The effect of the presence of alcohol in the dispersing phase of oxide sols on the properties of RuO2-TiO2/Ti anodes obtained by the sol-gel procedure
Abstract
The effect of the addition of ethanol and 2-propanol to the dispersing phase of TiO2 and RuO2 sols mixture on the morphology and, consequently, on the electrochemical properties of the sol-gel obtained activated titanium anodes was investigated. The properties of the obtained anodes were compared to those obtained by the thermal decomposition of appropriate chloride salts. The morphology of the anode coatings was examined by scanning tunneling microscopy. The electrochemical behaviour was investigated by cyclic voltammetry and by polarization measurements. An accelerated stability test was used for the examination of the stability of the anodes under simultaneous oxygen and chlorine evolution reaction. A dependence of the anode stability on the type of added alcohol is indicated.
Keywords:
activated titanium anodes / RuO2 sol / TiO2 sol / sol-gel procedure / accelerated stability testSource:
Journal of the Serbian Chemical Society, 2000, 65, 9, 649-660Collections
Institution/Community
VinčaTY - JOUR AU - Panic, V AU - Dekanski, Aleksandar B. AU - Milonjić, Slobodan K. AU - Atanasoski, R AU - Nikolić, Branislav Ž. PY - 2000 UR - https://vinar.vin.bg.ac.rs/handle/123456789/2375 AB - The effect of the addition of ethanol and 2-propanol to the dispersing phase of TiO2 and RuO2 sols mixture on the morphology and, consequently, on the electrochemical properties of the sol-gel obtained activated titanium anodes was investigated. The properties of the obtained anodes were compared to those obtained by the thermal decomposition of appropriate chloride salts. The morphology of the anode coatings was examined by scanning tunneling microscopy. The electrochemical behaviour was investigated by cyclic voltammetry and by polarization measurements. An accelerated stability test was used for the examination of the stability of the anodes under simultaneous oxygen and chlorine evolution reaction. A dependence of the anode stability on the type of added alcohol is indicated. T2 - Journal of the Serbian Chemical Society T1 - The effect of the presence of alcohol in the dispersing phase of oxide sols on the properties of RuO2-TiO2/Ti anodes obtained by the sol-gel procedure VL - 65 IS - 9 SP - 649 EP - 660 UR - https://hdl.handle.net/21.15107/rcub_vinar_2375 ER -
@article{ author = "Panic, V and Dekanski, Aleksandar B. and Milonjić, Slobodan K. and Atanasoski, R and Nikolić, Branislav Ž.", year = "2000", abstract = "The effect of the addition of ethanol and 2-propanol to the dispersing phase of TiO2 and RuO2 sols mixture on the morphology and, consequently, on the electrochemical properties of the sol-gel obtained activated titanium anodes was investigated. The properties of the obtained anodes were compared to those obtained by the thermal decomposition of appropriate chloride salts. The morphology of the anode coatings was examined by scanning tunneling microscopy. The electrochemical behaviour was investigated by cyclic voltammetry and by polarization measurements. An accelerated stability test was used for the examination of the stability of the anodes under simultaneous oxygen and chlorine evolution reaction. A dependence of the anode stability on the type of added alcohol is indicated.", journal = "Journal of the Serbian Chemical Society", title = "The effect of the presence of alcohol in the dispersing phase of oxide sols on the properties of RuO2-TiO2/Ti anodes obtained by the sol-gel procedure", volume = "65", number = "9", pages = "649-660", url = "https://hdl.handle.net/21.15107/rcub_vinar_2375" }
Panic, V., Dekanski, A. B., Milonjić, S. K., Atanasoski, R.,& Nikolić, B. Ž.. (2000). The effect of the presence of alcohol in the dispersing phase of oxide sols on the properties of RuO2-TiO2/Ti anodes obtained by the sol-gel procedure. in Journal of the Serbian Chemical Society, 65(9), 649-660. https://hdl.handle.net/21.15107/rcub_vinar_2375
Panic V, Dekanski AB, Milonjić SK, Atanasoski R, Nikolić BŽ. The effect of the presence of alcohol in the dispersing phase of oxide sols on the properties of RuO2-TiO2/Ti anodes obtained by the sol-gel procedure. in Journal of the Serbian Chemical Society. 2000;65(9):649-660. https://hdl.handle.net/21.15107/rcub_vinar_2375 .
Panic, V, Dekanski, Aleksandar B., Milonjić, Slobodan K., Atanasoski, R, Nikolić, Branislav Ž., "The effect of the presence of alcohol in the dispersing phase of oxide sols on the properties of RuO2-TiO2/Ti anodes obtained by the sol-gel procedure" in Journal of the Serbian Chemical Society, 65, no. 9 (2000):649-660, https://hdl.handle.net/21.15107/rcub_vinar_2375 .