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Transition metal complexes with Girard reagent-based ligands, Part I: Synthesis and crystal structure of the first cobalt(III) complexes with Schiff base derivative of Girard reagent
dc.creator | Vojinovic, LS | |
dc.creator | Leovac, Vukadin M. | |
dc.creator | Novaković, Slađana B. | |
dc.creator | Bogdanović, Goran A. | |
dc.creator | Csanadi, JJ | |
dc.creator | Češljević, Valerija I. | |
dc.date.accessioned | 2018-03-01T19:33:31Z | |
dc.date.available | 2018-03-01T19:33:31Z | |
dc.date.issued | 2004 | |
dc.identifier.issn | 1387-7003 | |
dc.identifier.uri | https://vinar.vin.bg.ac.rs/handle/123456789/2835 | |
dc.description.abstract | A new ligand, pyridoxilidene Girard-T hydrazone, [H3L]Cl-2 . 2H(2)O, and its octahedral cobalt(III) complexes [Co(HL) (NO2)(3)] . H2O (1) and [Co(HL)(2)](PF6)(3) (2) were synthesized. The X-ray analysis of (1) showed that the complex has a mer-octahedral configuration formed by coordination of the tridentate ONO neutral Schiff-base molecule and three monodentate N-bonded NO2 groups. Hydrogen bonds and intermolecular interactions for this complex are discussed. Complex (2) also has a mer-octahedral configuration. The ligand and complexes were characterized by elemental analysis, conductometric and magnetochemical measurements, IR and UV-Visible, H-1 and C-13 NMR spectra. (C) 2004 Published by Elsevier B.V. | en |
dc.rights | restrictedAccess | en |
dc.source | Inorganic Chemistry Communications | en |
dc.subject | cobalt(III) complexes | en |
dc.subject | pyridoxilidene Girard-T hydrazone | en |
dc.subject | X-ray crystal structure | en |
dc.title | Transition metal complexes with Girard reagent-based ligands, Part I: Synthesis and crystal structure of the first cobalt(III) complexes with Schiff base derivative of Girard reagent | en |
dc.type | article | en |
dcterms.abstract | Леовац, ВМ; Војиновиц, ЛС; Цсанади, ЈЈ; Цесљевиц, ВИ; Новаковић Слађана; Богдановић Горан; | |
dc.citation.volume | 7 | |
dc.citation.issue | 12 | |
dc.citation.spage | 1264 | |
dc.citation.epage | 1268 | |
dc.identifier.wos | 000225513200006 | |
dc.identifier.doi | 10.1016/j.inoche.2004.09.016 | |
dc.citation.rank | M22 | |
dc.identifier.scopus | 2-s2.0-9244240265 |
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