Ionization energies of LinX(n=2,3; X=Cl,Br,I) molecules
No Thumbnail
Authors
Veličković, SuzanaĐorđević, Vesna R.
Cvetićanin, Jelena M.
Đustebek, Jasmina B.
Veljković, Miomir V.
Nešković, Olivera M.
Article
Metadata
Show full item recordAbstract
Molecules of LinX (n = 2,3; X = Cl, Br, I) were examined with a magnetic sector mass spectrometer by surface ionization using a triple rhenium filament impregnated with fullerene (C-60). The ionization energies obtained for Li2Cl, Li2Br and Li2I Molecules are 3.8 +/- 0.1, 3.9 +/- 0.1 and 4.0 +/- 0.1 eV. respectively. The first ionization energy of Li2Cl is documented, while there are no literature data for the ionization energies of Li2Br and Li2I. The molecules of Li3Cl, Li3Br and Li3I were detected experimentally for the first time with ionization energies of 4.0 +/- 0.1, 4.1 +/- 0.1 and 4.1 +/- 0.1 eV, respectively. The ionization energies of LinX (n = 2, 3; X = Cl, Br, I) are in correlation with the theoretical prediction of their hyperlithiated configurations. Copyright (c) 2006 John Wiley and Sons, Ltd.
Source:
Rapid Communications in Mass Spectrometry, 2006, 20, 20, 3151-3153
DOI: 10.1002/rcm.2712
ISSN: 0951-4198
PubMed: 16986212
WoS: 000241332500019
Scopus: 2-s2.0-33750027372
Collections
Institution/Community
VinčaTY - JOUR AU - Veličković, Suzana AU - Đorđević, Vesna R. AU - Cvetićanin, Jelena M. AU - Đustebek, Jasmina B. AU - Veljković, Miomir V. AU - Nešković, Olivera M. PY - 2006 UR - https://vinar.vin.bg.ac.rs/handle/123456789/3102 AB - Molecules of LinX (n = 2,3; X = Cl, Br, I) were examined with a magnetic sector mass spectrometer by surface ionization using a triple rhenium filament impregnated with fullerene (C-60). The ionization energies obtained for Li2Cl, Li2Br and Li2I Molecules are 3.8 +/- 0.1, 3.9 +/- 0.1 and 4.0 +/- 0.1 eV. respectively. The first ionization energy of Li2Cl is documented, while there are no literature data for the ionization energies of Li2Br and Li2I. The molecules of Li3Cl, Li3Br and Li3I were detected experimentally for the first time with ionization energies of 4.0 +/- 0.1, 4.1 +/- 0.1 and 4.1 +/- 0.1 eV, respectively. The ionization energies of LinX (n = 2, 3; X = Cl, Br, I) are in correlation with the theoretical prediction of their hyperlithiated configurations. Copyright (c) 2006 John Wiley and Sons, Ltd. T2 - Rapid Communications in Mass Spectrometry T1 - Ionization energies of LinX(n=2,3; X=Cl,Br,I) molecules VL - 20 IS - 20 SP - 3151 EP - 3153 DO - 10.1002/rcm.2712 ER -
@article{ author = "Veličković, Suzana and Đorđević, Vesna R. and Cvetićanin, Jelena M. and Đustebek, Jasmina B. and Veljković, Miomir V. and Nešković, Olivera M.", year = "2006", abstract = "Molecules of LinX (n = 2,3; X = Cl, Br, I) were examined with a magnetic sector mass spectrometer by surface ionization using a triple rhenium filament impregnated with fullerene (C-60). The ionization energies obtained for Li2Cl, Li2Br and Li2I Molecules are 3.8 +/- 0.1, 3.9 +/- 0.1 and 4.0 +/- 0.1 eV. respectively. The first ionization energy of Li2Cl is documented, while there are no literature data for the ionization energies of Li2Br and Li2I. The molecules of Li3Cl, Li3Br and Li3I were detected experimentally for the first time with ionization energies of 4.0 +/- 0.1, 4.1 +/- 0.1 and 4.1 +/- 0.1 eV, respectively. The ionization energies of LinX (n = 2, 3; X = Cl, Br, I) are in correlation with the theoretical prediction of their hyperlithiated configurations. Copyright (c) 2006 John Wiley and Sons, Ltd.", journal = "Rapid Communications in Mass Spectrometry", title = "Ionization energies of LinX(n=2,3; X=Cl,Br,I) molecules", volume = "20", number = "20", pages = "3151-3153", doi = "10.1002/rcm.2712" }
Veličković, S., Đorđević, V. R., Cvetićanin, J. M., Đustebek, J. B., Veljković, M. V.,& Nešković, O. M.. (2006). Ionization energies of LinX(n=2,3; X=Cl,Br,I) molecules. in Rapid Communications in Mass Spectrometry, 20(20), 3151-3153. https://doi.org/10.1002/rcm.2712
Veličković S, Đorđević VR, Cvetićanin JM, Đustebek JB, Veljković MV, Nešković OM. Ionization energies of LinX(n=2,3; X=Cl,Br,I) molecules. in Rapid Communications in Mass Spectrometry. 2006;20(20):3151-3153. doi:10.1002/rcm.2712 .
Veličković, Suzana, Đorđević, Vesna R., Cvetićanin, Jelena M., Đustebek, Jasmina B., Veljković, Miomir V., Nešković, Olivera M., "Ionization energies of LinX(n=2,3; X=Cl,Br,I) molecules" in Rapid Communications in Mass Spectrometry, 20, no. 20 (2006):3151-3153, https://doi.org/10.1002/rcm.2712 . .