Production of N-graphene by microwave N-2-Ar plasma
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АуториDias, Ana Paula Soares
Dias, Francisco M.
Teodoro, O. M. N. D.
Henriques, Julio A. P.
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Self-standing N-graphene sheets were produced in low-pressure microwave N-2-Ar plasma. The graphene sheets were exposed to the plasma for various durations and doped with nitrogen atoms, which were incorporated into the hexagonal carbon lattice in pyridinic, pyrrolic and quaternary functional groups, mainly. Atomic nitrogen emissions at the substrate position in the plasma were detected using optical emission spectroscopy. Raman spectroscopy, x-ray photoelectron spectroscopy and transmission electron microscopy techniques were also applied for material characterization. Doping levels as high as 5.6% were achieved and an increase in the sp(2)/sp(3) ratio was observed for a relatively short exposure time.
Кључне речи:microwave plasma / N-graphene / nitrogen atoms
Извор:Journal of Physics. D: Applied Physics, 2016, 49, 5
- Функционални, функционализовани и усавршени нано материјали (RS-45005)
- Portuguese FCT- Fundacao para a Ciencia e a Tecnologia [UID/FIS/50010/2013, INCENTIVO/FIS/LA0010/2014, SFRH/BD/52413/2013], Slovenian Research Agency (ARRS) [L2-6769]
ISSN: 0022-3727 (print); 1361-6463 (electronic)