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dc.creatorStevanović, Dragana D.
dc.creatorBogdanović, Goran A.
dc.creatorVukicevic, Rastko D.
dc.date.accessioned2018-03-01T15:22:22Z
dc.date.available2018-03-01T15:22:22Z
dc.date.issued2014
dc.identifier.issn0277-5387 (print)
dc.identifier.urihttp://vinar.vin.bg.ac.rs/handle/123456789/98
dc.description.abstractThree series of ferrocene containing 3-(arylthio)propan-1-ones (each of eight examples) have been synthesized by thia-Michael addition of the corresponding thiophenols to acryloylferrocene, 1-ferroceny1-3-phenylprop-2-en-1-one and 3-ferrocenyl-1-phenylprop-2-en-1-one promoted by the catalyst generated from a sacrificial zirconium anode. All the newly synthesized compounds (16 in total) were characterized by spectral data, whereas single crystal X-ray structure analysis was performed for 3-[(4-chlorophenyl)thio]-1-ferrocenylpropan-1-one (1h), 3-[(4-chlorophenyl)thio]-1-ferrocenyl-3-phenylpropan-1 one (2h) and 3-[(4-chlorophenyl)thio]-3-ferrocenyl-1-phenylpropan-1-one (3h). Molecular geometry and structural characteristics of three thiaketones (1h, 2h and 3h) were analysed and compared in detail. It was found that all three molecules do not form classical H-bonds and pi center dot center dot center dot pi interactions (regardless of the presence of 3 or 4 aromatic rings per a molecule). However, all three crystal structures abound in intermolecular C-H center dot center dot center dot pi interactions while 2h and 3h in addition form intramolecular C-H center dot center dot center dot pi as only evident interaction within the molecules. (C) 2013 Elsevier Ltd. All rights reserved.en
dc.relationinfo:eu-repo/grantAgreement/MESTD/Basic Research (BR or ON)/172034/RS//
dc.relationinfo:eu-repo/grantAgreement/MESTD/Basic Research (BR or ON)/172014/RS//
dc.rightsrestrictedAccessen
dc.sourcePolyhedronen
dc.subjectFerroceneen
dc.subject3-(Arylthio)propan-1-onesen
dc.subjectCrystal structureen
dc.subjectZirconium catalysten
dc.subjectAnodic dissolutionen
dc.titleNew ferrocene containing 3-(arylthio)propan-1-ones: Synthesis, spectral characterization and crystal structure of 3-[(4-chlorophenyl)thio]-1-ferrocenylpropan-1-one, 3-[(4-chlorophenyl)thio]-1-ferrocenyl-3-phenylpropan-1-one and 3-[(4-chlorophenyl)thio]-3-ferrocenyl-1-phenylpropan-1-oneen
dc.typearticleen
dcterms.abstractБогдановић Горан; Стевановиц, Драгана; Вукицевиц, Растко Д.;
dc.citation.volume80
dc.citation.issueSI
dc.citation.spage10
dc.citation.epage19
dc.identifier.wos000341348300003
dc.identifier.doi10.1016/j.poly.2013.12.012
dc.citation.otherSpecial Issue: SI
dc.citation.rankM22
dc.identifier.scopus2-s2.0-84905577753


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