectrometry were 3.8 +/- 0.2 eV for Li2F, 4.0 +/- 0.2 eV for Li3F and 3.9 +/- 0.2 eV for Li4F. The ionization energies obtained by ab initio calculations support the experimental findings. The lowest energy structures of the LinF (n = 2-4) molecules and their cations were also predicted. (C) 2007 Elsevier B.V. All rights reserved. T2 - Chemical Physics Letters T1 - Experimental and theoretical investigation of new hypervalent molecules LinF (n=2-4) VL - 448 IS - 4-6 SP - 151 EP - 155 DO - 10.1016/j.cplett.2007.09.082 ER -
@article{ author = "Veličković, Suzana and Koteski, Vasil J. and Belošević-Čavor, Jelena and Đorđević, Vesna R. and Cvetićanin, Jelena M. and Đustebek, Jasmina B. and Veljković, Miomir V. and Nešković, Olivera M.", year = "2007", abstract = "Hypervalent molecules of Li3F and Li4F were detected experimentally for the first time. Ionization energies determined by the thermal ionization mass spectrometry were 3.8 +/- 0.2 eV for Li2F, 4.0 +/- 0.2 eV for Li3F and 3.9 +/- 0.2 eV for Li4F. The ionization energies obtained by ab initio calculations support the experimental findings. The lowest energy structures of the LinF (n = 2-4) molecules and their cations were also predicted. (C) 2007 Elsevier B.V. All rights reserved.", journal = "Chemical Physics Letters", title = "Experimental and theoretical investigation of new hypervalent molecules LinF (n=2-4)", volume = "448", number = "4-6", pages = "151-155", doi = "10.1016/j.cplett.2007.09.082" }
Veličković, S., Koteski, V. J., Belošević-Čavor, J., Đorđević, V. R., Cvetićanin, J. M., Đustebek, J. B., Veljković, M. V.,& Nešković, O. M.. (2007). Experimental and theoretical investigation of new hypervalent molecules LinF (n=2-4). in Chemical Physics Letters, 448(4-6), 151-155. https://doi.org/10.1016/j.cplett.2007.09.082
Veličković S, Koteski VJ, Belošević-Čavor J, Đorđević VR, Cvetićanin JM, Đustebek JB, Veljković MV, Nešković OM. Experimental and theoretical investigation of new hypervalent molecules LinF (n=2-4). in Chemical Physics Letters. 2007;448(4-6):151-155. doi:10.1016/j.cplett.2007.09.082 .
Veličković, Suzana, Koteski, Vasil J., Belošević-Čavor, Jelena, Đorđević, Vesna R., Cvetićanin, Jelena M., Đustebek, Jasmina B., Veljković, Miomir V., Nešković, Olivera M., "Experimental and theoretical investigation of new hypervalent molecules LinF (n=2-4)" in Chemical Physics Letters, 448, no. 4-6 (2007):151-155, https://doi.org/10.1016/j.cplett.2007.09.082 . .