Recovering of metals and metal oxides through thermal decomposition process of coal bottom ash: a comprehensive kinetic analysis
Authors
Janković, BojanJanković, Marija
Krneta Nikolić, Jelena
Rajačić, Milica
Vukanac, Ivana
Sarap, Nataša
Manić, Nebojša
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© Akadémiai Kiadó, Budapest, 2023
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In this work, the thermal decomposition process of coal bottom ash (collected after lignitecombustion in coal-fired power plant “Kostolac B” (TEKO-B), Serbia) was investigated, usingsimultaneous TG (thermogravimetry) – DTG (derivative thermogravimetry) techniquesin an inert (Ar) atmosphere, at various heating rates (10.3, 20.9 and 32.1 K/min). In additionto thermal characterization of the sample, the chemical composition and naturally occurredradionuclides were also determined. Using the model-free (isoconversional) (by Friedman(FR), Kissinger-Akahira-Sunose (KAS), Ozawa-Flynn-Wall (OFW) and Vyazovkin (VY)methods) analysis, the complex kinetic nature of the process was successfully resolved. Theconducted numerical optimization of the process (using non-linear least square optimization)had confirmed accuracy and reliability of estimated kinetic parameters. Model-based(model-fitting) kinetic analysis showed the existence of a complex reaction scheme, overtwo consecutive reactions steps a...nd one single-stage reaction step, via mechanism order An,F2, Fn, R3, Cnm (through n-dimensional nucleation/growth, chemical reactions, and n-thorder and m-power with autocatalysis mechanisms). Through physicochemical interpretationof mechanism scheme, an assessment of recovery of valuable metals and metal oxides wasperformed, by analysing the concentration of reaction species in a function of temperature ofindividual steps. Likewise, the influence of certain precursor involved in decomposition processas catalyst (in order to increase the yield of targeted product) was also inspected. Finally,the simulation of actual process using the results obtained from applied methods/models wasperformed, through application of modulated dynamic (MD) prediction.
Keywords:
bottom ash / TG-DTG / metals recovery / kinetic analysis / catalystSource:
JTACC 2023 : 3rd Journal of Thermal Analysis and Calorimetry Conference and 9th V4 (Joint Czech-Hungarian-Polish-Slovakian) Thermoanalytical Conference : Book of asbtracts, 2023, 263-263Publisher:
- Budapest : Akadémiai Kiadó
Funding / projects:
- Ministry of Science, Technological Development and Innovation of the Republic of Serbia, institutional funding - 200105 (University of Belgrade, Faculty of Mechanical Engineering) (RS-MESTD-inst-2020-200105)
Note:
- JTACC 2023 : June 20-23, Balatonfüred, Hungary, 2023.
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VinčaTY - CONF AU - Janković, Bojan AU - Janković, Marija AU - Krneta Nikolić, Jelena AU - Rajačić, Milica AU - Vukanac, Ivana AU - Sarap, Nataša AU - Manić, Nebojša PY - 2023 UR - https://vinar.vin.bg.ac.rs/handle/123456789/12589 AB - In this work, the thermal decomposition process of coal bottom ash (collected after lignitecombustion in coal-fired power plant “Kostolac B” (TEKO-B), Serbia) was investigated, usingsimultaneous TG (thermogravimetry) – DTG (derivative thermogravimetry) techniquesin an inert (Ar) atmosphere, at various heating rates (10.3, 20.9 and 32.1 K/min). In additionto thermal characterization of the sample, the chemical composition and naturally occurredradionuclides were also determined. Using the model-free (isoconversional) (by Friedman(FR), Kissinger-Akahira-Sunose (KAS), Ozawa-Flynn-Wall (OFW) and Vyazovkin (VY)methods) analysis, the complex kinetic nature of the process was successfully resolved. Theconducted numerical optimization of the process (using non-linear least square optimization)had confirmed accuracy and reliability of estimated kinetic parameters. Model-based(model-fitting) kinetic analysis showed the existence of a complex reaction scheme, overtwo consecutive reactions steps and one single-stage reaction step, via mechanism order An,F2, Fn, R3, Cnm (through n-dimensional nucleation/growth, chemical reactions, and n-thorder and m-power with autocatalysis mechanisms). Through physicochemical interpretationof mechanism scheme, an assessment of recovery of valuable metals and metal oxides wasperformed, by analysing the concentration of reaction species in a function of temperature ofindividual steps. Likewise, the influence of certain precursor involved in decomposition processas catalyst (in order to increase the yield of targeted product) was also inspected. Finally,the simulation of actual process using the results obtained from applied methods/models wasperformed, through application of modulated dynamic (MD) prediction. PB - Budapest : Akadémiai Kiadó C3 - JTACC 2023 : 3rd Journal of Thermal Analysis and Calorimetry Conference and 9th V4 (Joint Czech-Hungarian-Polish-Slovakian) Thermoanalytical Conference : Book of asbtracts T1 - Recovering of metals and metal oxides through thermal decomposition process of coal bottom ash: a comprehensive kinetic analysis SP - 263 EP - 263 UR - https://hdl.handle.net/21.15107/rcub_vinar_12589 ER -
@conference{ author = "Janković, Bojan and Janković, Marija and Krneta Nikolić, Jelena and Rajačić, Milica and Vukanac, Ivana and Sarap, Nataša and Manić, Nebojša", year = "2023", abstract = "In this work, the thermal decomposition process of coal bottom ash (collected after lignitecombustion in coal-fired power plant “Kostolac B” (TEKO-B), Serbia) was investigated, usingsimultaneous TG (thermogravimetry) – DTG (derivative thermogravimetry) techniquesin an inert (Ar) atmosphere, at various heating rates (10.3, 20.9 and 32.1 K/min). In additionto thermal characterization of the sample, the chemical composition and naturally occurredradionuclides were also determined. Using the model-free (isoconversional) (by Friedman(FR), Kissinger-Akahira-Sunose (KAS), Ozawa-Flynn-Wall (OFW) and Vyazovkin (VY)methods) analysis, the complex kinetic nature of the process was successfully resolved. Theconducted numerical optimization of the process (using non-linear least square optimization)had confirmed accuracy and reliability of estimated kinetic parameters. Model-based(model-fitting) kinetic analysis showed the existence of a complex reaction scheme, overtwo consecutive reactions steps and one single-stage reaction step, via mechanism order An,F2, Fn, R3, Cnm (through n-dimensional nucleation/growth, chemical reactions, and n-thorder and m-power with autocatalysis mechanisms). Through physicochemical interpretationof mechanism scheme, an assessment of recovery of valuable metals and metal oxides wasperformed, by analysing the concentration of reaction species in a function of temperature ofindividual steps. Likewise, the influence of certain precursor involved in decomposition processas catalyst (in order to increase the yield of targeted product) was also inspected. Finally,the simulation of actual process using the results obtained from applied methods/models wasperformed, through application of modulated dynamic (MD) prediction.", publisher = "Budapest : Akadémiai Kiadó", journal = "JTACC 2023 : 3rd Journal of Thermal Analysis and Calorimetry Conference and 9th V4 (Joint Czech-Hungarian-Polish-Slovakian) Thermoanalytical Conference : Book of asbtracts", title = "Recovering of metals and metal oxides through thermal decomposition process of coal bottom ash: a comprehensive kinetic analysis", pages = "263-263", url = "https://hdl.handle.net/21.15107/rcub_vinar_12589" }
Janković, B., Janković, M., Krneta Nikolić, J., Rajačić, M., Vukanac, I., Sarap, N.,& Manić, N.. (2023). Recovering of metals and metal oxides through thermal decomposition process of coal bottom ash: a comprehensive kinetic analysis. in JTACC 2023 : 3rd Journal of Thermal Analysis and Calorimetry Conference and 9th V4 (Joint Czech-Hungarian-Polish-Slovakian) Thermoanalytical Conference : Book of asbtracts Budapest : Akadémiai Kiadó., 263-263. https://hdl.handle.net/21.15107/rcub_vinar_12589
Janković B, Janković M, Krneta Nikolić J, Rajačić M, Vukanac I, Sarap N, Manić N. Recovering of metals and metal oxides through thermal decomposition process of coal bottom ash: a comprehensive kinetic analysis. in JTACC 2023 : 3rd Journal of Thermal Analysis and Calorimetry Conference and 9th V4 (Joint Czech-Hungarian-Polish-Slovakian) Thermoanalytical Conference : Book of asbtracts. 2023;:263-263. https://hdl.handle.net/21.15107/rcub_vinar_12589 .
Janković, Bojan, Janković, Marija, Krneta Nikolić, Jelena, Rajačić, Milica, Vukanac, Ivana, Sarap, Nataša, Manić, Nebojša, "Recovering of metals and metal oxides through thermal decomposition process of coal bottom ash: a comprehensive kinetic analysis" in JTACC 2023 : 3rd Journal of Thermal Analysis and Calorimetry Conference and 9th V4 (Joint Czech-Hungarian-Polish-Slovakian) Thermoanalytical Conference : Book of asbtracts (2023):263-263, https://hdl.handle.net/21.15107/rcub_vinar_12589 .