Synthesis, structure and magnetic properties of the first copper(II) complex with an (E)-4-aryl-4-oxo-2-butenoato ligand
Nema prikaza
Autori
Miodragovic, Zoran M.Bogdanović, Goran A.
Krajcinovic, Bojana B.
Drakulić, Branko J.
Kusigerski, Vladan
Miodragović Đenana U.
Spasojević, Vojislav
Hodzic, Ismet M.
Juranić, Ivan O.
Članak u časopisu
Metapodaci
Prikaz svih podataka o dokumentuApstrakt
A new binuclear Cu(II) complex with an (E)-4-(2,4-diisopropylphenyl)-4-oxo-2-butenoato ligand (L) was successfully synthesized and characterized by elemental analysis and IR-spectroscopy. The structures of (E)-4-(2,4-diisopropylphenyl)-4-oxo-2-butenoic acid (HL), and the corresponding (tetrakis)-mu-[(E)-4-(2,4-diisopropylphenyl)-4-oxo-2-butenoato]-bis(ethanol)-copper(II) complex, [Cu2L4(C2H5OH)(2)], were determined by single crystal X-ray analyses and are preliminarily discussed. This is the first complex of a transition metal with ligand L. as well as the first determined crystal structure of a metal complex with this type of ligand. Analysis of the magnetic susceptibility measurements of the isolated [Cu2L4(C2H5OH)(2)]center dot H2O complex shows the existence of a strong anti-ferromagnetic intra-dimer coupling, with an exchange integral value 2J of -260 cm(-1). (C) 2006 Elsevier B.V. All rights reserved.
Ključne reči:
(E)-4-(2,4-diisopropylphenyl)-4-oxo-2-butenoato ligand / Cu(II) complexes / X-ray analysis / magnetic propertiesIzvor:
Inorganic Chemistry Communications, 2006, 9, 12, 1173-1177
DOI: 10.1016/j.inoche.2006.07.029
ISSN: 1387-7003
WoS: 000242615800006
Scopus: 2-s2.0-33750945471
Kolekcije
Institucija/grupa
VinčaTY - JOUR AU - Miodragovic, Zoran M. AU - Bogdanović, Goran A. AU - Krajcinovic, Bojana B. AU - Drakulić, Branko J. AU - Kusigerski, Vladan AU - Miodragović Đenana U. AU - Spasojević, Vojislav AU - Hodzic, Ismet M. AU - Juranić, Ivan O. PY - 2006 UR - https://vinar.vin.bg.ac.rs/handle/123456789/3127 AB - A new binuclear Cu(II) complex with an (E)-4-(2,4-diisopropylphenyl)-4-oxo-2-butenoato ligand (L) was successfully synthesized and characterized by elemental analysis and IR-spectroscopy. The structures of (E)-4-(2,4-diisopropylphenyl)-4-oxo-2-butenoic acid (HL), and the corresponding (tetrakis)-mu-[(E)-4-(2,4-diisopropylphenyl)-4-oxo-2-butenoato]-bis(ethanol)-copper(II) complex, [Cu2L4(C2H5OH)(2)], were determined by single crystal X-ray analyses and are preliminarily discussed. This is the first complex of a transition metal with ligand L. as well as the first determined crystal structure of a metal complex with this type of ligand. Analysis of the magnetic susceptibility measurements of the isolated [Cu2L4(C2H5OH)(2)]center dot H2O complex shows the existence of a strong anti-ferromagnetic intra-dimer coupling, with an exchange integral value 2J of -260 cm(-1). (C) 2006 Elsevier B.V. All rights reserved. T2 - Inorganic Chemistry Communications T1 - Synthesis, structure and magnetic properties of the first copper(II) complex with an (E)-4-aryl-4-oxo-2-butenoato ligand VL - 9 IS - 12 SP - 1173 EP - 1177 DO - 10.1016/j.inoche.2006.07.029 ER -
@article{ author = "Miodragovic, Zoran M. and Bogdanović, Goran A. and Krajcinovic, Bojana B. and Drakulić, Branko J. and Kusigerski, Vladan and Miodragović Đenana U. and Spasojević, Vojislav and Hodzic, Ismet M. and Juranić, Ivan O.", year = "2006", abstract = "A new binuclear Cu(II) complex with an (E)-4-(2,4-diisopropylphenyl)-4-oxo-2-butenoato ligand (L) was successfully synthesized and characterized by elemental analysis and IR-spectroscopy. The structures of (E)-4-(2,4-diisopropylphenyl)-4-oxo-2-butenoic acid (HL), and the corresponding (tetrakis)-mu-[(E)-4-(2,4-diisopropylphenyl)-4-oxo-2-butenoato]-bis(ethanol)-copper(II) complex, [Cu2L4(C2H5OH)(2)], were determined by single crystal X-ray analyses and are preliminarily discussed. This is the first complex of a transition metal with ligand L. as well as the first determined crystal structure of a metal complex with this type of ligand. Analysis of the magnetic susceptibility measurements of the isolated [Cu2L4(C2H5OH)(2)]center dot H2O complex shows the existence of a strong anti-ferromagnetic intra-dimer coupling, with an exchange integral value 2J of -260 cm(-1). (C) 2006 Elsevier B.V. All rights reserved.", journal = "Inorganic Chemistry Communications", title = "Synthesis, structure and magnetic properties of the first copper(II) complex with an (E)-4-aryl-4-oxo-2-butenoato ligand", volume = "9", number = "12", pages = "1173-1177", doi = "10.1016/j.inoche.2006.07.029" }
Miodragovic, Z. M., Bogdanović, G. A., Krajcinovic, B. B., Drakulić, B. J., Kusigerski, V., Miodragović Đenana U., Spasojević, V., Hodzic, I. M.,& Juranić, I. O.. (2006). Synthesis, structure and magnetic properties of the first copper(II) complex with an (E)-4-aryl-4-oxo-2-butenoato ligand. in Inorganic Chemistry Communications, 9(12), 1173-1177. https://doi.org/10.1016/j.inoche.2006.07.029
Miodragovic ZM, Bogdanović GA, Krajcinovic BB, Drakulić BJ, Kusigerski V, Miodragović Đenana U., Spasojević V, Hodzic IM, Juranić IO. Synthesis, structure and magnetic properties of the first copper(II) complex with an (E)-4-aryl-4-oxo-2-butenoato ligand. in Inorganic Chemistry Communications. 2006;9(12):1173-1177. doi:10.1016/j.inoche.2006.07.029 .
Miodragovic, Zoran M., Bogdanović, Goran A., Krajcinovic, Bojana B., Drakulić, Branko J., Kusigerski, Vladan, Miodragović Đenana U., Spasojević, Vojislav, Hodzic, Ismet M., Juranić, Ivan O., "Synthesis, structure and magnetic properties of the first copper(II) complex with an (E)-4-aryl-4-oxo-2-butenoato ligand" in Inorganic Chemistry Communications, 9, no. 12 (2006):1173-1177, https://doi.org/10.1016/j.inoche.2006.07.029 . .