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Synthesis, structure and magnetic properties of the first copper(II) complex with an (E)-4-aryl-4-oxo-2-butenoato ligand
dc.creator | Miodragovic, Zoran M. | |
dc.creator | Bogdanović, Goran A. | |
dc.creator | Krajcinovic, Bojana B. | |
dc.creator | Drakulić, Branko J. | |
dc.creator | Kusigerski, Vladan | |
dc.creator | Miodragović Đenana U. | |
dc.creator | Spasojević, Vojislav | |
dc.creator | Hodzic, Ismet M. | |
dc.creator | Juranić, Ivan O. | |
dc.date.accessioned | 2018-03-01T19:58:23Z | |
dc.date.available | 2018-03-01T19:58:23Z | |
dc.date.issued | 2006 | |
dc.identifier.issn | 1387-7003 | |
dc.identifier.uri | https://vinar.vin.bg.ac.rs/handle/123456789/3127 | |
dc.description.abstract | A new binuclear Cu(II) complex with an (E)-4-(2,4-diisopropylphenyl)-4-oxo-2-butenoato ligand (L) was successfully synthesized and characterized by elemental analysis and IR-spectroscopy. The structures of (E)-4-(2,4-diisopropylphenyl)-4-oxo-2-butenoic acid (HL), and the corresponding (tetrakis)-mu-[(E)-4-(2,4-diisopropylphenyl)-4-oxo-2-butenoato]-bis(ethanol)-copper(II) complex, [Cu2L4(C2H5OH)(2)], were determined by single crystal X-ray analyses and are preliminarily discussed. This is the first complex of a transition metal with ligand L. as well as the first determined crystal structure of a metal complex with this type of ligand. Analysis of the magnetic susceptibility measurements of the isolated [Cu2L4(C2H5OH)(2)]center dot H2O complex shows the existence of a strong anti-ferromagnetic intra-dimer coupling, with an exchange integral value 2J of -260 cm(-1). (C) 2006 Elsevier B.V. All rights reserved. | en |
dc.rights | restrictedAccess | en |
dc.source | Inorganic Chemistry Communications | en |
dc.subject | (E)-4-(2,4-diisopropylphenyl)-4-oxo-2-butenoato ligand | en |
dc.subject | Cu(II) complexes | en |
dc.subject | X-ray analysis | en |
dc.subject | magnetic properties | en |
dc.title | Synthesis, structure and magnetic properties of the first copper(II) complex with an (E)-4-aryl-4-oxo-2-butenoato ligand | en |
dc.type | article | en |
dcterms.abstract | Миодраговиц, Зоран М.; Ходзиц, Исмет М.; Јураниц, Иван О.; Крајциновиц, Бојана Б.; Миодраговиц, Дјенана У.; Богдановић Горан; Дракулиц, Бранко Ј.; Кусигерски Владан; Спасојевић Војислав; | |
dc.citation.volume | 9 | |
dc.citation.issue | 12 | |
dc.citation.spage | 1173 | |
dc.citation.epage | 1177 | |
dc.identifier.wos | 000242615800006 | |
dc.identifier.doi | 10.1016/j.inoche.2006.07.029 | |
dc.citation.rank | M22 | |
dc.identifier.scopus | 2-s2.0-33750945471 |
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