Properties of humic acids from copper tailings 20 years after reclamation
Аутори
Radmanović, Svjetlana B.Marković, Mirjana
Jovanović, Uroš D.
Gajić-Kvaščev, Maja
Čokeša, Đuro
Lilić, Jasmina
Чланак у часопису (Објављена верзија)
Метаподаци
Приказ свих података о документуАпстракт
Part of Cu post flotation tailings of Serbia ZiJin Bor Copper, Serbia, was reclaimed by restoration of top soil with arable soils, and revegetation in 1991. Humic acids isolated from these Technosols were investigated to find out if their properties underwent any changes since reclamation. Two groups of control samples were used. Elemental composition (CHNS analysis) falls within the range of average soil humic acids. Humic acids belong to the type B pointing out to its lower humification degree (UV?Vis). Relative abundances of functional groups are ranged as follows: polysaccharide C ??aromatic C > carboxyl C > OH group > aliphatic C. Aromaticity indexes are low, 1.88? 3.25 (ATR-FTIR). Basic units at pH 10 are in the 11.7?26.8 nm range. Pronounced reaggregation (1462-?5218 nm) at pH 3 points out to less expressed humic acid sol stability, as well as to increase in aromatic condensation degree (dynamic light scattering). No significant changes have occurred in technosol humic acids sin...ce the recultivation, confirming stability of their properties over time (PCA). Nevertheless, humic acids from very strongly acidic Technosols show higher humifycation degree possibly originating from arable soils used in reclamation, but more likely from low soil pH and low litter input, results of unsuccessful reclamation.
Кључне речи:
Technosols / top soil restoration / revegetation / humification degreeИзвор:
Journal of the Serbian Chemical Society, 2020, 85, 3, 407-419Финансирање / пројекти:
- Проучавање утицаја квалитета земљишта и вода за наводњавање на ефикаснију производњу пољопривредних култура и очување животне средине (RS-37006)
- Синтеза, процесирање и карактеризација наноструктурних материјала за примену у области енергије, механичког инжењерства, заштите животне стредине и биомедицине (RS-45012)
DOI: 10.2298/JSC190717112R
ISSN: 0352-5139
WoS: 000522797400011
Scopus: 2-s2.0-85085365742
Институција/група
VinčaTY - JOUR AU - Radmanović, Svjetlana B. AU - Marković, Mirjana AU - Jovanović, Uroš D. AU - Gajić-Kvaščev, Maja AU - Čokeša, Đuro AU - Lilić, Jasmina PY - 2020 UR - https://vinar.vin.bg.ac.rs/handle/123456789/9020 AB - Part of Cu post flotation tailings of Serbia ZiJin Bor Copper, Serbia, was reclaimed by restoration of top soil with arable soils, and revegetation in 1991. Humic acids isolated from these Technosols were investigated to find out if their properties underwent any changes since reclamation. Two groups of control samples were used. Elemental composition (CHNS analysis) falls within the range of average soil humic acids. Humic acids belong to the type B pointing out to its lower humification degree (UV?Vis). Relative abundances of functional groups are ranged as follows: polysaccharide C ??aromatic C > carboxyl C > OH group > aliphatic C. Aromaticity indexes are low, 1.88? 3.25 (ATR-FTIR). Basic units at pH 10 are in the 11.7?26.8 nm range. Pronounced reaggregation (1462-?5218 nm) at pH 3 points out to less expressed humic acid sol stability, as well as to increase in aromatic condensation degree (dynamic light scattering). No significant changes have occurred in technosol humic acids since the recultivation, confirming stability of their properties over time (PCA). Nevertheless, humic acids from very strongly acidic Technosols show higher humifycation degree possibly originating from arable soils used in reclamation, but more likely from low soil pH and low litter input, results of unsuccessful reclamation. T2 - Journal of the Serbian Chemical Society T1 - Properties of humic acids from copper tailings 20 years after reclamation VL - 85 IS - 3 SP - 407 EP - 419 DO - 10.2298/JSC190717112R ER -
@article{ author = "Radmanović, Svjetlana B. and Marković, Mirjana and Jovanović, Uroš D. and Gajić-Kvaščev, Maja and Čokeša, Đuro and Lilić, Jasmina", year = "2020", abstract = "Part of Cu post flotation tailings of Serbia ZiJin Bor Copper, Serbia, was reclaimed by restoration of top soil with arable soils, and revegetation in 1991. Humic acids isolated from these Technosols were investigated to find out if their properties underwent any changes since reclamation. Two groups of control samples were used. Elemental composition (CHNS analysis) falls within the range of average soil humic acids. Humic acids belong to the type B pointing out to its lower humification degree (UV?Vis). Relative abundances of functional groups are ranged as follows: polysaccharide C ??aromatic C > carboxyl C > OH group > aliphatic C. Aromaticity indexes are low, 1.88? 3.25 (ATR-FTIR). Basic units at pH 10 are in the 11.7?26.8 nm range. Pronounced reaggregation (1462-?5218 nm) at pH 3 points out to less expressed humic acid sol stability, as well as to increase in aromatic condensation degree (dynamic light scattering). No significant changes have occurred in technosol humic acids since the recultivation, confirming stability of their properties over time (PCA). Nevertheless, humic acids from very strongly acidic Technosols show higher humifycation degree possibly originating from arable soils used in reclamation, but more likely from low soil pH and low litter input, results of unsuccessful reclamation.", journal = "Journal of the Serbian Chemical Society", title = "Properties of humic acids from copper tailings 20 years after reclamation", volume = "85", number = "3", pages = "407-419", doi = "10.2298/JSC190717112R" }
Radmanović, S. B., Marković, M., Jovanović, U. D., Gajić-Kvaščev, M., Čokeša, Đ.,& Lilić, J.. (2020). Properties of humic acids from copper tailings 20 years after reclamation. in Journal of the Serbian Chemical Society, 85(3), 407-419. https://doi.org/10.2298/JSC190717112R
Radmanović SB, Marković M, Jovanović UD, Gajić-Kvaščev M, Čokeša Đ, Lilić J. Properties of humic acids from copper tailings 20 years after reclamation. in Journal of the Serbian Chemical Society. 2020;85(3):407-419. doi:10.2298/JSC190717112R .
Radmanović, Svjetlana B., Marković, Mirjana, Jovanović, Uroš D., Gajić-Kvaščev, Maja, Čokeša, Đuro, Lilić, Jasmina, "Properties of humic acids from copper tailings 20 years after reclamation" in Journal of the Serbian Chemical Society, 85, no. 3 (2020):407-419, https://doi.org/10.2298/JSC190717112R . .