Isolated Coordination Polyhedron Confinement in ABP2O7:Mn2+(A=Ba/Sr; B=Mg/Zn)
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Li, SongZhang, ZhenZhen
Zhang, Jilin
Wu, Jiayu
Qiu, Zhongxian
Brik, Mikhail G.
Lian, Shixun
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Many research efforts have focused on designing new inorganic phosphors to meet different application requirements. The structure-photoluminescence relationship between activator ions and the matrix lattice plays an irreparable role in designing target phosphors. Herein, a series of ABP2O7:Mn2+ (A = Ba/Sr; B = Mg/Zn) phosphors are prepared for a detailed study on the relationship between the luminescence performance and spatial structure and symmetry of the doping site of Mn2+. Due to the weak interaction between nearest B-B pairs, [BO5] is defined as an isolated coordination polyhedron whose structure and symmetry directly influence the photoluminescence of Mn2+. The emission wavelength of Mn2+ is ∼620 nm when it occupies the triangular bipyramid [MgO5] in BaMgP2O7. When Mn2+ occupies the quadrangular pyramid-typed [MgO5] or [ZnO5] in SrMgP2O7, SrZnP2O7, and BaZnP2O7, the emission wavelengths peak at ∼670 nm. We propose a conception of isolated coordination polyhedral confinement to c...larify the luminescence performance of Mn2+ in the fivefold coordination configuration with different geometries, which has great theoretical research significance for designing inorganic phosphors.
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Inorganic Chemistry, 2023, 62, 45, 18740-18749Collections
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VinčaTY - JOUR AU - Li, Song AU - Zhang, ZhenZhen AU - Zhang, Jilin AU - Wu, Jiayu AU - Qiu, Zhongxian AU - Brik, Mikhail G. AU - Lian, Shixun PY - 2023 UR - https://vinar.vin.bg.ac.rs/handle/123456789/12041 AB - Many research efforts have focused on designing new inorganic phosphors to meet different application requirements. The structure-photoluminescence relationship between activator ions and the matrix lattice plays an irreparable role in designing target phosphors. Herein, a series of ABP2O7:Mn2+ (A = Ba/Sr; B = Mg/Zn) phosphors are prepared for a detailed study on the relationship between the luminescence performance and spatial structure and symmetry of the doping site of Mn2+. Due to the weak interaction between nearest B-B pairs, [BO5] is defined as an isolated coordination polyhedron whose structure and symmetry directly influence the photoluminescence of Mn2+. The emission wavelength of Mn2+ is ∼620 nm when it occupies the triangular bipyramid [MgO5] in BaMgP2O7. When Mn2+ occupies the quadrangular pyramid-typed [MgO5] or [ZnO5] in SrMgP2O7, SrZnP2O7, and BaZnP2O7, the emission wavelengths peak at ∼670 nm. We propose a conception of isolated coordination polyhedral confinement to clarify the luminescence performance of Mn2+ in the fivefold coordination configuration with different geometries, which has great theoretical research significance for designing inorganic phosphors. T2 - Inorganic Chemistry T1 - Isolated Coordination Polyhedron Confinement in ABP2O7:Mn2+(A=Ba/Sr; B=Mg/Zn) VL - 62 IS - 45 SP - 18740 EP - 18749 DO - 10.1021/acs.inorgchem.3c03238 ER -
@article{ author = "Li, Song and Zhang, ZhenZhen and Zhang, Jilin and Wu, Jiayu and Qiu, Zhongxian and Brik, Mikhail G. and Lian, Shixun", year = "2023", abstract = "Many research efforts have focused on designing new inorganic phosphors to meet different application requirements. The structure-photoluminescence relationship between activator ions and the matrix lattice plays an irreparable role in designing target phosphors. Herein, a series of ABP2O7:Mn2+ (A = Ba/Sr; B = Mg/Zn) phosphors are prepared for a detailed study on the relationship between the luminescence performance and spatial structure and symmetry of the doping site of Mn2+. Due to the weak interaction between nearest B-B pairs, [BO5] is defined as an isolated coordination polyhedron whose structure and symmetry directly influence the photoluminescence of Mn2+. The emission wavelength of Mn2+ is ∼620 nm when it occupies the triangular bipyramid [MgO5] in BaMgP2O7. When Mn2+ occupies the quadrangular pyramid-typed [MgO5] or [ZnO5] in SrMgP2O7, SrZnP2O7, and BaZnP2O7, the emission wavelengths peak at ∼670 nm. We propose a conception of isolated coordination polyhedral confinement to clarify the luminescence performance of Mn2+ in the fivefold coordination configuration with different geometries, which has great theoretical research significance for designing inorganic phosphors.", journal = "Inorganic Chemistry", title = "Isolated Coordination Polyhedron Confinement in ABP2O7:Mn2+(A=Ba/Sr; B=Mg/Zn)", volume = "62", number = "45", pages = "18740-18749", doi = "10.1021/acs.inorgchem.3c03238" }
Li, S., Zhang, Z., Zhang, J., Wu, J., Qiu, Z., Brik, M. G.,& Lian, S.. (2023). Isolated Coordination Polyhedron Confinement in ABP2O7:Mn2+(A=Ba/Sr; B=Mg/Zn). in Inorganic Chemistry, 62(45), 18740-18749. https://doi.org/10.1021/acs.inorgchem.3c03238
Li S, Zhang Z, Zhang J, Wu J, Qiu Z, Brik MG, Lian S. Isolated Coordination Polyhedron Confinement in ABP2O7:Mn2+(A=Ba/Sr; B=Mg/Zn). in Inorganic Chemistry. 2023;62(45):18740-18749. doi:10.1021/acs.inorgchem.3c03238 .
Li, Song, Zhang, ZhenZhen, Zhang, Jilin, Wu, Jiayu, Qiu, Zhongxian, Brik, Mikhail G., Lian, Shixun, "Isolated Coordination Polyhedron Confinement in ABP2O7:Mn2+(A=Ba/Sr; B=Mg/Zn)" in Inorganic Chemistry, 62, no. 45 (2023):18740-18749, https://doi.org/10.1021/acs.inorgchem.3c03238 . .