Kinetic study of oxy-combustion of plane tree (Platanus orientalis) seeds (PTS) in O2/Ar atmosphere
Само за регистроване кориснике
2020
Аутори
Janković, Bojan Ž.Manić, Nebojša G.
Dodevski, Vladimir
Radojević, Miloš
Stojiljković, Dragoslava
Чланак у часопису (Објављена верзија)
,
© 2019, Akadémiai Kiadó, Budapest, Hungary
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The combustion reactivity of plane tree seeds biomass feedstock was studied using the thermogravimetry. The effects of atmosphere (O2/Ar) and different oxygen concentrations (O2/Ar = 20:80% and O2/Ar = 50:50%) on the combustion characteristics were investigated. When combustion atmosphere changes from O2/Ar = 50:50% to O2/Ar = 20:80% (reducing oxygen concentrations), the burnout temperature increases by 29.50 °C for tested biomass. Obtained results demonstrate the ease of ignition of investigated lignocellulosic material for O2/Ar = 50:50% ratio compared with O2/Ar = 20:80% ratio, and the actual trend is maintained under the condition when the heating rate increases. The reducing of oxygen concentration strongly influenced the amount of final residue products, particularly at higher heating rates (beyond 10 °C min−1). Kinetic analysis applied to investigated process shows strongly dependencies of both the apparent activation energy (E) and pre-exponential factor (logA) with conversion ...(α), especially in devolatilization and combustion of volatiles reaction stages. Large variation in E is attributed to existence of multiple parallel reactions. In order to solve this problem, the deconvolution technique that uses Fraser–Suzuki function was applied. It was shown that Fraser–Suzuki function fits successfully kinetic rate curves of entire combustion process, assuming the best selected nth-order reaction model.
Кључне речи:
Oxy-combustion / Plane tree seed biomass / Combustion characteristics determination / Kinetic analysis / Fraser-Suzuki deconvolutionИзвор:
Journal of Thermal Analysis and Calorimetry, 2020, 142, 2, 953-976Финансирање / пројекти:
- Динамика нелинеарних физичкохемијских и биохемијских система са моделирањем и предвиђањем њихових понашања под неравнотежним условима (RS-MESTD-Basic Research (BR or ON)-172015)
- Фотоника микро и нано структурних материјала (RS-MESTD-Integrated and Interdisciplinary Research (IIR or III)-45010)
- Функционални, функционализовани и усавршени нано материјали (RS-MESTD-Integrated and Interdisciplinary Research (IIR or III)-45005)
DOI: 10.1007/s10973-019-09154-z
ISSN: 1388-6150
WoS: 000574704400002
Scopus: 2-s2.0-85077028456
Колекције
Институција/група
VinčaTY - JOUR AU - Janković, Bojan Ž. AU - Manić, Nebojša G. AU - Dodevski, Vladimir AU - Radojević, Miloš AU - Stojiljković, Dragoslava PY - 2020 UR - https://vinar.vin.bg.ac.rs/handle/123456789/8906 AB - The combustion reactivity of plane tree seeds biomass feedstock was studied using the thermogravimetry. The effects of atmosphere (O2/Ar) and different oxygen concentrations (O2/Ar = 20:80% and O2/Ar = 50:50%) on the combustion characteristics were investigated. When combustion atmosphere changes from O2/Ar = 50:50% to O2/Ar = 20:80% (reducing oxygen concentrations), the burnout temperature increases by 29.50 °C for tested biomass. Obtained results demonstrate the ease of ignition of investigated lignocellulosic material for O2/Ar = 50:50% ratio compared with O2/Ar = 20:80% ratio, and the actual trend is maintained under the condition when the heating rate increases. The reducing of oxygen concentration strongly influenced the amount of final residue products, particularly at higher heating rates (beyond 10 °C min−1). Kinetic analysis applied to investigated process shows strongly dependencies of both the apparent activation energy (E) and pre-exponential factor (logA) with conversion (α), especially in devolatilization and combustion of volatiles reaction stages. Large variation in E is attributed to existence of multiple parallel reactions. In order to solve this problem, the deconvolution technique that uses Fraser–Suzuki function was applied. It was shown that Fraser–Suzuki function fits successfully kinetic rate curves of entire combustion process, assuming the best selected nth-order reaction model. T2 - Journal of Thermal Analysis and Calorimetry T1 - Kinetic study of oxy-combustion of plane tree (Platanus orientalis) seeds (PTS) in O2/Ar atmosphere VL - 142 IS - 2 SP - 953 EP - 976 DO - 10.1007/s10973-019-09154-z ER -
@article{ author = "Janković, Bojan Ž. and Manić, Nebojša G. and Dodevski, Vladimir and Radojević, Miloš and Stojiljković, Dragoslava", year = "2020", abstract = "The combustion reactivity of plane tree seeds biomass feedstock was studied using the thermogravimetry. The effects of atmosphere (O2/Ar) and different oxygen concentrations (O2/Ar = 20:80% and O2/Ar = 50:50%) on the combustion characteristics were investigated. When combustion atmosphere changes from O2/Ar = 50:50% to O2/Ar = 20:80% (reducing oxygen concentrations), the burnout temperature increases by 29.50 °C for tested biomass. Obtained results demonstrate the ease of ignition of investigated lignocellulosic material for O2/Ar = 50:50% ratio compared with O2/Ar = 20:80% ratio, and the actual trend is maintained under the condition when the heating rate increases. The reducing of oxygen concentration strongly influenced the amount of final residue products, particularly at higher heating rates (beyond 10 °C min−1). Kinetic analysis applied to investigated process shows strongly dependencies of both the apparent activation energy (E) and pre-exponential factor (logA) with conversion (α), especially in devolatilization and combustion of volatiles reaction stages. Large variation in E is attributed to existence of multiple parallel reactions. In order to solve this problem, the deconvolution technique that uses Fraser–Suzuki function was applied. It was shown that Fraser–Suzuki function fits successfully kinetic rate curves of entire combustion process, assuming the best selected nth-order reaction model.", journal = "Journal of Thermal Analysis and Calorimetry", title = "Kinetic study of oxy-combustion of plane tree (Platanus orientalis) seeds (PTS) in O2/Ar atmosphere", volume = "142", number = "2", pages = "953-976", doi = "10.1007/s10973-019-09154-z" }
Janković, B. Ž., Manić, N. G., Dodevski, V., Radojević, M.,& Stojiljković, D.. (2020). Kinetic study of oxy-combustion of plane tree (Platanus orientalis) seeds (PTS) in O2/Ar atmosphere. in Journal of Thermal Analysis and Calorimetry, 142(2), 953-976. https://doi.org/10.1007/s10973-019-09154-z
Janković BŽ, Manić NG, Dodevski V, Radojević M, Stojiljković D. Kinetic study of oxy-combustion of plane tree (Platanus orientalis) seeds (PTS) in O2/Ar atmosphere. in Journal of Thermal Analysis and Calorimetry. 2020;142(2):953-976. doi:10.1007/s10973-019-09154-z .
Janković, Bojan Ž., Manić, Nebojša G., Dodevski, Vladimir, Radojević, Miloš, Stojiljković, Dragoslava, "Kinetic study of oxy-combustion of plane tree (Platanus orientalis) seeds (PTS) in O2/Ar atmosphere" in Journal of Thermal Analysis and Calorimetry, 142, no. 2 (2020):953-976, https://doi.org/10.1007/s10973-019-09154-z . .