Dy3+ and Dy3+/Ce3+ doped Al2O3 coatings obtained by plasma electrolytic oxidation: Photoluminescence and energy transfer from Ce3+ to Dy3+
Само за регистроване кориснике
2020
Чланак у часопису (Објављена верзија)
Метаподаци
Приказ свих података о документуАпстракт
In this paper, Dy3+ and Dy3+/Ce3+ doped Al2O3 coatings were synthesized by plasma electrolytic oxidation process of aluminum. Structural and photoluminescence (PL) properties of obtained coatings as well as energy transfer mechanism from Ce3+ to Dy3+ were studied. The PL excitation and emission spectra of Al2O3:Dy3+ featured weak bands attributed to f-f transitions of Dy3+. The PL emission spectrum of Al2O3:Dy3+ exhibits three emission bands in blue-yellow-red regions, assigned to F-4(9/2)-> H-6(15/2), F-4(9/2)-> H-6(13/2), and F-4(9/2)-> H-6(11/2) transitions of Dy3+, respectively. Under middle UV excitation the Ce3+ in Al2O3 emits broad band, peaked at about 330 nm, attributed to the 5d -> 4f transition of Ce3+. Because of the strong overlap between the PL emission of Ce3+ and the PL excitation of Dy3+ in Al2O3, energy transfer from Ce3+ to the Dy3+ in Al2O3:Dy3+/Ce3+ is observed upon 285 nm excitation. PL emissions due to F-4(9/2)-> H-6(J) (J = 11/2, 13/2, and 15/2) transitions of D...y3+ in Al2O3:Dy3+/Ce3+ is two to three orders of magnitude larger than in Al2O3:Dy3+. The values of CIE chromaticity coordinates for Al2O3:Dy3+/Ce3+ suggest their application for cold white light emission.
Кључне речи:
Dy3+ / Dy3+/Ce3+ / Photoluminescence / Energy transfer / Plasma electrolytic oxidation / Al2O3Извор:
Journal of Luminescence, 2020, 226, 117403-Финансирање / пројекти:
- Графитне и неорганске наноструктуре ниске димензионалности (RS-171035)
- Материјали редуковане димензионалности за ефикасну апсорпцију светлости и конверзију енергије (RS-45020)
DOI: 10.1016/j.jlumin.2020.117403
ISSN: 0022-2313
WoS: 000559072300015
Scopus: 2-s2.0-85085841991
Институција/група
VinčaTY - JOUR AU - Stojadinović, Stevan AU - Ćirić, Aleksandar PY - 2020 UR - https://vinar.vin.bg.ac.rs/handle/123456789/9030 AB - In this paper, Dy3+ and Dy3+/Ce3+ doped Al2O3 coatings were synthesized by plasma electrolytic oxidation process of aluminum. Structural and photoluminescence (PL) properties of obtained coatings as well as energy transfer mechanism from Ce3+ to Dy3+ were studied. The PL excitation and emission spectra of Al2O3:Dy3+ featured weak bands attributed to f-f transitions of Dy3+. The PL emission spectrum of Al2O3:Dy3+ exhibits three emission bands in blue-yellow-red regions, assigned to F-4(9/2)-> H-6(15/2), F-4(9/2)-> H-6(13/2), and F-4(9/2)-> H-6(11/2) transitions of Dy3+, respectively. Under middle UV excitation the Ce3+ in Al2O3 emits broad band, peaked at about 330 nm, attributed to the 5d -> 4f transition of Ce3+. Because of the strong overlap between the PL emission of Ce3+ and the PL excitation of Dy3+ in Al2O3, energy transfer from Ce3+ to the Dy3+ in Al2O3:Dy3+/Ce3+ is observed upon 285 nm excitation. PL emissions due to F-4(9/2)-> H-6(J) (J = 11/2, 13/2, and 15/2) transitions of Dy3+ in Al2O3:Dy3+/Ce3+ is two to three orders of magnitude larger than in Al2O3:Dy3+. The values of CIE chromaticity coordinates for Al2O3:Dy3+/Ce3+ suggest their application for cold white light emission. T2 - Journal of Luminescence T1 - Dy3+ and Dy3+/Ce3+ doped Al2O3 coatings obtained by plasma electrolytic oxidation: Photoluminescence and energy transfer from Ce3+ to Dy3+ VL - 226 SP - 117403 DO - 10.1016/j.jlumin.2020.117403 ER -
@article{ author = "Stojadinović, Stevan and Ćirić, Aleksandar", year = "2020", abstract = "In this paper, Dy3+ and Dy3+/Ce3+ doped Al2O3 coatings were synthesized by plasma electrolytic oxidation process of aluminum. Structural and photoluminescence (PL) properties of obtained coatings as well as energy transfer mechanism from Ce3+ to Dy3+ were studied. The PL excitation and emission spectra of Al2O3:Dy3+ featured weak bands attributed to f-f transitions of Dy3+. The PL emission spectrum of Al2O3:Dy3+ exhibits three emission bands in blue-yellow-red regions, assigned to F-4(9/2)-> H-6(15/2), F-4(9/2)-> H-6(13/2), and F-4(9/2)-> H-6(11/2) transitions of Dy3+, respectively. Under middle UV excitation the Ce3+ in Al2O3 emits broad band, peaked at about 330 nm, attributed to the 5d -> 4f transition of Ce3+. Because of the strong overlap between the PL emission of Ce3+ and the PL excitation of Dy3+ in Al2O3, energy transfer from Ce3+ to the Dy3+ in Al2O3:Dy3+/Ce3+ is observed upon 285 nm excitation. PL emissions due to F-4(9/2)-> H-6(J) (J = 11/2, 13/2, and 15/2) transitions of Dy3+ in Al2O3:Dy3+/Ce3+ is two to three orders of magnitude larger than in Al2O3:Dy3+. The values of CIE chromaticity coordinates for Al2O3:Dy3+/Ce3+ suggest their application for cold white light emission.", journal = "Journal of Luminescence", title = "Dy3+ and Dy3+/Ce3+ doped Al2O3 coatings obtained by plasma electrolytic oxidation: Photoluminescence and energy transfer from Ce3+ to Dy3+", volume = "226", pages = "117403", doi = "10.1016/j.jlumin.2020.117403" }
Stojadinović, S.,& Ćirić, A.. (2020). Dy3+ and Dy3+/Ce3+ doped Al2O3 coatings obtained by plasma electrolytic oxidation: Photoluminescence and energy transfer from Ce3+ to Dy3+. in Journal of Luminescence, 226, 117403. https://doi.org/10.1016/j.jlumin.2020.117403
Stojadinović S, Ćirić A. Dy3+ and Dy3+/Ce3+ doped Al2O3 coatings obtained by plasma electrolytic oxidation: Photoluminescence and energy transfer from Ce3+ to Dy3+. in Journal of Luminescence. 2020;226:117403. doi:10.1016/j.jlumin.2020.117403 .
Stojadinović, Stevan, Ćirić, Aleksandar, "Dy3+ and Dy3+/Ce3+ doped Al2O3 coatings obtained by plasma electrolytic oxidation: Photoluminescence and energy transfer from Ce3+ to Dy3+" in Journal of Luminescence, 226 (2020):117403, https://doi.org/10.1016/j.jlumin.2020.117403 . .