Tris(3,5-dimethyl-1H-pyrazole-1-thiocarboxamidato-kappa N-2(2),N)cobalt(III)
Abstract
In the crystal structure of the title complex, [Co(C6H8N3S)(3)], the Co-III atom is octahedrally coordinated by three monodeprotonated bidentate 3,5-dimethyl-1H-pyrazole-1-thiocarboxamide ligands with two thiocarboxamide N atoms in axial positions. The asymmetric unit contains two molecules (A and B) and these molecules are arranged in chains in an alternating fashion connected by N-H...S interactions.
Source:
Acta Crystallographica. Section C: Crystal Structure Communications, 2003, 59, M381-M383
DOI: 10.1107/S0108270103016755
ISSN: 0108-2701
PubMed: 14532648
WoS: 000185699000004
Scopus: 2-s2.0-3142695416
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Institution/Community
VinčaTY - JOUR AU - Jacimovic, ZK AU - Tomić, Zoran D. AU - Giester, Gerald AU - Leovac, Vukadin M. PY - 2003 UR - https://vinar.vin.bg.ac.rs/handle/123456789/2675 AB - In the crystal structure of the title complex, [Co(C6H8N3S)(3)], the Co-III atom is octahedrally coordinated by three monodeprotonated bidentate 3,5-dimethyl-1H-pyrazole-1-thiocarboxamide ligands with two thiocarboxamide N atoms in axial positions. The asymmetric unit contains two molecules (A and B) and these molecules are arranged in chains in an alternating fashion connected by N-H...S interactions. T2 - Acta Crystallographica. Section C: Crystal Structure Communications T1 - Tris(3,5-dimethyl-1H-pyrazole-1-thiocarboxamidato-kappa N-2(2),N)cobalt(III) VL - 59 SP - M381 EP - M383 DO - 10.1107/S0108270103016755 ER -
@article{ author = "Jacimovic, ZK and Tomić, Zoran D. and Giester, Gerald and Leovac, Vukadin M.", year = "2003", abstract = "In the crystal structure of the title complex, [Co(C6H8N3S)(3)], the Co-III atom is octahedrally coordinated by three monodeprotonated bidentate 3,5-dimethyl-1H-pyrazole-1-thiocarboxamide ligands with two thiocarboxamide N atoms in axial positions. The asymmetric unit contains two molecules (A and B) and these molecules are arranged in chains in an alternating fashion connected by N-H...S interactions.", journal = "Acta Crystallographica. Section C: Crystal Structure Communications", title = "Tris(3,5-dimethyl-1H-pyrazole-1-thiocarboxamidato-kappa N-2(2),N)cobalt(III)", volume = "59", pages = "M381-M383", doi = "10.1107/S0108270103016755" }
Jacimovic, Z., Tomić, Z. D., Giester, G.,& Leovac, V. M.. (2003). Tris(3,5-dimethyl-1H-pyrazole-1-thiocarboxamidato-kappa N-2(2),N)cobalt(III). in Acta Crystallographica. Section C: Crystal Structure Communications, 59, M381-M383. https://doi.org/10.1107/S0108270103016755
Jacimovic Z, Tomić ZD, Giester G, Leovac VM. Tris(3,5-dimethyl-1H-pyrazole-1-thiocarboxamidato-kappa N-2(2),N)cobalt(III). in Acta Crystallographica. Section C: Crystal Structure Communications. 2003;59:M381-M383. doi:10.1107/S0108270103016755 .
Jacimovic, ZK, Tomić, Zoran D., Giester, Gerald, Leovac, Vukadin M., "Tris(3,5-dimethyl-1H-pyrazole-1-thiocarboxamidato-kappa N-2(2),N)cobalt(III)" in Acta Crystallographica. Section C: Crystal Structure Communications, 59 (2003):M381-M383, https://doi.org/10.1107/S0108270103016755 . .