Synthesis, physicochemical properties and crystal structure of isothiocianato [2-(diphenylphosphino)benzaldehyde selenosemicarbazonato(1(-))] nickel(II)
Abstract
The syntheses of a new ligand 2-(diphenylphosphino)benzaldehyde selenosemicarbazone (HL) and the corresponding complex with Ni(II) of the formula [Ni(L)(NCS)] are reported. The complex was characterized by single crystal X-ray analysis. The compound complex is diamagnetic and has a markedly deformed square-planar structure with PNSe set of donor atoms of the ligand, the Schiff base monoanion, and the N atom of the coordinated NCS group. The phosphorus atom deviates even by 0.494(3) Angstrom from the mean plane defined by the other coordination atoms (NSeN) and the metal atom. (C) 2003 Published by Elsevier B.V.
Keywords:
nickel(II) complex / 2-(diphenylphosphino)benzaldehyde selenosemicarbazone / crystal structure / IR spectra / deformed coordination geometrySource:
Inorganic Chemistry Communications, 2004, 7, 2, 253-256
DOI: 10.1016/j.inoche.2003.11.013
ISSN: 1387-7003
WoS: 000188859000029
Scopus: 2-s2.0-0842277653
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VinčaTY - JOUR AU - Brceski, ID AU - Leovac, Vukadin M. AU - Bogdanović, Goran A. AU - Sovilj, Sofija P. AU - Revenco, M PY - 2004 UR - https://vinar.vin.bg.ac.rs/handle/123456789/2709 AB - The syntheses of a new ligand 2-(diphenylphosphino)benzaldehyde selenosemicarbazone (HL) and the corresponding complex with Ni(II) of the formula [Ni(L)(NCS)] are reported. The complex was characterized by single crystal X-ray analysis. The compound complex is diamagnetic and has a markedly deformed square-planar structure with PNSe set of donor atoms of the ligand, the Schiff base monoanion, and the N atom of the coordinated NCS group. The phosphorus atom deviates even by 0.494(3) Angstrom from the mean plane defined by the other coordination atoms (NSeN) and the metal atom. (C) 2003 Published by Elsevier B.V. T2 - Inorganic Chemistry Communications T1 - Synthesis, physicochemical properties and crystal structure of isothiocianato [2-(diphenylphosphino)benzaldehyde selenosemicarbazonato(1(-))] nickel(II) VL - 7 IS - 2 SP - 253 EP - 256 DO - 10.1016/j.inoche.2003.11.013 ER -
@article{ author = "Brceski, ID and Leovac, Vukadin M. and Bogdanović, Goran A. and Sovilj, Sofija P. and Revenco, M", year = "2004", abstract = "The syntheses of a new ligand 2-(diphenylphosphino)benzaldehyde selenosemicarbazone (HL) and the corresponding complex with Ni(II) of the formula [Ni(L)(NCS)] are reported. The complex was characterized by single crystal X-ray analysis. The compound complex is diamagnetic and has a markedly deformed square-planar structure with PNSe set of donor atoms of the ligand, the Schiff base monoanion, and the N atom of the coordinated NCS group. The phosphorus atom deviates even by 0.494(3) Angstrom from the mean plane defined by the other coordination atoms (NSeN) and the metal atom. (C) 2003 Published by Elsevier B.V.", journal = "Inorganic Chemistry Communications", title = "Synthesis, physicochemical properties and crystal structure of isothiocianato [2-(diphenylphosphino)benzaldehyde selenosemicarbazonato(1(-))] nickel(II)", volume = "7", number = "2", pages = "253-256", doi = "10.1016/j.inoche.2003.11.013" }
Brceski, I., Leovac, V. M., Bogdanović, G. A., Sovilj, S. P.,& Revenco, M.. (2004). Synthesis, physicochemical properties and crystal structure of isothiocianato [2-(diphenylphosphino)benzaldehyde selenosemicarbazonato(1(-))] nickel(II). in Inorganic Chemistry Communications, 7(2), 253-256. https://doi.org/10.1016/j.inoche.2003.11.013
Brceski I, Leovac VM, Bogdanović GA, Sovilj SP, Revenco M. Synthesis, physicochemical properties and crystal structure of isothiocianato [2-(diphenylphosphino)benzaldehyde selenosemicarbazonato(1(-))] nickel(II). in Inorganic Chemistry Communications. 2004;7(2):253-256. doi:10.1016/j.inoche.2003.11.013 .
Brceski, ID, Leovac, Vukadin M., Bogdanović, Goran A., Sovilj, Sofija P., Revenco, M, "Synthesis, physicochemical properties and crystal structure of isothiocianato [2-(diphenylphosphino)benzaldehyde selenosemicarbazonato(1(-))] nickel(II)" in Inorganic Chemistry Communications, 7, no. 2 (2004):253-256, https://doi.org/10.1016/j.inoche.2003.11.013 . .