Pentagonal bipyramidal complexes of Co(II) with singly- and doubly-deprotonated 2 ,2 -(2,6-pyridindiyldiethylidene)dioxamohydrazide - The crystal structure of [diaqua-2 ,2 -(2,6-pyridindiyldiethylidene)dioxamohydrazidecobalt(II)] hexahydrate
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1997
Authors
Ivanović, IvanaAnđelković, Katarina
Beljanski, Vladimir
Prelesnik, Bogdan V.
Leovac, Vukadin M.
Momirović, Mirjana
Article (Published version)
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This paper reports the first Co(II) complexes with a singly-and doubly-deprotonated H2L ligand (H2L = 2,2-(2,6-pyridindiyldiethylidene)dioxamohydrazide belonging to the planar pentadentate class. The complexes were characterized by elemental analysis, thermal analysis, IR spectroscopy, molar conductivity and magnetic susceptibility measurements. The crystal structure of [Co(L)(H2O)(2)].6H(2)O complex has been determined. The pentagonal bipyramidal geometry present in the previously synthesized complex [Co(H2L)(H2O)(MeOH)](ClO4)2(,) wherein the ligand is present in a neutral form, has been preserved around Co(II).
Keywords:
pentagonal bipyramidal complexes / cobalt(II) / pentadentates / X-ray structureSource:
Journal of Coordination Chemistry, 1997, 42, 4, 335-342
DOI: 10.1080/00958979708022862
ISSN: 0095-8972
WoS: 000073391500007
Scopus: 2-s2.0-0000645129
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VinčaTY - JOUR AU - Ivanović, Ivana AU - Anđelković, Katarina AU - Beljanski, Vladimir AU - Prelesnik, Bogdan V. AU - Leovac, Vukadin M. AU - Momirović, Mirjana PY - 1997 UR - https://vinar.vin.bg.ac.rs/handle/123456789/2136 AB - This paper reports the first Co(II) complexes with a singly-and doubly-deprotonated H2L ligand (H2L = 2,2-(2,6-pyridindiyldiethylidene)dioxamohydrazide belonging to the planar pentadentate class. The complexes were characterized by elemental analysis, thermal analysis, IR spectroscopy, molar conductivity and magnetic susceptibility measurements. The crystal structure of [Co(L)(H2O)(2)].6H(2)O complex has been determined. The pentagonal bipyramidal geometry present in the previously synthesized complex [Co(H2L)(H2O)(MeOH)](ClO4)2(,) wherein the ligand is present in a neutral form, has been preserved around Co(II). T2 - Journal of Coordination Chemistry T1 - Pentagonal bipyramidal complexes of Co(II) with singly- and doubly-deprotonated 2 ,2 -(2,6-pyridindiyldiethylidene)dioxamohydrazide - The crystal structure of [diaqua-2 ,2 -(2,6-pyridindiyldiethylidene)dioxamohydrazidecobalt(II)] hexahydrate VL - 42 IS - 4 SP - 335 EP - 342 DO - 10.1080/00958979708022862 ER -
@article{ author = "Ivanović, Ivana and Anđelković, Katarina and Beljanski, Vladimir and Prelesnik, Bogdan V. and Leovac, Vukadin M. and Momirović, Mirjana", year = "1997", abstract = "This paper reports the first Co(II) complexes with a singly-and doubly-deprotonated H2L ligand (H2L = 2,2-(2,6-pyridindiyldiethylidene)dioxamohydrazide belonging to the planar pentadentate class. The complexes were characterized by elemental analysis, thermal analysis, IR spectroscopy, molar conductivity and magnetic susceptibility measurements. The crystal structure of [Co(L)(H2O)(2)].6H(2)O complex has been determined. The pentagonal bipyramidal geometry present in the previously synthesized complex [Co(H2L)(H2O)(MeOH)](ClO4)2(,) wherein the ligand is present in a neutral form, has been preserved around Co(II).", journal = "Journal of Coordination Chemistry", title = "Pentagonal bipyramidal complexes of Co(II) with singly- and doubly-deprotonated 2 ,2 -(2,6-pyridindiyldiethylidene)dioxamohydrazide - The crystal structure of [diaqua-2 ,2 -(2,6-pyridindiyldiethylidene)dioxamohydrazidecobalt(II)] hexahydrate", volume = "42", number = "4", pages = "335-342", doi = "10.1080/00958979708022862" }
Ivanović, I., Anđelković, K., Beljanski, V., Prelesnik, B. V., Leovac, V. M.,& Momirović, M.. (1997). Pentagonal bipyramidal complexes of Co(II) with singly- and doubly-deprotonated 2 ,2 -(2,6-pyridindiyldiethylidene)dioxamohydrazide - The crystal structure of [diaqua-2 ,2 -(2,6-pyridindiyldiethylidene)dioxamohydrazidecobalt(II)] hexahydrate. in Journal of Coordination Chemistry, 42(4), 335-342. https://doi.org/10.1080/00958979708022862
Ivanović I, Anđelković K, Beljanski V, Prelesnik BV, Leovac VM, Momirović M. Pentagonal bipyramidal complexes of Co(II) with singly- and doubly-deprotonated 2 ,2 -(2,6-pyridindiyldiethylidene)dioxamohydrazide - The crystal structure of [diaqua-2 ,2 -(2,6-pyridindiyldiethylidene)dioxamohydrazidecobalt(II)] hexahydrate. in Journal of Coordination Chemistry. 1997;42(4):335-342. doi:10.1080/00958979708022862 .
Ivanović, Ivana, Anđelković, Katarina, Beljanski, Vladimir, Prelesnik, Bogdan V., Leovac, Vukadin M., Momirović, Mirjana, "Pentagonal bipyramidal complexes of Co(II) with singly- and doubly-deprotonated 2 ,2 -(2,6-pyridindiyldiethylidene)dioxamohydrazide - The crystal structure of [diaqua-2 ,2 -(2,6-pyridindiyldiethylidene)dioxamohydrazidecobalt(II)] hexahydrate" in Journal of Coordination Chemistry, 42, no. 4 (1997):335-342, https://doi.org/10.1080/00958979708022862 . .