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Autoxidation of tryptophan in aqueous solutions
dc.creator | Janković, Ivana A. | |
dc.creator | Josimović, Ljubica R. | |
dc.date.accessioned | 2018-03-01T19:01:45Z | |
dc.date.available | 2018-03-01T19:01:45Z | |
dc.date.issued | 2001 | |
dc.identifier.issn | 0352-5139 | |
dc.identifier.uri | https://vinar.vin.bg.ac.rs/handle/123456789/2468 | |
dc.description.abstract | Autoxidation of tryptophan was investigated in aqueous solutions by the gamma radiolytic technique. The oxygen uptake and formation of peroxide materials was followed as a function of pH, dose rate and concentration of tryptophan. The results obtained indicate that TrpH(OH)OO . radicals react with tryptophan by adduct formation thus propagating autoxidation. The chain propagation length (CPL) for a 2x10(-2) mol dm(-3) tryptophan solution at pH 9.5 and a dose rate 0.01 Gy s(-1) was estimated to be approximate to5.8, which shows that the autoxidation of tryptophan is a short chain reaction. | en |
dc.rights | openAccess | en |
dc.source | Journal of the Serbian Chemical Society | en |
dc.subject | autoxidation | en |
dc.subject | tryptophan | en |
dc.subject | peroxy radicals | en |
dc.title | Autoxidation of tryptophan in aqueous solutions | en |
dc.type | article | en |
dcterms.abstract | Јанковиц, ИA; Јосимовиц, ЛР; | |
dc.citation.volume | 66 | |
dc.citation.issue | 9 | |
dc.citation.spage | 571 | |
dc.citation.epage | 580 | |
dc.identifier.wos | 000171531500001 | |
dc.citation.rank | M23 | |
dc.identifier.rcub | https://hdl.handle.net/21.15107/rcub_vinar_2468 |
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