Transition metal complexes with Girard reagent-based ligands, Part I: Synthesis and crystal structure of the first cobalt(III) complexes with Schiff base derivative of Girard reagent
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Vojinovic, LSLeovac, Vukadin M.
Novaković, Slađana B.
Bogdanović, Goran A.
Csanadi, JJ
Češljević, Valerija I.
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A new ligand, pyridoxilidene Girard-T hydrazone, [H3L]Cl-2 . 2H(2)O, and its octahedral cobalt(III) complexes [Co(HL) (NO2)(3)] . H2O (1) and [Co(HL)(2)](PF6)(3) (2) were synthesized. The X-ray analysis of (1) showed that the complex has a mer-octahedral configuration formed by coordination of the tridentate ONO neutral Schiff-base molecule and three monodentate N-bonded NO2 groups. Hydrogen bonds and intermolecular interactions for this complex are discussed. Complex (2) also has a mer-octahedral configuration. The ligand and complexes were characterized by elemental analysis, conductometric and magnetochemical measurements, IR and UV-Visible, H-1 and C-13 NMR spectra. (C) 2004 Published by Elsevier B.V.
Keywords:
cobalt(III) complexes / pyridoxilidene Girard-T hydrazone / X-ray crystal structureSource:
Inorganic Chemistry Communications, 2004, 7, 12, 1264-1268
DOI: 10.1016/j.inoche.2004.09.016
ISSN: 1387-7003
WoS: 000225513200006
Scopus: 2-s2.0-9244240265
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VinčaTY - JOUR AU - Vojinovic, LS AU - Leovac, Vukadin M. AU - Novaković, Slađana B. AU - Bogdanović, Goran A. AU - Csanadi, JJ AU - Češljević, Valerija I. PY - 2004 UR - https://vinar.vin.bg.ac.rs/handle/123456789/2835 AB - A new ligand, pyridoxilidene Girard-T hydrazone, [H3L]Cl-2 . 2H(2)O, and its octahedral cobalt(III) complexes [Co(HL) (NO2)(3)] . H2O (1) and [Co(HL)(2)](PF6)(3) (2) were synthesized. The X-ray analysis of (1) showed that the complex has a mer-octahedral configuration formed by coordination of the tridentate ONO neutral Schiff-base molecule and three monodentate N-bonded NO2 groups. Hydrogen bonds and intermolecular interactions for this complex are discussed. Complex (2) also has a mer-octahedral configuration. The ligand and complexes were characterized by elemental analysis, conductometric and magnetochemical measurements, IR and UV-Visible, H-1 and C-13 NMR spectra. (C) 2004 Published by Elsevier B.V. T2 - Inorganic Chemistry Communications T1 - Transition metal complexes with Girard reagent-based ligands, Part I: Synthesis and crystal structure of the first cobalt(III) complexes with Schiff base derivative of Girard reagent VL - 7 IS - 12 SP - 1264 EP - 1268 DO - 10.1016/j.inoche.2004.09.016 ER -
@article{ author = "Vojinovic, LS and Leovac, Vukadin M. and Novaković, Slađana B. and Bogdanović, Goran A. and Csanadi, JJ and Češljević, Valerija I.", year = "2004", abstract = "A new ligand, pyridoxilidene Girard-T hydrazone, [H3L]Cl-2 . 2H(2)O, and its octahedral cobalt(III) complexes [Co(HL) (NO2)(3)] . H2O (1) and [Co(HL)(2)](PF6)(3) (2) were synthesized. The X-ray analysis of (1) showed that the complex has a mer-octahedral configuration formed by coordination of the tridentate ONO neutral Schiff-base molecule and three monodentate N-bonded NO2 groups. Hydrogen bonds and intermolecular interactions for this complex are discussed. Complex (2) also has a mer-octahedral configuration. The ligand and complexes were characterized by elemental analysis, conductometric and magnetochemical measurements, IR and UV-Visible, H-1 and C-13 NMR spectra. (C) 2004 Published by Elsevier B.V.", journal = "Inorganic Chemistry Communications", title = "Transition metal complexes with Girard reagent-based ligands, Part I: Synthesis and crystal structure of the first cobalt(III) complexes with Schiff base derivative of Girard reagent", volume = "7", number = "12", pages = "1264-1268", doi = "10.1016/j.inoche.2004.09.016" }
Vojinovic, L., Leovac, V. M., Novaković, S. B., Bogdanović, G. A., Csanadi, J.,& Češljević, V. I.. (2004). Transition metal complexes with Girard reagent-based ligands, Part I: Synthesis and crystal structure of the first cobalt(III) complexes with Schiff base derivative of Girard reagent. in Inorganic Chemistry Communications, 7(12), 1264-1268. https://doi.org/10.1016/j.inoche.2004.09.016
Vojinovic L, Leovac VM, Novaković SB, Bogdanović GA, Csanadi J, Češljević VI. Transition metal complexes with Girard reagent-based ligands, Part I: Synthesis and crystal structure of the first cobalt(III) complexes with Schiff base derivative of Girard reagent. in Inorganic Chemistry Communications. 2004;7(12):1264-1268. doi:10.1016/j.inoche.2004.09.016 .
Vojinovic, LS, Leovac, Vukadin M., Novaković, Slađana B., Bogdanović, Goran A., Csanadi, JJ, Češljević, Valerija I., "Transition metal complexes with Girard reagent-based ligands, Part I: Synthesis and crystal structure of the first cobalt(III) complexes with Schiff base derivative of Girard reagent" in Inorganic Chemistry Communications, 7, no. 12 (2004):1264-1268, https://doi.org/10.1016/j.inoche.2004.09.016 . .