Transition metal complexes with thiosemicarbazide-based ligands. XLIV. The supramolecular arrangement in the Ni(II) complexes of S-methylisothiosemicarbazide
Apstrakt
The reaction of the octahedral complex [Ni(lTSC)(2)(NO3)(2)] (1) with sodium terephthalate yielded the novel octahedral complex [Ni(ITSC)(2)(H2O)(2)](tere) (.) 2H(2)O (2), (ITSC = S-methylisothiosemicarbazide, tere = terephthalate dianion). The X-ray structural analysis of the starting and the final compound showed that they have a centrosymmetric octahedral geometry with the NiN4O2 chromophore. As a result of the non-covalent intermolecular interactions, molecules of both complexes tend to associate into the characteristic 2D blocks separated by S-methyl moieties. In the case of 2, the terephthalate anions, located between the S-methyl groups, enable the transformation of the 2D into 3D supramolecular structure. The similar structural arrangement is also found, in two previously published structures. (C) 2004 Published by Elsevier B.V.
Ključne reči:
nickel(II) complexes / S-methylisothiosemicarbazide / 2D supramolecular block / X-ray analysis / supramolecular structureIzvor:
Inorganic Chemistry Communications, 2005, 8, 1, 9-13
DOI: 10.1016/j.inoche.2004.10.001
ISSN: 1387-7003
WoS: 000226148900003
Scopus: 2-s2.0-10944248532
Kolekcije
Institucija/grupa
VinčaTY - JOUR AU - Novaković, Slađana B. AU - Bogdanović, Goran A. AU - Leovac, Vukadin M. PY - 2005 UR - https://vinar.vin.bg.ac.rs/handle/123456789/2841 AB - The reaction of the octahedral complex [Ni(lTSC)(2)(NO3)(2)] (1) with sodium terephthalate yielded the novel octahedral complex [Ni(ITSC)(2)(H2O)(2)](tere) (.) 2H(2)O (2), (ITSC = S-methylisothiosemicarbazide, tere = terephthalate dianion). The X-ray structural analysis of the starting and the final compound showed that they have a centrosymmetric octahedral geometry with the NiN4O2 chromophore. As a result of the non-covalent intermolecular interactions, molecules of both complexes tend to associate into the characteristic 2D blocks separated by S-methyl moieties. In the case of 2, the terephthalate anions, located between the S-methyl groups, enable the transformation of the 2D into 3D supramolecular structure. The similar structural arrangement is also found, in two previously published structures. (C) 2004 Published by Elsevier B.V. T2 - Inorganic Chemistry Communications T1 - Transition metal complexes with thiosemicarbazide-based ligands. XLIV. The supramolecular arrangement in the Ni(II) complexes of S-methylisothiosemicarbazide VL - 8 IS - 1 SP - 9 EP - 13 DO - 10.1016/j.inoche.2004.10.001 ER -
@article{ author = "Novaković, Slađana B. and Bogdanović, Goran A. and Leovac, Vukadin M.", year = "2005", abstract = "The reaction of the octahedral complex [Ni(lTSC)(2)(NO3)(2)] (1) with sodium terephthalate yielded the novel octahedral complex [Ni(ITSC)(2)(H2O)(2)](tere) (.) 2H(2)O (2), (ITSC = S-methylisothiosemicarbazide, tere = terephthalate dianion). The X-ray structural analysis of the starting and the final compound showed that they have a centrosymmetric octahedral geometry with the NiN4O2 chromophore. As a result of the non-covalent intermolecular interactions, molecules of both complexes tend to associate into the characteristic 2D blocks separated by S-methyl moieties. In the case of 2, the terephthalate anions, located between the S-methyl groups, enable the transformation of the 2D into 3D supramolecular structure. The similar structural arrangement is also found, in two previously published structures. (C) 2004 Published by Elsevier B.V.", journal = "Inorganic Chemistry Communications", title = "Transition metal complexes with thiosemicarbazide-based ligands. XLIV. The supramolecular arrangement in the Ni(II) complexes of S-methylisothiosemicarbazide", volume = "8", number = "1", pages = "9-13", doi = "10.1016/j.inoche.2004.10.001" }
Novaković, S. B., Bogdanović, G. A.,& Leovac, V. M.. (2005). Transition metal complexes with thiosemicarbazide-based ligands. XLIV. The supramolecular arrangement in the Ni(II) complexes of S-methylisothiosemicarbazide. in Inorganic Chemistry Communications, 8(1), 9-13. https://doi.org/10.1016/j.inoche.2004.10.001
Novaković SB, Bogdanović GA, Leovac VM. Transition metal complexes with thiosemicarbazide-based ligands. XLIV. The supramolecular arrangement in the Ni(II) complexes of S-methylisothiosemicarbazide. in Inorganic Chemistry Communications. 2005;8(1):9-13. doi:10.1016/j.inoche.2004.10.001 .
Novaković, Slađana B., Bogdanović, Goran A., Leovac, Vukadin M., "Transition metal complexes with thiosemicarbazide-based ligands. XLIV. The supramolecular arrangement in the Ni(II) complexes of S-methylisothiosemicarbazide" in Inorganic Chemistry Communications, 8, no. 1 (2005):9-13, https://doi.org/10.1016/j.inoche.2004.10.001 . .